• 제목/요약/키워드: Ca-source

검색결과 751건 처리시간 0.027초

한반도 서해안 배경지역 미세입자의 화학적 특성 연구 (Study on the Chemical Characteristics of $PM_{10}$ at Background Area in Korean Peninsula)

  • 방소영;백광욱;정진도;남재철
    • 한국환경보건학회지
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    • 제30권5호
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    • pp.455-468
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    • 2004
  • The purpose of this paper is to understand the time series and origin of a chemical component and to compare the difference during yellow sand episodes for analysis $PM_{10}$ chemical components in the region of west in Korean Peninsula, 1999-2001. An annual mean concentration of $PM_{10}$ is $29.1\;{\mu}g/m^3$. A monthly mean and standard deviation of $PM_{10}$ concentration are very high in spring but there is no remarkably seasonal variation. Also, water soluble ionic component of $PM_{10}$ be influenced by double more total anion than total cation, be included $NO_{3}^-\;and\;SO_{4}^{2-}$ for the source of acidity and $NH_{4}^+$ to neutralize. Tracer metals of $PM_{10}$ slowly increases caused by emitted for soil and ocean (Fe, Al, Ca, Mg, Na) and Zn, Pb, Cu, Mn for anthropogenic source. According to method of enrichment factor (E.F) and statistics, assuming that the origin of metal component in $PM_{10}$ most of element in the Earth's crust e.g. Mg, Ca, Fe originates soil and Cu, Zn, Cd, Pb derives from anthropogenic sources. The ionic component for $Na^{+}\;Cl^-,\;Mg^{2+}\;and\;Ca^{2+}$ and Mg, Al, Ca, Fe originated by soil component largely increase during yellow sand period and then tracer metal component as Pb, Cd, Zn decrease. According to factor analysis, the first group is ionic component ($Na^+,\;Mg^{2+},\;Ca^{2+}$) and metal component (Na, Fe, Mn and Ni) be influenced by soil. The second group, Mg, Cr also be influenced by soil particle.

Utilization of Dietary Nutrients, Retention and Plasma Level of Certain Minerals in Crossbred Dairy Cows as Influenced by Source of Mineral Supplementation

  • Gowda, N.K.S.;Prasad, C.S.;Ashok, L.B.;Ramana, J.V.
    • Asian-Australasian Journal of Animal Sciences
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    • 제17권2호
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    • pp.221-227
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    • 2004
  • Nutrient utilization and plasma level of minerals were studied in lactating crossbred cows fed diet supplemented from different source of minerals. Twelve crossbred cows of first to third lactation during their mid stage of lactation were distributed equally under two groups and were fed concentrate mixture, green fodder (para grass) and finger millet straw as per requirement. Cows in group I were fed concentrate mixture supplemented with 1% mineral mixture whereas cows in group II were not supplemented with mineral mixture in the concentrate mixture but were offered additional quantity of green fodder (1 kg DM/cow/day) to compensate for the requirement of minerals. Balance study conducted towards the end of 120 days of feeding experiment indicated that the total dry matter intake in both the groups did not differ significantly. The cows in group II offered additional quantity of green fodder consumed significantly (p<0.05) more of green fodder (5.11 vs. 4.51 kg /animal/day) and the cows in group I consumed significantly (p<0.01) more of finger millet straw (1.71 vs. 0.92 kg/animal/day). The digestibility of major nutrients did not differ between the groups except for ether extract which was significantly (p<0.05) lower in cows fed additional green fodder. The total daily intake of P, Cu, Fe and Co did not differ significantly in both the groups whereas significantly higher intakes of Ca, Mg, Zn and Mn were observed in cows supplemented with inorganic source of minerals. However, supplementation through both the sources could meet the mineral requirement in group I and group II. The gut absorption (%) of all the minerals was comparable between the groups except for Mg which was significantly (p<0.05) higher in cows supplemented mineral mixture. The net retention of all the minerals was significantly more in the group supplemented with inorganic source of minerals. Except for P, Mg and Co the retention as percentage of total intake was comparable for all minerals in both the groups. Irrespective of source of mineral supplementation the average monthly blood plasma mineral levels (Ca, P, Mg, Cu, Zn, Fe) were within the normal range and comparable between the groups. Lower level of Cu observed at the start of the experimental feeding in both the groups increased with the advancement of supplemental feeding. The plasma Zn and Fe content in cows of both the groups did not vary. The blood plasma level of some minerals (Ca, P, Mg and Cu) was significantly higher towards the end of experimental feeding as compared to the initial values due to the reduction in milk yield with advancement of lactation or due to supplemental effect of minerals. It could be concluded that supplementation of minerals through inorganic source is better utilized in terms of retention as compared to green fodder (para grass), which is a moderate source of most nutrients.

한반도의 황사 관측현황 및 배경지역 미세먼지의 화학적 조성에 관한 연구 (Study on the Yellow Sandy Dust Phenomena in Korean Peninsula and Chemical Compositions in Fine Particles at Background Sites of Korea.)

  • 백광욱;정진도
    • 환경위생공학
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    • 제19권4호
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    • pp.9-18
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    • 2004
  • In this study, the observation data for the yellow sandy dust phenomena from the year 1999 to 2003 at background sites in Korea were collected at Global Atmospheric Observatory at An-Myeon island and its temporal variation were analyzed. The chemical characteristics of the fine particles were also analyzed in order to evaluate sources of the yellow sandy dust particles. The results showed that the monthly average mass concentration of the fine particles was the highest in springtime and the lowest in summertime in general. The magnitude of its variation was also the highest in March in which the occurrence of yellow sandy dust was the most frequent and thus the number of samples was the largest, while the lowest in June through September. The yearly variation of ion components contributions to the total mass concentration of the fine particles was slowly decreasing, showing that $63\%$ in 1999, $59\%$ in 2000 and $56\%$ in 2003. The most prevalent ion components in the fine particles were found to be $NO_3$ and $SO_4^{2-}$, which are known to be source materials of acidic precipitation, and $NH_4^+$, a neutralizing material of the acid precipitation. Relative proportion of metal components in the fine particles was calculated as $14\%$ in average, and their concentrations are in an order of Fe > Al > Na > Ca > Zn > Pb > Cu > Mn > Ni > Cd > Cr > Co > U. The results indicated that main sources of the metals was soil-originated Fe, Al, Ca, and Mg, and the contribution of anthropogenic air Pollution-originated Zn, Pb, Cu, Mn were also high and keep slightly increasing. Statistical analysis showed that the chemical components could be divided into soil-originated group of Mg, Al, Ca, Fe, and Mn and air pollution-originated group of $NO_3$, Zn, Pb, and they are occupying more than $60\%$of all the components in the dusty sand. The results explain that An-Myeon island is more influenced by soil-originated source than ocean-originated one and also the influencing strength of anthropogenic poilution-originated source is less than $50\%$ of that of soil-originated sources. Compared to non-yellow sandy period, the yellow sandy dust period showed that the amounts of soil-originated $Mg^{2+}$ and $Ca^{2+}$ and ocean-originated $Na^+$ and $Cl^-$ were increased to more than double and the metals of Mg, Al, Ca, Fe were also highly increased, while micro metal components such as Pb, Cd, Zn, which have a tendency of concentrating in air, were either decreased or maintained at nearly constant level. In the period of yellow sandy dust, a strong positive correlation was observed between water soluble ions and between metals in terms of its concentration, respectively. Factor analysis showed that the first group being comprised of about $43\%$ of the total inorganic components was affected by soil and they are ions of $Na^+,\;Mg^{2+}\;and\;Ca^{2+}$ and metals of Na, Fe, Mn and Ni. The result also showed that the metals of Mg and Cr were classified as second group and they were also highly affected by soil sources.

Thyroid Hormone-Induced Alterations of $Ca^{2+}-ATPase$ and Phospholamban Protein Expression in Cardiac Sarcoplasmic Reticulum

  • Kim, Hae-Won;Noh, Kyung-Min;Park, Mi-Young;Lee, Hee-Ran;Lee, Eun-Hee
    • The Korean Journal of Physiology and Pharmacology
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    • 제3권2호
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    • pp.223-230
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    • 1999
  • Alterations of cardiovascular function associated with various thyroid states have been studied. In hyperthyroidism left ventricular contractility and relaxation velocity were increased, whereas these parameters were decreased in hypothyroidism. The mechanisms for these changes have been suggested to include alterations in the expression and/or activity levels of various proteins; ${\alpha}-myosin$ heavy chain, ${\beta}-myosin$ heavy chain, ${\beta}-receptors,$ the guanine nucleotide-binding regulatory protein, and the sarcolemmal $Ca^{2+}-ATPase.$ All these cellular alterations may be associated with changes in the intracellular $Ca^{2+}$ concentration. The most important regulator of intracellular $Ca^{2+}$ concentration is the sarcoplasmic reticulum (SR), which serves as a $Ca^{2+}$ sink during relaxation and as a $Ca^{2+}$ source during contraction. The $Ca^{2+}-ATPase$ and phospholamban are the most important proteins in the SR membrane for muscle relaxation. The dephosphorylated phospholamban inhibits the SR $Ca^{2+}-ATPase$ through a direct interaction, and phosphorylation of phospholamban relieves the inhibition. In the present study, quantitative changes of $Ca^{2+}-ATPase$ and phospholamban expression and the functional consequences of these changes in various thyroid states were investigated. The effects of thyroid hormones on (1) SR $Ca^{2+}$ uptake, (2) phosphorylation levels of phospholamban, (3) SR $Ca^{2+}-ATPase$ and phospholamban protein levels, (4) phospholamban mRNA levels were examined. Our findings indicate that hyperthyroidism is associated with increases in $Ca^{2+}-ATPase$ and decreases in phospholamban levels whereas opposite changes in these proteins occur in hypothyroidism.

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외부화염에 의해 소손된 비닐 코드의 단락 특성에 관한 연구 (A Study on the Short-Circuit Characteristics of Vinyl Cords Damaged by External Flame)

  • 최충석;김향곤;송길목
    • 한국화재소방학회논문지
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    • 제18권4호
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    • pp.72-77
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    • 2004
  • 본 연구에서는 외부화염에 의한 비닐코드의 손상에 따른 단락 진행과정, 외형 및 표면 구조,조성 변화 등 단락 특성을 연구하였다. 초고속이미지시스템(HSIS)을 이용하여 단락과정을 분석한 결과, 열적피로에 의해 피복이 소실되면서 전선 도체가 닿아 수회에 걸쳐 단락이 발생하였으며. 실체현미경과 SEM을 이용하여 외형과 표면구조를 분석한 결과, 전원 측 전선은 두 가닥 모두에 용융흔이 형성되었으며 V자형의 흠을 나타냈다. 부하 측 전선의 용융흔은 전원 측 보다 큼을 알 수 있었다. EDX에 의한 조성분석 결과. 전원 측에서는 Cu와 O가 검출되었으며 부하 측에서는 Cu와 O 이외에 피복재료인 Cl과 Ca를 검출할 수 있었다. 이와 같은 실험과 분석결과를 바탕으로 전기화재의 원인을 규명하는데 많은 도움이 될 것으로 기대한다.

LiCl-$CaCl_2-Zn(NO_3)_2$ 수용액을 사용하는 흡수 2중효용 시스템에서 태양열을 증발기 열원으로 사용하는 난방기의 열역학적 해석 (Thermodynamic Analysis of a Double-Effect Absorption Heating System Using Water-LiCl-$CaCl_2-Zn(NO_3)_2$ Solution at Solar Evaporator Heating)

  • 원승호
    • 한국태양에너지학회 논문집
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    • 제27권3호
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    • pp.87-94
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    • 2007
  • In this paper, with water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture which utilizes solar energy at the evaporator heat source, a thermodynamic analysis was performed to provide design data for a double-effect absorption heating system. A comparative study of the water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture against the water-LiBr pair was conducted by a computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water-LiCl-$CaCl_2-Zn(NO_3)_2$ mixture than for the water-LiBr pair, and FR is lower for the former.

EFFECTS OF CAFFEINE AND 2,5-DI-(tert-BUTYL)-1,4-BENZOHYDROQUINONE ON BLUE LIGHT-DEPENDENT $H^+$ PUMPING IN GUARD CELL PROTOPLASTS FROM Vicia faba L.

  • Goh, Chang-Hyo;Shimazaki, Ken-Ichiro
    • Journal of Photoscience
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    • 제4권2호
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    • pp.35-40
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    • 1997
  • The sensory transduction processes of blue light in guard cells have been suggested the involvement of Ca$^{2+}$/calmodulin-dependent myosin light chain kinase (MLCK) or MLCK-like proteins. The source of Ca$^{2+}$ required for the signal transduction process was investigated in guard cell protoplasts (GCPs). The GCPs showed the typical H$^+$ pumping activity by blue light (200 $\mu$mol m$^{-2}$ s$^{-1}$) and fusicoccin (10 $\mu$M) under background red light (600 $\mu$mol m$^{-2}$ s$^{-1}$). The blue light-dependent H$^+$ pumping was not significantly affected by the externally changed Ca$^{2+}$ concentrations. The addition of 1 mM Ca$^{2+}$ in the bathing medium ratherly inhibited the H$^+$ pumping. In contrast, the blue light-dependent H$^+$ pumping was inhibited by caffeine and 2,5-di-(tert-butyl)-1,4-benzohydroquinone (BHQ), inhibitor of C$^{2+}$-ATPase in endoplasmic reticulum (ER) without inhibiting the H $^+$ pump. The inhibition by caffeine and BHQ was fully reversible. The extent of inhibition by caffeine and BHQ was larger when they were added together than when added separately. The results suggest that Ca$^{2+}$ required for the blue light-dependent H$^+$ pumping may be released from the intracellular Ca$^{2+}$ stores, probably ER in guard cells.

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Effect of Exchangeable Cation on Radionuclide Diffusion In Compacted Bentonite

  • Park, Jong-Won;Park, Hyun-Soo;Dennis W. Oscarson
    • Nuclear Engineering and Technology
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    • 제28권3호
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    • pp.274-279
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    • 1996
  • Diffusion coefficient is a critical parameter for predicting radiological source term(migration rate and flux of radionuclide) through given near field conditions in spent fuel or high level waste repository. The effect of exchangeable cation-$Na^+$ and $Ca^{2+} - on the diffusion of $I^- \;and^3H$ (as HTO) in compacted bentonite was examined using a through-diffusion method. Bentonite material used here was compacted to a density of 1.3 Mg/m$^3$, and Na-bentonite was saturated with a solution of 100 mol NaCl/m$^3$ and Ca-bentonite with 50 $mol\;CaCl_2$/m$^3$. The results show that effective diffusion coefficients are generally higher by a factor of two to five in Ca-than Na-clay. This is attributed to the larger particle size of Ca-compared to Na-bentonite; hence, Ca-bentonite has a greater proportion of relatively large pores, which make a greater contribution to mass transport than small pores. Although the nature of the exchangeable cation affects mass diffusion in compacted bentonite, the effect is small and not likely to influence performance assessment modeling of compacted bentonite-based barriers.

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환경조건(環境條件)이 대두(大豆) 탄저병균(炭疽病菌)(Colletotrichum truncatum)의 부착기형성(附着器形成)에 미치는 영향(影響) (Effect of Environmental Factors on Appressorium Formation of Colletotrichum truncatum)

  • 도은수;백수봉
    • 한국균학회지
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    • 제15권3호
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    • pp.142-148
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    • 1987
  • 대두(大豆) 탄저병(炭疽病)(C. truncatum)을 공시(供試)하여 In vitro에서 광(光), pH 및 영양원(營養源)과 In vivo에서 시비수준(施肥水準)(P, K 및 Ca)이 부착기형성(附着器形成)에 미치는 영향(影響)을 조사(調査)한 바는 다음과 같다. 1. 3시간(時間) 및 6시간(時間)이 지난후의 조사(調査)에 따르면 광처리(光處理)를 한 것이 암처리(暗處理)를 한 것보다 부착기형성률(附着器形成率)이 양호(良好)하였다. 그러나 시간이 진행(進行)됨에 따라서는 각처리(各處理)에서 부착기형성률(附着器形成率)이 높아졌다. 2. 부착기형성(附着器形成)에 적정 pH는 $pH\;6{\sim}8$이었다. 3. 탄소원(炭素源) 및 질소원(窒素源) 공(供)히 무처리구(無處理區)에서 부착기형성률(附着器形成率)이 양호(良好)하였고 농도(濃度)가 높을수록 억제되는 경향이었으며 질소원(窒素源)에 비(比)하여 탄소원(炭素源)에서의 부착기형성률(附着器形成率)이 양호(良好)하였다. 그리고 시간(時間)이 경과함에 따라서 부착기형성률(附着器形成率)이 상승했다. 4. 3시간(時間) 경과후의 조사(調査)에서는 인산 및 칼륨처리(處理)는 증시(增施)했을 경우 다소 부착기형성(附着器形成)이 억제되었으나, 칼슘처리(處理)에 있어서는 무비구(無肥區)<표준비구(標準肥區)<2배비구(培肥區)의 순(順)으로 부착기형성(附着器形成)이 상당히 억제되는 경향이었다. 그러나 시간(時間)이 경과함에 따라서는 부착기형성률(附着器形成率)이 시비수준(施肥水準)과 관계없이 상당히 증가(增加)됨을 보였다.

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The Effects of Alkali Sulfate on the Hydration of a C3A−CaSO4⋅2H2O System

  • Lee, Jong-Kyu;Chu, Yong-Sik;Kwon, Choon-Woo
    • 한국세라믹학회지
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    • 제44권9호
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    • pp.471-476
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    • 2007
  • The hydration mechanism of the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system in the presence of alkali sulfates has been investigated. The early hydration rate of $3CaO{\cdot}Al_2O_3$ was accelerated by the addition of $Na_2SO_4$ and $K_2SO_4$. This is closely related to the formation of syngenite $(CaSO_4{\cdot}K_2SO_4{\cdot}H_2O)$, and the U-phase added $K_2SO_4$ and $Na_SO_4$ in the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system, respectively. The formation of the rigid syngenite and U-phase structure led to rapid setting and decreases the sulfate content in the liquid phase of the hydrating cement to the extent that it cannot adequately retard the hydration of $3CaO{\cdot}Al_2O_3$. In case of the alkali sulfate not added to the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system, the ettringite was transformed to monosulfoaluminate immediately after the consumption of gypsum. However, when the alkali sulfates were added to this system, the ettringite did not transform to monosulfoaluminate immediately even though the gypsum was completely consumed. There was a stagnation period to transform to the monosufoaluminate after the consumption of gypsum because the syngenite and U-phase remained as the sulfate source.