• 제목/요약/키워드: Calibration Factor

검색결과 435건 처리시간 0.028초

Trace Mercury Determination by Differential Pulse Anodic Stripping Voltammetry Using Polythiophene-Quinoline/Glassy Carbon Modified Electrode

  • Yoo, Kwang-Sik;Woo, Sang-Beom;Jyoung, Jy-Young
    • Bulletin of the Korean Chemical Society
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    • 제24권1호
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    • pp.27-31
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    • 2003
  • A Polythiophene-quinoline/glassy carbon (PTQ/GC) modified electrode was developed for the determination of trace mercury in industrial waste water, natural water, soil, and other media. The electrode was prepared by the cyclic voltammetric polymerization of thiophene and quinoline on glassy carbon (GC) electrode by the potential application from -0.6 V to +2.0 V (50 mV/sec) in a solution of 0.1 M thiophene, quinoline and tetrabutyl ammonium perchlorate (TBAP) in acetonitrile. Optimum thickness of the polymer membrane on the GC electrode was obtained with 20 repeated potential cyclings. The redox behavior of Cu(Ⅱ) and Hg(Ⅱ) were almost identical on this electrode. The addition of 4-(2-pyridylazo)resorcinol (PAR) to the solution containing Cu(Ⅱ) and Hg(Ⅱ) allowed the separation of the components due to the formation of the Cu(Ⅱ)-PAR complex reduced at -0.8V, which was different from the Hg(Ⅱ) reduced at -0.5 V on a saturated calomel electrode (SCE). The calibration graph of Hg(Ⅱ) shows good linear relationship with the correlation factor of 0.9995 and the concentration gradient of 0.33 ㎂/㎠/ppb down to 0.4 ppb Hg. The method developed was successfully applied to the determination of mercury in samples such as river, waste water, and sea water.

충돌제트를 갖는 회전원판 위 3차원 경계층의 난류특성 (I) - 평균유동장 - (Turbulence Characteristics of a Three-Dimensional Boundary Layer on a Rotating Disk with an Impinging Jet (I) - Mean Flow -)

  • 강형석;유정열;최해천
    • 대한기계학회논문집B
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    • 제22권9호
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    • pp.1277-1289
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    • 1998
  • The objective of the present study is to investigate experimentally the mean flow characteristics of the three-dimensional turbulent boundary layer over a rotating disk with an impinging jet at the center of the disk, which may be regarded as one of the simplest models for the flow in turbomachinery. A relatively strong radial outflow (crossflow) generated from the impinging jet is added to the radial outflow (crossflow) induced by the centrifugal force in order to create the three-dimensional boundary layer. A new calibration technique has been introduced to determine the velocity direction and magnitude using an I-wire probe, where the uncertainties are ${\pm}1.5^{\circ}$ and ${\pm}0.35\;m/s$, respectively, in the laminar boundary layer region, compared with the known exact solutions. The flow in the tangential direction is of similar type to that associated with a favorable pressure gradient, considering that no wake region appears in wall coordinate velocity profiles and the Clauser shape factor is between 4.0 and 5.3. The flow angle is significantly changed by the crossflow generated by the impinging jet.

봉다발 부수로의 단상 국부열전달 계수 측정기법에 관한 연구 (Measurement Technique for Single Phase Local Heat Transfer Coefficients of Subchannels in a Rod Bundle using a Copper Sensor)

  • 서정식;최영돈;배경근;안정수
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2007년도 동계학술발표대회 논문집
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    • pp.191-196
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    • 2007
  • This paper presents the measuring technique for local heat transfer coefficients using a copper sensor in a rod bundle with mixing vanes. A copper sensor consists of a cartridge heater and four pieces of thermocouple. The Heater is located at the center of the copper sensor and thermocouples measure the surface temperature of the copper sensor. Unheated copper sensor and heated copper sensor are able to measure the local heat transfer coefficient at the position where the heated copper sensor is installed. However the entire region of a rod bundle is actually not heated, the decay of local heat transfer coefficients measured represents overestimated value rather than an actual value. The calibration curve for local heat transfer coefficients is presented using the correction factor calculated by CFD.

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다중화 Fabry-Perot 간섭형 광섬유 센서 시스템 (Multiplexed fabry-perot interferometric sensor system)

  • 나도성;예윤해;이동영;박광순
    • 한국광학회지
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    • 제10권4호
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    • pp.273-278
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    • 1999
  • 광섬유 Fabry-Perot 간섭계를 센서로 하는 TDM 다중화 광섬유 압력/온도 센서시스템을 개발하고, 이 시스템을 이용하여 수위와 온도 측정실험을 행하였다. 측정시스템의 측정속도는 측정데이타를 저장하지 않는 경우 최대 초당 4500회이며, 센서의 응답속도는 ~1 ms로 추정된다. 압력센서와 온도센서의 특성은 이론적 추정치와 비교하여 각각 +13.7%,-18%의 차이를 보였으며, 반복실험을 통하여 선형화한 후의 선형화 오차는 1%이내, 온도의 변화가 $<0.1>^{\circ}C$이내 일 때 수위측정의 오차는 $\pm$0.3cm이며, 수위측정에 대한 시스템 잡음은 측정하지 않았다. 온도센서의 시스템 잡음은 0.1$^{\circ}C$이내였으며, 이 시스템을 이용하여 수위 및 온도 변화량에 대한 고속 측정실험을 수행할 결과 예상된 결과를 얻을 수 있었다.

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Parameter Identification of 3R-C Equivalent Circuit Model Based on Full Life Cycle Database

  • Che, Yanbo;Jia, Jingjing;Yang, Yuexin;Wang, Shaohui;He, Wei
    • Journal of Electrical Engineering and Technology
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    • 제13권4호
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    • pp.1759-1768
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    • 2018
  • The energy density, power density and ohm resistance of battery change significantly as results of battery aging, which lead to decrease in the accuracy of the equivalent model. A parameter identification method of the equivale6nt circuit model with 3 R-C branches based on the test database of battery life cycle is proposed in this paper. This database is built on the basis of experiments such as updating of available capacity, charging and discharging tests at different rates and relaxation characteristics tests. It can realize regular update and calibration of key parameters like SOH, so as to ensure the reliability of parameters identified. Taking SOH, SOC and T as independent variables, lookup table method is adopted to set initial value for the parameter matrix. Meanwhile, in order to ensure the validity of the model, the least square method based on variable forgetting factor is adopted for optimizing to complete the identification of equivalent model parameters. By comparing the simulation data with measured data for charging and discharging experiments of Li-ion battery, the effectiveness of the full life cycle database and the model are verified.

The Ka-band Low Noise and Stable Receiver Design of Digital Correlation Radiometer for High Spatial Resolution

  • Choi, Jun-Ho;Kim, Sung-Hyun;Kang, Gum-Sil;Park, Hyuk;Choi, Seh-Wan;Jiang, Jing-Shan;Kim, Yong-Hoon
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2002년도 Proceedings of International Symposium on Remote Sensing
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    • pp.297-302
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    • 2002
  • The subsystems of two channel correlation radiometer such as RF front-end, IF and LF unit, LO unit, software based I/Q demodulator and complex correlator are characterized and their performance is analyzed in this paper. The limited hardware calibration method and receiver design consideration are discussed. The receiver architecture of 37GHz correlation radiometer is integrated. The designed radiometer employs a single-sideband superheterodyne receiver. The center frequency of the radiometer is 37 GHz and IF center frequency is 1.95 GHz with the equivalent noise bandwidth of 79.6 MHz. The receiver has less than 4.2 dB noise figure which is calculated by the Y-factor method and its gain can be adjusted from 60 dB to 80 dB.

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Influence of steel fiber and reinforcing details on the ultimate bearing strength of the post-tensioning anchorage zone

  • Kim, Jin-Kook;Yang, Jun-Mo;Kwon, Yangsu
    • Structural Engineering and Mechanics
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    • 제59권5호
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    • pp.867-883
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    • 2016
  • In this paper, the effects of steel-fiber and rebar reinforcements on the ultimate bearing strength of the local anchorage zone were investigated based on experiments and comparisons between test results and design-equation predictions (AASHTO 2012, NCHRP 1994). Eighteen specimens were fabricated using the same anchorage device, which is one of the conventional anchorage devices, and two transverse ribs were used to secure an additional bearing area for a compact anchorage-zone design. Eight of the specimens were reinforced with only steel fiber and are of two concrete strengths, while six were reinforced with only rebars for two concrete strengths. The other four specimens were reinforced with both rebars and steel fiber for one concrete strength. The test and the comparisons between the design-equation predictions and the test results showed that the ultimate bearing strength and the section efficiency are highly affected by the reinforcement details and the concrete strength; moreover, the NCHRP equation can be conservatively applied to various local anchorage zones for the prediction of the ultimate bearing strength, whereby conditions such as the consideration of the rib area and the calibration factor are changed.

Simulation and Model Validation of a Parabolic Trough Solar Collector for Water Heating

  • Euh, Seung-Hee;Kim, Dae Hyun
    • 한국태양에너지학회 논문집
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    • 제33권3호
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    • pp.17-26
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    • 2013
  • The aim of this study is to analyze the performance of a parabolic trough solar collector (PTC) for water heating and to validate the model performance. The simulated model was compared, calibrated and verified with the experimental results. RMSE (Root mean square error) was used to calibrate the convective heat transfer coefficient between the absorber pipe and the ambient air which was the main factor affecting the heat transfer associated with the PTC. The calibrated model was better fitted with the experimental model. The maximum, minimum and mean deviation between the measured and predicted water temperatures differed only $0.81^{\circ}C$, $0.09^{\circ}C$ and $0.31^{\circ}C$ respectively in the calibrated model. RMSE values were decreased from 0.5389 to 0.4910, 0.0134 to 0.0125 and R-squared was increased from 0.9955 to 0.9956 after calibration. The temperature of water was increased from $33.7^{\circ}C$ to $48^{\circ}C$ in 12hour test. The thermal efficiency of the collector was calculated to be 55%. The calibrated model showed good agreement with the experimental data for model validation.

CONSTRUCTION OF AN ENVIRONMENTAL RADON MONITORING SYSTEM USING CR-39 NUCLEAR TRACK DETECTORS

  • AHN GIL HOON;LEE JAI-KI
    • Nuclear Engineering and Technology
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    • 제37권4호
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    • pp.395-400
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    • 2005
  • An environmental radon monitoring system, comprising a radon-cup, an etching system, and a track counting system, was constructed. The radon cup is a cylindrical chamber with a radius of 2.2 cm and a height of 3.2 cm in combination with a CR-39 detector. Carbon is impregnated in the bodies of the detector chamber to avoid problem of an electrostatic charge. The optimized etching condition for the CR-39 exposed to a radon environment turned out to be a 6 N NaOH solution at 70^{\circ}$ over a 7hour period. The bulk etch rate under the optimized condition was $1.14{\pm}0.03\;{\mu}m\;h^{-1}$. The diameter of the tracks caused by radon and its progeny were found to be in the range of $10\~25\;{\mu}m$ under the optimized condition. The track images were observed with a track counting system, which consisted of an optical microscope, a color charged couple device (CCD) camera, and an image processor. The calibration factor of this system is obtained to be $0.105{\pm}0.006$ tracks $cm^2$ per Bq $m^{-3}$ d.

한국형 토양유실공식에 의한 토양유실량 현장예측 (Application of KORSLE to Estimate Soil Erosion at Field Scale)

  • 송재민;양재의;임경재;박윤식
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제24권5호
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    • pp.31-41
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    • 2019
  • In 2013, the Ministry of Environment in South Korea promulgated a new regulatory bulletin that contained revised enforcement ordinance on soil management protocols. The bulletin recommends the use of Universal Soil Loss Equation (USLE) for the soil erosion estimation, but USLE has limited applicability in prediction of soil erosion because it does not allow direct estimation of actual mass of soil erosion. Therefore, there is a great need of revising the protocol to allow direct comparison between the measured and estimated values of soil erosion. The Korean Soil Loss Equation (KORSLE) was developed recently and used to estimate soil loss in two fields as an alternative to existing USLE model. KORSLE was applied to estimate monthly rainfall erosivity indices as well as temporal variation in potential soil loss. The estimated potential soil loss by KORSLE was adjusted with correction factor for direct comparison with measured soil erosion. The result was reasonable since Nash-Stucliff efficiency were 0.8020 in calibration and 0.5089 in validation. The results suggest that KORSLE is an appropriate model as an alternative to USLE to predict soil erosion at field scale.