• Geomechanics and Engineering
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• 제29권1호
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• pp.79-90
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• 2022

Soybean-urease induced carbonate precipitation (EICP), as an alternative to microbially induced carbonate precipitation (MICP), was employed for soil improvement. Meanwhile, soluble calcium produced from industrial waste carbide slag powder (CSP) via the acid dissolution method was used for the EICP process. The ratio of CSP to the acetic acid solution was optimized to obtain a desirable calcium concentration with an appropriate pH. The calcium solution was then used for the sand columns test, and the engineering properties of the EICP-treated sand, including unconfined compressive strength, permeability, and calcium carbonate content, were evaluated. Results showed that the properties of the biocemented sand using the CSP derived calcium solution were comparable to those using the reagent grade CaCl₂. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses revealed that spherical vaterite crystals were mainly formed when the CSP-derived calcium solution was used. In contrast, spherical calcite crystals were primarily formed as the reagent grade CaCl₂ was used. This study highlighted that it was effective and sustainable to use soluble calcium produced from CSP for the EICP process.

• 한국정밀공학회지
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• 제1권2호
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• pp.41-46
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• 1984

The machinability of calicium-deoxidized steel is studied in turning by being compared with that of Fe-Si deoxidized steel under a given set of cutting condition. Tool life, cutting force and cutting mechanism are examined on a few sorts of steel. It is found that adhesive layer "Belag" is developed on the cemented carbide tool and the peak value is observed at the cutting speed of 300m/min followed by gradual increase in the thickness of Belag with the increase of cutting speed. the maximum thickness of Belag is also shown at the feed of 0.3mm/rev. On the other hand, the tool life of carbide tool is more favorable than that of high speed steel (SKH 9) in cutting calcium- deoxidized steel. It is considered that the steel deoxidized with Ca-Si shows better machinability a little than that with Fe-Si. However, the cutting force and the shear angle of the former are similar to those of the latter in turning.n turning.

• 자원리싸이클링
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• 제19권3호
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• pp.33-44
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• 2010

본 연구에서는 아세틸렌가스 제조 공정에서 배출되어 나오는 부산소석회에 대한 고로수쇄슬래그의 알칼리 활성화제로서의 활용 가능성을 조사하고자 하였다. 부산소석회의 물리 화학적 분석을 실시하였으며, 알칼리 활성화제로서의 특성분석을 위하여 세 가지 형태로 부산소석회를 사용하였다. 부산소석회는 고로수쇄슬래그에 0, 10, 20, 30 wt.% 첨가하였으며, 소석회가 혼합된 고로수쇄슬래그를 보통포틀랜드시멘트에 0, 10, 30, 50 wt.%첨가하여 수화 및 물리적 특성을 조사하였다. 수화특성 분석결과 $800^{\circ}C$에서 열처리 후 재수화 시킨 소석회를 사용한 경우 다른 시료들 보다 높은 수화율을 보였다. 압축강도실험결과 325 mesh 이하크기의 부산소석회와 열처리 후 재수화시킨 소석회를 사용한 경우 수화 7일부터 OPC 보다 높은 강도 값을 나타내었으며, 325 mesh 이하크기 부산소석회를 활성화재로 사용한 OPC50 wt.%-BFS 45 wt.%-AA5 wt.%계에서 가장 높은 압축강도를 보였다.

• 한국세라믹학회지
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• 제39권5호
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• pp.503-510
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• 2002

가압유동층 복합발전용으로 사용 가능한 탄화규소 캔들형 필터를 압출성형법으로 제조하였다. 필터의 기공율을 조절하기 위해 2.5 vol%의 탄소분말을 첨가하였고, 필터의 강도를 부여하기 위해 무기결합제로써 점토와 $CaCO_3$를 첨가하였다. 평균 기공율이 약 40%, 평균 기공크기가 약 $47{\mu}m$인 지지체 위에 평균 기공크기가 약 $10{\mu}m$를 갖도록 탄화규소 분말을 분무 코팅하였고, 이후 대기압 분위기 하에서 1400${\circ}C$의 온도로 소결하였다. 코팅층이 형성된 캔들형 필터를 500${\circ}C$, $5kgf/cm^2$의 고온, 고압 하에서 성능평가를 행한 결과 입자크기별 집진 성능이 모두 99.99% 이상을 나타내었다. 따라서 제조된 탄화규소 캔들형 필터는 가압유동층 연소가스에 포함되어 있는 미세한 먼지를 효과적으로 제거할 수 있을 것으로 판단되었다.

• 한국지반공학회논문집
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• 제33권1호
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• pp.57-65
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• 2017

본 연구에서는 성토, 보조기층, 옹벽 뒤채움 토사의 함수비를 신속하게 측정할 목적으로 현장에서 주로 사용되는 칼슘 카바이드의 화학적 반응을 이용한 급속 함수비 측정방법의 정확도 및 신뢰성에 대해 연구하였다. 이를 위해 급속 함수비 측정방법에서 얻은 실험 결과와 항온 건조로 및 전자레인지를 이용하여 얻은 결과를 비교, 분석하였다. 함수비시험에는 국내 현장에서 채취한 화강풍화토와 낙동강모래를 비롯하여 모래-카올리나이트 혼합토를 사용하였다. 먼저 급속 함수비시험에서는 20, 22, 24, 26, 28, 30g의 시료를 각각 1, 3, 5분으로 작동하여 시료 양과 작동시간에 따른 함수비의 영향을 비교, 분석하였다. 시료 양과 작동시간이 증가함에 따라 급속 함수비도 일반적으로 증가하였으며, 작동시간보다는 시료 양이 더 큰 영향을 미쳤다. 흙의 통일분류법 상 SM으로 분류된 화강풍화토의 경우에는 24g으로 3분 측정한 급속 함수비가 항온 건조로로 구한 함수비와 가장 유사하였으며, SP로 분류된 낙동강모래의 경우에는 30g으로 3분 측정한 경우가 가장 유사하였다. 낙동강모래에 카올리나이트가 20-50% 함유된 인공 시료의 경우, 급속 함수비는 점토 함유량이 증가함에 따라 증가하는 경향을 보였다.

• Journal of Magnetics
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• 제22권2호
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• pp.244-249
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• 2017

To get deeper insight into the effect of intergranular additives in sintered Nd-Fe-B magnet and consequently improve the properties better, the interaction between additives (oxide, nitride, and carbide) and Nd-rich phase in the temperature range of 298.15-1400 K was analyzed thermodynamically. It can be found that the oxide additives became less stable than nitrides and carbides. Except for calcium oxide, almost all oxides could react with Nd from Nd-rich phase. To be different from oxide additives, the mechanism of nitrides and carbides was defined with various elements, either reaction with Nd from Nd-rich phase or not. The two different mechanisms would show different effects on the microstructure and hence properties of magnet. The thermodynamic analysis had a better agreement with the experimental information.

• 한국토양비료학회지
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• 제16권2호
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• pp.179-182
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• 1983

비닐하우스내(內) 풋고추 재배단지에서 카바이트 부산소석회 시용(施用)에 의(依)한 피해실태조사와 그 원인(原因)을 구명(究明)하기 위하여 재현시험을 실시한 결과(結果) 1. 카바이트 부산소석회 시용구에서는 정식후(定植後) 새 뿌리 발생이 전연 안되었으며 엽면(葉面)에는 많은 암갈색(暗褐色) 얼룩점이 산재(散在)하였고 위조낙엽(萎凋落葉)되면서 뿌리 내림이 불량(不良)하였다. 2. 카바이트 부산소석회 시용구의 식물체는 소석회 시용구의 식물체보다 호흡량(呼吸量)이 떨어졌다. 3. 카바이트 부산소석회에는 아세틸렌가스($C_2H_2$) 발생이 많았고 이 석회를 시용(施用)한 피해(被害) 토양에서도 가스가 발생되었으며 발생량이 많을수록 고추의 피해(被害)가 심(甚)하였다.

• 대한화학회지
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• 제8권4호
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• pp.188-191
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• 1964

微量元素分析用 燃燒爐 內에서 內部酸化劑(酸化銀과 二酸化 망간의 混合物)와 함께 有機試料를 헤륨 氣流下에서 燃燒시키고 發生한 물은 칼슘카바이드管에 通하여 아세틸렌으로 變換시킨다. 二酸化炭素와 아세틸렌을 molecular sieve 5A 管에 室溫에서 吸着시킨 후 $340^{\circ}C$까지 溫度${\cdot}$프로그탬法으로 脫着시켜 실리카켈管을 通하여 分別流出시키고 熱傳導式 檢知器로 $CO_2$와 $C_2H_2$를 定量하는 方法을 發展시켰다. 벤조酸을 標準物質로 하여 作成한 檢量線을 使用하여 各種 有機試料中의 炭素 및 水素含量을 分析한 結果 平均誤差가 炭素의 경우 ${\pm}0.5%$, 水素인 경우${\pm}0.33%$ 이었다.

• Restorative Dentistry and Endodontics
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• 제41권4호
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• pp.255-261
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• 2016

Objectives: This study aimed to analyze the mineral composition of naturally- and artificially-produced caries-affected root dentin and to determine the elemental incorporation of resin-modified glass ionomer (RMGI) into the demineralized dentin. Materials and Methods: Box-formed cavities were prepared on buccal and lingual root surfaces of sound human premolars (n = 15). One cavity was exposed to a microbial caries model using a strain of Streptococcus mutans. The other cavity was subjected to a chemical model under pH cycling. Premolars and molars with root surface caries were used as a natural caries model (n = 15). Outer caries lesion was removed using a carbide bur and a hand excavator under a dyeing technique and restored with RMGI (FujiII LC, GC Corp.). The weight percentages of calcium (Ca), phosphate (P), and strontium (Sr) and the widths of demineralized dentin were determined by electron probe microanalysis and compared among the groups using ANOVA and Tukey test (p < 0.05). Results: There was a pattern of demineralization in all models, as visualized with scanning electron microscopy. Artificial models induced greater losses of Ca and P and larger widths of demineralized dentin than did a natural caries model (p < 0.05). Sr was diffused into the demineralized dentin layer from RMGI. Conclusions: Both microbial and chemical caries models produced similar patterns of mineral composition on the caries-affected dentin. However, the artificial lesions had a relatively larger extent of demineralization than did the natural lesions. RMGI was incorporated into the superficial layer of the caries-affected dentin.

• 자원환경지질
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• 제3권1호
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• pp.17-24
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• 1970

The purpose of this report is to prepare a data for the economic evaluation on the Goobong Limestone Mine which is located at the south-eastern corner of the Yongchun Quadrangle scaled in 1:50,000. The accessibility from the mine to railroad was considered in two ways. One is to Dodam Station on Central Railway Line and the other is to reach Songjung-ni village which is near Sangyong Station on Hamback Railway Line. The distance of the former way is 26.7km and the later is 24.2km. Geologically the mine is situated near the base of the Greast Limestone Series which strikes generally $N25^{\circ}{\sim}30^{\circ}E$. The series comprises six different formations from older to younger; Pungchon Limestone Formation and Whajol Formation of Cambrian age, and Dongjum Quartzite Formation, Dumudong Formation, Maggol Limestone Formation and Goseong Formation of lower to middle Ordovician age. 82 samples; 48 from Pungchon Limestone Formation, 11 from Dumudong Formation, 15 from Maggol Limestone Formation and 8 from Goseong Formation, were taken from the series in the crossed direction to the general trend of the series as shown in geological map. They were chemically analyzed on the components of CaO, MgO, $SiO_2$, $R_2O_3(Al_2O_3+Fe_2O_3)$ and ignition loss as shown in table 2, table 3, table 4, and table 5. As seen from the tables, among the formations of the series, middle to upper parts of the Pungchon Limestone Formation and middle and upper parts of the Dumudong Formation have chemical composition as available source for the raw material of cement industry, not only that but also the part of the Pungchon Formation was highly evaluated as source for the flux of iron smelting and the raw material of carbide manufacturing because of its high purity of calcium carbonate.