• Korean Journal of Optics and Photonics
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• v.17 no.5
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• pp.391-395
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• 2006

In this paper, radiometric calibration of a FTIR spectrometer for passive remote sensing application was introduced and verified. Radiometric calibration is a significant signal processing procedure to retrieve the object radiance from the measured spectrum. The object radiance is measured and registered distorted by the detector's responsivity dependent on wavelength and instrument self-emission. Radiance of two temperature points, hot temperature and cold temperature, from a well-controlled blackbody was measured and used to obtain the scale factor and offset factor which are required for radiometric calibration. For gas phase C2H5OH. radiometric calibration was done and verified through comparison of its emission line width and intensity with the standard spectrum.

• Journal of the Korean Chemical Society
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• v.47 no.1
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• pp.19-25
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• 2003

A spectrophotometric method for the simultaneous determination of anionic and nonionic surfactant based on the application of multivariate calibration method such as principal component regression(PCR) and partial least squares(PLS) has been studied. The calibration models in PCR and PLS were obtained from the spectral data in the range of 400~700 nm for each standard of a calibration set of 26 standards, each containing different amounts of two surfactants. The relative standard error of prediction(RSEP$_{\alpha}$) was obtained to assess the model goodness in quantifying each analyte in a 5 validation samples which containing different amounts of two surfactants.

• Proceedings of the KSME Conference
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• 2007.05a
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• pp.891-896
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• 2007

This paper contained the flight test calibration for the airspeed indicator and the altimeter of the light airplane ChangGong-91, which is the first type certified aircraft from Korean Ministry of Construction and Transportation, as a part of the flight test validation. The flight test for airspeed position error calibration was performed using tower fly by method in order to calibrate swivel head testboom which is attached to the right wing tip of the airplane, and using system to system method for airspeed indicator. The altimeter calibration was calculated using flight test data for airspeed calibration. The flight test was conducted at the basis of the 'Korean Airworthiness Standard' regulation of Korean Ministry of Construction and Transportation.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.10a
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• pp.656-659
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• 2004

As the demand for traceable calibrations of torque measuring devices has considerably increased both in the production sector and in research institutes, suitable standard machines had to be developed at the Korea Research Institute of Standards and Science. Owing to its special design, the small uncertainty of measurement required for the realization of the static torque can be reached (relative uncertainty of measurement ＆lt; 5$\times$10$^{-5}$ in the measurement range between 500 and 2000 Nm, and ＆lt; 1$\times$10$^{-4}$ in the measurement range from 10 to 500 Nm). The relative discrepancy between our torque calibration results of 2 kNm and PTB s (Physikalisch Technische Bundesanstalt, Germany) results was less than 2$\times$10$^{-5}$ , which confirming our uncertainty estimation.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.56 no.7
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• pp.1268-1274
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• 2007

A recently developed methods for the on-site calibration of the voltage transformer (VT) comparator system have been reviewed in the paper. The method utilizes the several traveling standards consisting of the VT, the non-reactive standard resistors, the wide ratio error VT, and the decade resistors. The VT is used for the absolute evaluation of a standard VT belonging to the industry. The non-reactive standard resistor and wide ratio error VT are used for the linearity check of errors in the voltage comparator of the industry. The decade resistors are used for evaluation of a VT burden of the industry.

• YAKHAK HOEJI
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• v.47 no.5
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• pp.261-265
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• 2003

Near-infrared (NIR) system was used to determine rapidly and simply indomethacin in buffer solution for a dissolution test of tablets and capsules. Indomethacin standards were prepared ranging from 10 to 50 ppm using the mixture of phosphate buffer (pH 7.2) and water (1 : 4). The near-infrared (NIR) transmittance spectra of indomethacin standard solutions were collected by using a quartz cell in 1 mm and 2 mm pathlength. Partial least square regression (PLSR) was explored to develop calibration models over the spectral range 1100∼1700 nm. The model using 1 mm quartz cell was better than that using 2 mm quartz cell. The PLSR models developed gave standard error of prediction (SEP) of 0.858 ppm. In order to validate the developed calibration model, routine analysis was performed using another standard solutions. The NIR routine analysis showed good correlation with actual values. Standard error of prediction (SEP) is 1.414 ppm for 7 indomethacin samples in routine analysis and its error was permeable in the regulation of Korean Pharmacopoeia (VII). These results show the potential use of the real time monitoring for indomethacin during a dissolution test.

• Analytical Science and Technology
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• v.19 no.6
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• pp.553-558
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• 2006

In this study, an attempt was made to measure uncertainties involved in the VOC analysis for the VOC working standards prepared by a dilution technique using Tedlar bags. For this purpose, VOC standard gases of benzene, toluene, xylene, and styrene were prepared at four different concentrations (4, 8, 20, and 40 ppb). These standard samples were then loaded on to the GC system equipped with air server/thermal desorption (AS/TD) system. Each of these four standard concentrations was analyzed individually to derive their respective calibration results. These calibration data sets were then compared across four different compounds. According to this comparison, differences in calibration patterns were moderately insignificant within the selected concentration range of 4~40 ppb. It was also observed that the loss of styrene standard was fairly high compared to other VOCs investigated simultaneously. The results of our study suggest that the analytical uncertainty associated with the preparation of VOC starndard gas using a dilution technique can be assessed in a fairly reasonable manner for samples with a narrow concentration range.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.20 no.9
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• pp.1808-1815
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• 2016

Stable operation of the dam and the river is directly related to the life and property of citizens, and hydrological observation data reliability is essential to the safety against disaster. Even though real-time data acquisition with high accuracy is needed for scientific and reliable water resources management, currently operating water gauges installed on the upper and down stream of dams or rivers are not easy to be calibrated or corrected on site to ensure higher reliability. K-water Institute has been operating an international accredited calibration laboratory for flows meters, rainfall and water gauges. Rainfall gauges are calibrated in the fixed standard room or on-site. However, due to the absence of on-site calibration procedure and system, on-site calibration for the water gauges are performed by an external agency. Therefore, a development of standard calibration procedure and system for on-site calibration of water gauges is needed to improve the reliability of observed hydrological data.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1242-1242
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• 2001

The use of fibre optic probes for NIR quality control in the industry is becoming very important, as it provides a powerful tool to reduce sample analysis time and it facilitates the implementation of on-line analyses. However, most of the applications of fibre optics and probes have been done on suspensions, clear liquids and films, chemical and pharmaceutical products and also on fruits and animal products. Traditional applications of near infrared spectroscopy in agriculture have been developed in reflectance mode and calibration transfer could be an interesting way to reduce efforts. Classical methods for calibration transfer between different instruments involve the use of sealed reference cups, but, as fibre optic analysis does not use cups, it is necessary to develop new methods for calibration transfer without standards (Blank et al., 1996). In this paper, we have studied how the most used mathematical pretreatments (three methods of Multiplicative Scatter Correction, Standard Normal Variate, Detrending and derivatives) and their combinations applied to calibration development can contribute to reduce spectral differences between instruments. Calibration equations were obtained for three sets of cereals (barley, wheat and maize) scanned in reflectance mode and then they were validated with samples analysed in reflectance and interactance-reflectance mode (fibre optic). Preliminary results show how some combination of pretreatments reduce the differences in the predicted values, measured as standard error of differences, facilitating the use of calibrations obtained in reflectance for samples analysed by interactance-reflectance. However, the application of pretreatments is not enough to satisfy the control limits for calibration transfer suggested by Shenk et al. (1992), and it should be necessary to combine them with a specific algorithm for instruments standardization.

• Animal Bioscience
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• v.37 no.7
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• pp.1196-1203
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• 2024

Objective: A study was conducted to quantify the performance differences of the near-infrared spectroscopy (NIRS) calibration models developed with different degrees of hay sample preparations. Methods: A total of 227 imported alfalfa (Medicago sativa L.) and another 360 imported timothy (Phleum pratense L.) hay samples were used to develop calibration models for nutrient value parameters such as moisture, neutral detergent fiber, acid detergent fiber, crude protein, and in vitro dry matter digestibility. Spectral data of hay samples prepared by milling into 1-mm particle size or unground were separately regressed against the wet chemistry results of the abovementioned parameters. Results: The performance of the developed NIRS calibration models was evaluated based on R², standard error, and ratio percentage deviation (RPD). The models developed with ground hay were more robust and accurate than those with unground hay based on calibration model performance indexes such as R² (coefficient of determination), standard error, and RPD. Although the R² of calibration models was mainly greater than 0.90 across the feed value indexes, the R² of cross-validations was much lower. The R² of cross-validation varies depending on feed value indexes, which ranged from 0.61 to 0.81 in alfalfa, and from 0.62 to 0.95 in timothy. Estimation of feed values in imported hay can be achievable by the calibrated NIRS. However, the NIRS calibration models must be improved by including a broader range of imported hay samples in the modeling. Conclusion: Although the analysis accuracy of NIRS was substantially higher when calibration models were developed with ground samples, less sample preparation will be more advantageous for achieving rapid delivery of hay sample analysis results. Therefore, further research warrants investigating the level of sample preparations compromising analysis accuracy by NIRS.