• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 추계총회 및 연구발표회 초록집
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• pp.167.2-167
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• 2003

• 한국세라믹학회지
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• 제31권4호
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• pp.448-456
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• 1994

The reaction-sintered alumina and zirconia-alumina ceramics were fabricated from the Al/Al2O3 or Zl/ZrO2(Ca-PSZ) powder mixtures via the attrition milling. And the effects of the milling characteristics of used raw powders on reaction sintering were investigated. After attrition milling and isopressing at 400 MPa the Al/Al2O3 specimen was oxidated at 1200℃ for 8 hours followed by sintering at 1550℃ for 3 hours. Because mixed powders of flake-type Al with coarse alumina was much more effectively comminuted than the globular-type Al with coarse alumina powders, it's sintered body of more than 97% theoretical density was achived, but low contents of Al leads to relatively higher shrinkage of about 8%. And because coarse alumina particles was much more beneficial in cutting and reducing the ductile Al particles, using the coarse alumina powder was much more effective in reaction sintering. Fused Ca-PSZ powder was reaction sintered with Al at 1550℃ for 3 hours and low shrinkage ZrO2-Al2O3 composites were fabricated. But because Al/Ca-PSZ powder mixtures were not effectively milled the reaction sintering and densification was difficult. And the Ca ion in Ca-PSZ grains diffused into alumina grains during sintering so that the unstabilization of Ca-PSZ body was occured which gave the microcracks in the specimens.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 춘계총회 및 연구발표회 초록집
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• pp.116.2-116
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• 2003

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.153-156
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• 2001

(Ba$_{0.6-x}$Sr$_{0.4}$Ca$_{x}$)TiO$_3$ (x=0.10, 0.15, 0.20) ceramics were fabricated by the mixed-oxide method and their dielectric properties were investigated with variation of composition ratio, doped ZrO$_2$ (0.5, 1.0, 1.5, 2.0, 3.0 wt%) and sintered at 145$0^{\circ}C$. The dielectric constant and loss of the x=0.10 specimen applied field were 19.86 and 0.302 % at 0 V/cm, and 25.937 and 0.339 % at 300 V/cm, respectively. Dielectric constant were increased with increased applied field and decreased with increased frequency, and dielectric loss were within 0.1% at applied 800 MHz, respectively. all specimens showed fairly good applied field. Although, dielectric constant and loss of all specimen showed to tend of nearly the same. same.

• 한국전기전자재료학회논문지
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• 제29권7호
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• pp.404-407
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• 2016

In this study, to develop low temperature sintering capacitor composition ceramics with the good dielectric properties, $(Ba_{0.86}Ca_{0.14})(Ti_{0.85}Zr_{0.12}Sn_{0.03})O_3$ (BCTZ) ceramics were prepared by the conventional solid-state reaction method. The effects of $B_2O_3$ addition on the dielectric properties and microstructure was investigated. The XRD patterns demonstrated that all the specimens showed Perovskite phase, and secondary phases are indicated in the measurement range of XRD. And also, temperature coefficient of capacitance(TCC) of all the specimen sintered at $1,180^{\circ}C$ showed +3~-56% except for x=0.006. For all the specimens, observed one peak was tetragonal cubic difuse phase transition temperature(Tc), which is located in the vicinity of room temperature.

• 대한화학회지
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• 제37권7호
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• pp.635-641
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• 1993

고체 전해질의 특성을 조사하기 위해 전기화학전지, $Pt|ar(PO_2=5.3{\times}10^{-3}atm)|Zr_{0.85}Ca_{0.15}O_{1.85}|air(PO_2=0.21atm)|Pt$을 제작하고 600~1000${\circ}$C의 온도구간에서 기전력의 온도 의존성을 측정하였다. 고체 전해질은 산소 음이온에 의한 순수한 이온성 전기전도도를 나타낸다. Fe-FexO, Co-CoO, Ni-NiO, 및 $Cu_2_O-CuO$전극들은 금속과 금속산화물을 1:1 몰비로 혼합한 후 800${\circ}$C에서 6h 동안 열처리하여 제조하였다. 전기 화학전지 Pt|M(s), $MO(s)|Zr_P{0.85}Ca_{0.15}O_{1.85}|air(PO_2=0.21atm)|Pt$을 제작하고 같은 온도 구간에서 기전력의 온도 의존성을 측정하였다 .그 전지들의 기전력과 기전력의 온도 의존성을 사용하여 금속산화물의 생성에 대한 열역학적 상태함수 변화들을 계산한다. 그 함수 변화들로 이들 산화물계의 물성을 논의하였다.

• 한국세라믹학회지
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• 제28권10호
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• pp.819-823
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• 1991

Pure zirconia ceramic fiber experiences severe volume changes through thermal cyclings of heating and cooling. Zirconia fiber was doped with CaO to stabilize the phase and its effect of CaO was studied on volumetric ratio of each phases, phase transition temperature and microstructure. Tetragonal phase was increased as CaO increases up to 10 mol% and cubic phase was stabilized when CaO was added more than 10 mol%. The average grain size of zirconia fiber was increased as CaO increased and transition temperature was shifted to lower temperature.

• The Korean Journal of Ceramics
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• 제5권4호
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• pp.336-340
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• 1999

Glasses in the system $CaO-TiO_2-SiO_2-Al_2O_3-ZrO_2-B_2O_3$ were investigated to find the glass seal compositions suitable for use in the planar solid oxide fuel cell (SOFC). Glass-ceramics prepared from the glasses by one-stage heat treatment at $1,000^{\circ}C$ showed various thermal expansion coefficients (i,e., $8.6\times10^{-6^{\circ}}C^{-1}$ to $42.7\times10^{-6^{\circ}}C^{-1}$ in the range 25-$1,000^{\circ}C$) due to the viscoelastic response of glass phase. The average values of contact angles between the zirconia substrate and the glass particles heated at 1,000-$1,200^{\circ}C$ were in the range of $131^{\circ}\pm4^{\circ}$~$137^{\circ}\pm9^{\circ}$, indicating that the glass-ceramic was in partial non-wetting condition with the zirconia substrate. With increasing heat treatment time of glass samples from 0.5 to 24 h at $1,100^{\circ}C$, the DC electrical conductivity of the resultant glass-ceramics decreased from at $800^{\circ}C$. Isothermal hold of the glass sample at $1100^{\circ}C$ for 48h resulted in diffusion of Ca, Si, and Al ions from glass phase into the zirconia substrate through the glass/zirconia bonding interface. Glass phase and diffusion of the moving ion such as $Ca^{2+}$ in glass phase is responsible for the electrical conduction in the glass-ceramics.

• 한국광물학회지
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• 제16권4호
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• pp.307-320
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• 2003

Fe­석류석인 경우, 사면체 배위를 하는 Fe의 이온반경이 Si보다 크기 때문에 고준위 방사성 폐기물에 다량 함유되어 있는 악티나이드 원소들을 고정화시킬 수 있는 매트릭스로 고려되고 있다. 따라서 본 연구에서는 $Ca_{2,5}$C $e_{0.5}$Z $r_2$F $e_3$ $O_{12}$ 및 $Ca_2$CeZrFeF $e_3$ $O_{12}$인 조성을 가진 석류석을 합성하여 이들의 상평형 관계 및 특성을 연구하였다. 혼합된 시료는 200∼400 kg/$\textrm{cm}^2$의 압력으로 성형한 후, 1100∼140$0^{\circ}C$ 범위에서 온도 및 분위기를 변화시키면서 소결하였으며 합성된 시료는 XRD, SEM/EDS를 사용하여 상분석과 정량분석을 실시하였다. 실험결과, 이들 조성을 가진 석류석들은 130$0^{\circ}C$로 가열하였을 때, 최적 합성상을 얻을 수 있었지만 소량의 페롭스카이트 등 부수상이 공존하였다. $Ca_{2,5}$C $e_{0.5}$Z $r_2$F $e_3$ $O_{12}$ 및 $Ca_2$CeZrFeF $e_3$ $O_{12}$인 조성으로부터 합성된 Fe­석류석의 조성이 각각 $Ca_{2.5­3.2}$C $e_{0.3­0.7}$Z $r_{1.8­2.8}$F $e_{1.9­3.2}$ $O_{12}$ 및 $Ca_{2.2­2.5}$C $e_{0.8­1.0}$Z $r_{1.3­1.6}$F $e_{0.4­.07}$ F $e_{3­3.2}$ $O_{12}$였다. 특히 화학양론적 조성과 비교시, 합성된 석류석의 8배위 자리를 점하고 있는 Ca이 초과된 양상을 보였고, Ce의 함량은 초과 또는 결핍된 양상을 보였다. 이는 8배위 자리에서의 Ca과 Ce의 이온반경의 상대적인 차이 및 전하보상적 차원에서 비롯된 것으로 해석된다.에서 비롯된 것으로 해석된다.

• 통합자연과학논문집
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• 제8권4호
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• pp.244-249
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• 2015

The PZT thin films were deposited on Si(100) substrate using RF magnetron sputtering method. And the PZT thin films were post annealed at various temperatures to form perovskite phase. To analyze PZT thin films, surface profiler, XRD, XPS, CA, and SFE were used. The thickness increased from 536.5 to 833.2 nm as post annealing temperature increased. The perovskite PZT was observed from PZT-823 and pyrochlore PZT, $ZrO_2$, $TiO_2$, and perovskite $PbZrO_3$ were observed. From the XPS, the atomic percentages of Pb, Zr, Ti, and O were calculated and the portion of Pb increased to PZT-823 and decreased to PZT-923 and then increased to PZT-1023. Also, the CA and SFE was effected on post annealing temperature and as a function of atomic percentage of Pb, the CA and SFE was transformed.