• Analytical Science and Technology
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• v.5 no.4
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• pp.401-408
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• 1992

The ion-selectrodes based on calcium ferrite were prepared by mixing calcium oxide with ferric oxide on molar ratio of 0.6:1.4, 0.8:1.2, 1.0:1.0, respectively. The specimens were sintered at $1400^{\circ}C$ for 2hrs in $O_2$ and for 20min in $H_2$ atmosphere. The selectrode sintered in hydrogen atmosphere showed better responded potential and wider range of responded concentration than selectrode sintered in oxygen atmosphere. The ion-selectrodes base on calcium ferrite(0.6:1.4 molar ratio.) showed the highest potential to bivalent cations such as $Ca^{2+}$, $Ba^{2+}$, $Mg^{2+}$, $Zn^{2+}$ and halogen anions such as $I^-$, $Br^-$ in the range of $10^{-1}{\sim}10^{-7}M$. It showed good agreement with theoretical nernstian values.

• Resources Recycling
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• v.23 no.5
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• pp.12-20
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• 2014

Calcium ferrite is a major bonding material self-fluxed sintered ore, and it is used as a flux in the steelmaking process. Calcium ferrite is more effective binder for making sintered ore and flux for steel making because of it's low melting temperature. In this Study, calcium ferrite was made by using variety industrial by-products from steel plant. The property of calcium ferrites was investigated on the basis of test method using in the cement manufacturing process. Crystal analysis, compression test as well as thermal analysis were carried out to evaluate physical properties of calcium ferrite.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.10 no.3
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• pp.264-270
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• 2000

Quantitative analysis of iron ore sinter consisting of hematite, magnetite, calcium ferrite and slag was investigated by X-ray internal standard method. After selecting NaF and $SiO_2$as internal standard materials, the calibration curves were determined and were applied to quantitative analysis of the internal standard method. Calcium ferrite was identified as a solid solution of CaO.$2Fe_2$$O_3$with 7 wt% and 3 wt% solubility of $AI_2$$O_3$and $SiO_2$, respectively. The maximum deviation of quantitative analysis of synthetic iron ore was about $\pm$5 wt%. The contents of each mineral calculated in industrial sinter were 27~40 wt% of hematite, 20~30 wt% of magnetite, 22~33 wt% of calcium ferrite and 10~20 wt% of slag.

• Resources Recycling
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• v.23 no.5
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• pp.3-11
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• 2014

Calcium ferrite is more effective binder for making sintered ore and flux for steel making because of it's low melting temperature. In this Study, calcium ferrite was made by calcinating method in the cement manufacturing process in order to reduce manufacturing costs and increase productivity. Limestone and calcination sludge were used as CaO source, steelmaking sludge, blast furnace dust and iron ore were used as Fe-bearing raw materials. The sintering temperature of specimens is in the range of $950{\sim}1170^{\circ}C$. For Calcium ferrite can be used 'binder for making sintered ore' or 'flux for converter/electric furnace' with a low melting point properties, the raw material characteristics and sintering properties were investigated.

• Resources Recycling
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• v.3 no.3
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• pp.12-20
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• 1994

Difficulties lies on using the dust from iron making process as a raw material for sintering process mainly because of high amount of Zn or alkali content and its ultra fine characteristics. To eliminate these toxic influence, new fluxing materials were tested and could get a very successful results. This fluxing materials, Calcium-ferrite of magnesio-ferrite were made from various waste materials such as lime stone sludge, bag filter dust, waste EP dust and dolomite sludge by simple way of pre-sintering. Sintering behavior as a fluxing materials was revealed to be good in any aspects and new concept of total recycling system could be established.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1996.11a
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• pp.125-127
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• 1996

This paper deals with the fabrication of 4 poles anisotropic Sr·ferrite plastic magnets. After Polyamide6 and polyamlde12 are kneaded respectively with Sr·ferrite powder, silane coupling and calcium stearate of lwt% are added for coating and pelleting. The pelleted specimen are injection-moulded under the magnetic field using 4 poles mould. For 4 poles anisotropic Sr·ferrite plastic magnets with polyamide6 as a binder, the surface magnetic flux density distribution is +943.8∼-943.87kG and the deviation is 5.2%, where as with polyamide12, the distribution is +1040.9∼-1040.9kG and the deviation is 5.4%. It shows that both of the magnet distributions are stable. As the results of the experiments, we find 4 poles anisotropic Sr·ferrite magnets have good properties as the materials appropriate for manufacturing magnet type synchronous motors.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.9-15
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• 2023

The cement is a typical CO₂ emission industry. Manufacturing process improvements and increased use of alternative materials are needed to reduce energy consumption and CO₂ emissions. This study confirmed the basic characteristics of cement hydration by sintering CAF at low temperature as a CO₂ adsorbent material. For the hydration product of the synthetic CAF, crystal phase analysis, porosity, and structural images were confirmed, and the compressive strength was measured. The replacement rate of SCAF was 10, 20, and 100 %, and the compressive strength tended to decrease as the replacement rate increased. In addition, when the SCAF substitution rate is 100 %, the hydration products of the early age are calcium aluminum oxide hydrate (Ca₃Al₂O₆ x H₂O) and calcium iron hydroxide (Ca₃Fe(OH)₁₂), and at substitution rates of 10 and 20 %, CAF compounds other than general cement hydrates brownmillerite was observed. As for the porosity, the pore size increased and the porosity increased with the increase of the replacement ratio. As a result of this study, CAF manufactured by low-temperature sintering seems to be difficult to use alone and general curing for utilization as a CO₂ adsorbing material.

• Electrical & Electronic Materials
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• v.10 no.5
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• pp.440-446
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• 1997

This research has been performed for the fabrication of high quality ferrite plastic magnet. The magnetic properties of S $r_{5.9}$F $e_2$ $O_3$ ferrite bonded magnets by injection moulding with a variety of applied magnetic field were investigated. 0.3wt% CaCO3, 0.2wt% $SiO_2$, 0.5wt% $Al_2$ $O_3$and 0.5wt% N $a_2$ $SiO_3$are added in order to improve the magnetic properties of Sr-ferrite plastic magnets during the powder fabrication. For carbon coating on chemical compound specimen, 5wt% polyvinyl alcohol is added, and then calcinated under $N_2$ environment of 12$25^{\circ}C$. The particle size is distributed from 0.9~1.2${\mu}{\textrm}{m}$ which approximates to the single domain. The obtained Sr ferrite powder is well mixed with silane coupling and calcium stearate of 1wt%. Nest, the specimen is pelleted after kneading each of them with polyamidel2 as a binder. When the temperature of injection and mould were 25$0^{\circ}C$ and 8$0^{\circ}C$ respectively at injection pressure of 200kgf/$\textrm{cm}^2$, the degree of orientation was 85.3% under the applied magnetic field of 12kOe. As the results, when the packing density of Sr ferrite powder was 90wt%, the magnetic properties of Sr ferrite bonded magnet were follows : $_{B}$ $H_{c}$=2.41kOe, Br=3.1kG, (BH)$_{max}$=2.21MgOe. Especially, the Sr-ferrite bonded magnet with 10wt% N $d_2$F $e_{14}$B additive were as follows : $_{B}$ $H_{c}$=2.57kOe, Br=3.14kG and (BH)$_{max}$=2.39MGOe.GOe.GOe.GOe.e.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.11a
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• pp.120-123
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• 1997

In this paper, we deal with the effect on magnetic properties when Nd is added to Sr ferrite bonded magnet. First, we choose SrO$_{n}$.Fe$_2$O$_3$(n=5.9), which is nonstoichiomatric composition, as specimen ferrite. Then, we add 5wt% polyvinyl alcohol and calcinate at 12$25^{\circ}C$ under $N_2$ environment for carbon coating on chemical compound specimen. After that we obtain 1.2${\mu}{\textrm}{m}$ single domain powder through grinding process for 18 hours. The single domain Sr ferrite Powder is well mixed with silage coupling and calcium stearate of 1wt% Then, it is kneaded by using polyamide12 as a binder and is pelleted. After adding Nd-Fe-B powder to the pelleted specimen, we injection-mould it under magnetic field by using anisotropic mould. Especially, when we add l3wt% Nd-Fe-B powder to the polyamide12, we obtain excellent magnetic propertiecs which are $_{B}$H$_{C}$=2.65KOe, Br=3.16KG and (BH)$_{max}$=2.61MGOeOeOeOeOe

• Resources Recycling
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• v.11 no.1
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• pp.3-8
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• 2002

In order to make the high purity Mn$_3$O$_4$powder for the raw material of soft ferrite, Mn is extracted from the dust and the extracted solution is refined. The dust is generated in producing a medium-low carbon ferromanganese and contains 90% Mn$_3$O$_4$. Mn$_3$O$_4$in the dust was reduced into MnO by roasting with charcoal. Injection of the 180g/L of the reduced dust into 4N HCI solution increased pH of the leaching solution higher than 5 and then a ferric hydroxide was precipitated. Because the ferric hydroxide co-precipitates with Si ion etc, Fe and Si ion was removed from the solution and the about 10% Mn solution was obtained. The solution was diluted with water to Mn-15000 ppm and $NH_4$F was injected into the diluted solution at $70^{\circ}C$ to the F-3000 ppm. As a result, Ca ion is precipitated as $CaF_2$and the residual concentration of Ca was 14 ppm. Injection of the equivalent (NH$1.5M_4$)$_2$$CO_3$solution as 2 L/min at $25^{\circ}C$ into the above solution precipitated a fine and high purity $MnCO_3$powder. The deposition was filtrated and roasted at $1000^{\circ}C$ for 2 hours. As a result, $MnCO_3$powder is converted into $Mn_3$$O_4$powder and it had $8.2\mu$m of median size. The final production is above 99% $Mn_3$$O_4$powder and it satisfied the requirement of high purity $Mn_3$$O_4$powder for a raw material of soft ferrite.