• Journal of the Korean Crystal Growth and Crystal Technology
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• v.24 no.5
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• pp.196-201
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• 2014

We investigated defects and surface polarity in AlN and GaN by using wet chemical etching. Therefore, the effectiveness and reliability of estimating the single crystals by defect selective etching in NaOH/KOH eutectic alloy have been successfully demonstrated. High-quality AlN and GaN single crystals were etched in molten NaOH/KOH eutectic alloy. The etching characteristics and surface morphologies were carried out by scanning electron microscope (SEM) and atomic force microscope (AFM). The etch rates of AlN and GaN surface were calculated by etching depth as a function of etching time. As a result, two-types of etch pits with different sizes were revealed on AlN and GaN surface, respectively. Etching produced hexagonal pits on the metal-face (Al, Ga) (0001) plane, while hexagonal hillocks formed on the N-face. On etching rate calibration, it was found that N-face had approximately 109 and 15 times higher etch rate than the metal-face of AlN and GaN, respectively. The size of etch pits increased with an increase of the etching time and they tend to merge together with a neighbouring etch pits. Also, the chemical mechanism of each etching process was discussed. It was found that hydroxide ion ($OH^-$) and the dangling bond of nitrogen play an important role in the selective etching of the metal-face and N-face.

• Journal of the Korea Concrete Institute
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• v.23 no.4
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• pp.421-430
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• 2011

As a fundamental study to introduce the reliability-based design code, a statistical study is conducted for the material strength data collected from domestic construction sites. In order to develop a rational design code based on statistics and reliability theory, it is essential to obtain the statistical properties of material strength. Material strength data for concrete, reinforcing bars, and prestressing strands which are used in domestic construction sites are collected and statistically analyzed. Then, the statistical properties are compared with those used in the process of the reliability-based calibration of internationally leading design codes. The statistical properties of the domestic data are such that the bias factor is relatively uniform between 1.13 and 1.20 and the coefficient of variation is below 0.10. Reinforcing bar data show difference among different manufacturers but there is not much difference among re-bar diameters. In the case of tendons, which are high strength materials, both of the domestic and foreign data show smaller values of the bias factor and the coefficient of variation than those of concrete and re-bar. Statistical distribution of all the material strength can be properly assumed as normal, log-normal, or Gumbel distribution after analyzing the classified data by individual construction site and manufacturer rather than the mixed data obtained from different sources in order to express the individual distribution of each structure.

• Journal of the Korean Chemical Society
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• v.44 no.3
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• pp.212-219
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• 2000

An absorption spectrometry coupled with flow injection analysis has been developed and tested for the analysis of the Cr$_2O_7^{2-}$/Nn$O_4^-$ mixtures. Even though one has to inject the sample twice into the FIA system and the process of the sample treatment is required to completely destroy the Mn$O_4^-$ ion for the analysis of the Cr$_2O_7^{2-}$ ion, the new method has definite advantages over the current method. It utilizes only a single analytical wavelength (570 nm) and enables one to construct calibration curves which accurately follow the Beer's law over wide ranges of analytical concentrations of both ions ($2.0{\times}10^{-6}$M∼$8.0{\times}10^{-3}$M for Cr$_2O_7^{2-}$ ion, $2.0{\times}10^{-6}$M∼$4.0{\times}10^{-3}$M for MnO4- ion).

• Journal of Korea Water Resources Association
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• v.40 no.8
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• pp.617-628
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• 2007

The purpose of this paper is to prepare snowmelt parameters using RS and GIS and to assess the snowmelt impact in SLURP (Semi-distributed Land Use-based Runoff Process) model for Chungju-Dam watershed $(6,661.5km^2)$. Three sets of NOAA AVHRR images (1998-1999, 2000-2001, 2001-2002) were analyzed to prepare snow-related data of the model during winter period. Snow cover areas were extracted using 1, 3 and 4 channels, and the snow depth was spatially interpolated using snowfall data of ground meteorological stations. With the snowmelt parameters, DEM (Digital Elevation Model), land cover, NDVI (Normalized Difference Vegetation Index) and weather data, the model was calibrated for 3 years (1998, 2000, 2001), and verified for 1 year (1999) using the calibrated parameters. The average Nash-Sutcliffe efficiencies for 4 years (1998-2001) discharge comparison with and without snowmelt parameters were 0.76 and 0.73 for the full period, and 0.57 and 0.19 for the period of January to May. The results showed that the spatially prepared snow-related data reduced the calibration effort and enhanced the model results.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1265-1265
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• 2001

The organic materials included in excreta of livestock are important resources for organic manure and for improving soil quality, although there is still far from effective using. One reason for this is still unclearly standard of quality for evaluation of manure made from excreta of livestock. Therefore, the objective of this study is to develop rapid and accurate analytical method for analyzing organic compositions of manure made from excreta of livestock, and to establish quality evaluation method based on the compositions predicted by near infrared reflectance spectroscopy (NIRS). Sixteen samples of manure, each eight samples prepared from two treatments, were used in this study. The manure samples were prepared by mixing 560 kg feces of swine,60 kg sawdust with moisture content was adjusted to be 65%. The mixture was then keep under two kinds of shelter, black and clear sheets, as a treatment on the effect of sunlight. Samples were taken in every week (form week-0 to 7) during the process of manure making. Samples were analyzed to determine neutral detergent fiber (NDF), acid detergent fiber (ADF) and acid detergent lignin (ADL) by detergent methods, and organic cell wall (OCW) and fibrous content of low digestibility in OCW (Ob) by enzymatic methods. Biological oxygen demand (BOD) was analyzed by coulometric respirometer method. These compositions were carbohydrateds and lignin that were hardly digested. Spectra of samples were scanned by NIR instrument model 6500 (Pacific Scientific) and read over the range of wavelength between 400 and 2500nm. Calibration equations were developed using eight manure samples collected from black sheet shelter, while prediction was conducted to the other eight samples from clear sheet shelter. Accuracy of NTRS prediction was evaluated by correlation coefficients (r), standard error of prediction (SEP) and ration of standard deviation of reference data in prediction sample set to SEP (RPD). The r, SEP and RPD value of forage were 0.99, 0.69 and 7.6 for ADL, 0.96, 1.03 and 4.1 for NDF, 0.98, 0.60 and 4.9 for ADF, 0.92, 1.24 and 2.6 for Ob, and 0.91, 1.02 and 7.3 for BOD, respectively. The results indicated that NIRS could be used to measure the organic composition of forage used in manure samples.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1612-1612
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• 2001

The production of grain for export and domestic use is one of Australia's most important agricultural industries, and the NIR technique has been used extensively over many years for the routine monitoring of grain quality, particularly moisture and protein content. Because most Australian grain is intended for human food production, the determinants of grain quality for livestock feed, apart from protein, have been largely ignored. However the increasing use of grain for feeding to pigs, poultry, beef cattle and dairy cows has led to an important national research project entitled “Premium Grains for Livestock”. Two of the objectives of this project are to determine the compositional and functional characteristics of grains which influence their nutritional quality for the various classes of livestock, and to adopt rapid and objective analytical tests for these quality criteria. NIR has been used in this project firstly to identify a set of grain samples from a large population of breeders' lines which showed a wide spectral variation, and hence a potentially wide variation in nutritional value. The selected samples were not only subjected to an extensive array of chemical, physical and in vitro analyses, but also were grown out to produce sufficient quantities of grain to feed to animals in vivo studies. Additional grains were also strategically selected from farms in order to include the effect of weather damage, such as rain, drought and frost. In this study to date, NIR calibrations have been derived or attempted, on both ground and whole grains, for in vivo dry matter digestibility (DMD), pepsin-cellulase dry matter disappearance, protein, fat, acid detergent fibre, neutral detergent fibre, starch, in sacco DMD and in vitro assays to simulate starch digestion in the lumen and small intestine. Results so far indicate high calibration accuracy for chemical components (SECV 0.3 to 2.6%) and very promising statistics for in vivo DMD (SECV 1.8, $R^2$ 0.93, SD 7.0, range 61.9 to 92.3, n=60). There appears to be some potential for NIR to estimate some in vitro properties, depending upon the accuracy of reference methods and appropriate sample populations. Current work is in progress to extend the range of grains with in vivo DMD values (a very laborious and expensive process) and to increase the robustness of the various NIR calibrations, with the aim of implementing uniform testing procedures for nutritional value of grains throughout Australia.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1523-1523
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• 2001

The wine industry requires practical methods for objectively measuring the composition of both red wine grapes on the vine to determine optimal harvest time; and of freshly harvested grapes for efficient allocation to vinery process streams for particular red wine products, and to determine payment of contract grapegrowers. To be practical for industry application these methods must be rapid, inexpensive and accurate. In most cases this restricts the analyses available to measurement of TSS (total soluble solids, predominantly sugars) by refractometry and pH by electropotentiometry. These two parameters, however, do not provide a comprehensive compositional characterization for the purpose of winemaking. The concentration of anthocyanin pigment in red wine grapes is an accepted indicator of potential wine quality and price. However, routine analysis for total anthocyanins is not considered as a practical option by the wider wine industry because of the high cost and slow turnaround time of this multi-step wet chemical laboratory analysis. Recent work by this ${group}^{l,2}$ has established the capability of near infrared (NIR) spectroscopy to provide rapid, accurate and simultaneous measurement of total anthocyanins, TSS and pH in red wine grapes. The analyses may be carried out equally well using either research grade scanning spectrometers or much simpler reduced spectral range portable diode-array based instrumentation. We have recently expanded on this work by collecting thousands of red wine grape samples in Australia. The sample set spans two vintages (1999 and 2000), five distinct geographical winegrowing regions and three main red wine grape varieties used in Australia (Cabernet Sauvignon, Shiraz and Merlot). Homogenized grape samples were scanned in diffuse reflectance mode on a FOSE NIR Systems6500 spectrometer and subject to laboratory analysis by the traditional methods for total anthocyanins, TSS and pH. We report here an analysis of the correlations between the NIR spectra and the laboratory data using standard chemometric algorithms within The Unscrambler software package. In particular, various subsets of the total data set are considered in turn to elucidate the effects of vintage, geographical area and grape variety on the measurement of grape composition by NIR spectroscopy. The relative ability of discrete calibrations to predict within and across these differences is considered. The results are then used to propose an optimal calibration strategy for red wine grape analysis.

• Spatial Information Research
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• v.18 no.3
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• pp.1-11
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• 2010

Recently, the construction of three dimensional spatial information of Dam reservoir area is very important part in Dam management work such as sediment survey, but it is difficult to acquire detailed terrain data because totalstation and single beam echo sounder are applied to terrain survey. This study presented method to construct detailed terrain data of Dam reservoir area using LiDAR and multi beam echo sounder. First, LiDAR survey was carried out in land zone and calibration process was applied by ground control point. And also the DEM of land zone was constructed by using algorithm, which eliminated building and vegetation class. As the result of validation of LiDAR DEM using GPS terrain survey, it was possible to construct three dimensional terrain data that was satisfied with the tolerance error of LiDAR, which was the standard error of LiDAR DEM showed as 0.108m. Also multi beam echo sounder was applied to the survey of water zone and it could construct spatial information that was satisfied with bathymetry surveying tolerance error of International Hydrographic Organization by validation with terrain survey data. And LiDAR and multi beam echo sounder data were integrated and it was possible to construct three dimensional spatial imagery information that can be applied to Dam management work such as the estimation of sediment amounts or the monitoring of terrain change by linking with high resolution orthophoto.

• International Journal of Highway Engineering
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• v.18 no.3
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• pp.47-57
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• 2016

PURPOSES : This study aims to examine the differences between the existing traffic demand forecasting method and the traffic demand forecasting method considering future regional development plans and new road construction and expansion plans using a four-step traffic demand forecast for a more objective and sophisticated national highway maintenance. This study ultimately aims to present future pavement deterioration and budget forecasting planning based on the examination. METHODS : This study used the latest data offered by the Korea Transport Data Base (KTDB) as the basic data for demand forecast. The analysis scope was set using the Daejeon Metropolitan City's O/D and network data. This study used a traffic demand program called TransCad, and performed a traffic assignment by vehicle type through the application of a user equilibrium-based multi-class assignment technique. This study forecasted future traffic demand by verifying whether or not a realistic traffic pattern was expressed similarly by undertaking a calibration process. This study performed a life cycle cost analysis based on traffic using the forecasted future demand or existing past pattern, or by assuming the constant traffic demand. The maintenance criteria were decided according to equivalent single axle loads (ESAL). The maintenance period in the concerned section was calculated in this study. This study also computed the maintenance costs using a construction method by applying the maintenance criteria considering the ESAL. The road user costs were calculated by using the user cost calculation logic applied to the Korean Pavement Management System, which is the existing study outcome. RESULTS : This study ascertained that the increase and decrease of traffic occurred in the concerned section according to the future development plans. Furthermore, there were differences from demand forecasting that did not consider the development plans. Realistic and accurate demand forecasting supported an optimized decision making that efficiently assigns maintenance costs, and can be used as very important basic information for maintenance decision making. CONCLUSIONS : Therefore, decision making for a more efficient and sophisticated road management than the method assuming future traffic can be expected to be the same as the existing pattern or steady traffic demand. The reflection of a reliable forecasting of the future traffic demand to life cycle cost analysis (LCCA) can be a very vital factor because many studies are generally performed without considering the future traffic demand or with an analysis through setting a scenario upon LCCA within a pavement management system.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.36 no.1
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• pp.143-149
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• 2016

This study evaluated the shear behavior of geogrid reinforced ballast material using a large scale direct shear test and discrete element method (DEM) based on PFC 3D program. The direct shear test was conducted on ballast materials that have different particle size distributions. Whereas the test results revealed that the shear strength generally increased with the larger particle size of ballast material without geogrid reinforcement, the shear behavior of ballast material was found to change pertaining to the relationship between particle size distribution and geogrid rib size. Generally, it is deemed the effectiveness of reinforcement can be achieved when the rib size is two times greater than average particle size. A numerical analysis based on DEM was conducted to verify the test results. The geogrid modeling was successfully completed by calibration process along with sensitivity analysis to have actual tensile strength provided by manufacturer. With a given geogrid model, the parametric evaluation was further carried out to examine the interactive behavior between geogrid and ballast material. Consequently, it was found that the effectiveness zone of geogrid reinforcement generated within a specific depth.