• Title/Summary/Keyword: Calcium Carbide

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Biocementation via soybean-urease induced carbonate precipitation using carbide slag powder derived soluble calcium

  • Qi, Yongshuai;Gao, Yufeng;Meng, Hao;He, Jia;Liu, Yang
    • Geomechanics and Engineering
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    • v.29 no.1
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    • pp.79-90
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    • 2022
  • Soybean-urease induced carbonate precipitation (EICP), as an alternative to microbially induced carbonate precipitation (MICP), was employed for soil improvement. Meanwhile, soluble calcium produced from industrial waste carbide slag powder (CSP) via the acid dissolution method was used for the EICP process. The ratio of CSP to the acetic acid solution was optimized to obtain a desirable calcium concentration with an appropriate pH. The calcium solution was then used for the sand columns test, and the engineering properties of the EICP-treated sand, including unconfined compressive strength, permeability, and calcium carbonate content, were evaluated. Results showed that the properties of the biocemented sand using the CSP derived calcium solution were comparable to those using the reagent grade CaCl2. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses revealed that spherical vaterite crystals were mainly formed when the CSP-derived calcium solution was used. In contrast, spherical calcite crystals were primarily formed as the reagent grade CaCl2 was used. This study highlighted that it was effective and sustainable to use soluble calcium produced from CSP for the EICP process.

A Study on Machinability of Calcium-Deoxidized Steel (1st Report) (Ca탈산강의 피삭성에 관한 연구(제1보))

  • Lee, Yong-Seong
    • Journal of the Korean Society for Precision Engineering
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    • v.1 no.2
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    • pp.41-46
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    • 1984
  • The machinability of calicium-deoxidized steel is studied in turning by being compared with that of Fe-Si deoxidized steel under a given set of cutting condition. Tool life, cutting force and cutting mechanism are examined on a few sorts of steel. It is found that adhesive layer "Belag" is developed on the cemented carbide tool and the peak value is observed at the cutting speed of 300m/min followed by gradual increase in the thickness of Belag with the increase of cutting speed. the maximum thickness of Belag is also shown at the feed of 0.3mm/rev. On the other hand, the tool life of carbide tool is more favorable than that of high speed steel (SKH 9) in cutting calcium- deoxidized steel. It is considered that the steel deoxidized with Ca-Si shows better machinability a little than that with Fe-Si. However, the cutting force and the shear angle of the former are similar to those of the latter in turning.n turning.

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Use of By-product Hydrated Lime as Alkali Activator of Blast Furnace Slag Blended Cement (고로수쇄(高爐水碎)슬래그 혼합(混合)시멘트의 알칼리 자극제(刺戟劑)로 부산소석회(副産消石灰)의 활용(活用))

  • Cho, Jin-Sang;Yu, Young-Hwan;Choi, Moon-Kwan;Cho, Kye-Hong;Kim, Hwan;Yeon, Kyu-Seok
    • Resources Recycling
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    • v.19 no.3
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    • pp.33-44
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    • 2010
  • In this study, the possibility of utilizing carbide lime waste, obtained from the generation of acetylene process, as a alkali activator of blast furnace slag cement was investigated. The physical and chemical analysis of the carbide lime waste was studied and three types lime waste in order to investigate behaviour as alkali activator were used. Lime wastes were added 0, 10, 20 and 30 wt.% in blast furnace slag and blast furnace slag containing lime waste were added 0, 10, 30 and 50 wt.% in OPC. As a result of analysis of hydration properties, in the case of calcium hydroxide rehydrated after heat treatment at $800^{\circ}C$, it was higher hydration rate than other specimens. For the results of compressive strength test, when lime waste passed 325 mesh sieve and rehydrated calcium hydroxide were used, it was higher compressive strength than OPC from hydration 7days. At OPC50 wt.%-BFS45 wt.%-AA5 wt.% system using lime waste of 325 mesh under, the highest compressive strength appeared.

Fabrication of Silicon Carbide Candle Filter and Performance Evaluation at High Temperature and Pressure (탄화규소 캔들형 필터의 제조 및 고온고압 하에서의 성능평가)

  • Lee, Sang-Hun;Lee, Seung-Won;Lee, Kee-Sung;Han, In-Sub;Seo, Doo-Won;Park, Seok-Joo;Park, Young-Ok;Woo, Sang-Kuk
    • Journal of the Korean Ceramic Society
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    • v.39 no.5
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    • pp.503-510
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    • 2002
  • Silicon carbide candle filters for the pressurized fluidized bed combustion system were fabricated by extrusion process. Carbon black was added to control the porosity. Inorganic additives such as clay and calcium carbonate were added to exhibit appropriate strength. Silicon carbide layer with a finer pore size (mean pore diameter ~$10{\mu}m$) was coated on the silicon carbide support layer (mean pore diameter ~$47{\mu}m$, porosity ∼40%). After that, the filter was sintered at 1400${\circ}C$ in air. We evaluated the filtration performances of the filter at 500${\circ}C$ and $5kgf/cm^2$ of pressure. As a result, high separation efficiency, >99.999% was measured. It is expected that silicon carbide candle filter can be successfully used for the pressurized fluidized bed combustion system.

A Study on Speedy Water Content Measurement Method for Soils (흙의 급속 함수비 측정방법에 관한 연구)

  • Park, Sung-Sik;Kim, Ju-Young;Lee, Sae-Byeok
    • Journal of the Korean Geotechnical Society
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    • v.33 no.1
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    • pp.57-65
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    • 2017
  • During a construction of embankment, sub base, or retaining wall backfill, the speedy measurement of water content is necessary. In this study, a test method for field determination of water content of soil by the calcium carbide gas pressure (speedy water content measurement method) was evaluated for its reliability and accuracy. Dry oven and microwave oven methods were also used for water content measurement. In the test, weathered granite and Nakdong River sand in the site and kaolinite were used for water content measurement. The mass of 20, 22, 24, 26, 28, and 30 g of soil was respectively tested for 1, 3, and 5 min. The effect of each sample on water content was compared one another and analyzed. As the mass and testing time increased, the water content increased. The amount of soil was more important factor than testing time for the speedy water content measurement. In order to obtain similar result to that of dry oven method, 3 min of testing time with 24 g of soil was necessary for weathered granite classified as SM and 3 min with 30 g for Nakdong River sand classified as SP. For Nakdong River sand with 20-50% of kaolinite, the water content by speedy measurement increased as the clay content increased.

Thermodynamic Analysis of Intergranular Additives in Sintered Nd-Fe-B Magnet

  • Cui, X.G.;Wang, X.H.;Cui, C.Y.;Yin, G.C.;Xia, C.D.;Cheng, X.N.;Xu, X.J.
    • Journal of Magnetics
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    • v.22 no.2
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    • pp.244-249
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    • 2017
  • To get deeper insight into the effect of intergranular additives in sintered Nd-Fe-B magnet and consequently improve the properties better, the interaction between additives (oxide, nitride, and carbide) and Nd-rich phase in the temperature range of 298.15-1400 K was analyzed thermodynamically. It can be found that the oxide additives became less stable than nitrides and carbides. Except for calcium oxide, almost all oxides could react with Nd from Nd-rich phase. To be different from oxide additives, the mechanism of nitrides and carbides was defined with various elements, either reaction with Nd from Nd-rich phase or not. The two different mechanisms would show different effects on the microstructure and hence properties of magnet. The thermodynamic analysis had a better agreement with the experimental information.

Influence of the Carbide By-product Lime on the Physiological Disorder of Green-pepper Plant in the On-farm Vinyl House (카바이드 부산소석회 시용(施用)에 의(依)한 비닐하우스 풋고추의 생리장해(生理障害))

  • Sung, Deok-Ki;Kang, Yang-Soon;Jung, Yeun-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.2
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    • pp.179-182
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    • 1983
  • A survey on the physiological disorder of green pepper plant in the on-farm vinyl house where the by-product lime of $CaC_2$ applied and a pot experiment were carried out simultaneous to find out the causes. The results are as follows: 1. The pepper plants grown under the application of by-product lime were characterized with the dark brown spots on the leaves and the hindered rooting. Finally the leaves wilted and fell down. 2. Respiration of pepper plant grown in field where tile by-product lime of calcium car-bide applied decreased. 3. Acethylene gas was considerably detected from by-product lime and from the soil where the by-product was used. The severity of physiological disorder increased as the amount of the gas detected.

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A New Gas-Chromatograghic Method of Organic Elemental Analysis (가스크로마토그래피에 依한 微量元素分析)

  • Kim, You-Sun;Son, Youn-Soo;Choi, Q.Won
    • Journal of the Korean Chemical Society
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    • v.8 no.4
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    • pp.188-191
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    • 1964
  • A new gas-chromatographic method for determining carbon and hydrogen in organic compounds has been developed. After sample combustion was performed in a regular analytical combustion tube with an internal oxidant (a mixture of silver oxide and manganese dioxide) under a helium flow, the water produced was converted to acetylene by passing through a calcium carbide tube. The carbon dioxide and acetylene were trapped by a molecular sieve 5A column at room temperature. The trapped gases were released under programmed temperature raise up to $340^{\circ}C$ and the released gases were passed through a silica gel column. The adsorption of $CO_2$ and $C_2H_2$ in the molecular sieve 5A trapping column were found to be quantitative and the silica gel column showed an excellent resolution of $CO_2$ and $C_2H_2$ for analytical purpose. The analytical results for various known compounds based on the out-put of the thermal conductivity cell calibrated for the amounts of carbon and hydrogen contents in benzoic acid, showed average errors ${\pm}0.5%$ and ${\pm}0.33%$ for carbon and hydrogen, respectively.

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Elemental analysis of caries-affected root dentin and artificially demineralized dentin

  • Sung, Young-Hye;Son, Ho-Hyun;Yi, Keewook;Chang, Juhea
    • Restorative Dentistry and Endodontics
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    • v.41 no.4
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    • pp.255-261
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    • 2016
  • Objectives: This study aimed to analyze the mineral composition of naturally- and artificially-produced caries-affected root dentin and to determine the elemental incorporation of resin-modified glass ionomer (RMGI) into the demineralized dentin. Materials and Methods: Box-formed cavities were prepared on buccal and lingual root surfaces of sound human premolars (n = 15). One cavity was exposed to a microbial caries model using a strain of Streptococcus mutans. The other cavity was subjected to a chemical model under pH cycling. Premolars and molars with root surface caries were used as a natural caries model (n = 15). Outer caries lesion was removed using a carbide bur and a hand excavator under a dyeing technique and restored with RMGI (FujiII LC, GC Corp.). The weight percentages of calcium (Ca), phosphate (P), and strontium (Sr) and the widths of demineralized dentin were determined by electron probe microanalysis and compared among the groups using ANOVA and Tukey test (p < 0.05). Results: There was a pattern of demineralization in all models, as visualized with scanning electron microscopy. Artificial models induced greater losses of Ca and P and larger widths of demineralized dentin than did a natural caries model (p < 0.05). Sr was diffused into the demineralized dentin layer from RMGI. Conclusions: Both microbial and chemical caries models produced similar patterns of mineral composition on the caries-affected dentin. However, the artificial lesions had a relatively larger extent of demineralization than did the natural lesions. RMGI was incorporated into the superficial layer of the caries-affected dentin.

Geologic Report on the Goobong Limestone Mine (구봉석회석광산의 지질조사보고(地質調査報告))

  • Lee, Dai Sung
    • Economic and Environmental Geology
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    • v.3 no.1
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    • pp.17-24
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    • 1970
  • The purpose of this report is to prepare a data for the economic evaluation on the Goobong Limestone Mine which is located at the south-eastern corner of the Yongchun Quadrangle scaled in 1:50,000. The accessibility from the mine to railroad was considered in two ways. One is to Dodam Station on Central Railway Line and the other is to reach Songjung-ni village which is near Sangyong Station on Hamback Railway Line. The distance of the former way is 26.7km and the later is 24.2km. Geologically the mine is situated near the base of the Greast Limestone Series which strikes generally $N25^{\circ}{\sim}30^{\circ}E$. The series comprises six different formations from older to younger; Pungchon Limestone Formation and Whajol Formation of Cambrian age, and Dongjum Quartzite Formation, Dumudong Formation, Maggol Limestone Formation and Goseong Formation of lower to middle Ordovician age. 82 samples; 48 from Pungchon Limestone Formation, 11 from Dumudong Formation, 15 from Maggol Limestone Formation and 8 from Goseong Formation, were taken from the series in the crossed direction to the general trend of the series as shown in geological map. They were chemically analyzed on the components of CaO, MgO, $SiO_2$, $R_2O_3(Al_2O_3+Fe_2O_3)$ and ignition loss as shown in table 2, table 3, table 4, and table 5. As seen from the tables, among the formations of the series, middle to upper parts of the Pungchon Limestone Formation and middle and upper parts of the Dumudong Formation have chemical composition as available source for the raw material of cement industry, not only that but also the part of the Pungchon Formation was highly evaluated as source for the flux of iron smelting and the raw material of carbide manufacturing because of its high purity of calcium carbonate.

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