• Title/Summary/Keyword: CaO recovery

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Optimization of Extended UNIQUAC Parameter for Activity Coefficients of Ions of an Electrolyte System using Genetic Algorithms

  • Hashemi, Seyed Hossein;Dehghani, Seyed Ali Mousavi;Khodadadi, Abdolhamid;Dinmohammad, Mahmood;Hosseini, Seyed Mohsen;Hashemi, Seyed Abdolrasoul
    • Korean Chemical Engineering Research
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    • v.55 no.5
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    • pp.652-659
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    • 2017
  • In the present research, in order to predict activity coefficient of inorganic ions in electrolyte solution of a petroleum system, we studied 13 components in the electrolyte solution, including $H_2O$, $CO_2$ (aq), $H^+$, $Na^+$, $Ba^{2+}$, $Ca^{2+}$, $Sr^{2+}$, $Mg^{2+}$, $SO_4$, $CO_3$, $OH^-$, $Cl^-$, and $HCO_3$. To predict the activity coefficient of the components of the petroleum system (a solid/liquid equilibrium system), activity coefficient model of Extended UNIQUAC was studied, along with its adjustable parameters optimized based on a genetic algorithm. The total calculated error associated with optimizing the adjustable parameters of Extended UNIQUAC model considering the 13 components under study at three temperature levels (298.15, 323.15, and 373.15 K) using the genetic algorithm is found to be 0.07.

Effect of oxygen containing compounds in uranium tetrafluoride on its non-adiabatic calciothermic reduction characteristics

  • Gupta, Sonal;Kumar, Raj;Satpati, Santosh K.;Sahu, Manharan L.
    • Nuclear Engineering and Technology
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    • v.53 no.6
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    • pp.1931-1938
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    • 2021
  • Uranium ingot is produced by metallothermic reduction of uranium tetrafluoride using magnesium or calcium as reductant. Presence of oxygen containing compounds viz. uranyl fluoride and uranium oxide in the starting uranium fluoride has a significant effect on the firing time, final temperature of the charge, slag-metal separation and hence the metal recovery. As reported in the literature, the maximum tolerable limit for uranyl fluoride in the UF4 is 2.5 wt% and limit for uranium oxide content is in the range 2-3 wt%. No theoretical or experimental basis is available till date for these limits. Analyses have been carried out in this study to understand the effect of UO2F2 concentration in the starting fluoride on the final temperature of the products and thus the reduction characteristics. UF4 having uranyl fluoride concentration, less than as well as more than 2.5 wt%, have been investigated. Thermodynamic calculations have been carried out to arrive at a general expression for the final temperature attained by the products during calciothermic reduction of UF4. Finally, an upper limit for the oxygen containing impurities has been estimated using the CaO-CaF2 phase diagram.

Studies on the Grassland Development in the Foerst III. Effect of fertilizer level on quality , mineral constituents and tree growth of grass-clover mixtures grown under pine trees (임간초지 개발에 관한 연구 III. 임간혼파초지에서 3요소 시비수준이 목초의 품질과 무기성분함량 및 나무생장에 미치는 영향)

  • Seo, S.;Han, Y.C.;Park, M.S.;Lee, J.Y.
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.5 no.3
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    • pp.187-194
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    • 1985
  • This field experiment was carried out to determine the effects of thirteen different fertilizer levels of nitrogen(N), phosphorus($P_2O_5$) and potassium($K_2O$) on the content of crude protein, crude fiber, mineral constituents of product and tree growth forest pasture with 40-50% shading. The experiment was arranged as a randomized block design and performed in the suburban forest of Suweon in 1984. The results obtained are summarized as follows: 1. Crude protein content and total protein yield were higher in the plot of 28 and 42kg $N/_{10a}$, regardless of $P_2O_5\;and\;K_2O$ level, while those were the lowest in zero fertilizer and N-zero fertilizer plots. 2. The contents of lignin and silica were significantly low in the high N fertilizer level, and the contents of NDF, ADF, cellulose and hemicellulose were not affected by different fertilizer levels. However, the content of crude fiber tended to be low with high N, regardless of $P_2O_5\;and\;K_2O$. 3. The contents of N,K and $SiO_2$ of grasses were influenced by different fertilizer levels. However, those of P,Ca,Ma and Na showed little differences. 4. The recovery percentage of NPK was higher in the plot of standard fertilizer level with 28-20-24 kg/10a, and higher recovery percentage was observed in $K_2O$, followed by N and $P_2O_5$ in that order. 5. The growth of tree was increased as the level of N fertilizer was increased, but no such trend was noted by $P_2O_5\;and\;K_2O$ levels. 6. Crude protein, crude fiber, some mineral contituents of grasses, and growth of tree were influenced by N level, regardless of $P_2O_5\;and\;K_2O$. And the optimum fertilizer level of $N-P_2O_5-K_2O$ seemed to be 28-20-24 kg/10a for the production of grasses with higher quality and more yield in the forest.

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Chemical Stability through CO2 Curing of Cement Paste Exposed to High Temperature (고온 환경에 노출된 시멘트 페이스트의 DCG 양생을 통한 화학적 안정화)

  • Kim, Min-Hyouck;Cho, Hyeon-Seo;Lee, Gun-Cheo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.73-74
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    • 2019
  • In order to examine the chemical stabilization through DCG curing of cement paste exposed to high temperature environment, we produced a sample of 40% W/C cement paste and heated it for 180 minutes under the heating temperature of $800^{\circ}C$. The DCG curing time was 6, Three time conditions were divided into 12 and 18 hours. As a result of XRD analysis, Calcite ($CaCO_3$) was found in Theta 29.4, 40, and 46.5o. As the curing time increased, the peak of Calcite also increased, which is due to the increased reaction time with DCG. Therefore, Calcite produced through DCG curing seems to have stabilized chemically by filling the pores generated by heating.

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A Study on Making of High-Purity Ferro-manganese from $Mn_3O_4$ Waste Dust ($Mn_3O_4$ 분진으로부터 고순도 훼로망간 제조에 관한 연구)

  • Kim, Youn-Che;Song, Young-Jun;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.135-139
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    • 2011
  • In order to make high-purity ferro-manganese from $Mn_3O_4$ waste dust, the application of aluminothermite process to the reduction of the waste dust was investigated. The mixture from $Mn_3O_4$ dust as metallic source and Al metal powder as the reductant ignited, and reduced with an extremely intense exothermic reaction. The rapid propagation of the aluminothermite reaction occurred spontaneously and stably by ignition of the mixture. The Manganese having some alloy elements emerged as liquids due to the high temperatures reached up to about $2,500^{\circ}C$ and separated from the liquid by their differences of specific gravity. The result of thermite reaction showed the fact that can be obtained high purity ferro-manganese which have over about 90% of manganese content and lower impurities such as C, P, S than those of KS D3712 specification. The recovery of manganese from $Mn_3O_4$ dust was lower level of about 65% than about 75% from manganese ore by electric furnace process, that is due to spatter loss because of its extremely intense thermite reaction. But it will be improved by the process designed to provide CaO as the cooler or to use the Al metal powder having larger particle size distribution.

Leaching of Molybdenite by Hydrochloric Acid Solution Containing Sodium Chlorate (NaClO3를 함유한 염산용액으로 몰리브데나이트광의 침출)

  • Nguyen, Thi Nhan Hau;Nguyen, Thi Thu Huong;Lee, Man Seung
    • Resources Recycling
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    • v.31 no.5
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    • pp.26-33
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    • 2022
  • Molybdenum is widely used in many materials; thus, its recovery from ores and secondary resources has attracted considerable attention. In this study, the leaching of molybdenite ore using hydrochloric acid containing sodium chlorate as an oxidizing agent was studied. The effects of several variables, such as the concentrations of HCl and NaClO3, reaction temperature and time, and pulp density, on the leaching of the ore were investigated. Under strong acidic and oxidizing conditions, the sulfide in the ore was dissolved as a sulfate ion, which formed gypsum with Ca(II), leading to a decrease in the leaching percentage of Mo(VI) from the ore. The leaching percentage of molybdenum was greater than 90%, while those of iron, calcium, and silicon were 38, 29, and 67%, respectively, under the optimum conditions: 2.0 M HCl, 0.5 M NaClO3, pulp density of 5 g/L, temperature of 90 ℃, and treatment time of 60 min.

Studies on the analysis of phytin by the Chelatometric method (Chelate 법(法)에 의(依)한 Phytin 분석(分析)에 관(關)한 연구(硏究))

  • Shin, Jai-Doo
    • Applied Biological Chemistry
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    • v.10
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    • pp.1-13
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    • 1968
  • Phytin is a salt(mainly calcium and magnesium) of phytic acid and its purity and molecular formula can be determined by assaying the contents of phosporus, calcium and magnesium in phytin. In order to devise a new method for the quantitative analysis of the three elements in phytin, the chelatometric method was developed as follows: 1) As the pretreatment for phytin analysis, it was ashfied st $550{\sim}600^{\circ}C$ in the presence of concentrated nitric acid. This dry process is more accurate than the wet process. 2) Phosphorus, calcium and megnesium were analyzed by the conventional and the new method described here, for the phytin sample decomposed by the dry process. The ashfied phytin solution in hydrochloric acid was partitioned into cation and anion fractions by means of a ration exchange resin. A portion of the ration fraction was adjusted to pH 7.0, followed by readjustment to pH 10 and titrated with standard EDTA solution using the BT [Eriochrome black T] indicator to obtain the combined value of calcium and magnesium. Another portion of the ration fraction was made to pH 7.0, and a small volume of standard EDTA solution was added to it. pH was adjusted to $12{\sim}13$ with 8 N KOH and it was titrate by a standard EDTA solution in the presence of N-N[2-Hydroxy-1-(2-hydroxy-4-sulfo-1-naphytate)-3-naphthoic acid] diluted powder indicator in order to obtain the calcium content. Magnesium content was calculated from the difference between the two values. From the anion fraction the magnesium ammonium phosphate precipitate was obtained. The precipitate was dissolved in hydrochloric acid, and a standard EDTA solution was added to it. The solution was adjusted to pH 7.0 and then readjusted to pH 10.0 by a buffer solution and titrated with a standard magnesium sulfate solution in the presence of BT indicator to obtain the phosphorus content. The analytical data for phosphorus, calcium and magnesium were 98.9%, 97.1% and 99.1% respectively, in reference to the theoretical values for the formula $C_6H_6O_{24}P_6Mg_4CaNa_2{\cdot}5H_2O$. Statical analysis indicated a good coincidence of the theoretical and experimental values. On the other hand, the observed values for the three elements by the conventional method were 92.4%, 86.8% and 93.8%, respectively, revealing a remarkable difference from the theoretical. 3) When sodium phytate was admixed with starch and subjected to the analysis of phosphorus, calcium and magnesium by the chelatometric method, their recovery was almost 100% 4) In order to confirm the accuracy of this method, phytic acid was reacted with calcium chloride and magnesium chloride in the molar ratio of phytic: calcium chloride: magnesium chloride=1 : 5 : 20 to obtain sodium phytate containing one calcium atom and four magnesium atoms per molecule of sodium phytate. The analytical data for phosporus, calcium and magnesium were coincident with those as determine d by the aforementioned method. The new method employing the dry process, ion exchange resin and chelatometric assay of phosphorus, calcium and magnesium is considered accurate and rapid for the determination of phytin.

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Solvent Extraction of Silver (Ag) by Cyanex 301 (Cyanex 301에 의한 은(Ag) 용매추출)

  • Cho, Yeon-Chul;Kang, Myeong-Sik;Ahn, Jae-Woo;Ryu, Ho-jin
    • Resources Recycling
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    • v.25 no.5
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    • pp.50-56
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    • 2016
  • Extraction behaviour of silver from nitric acid solutions by Cyanex 301 as an extractant was examined. Detailed studies have been conducted to evaluate the effect of different variables influencing the extraction such as concentration of nitric acid and extractant, phase ratio(O/A) and synergism of mixed extractant. The extraction behaviour of associated metals namely Ca, Al, Fe, Zn and Sr has been investigated. The extraction results show that Ag can be extracted effectively by Cyanex 301 and selectively extracted from 3.0M $HNO_3$ using 5% Cyanex 301. Impurity metals loaded in organic phase can be effective scrubbed by 4.0M HCl. Finally, pure silver solution can be obtained efficiently by thiourea as a stripping reagent.

Fabrication of Casting Pig Iron from Copper Smelting Slag by Carbothermic Reduction (탄소열환원 반응에 의한 동제련슬래그로부터 주철용 선철 제조 연구)

  • Choi, Moo-Sung;Choi, Dong-Hyeon;Wang, Jei-Pil
    • Resources Recycling
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    • v.28 no.3
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    • pp.59-67
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    • 2019
  • This study was conducted to fabrication pig iron containing copper and to reduce sulfur content pig iron. Roasting test was conducted for 1 ~ 9 hours at each temperature of $500^{\circ}C$, $700^{\circ}C$, and $900^{\circ}C$. In addition, the effect of oxygen partial pressure with 0.5, 0.8, and 1 atm was carried out for 30 minutes at $900^{\circ}C$. It was found that there is no effect to reduce sulfure in pig iron through roasting and oxygen partial pressures. The addition of CaO with 15 wt.% was found to reduce sulfur content up to 0.001 wt.%. The suitable temperature and reactive time for carbothermic reduction were $1600^{\circ}C$ and 30 minutes which shows the highest recovery rate of iron from the copper slag.

Effects of $K^+$ Channel Modulators on Extracellular $K^+$ Accumulation during Ischemia in the Rat Hippocampal Slice (해마절편의 허혈성 $K^+$ 축적에 대한 $K^+$채널 조절 약물의 작용)

  • Choi, Jin-Kyu;Chun, Boe-Gwun;Ryu, Pan-Dong
    • The Korean Journal of Physiology and Pharmacology
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    • v.1 no.6
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    • pp.681-690
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    • 1997
  • Loss of synaptic transmission and accumulation of extracellular $K^+([K^+]_O)$ are the key features in ischemic brain damage. Here, we examined the effects of several $K^+$channel modulators on the early ischemic changes in population spike (PS) and $[K^+]_o$ in the CA1 pyramidal layer of the rat hippocampal slice using electrophysiological techniques. After onset of anoxic aglycemia (AA), orthodromic field potentials decreased and disappeared in $3.3{\pm}0.22\;min$ $(mean{\pm}SEM,\;n=40)$. The hypoxic injury potential (HIP), a transient recovery of PS appeared at $6.0{\pm}0.25\;min$ (n=40) in most slices during AA and lasted for $3.3{\pm}0.43\;min$. $[K^+]_o$ increased initially at a rate of 0.43 mM/min (Phase 1) and later at a much faster rate (12.45 mM/min, Phase 2). The beginning of Phase 2 was invariably coincided with the disappearance of HIP. Among $K^+$ channel modulators tested such as 4-aminopyridine (0.03, 0.3 mM), tetraethylammonium (0.1 mM), NS1619 $(0.3{\sim}10\;{\mu}M)$, niflumic acid (0.1 mM), glibenclamide $(40\;{\mu}M)$, tolbutamide $(300\;{\mu}M)$ and pinacidil $(100\;{\mu}M)$, only 4-aminopyridine (0.3 mM) induced slight increase of $[K^+]_o$ during Phase 1. However, none of the above agents modulated the pattern of Phase 2 in $[K^+]_o$ in response to AA. Taken together, the experimental data suggest that 4-aminopyridine-sensitive $K^+$channels, large conductance $Ca^{2+}-activated$ $K^+$ channels and ATP-sensitive $K^+$ channels may not be the major contributors to the sudden increase of $[K^+]_o$ during the early stage of brain ischemia, suggesting the presence of other routes of $K^+$ efflux during brain ischemia.

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