• Title/Summary/Keyword: Ca-형

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Synthesis and Crystallization of Amorphous Calcium Carbonate by Gas-Liquid Reaction of System Ca($OH_2 O$)-$H_2$-$CO_2$ (Ca($OH_2$)-$H_2 O$-$CO_2$계의 기액반응으로부터 비정질 탄산칼슘의 합성 및 결정화)

  • Im, Jae-Seok;Kim, Ga-Yeon;Im, Goeng
    • The Journal of Engineering Research
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    • v.5 no.1
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    • pp.73-87
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    • 2004
  • The synthesis and crystallization of amorphous calcium carbonate($CaCO_3$.$nH_2 O$) obtained from gas-liquid reaction between aqueous solution of calcium hydroxide and carbon dioxide at 15~$50^{\circ}C$ are investigated by electrical conductometry, XRD and TEM. The results are as follows: The initial reaction products prior to the formation of precipitated calcium carbonate is amorphous calcium carbonate. The electrical conductivity values in the slurry are decreased during the formation of amorphous calcium carbonate which covers particle surface of calcium hydroxide and retard the dissolution of calcium hydroxide into the solution. that amorphous calcium carbonate is unstable in the aqueous solution and crystallizes finally to calcite by the through-solution reaction. While amorphous calcium carbonate crystallizes into chain-like calcite, the conductivity values are recovered rapidly and the apparent viscosity of slurry containing higher concentration of calcium hydroxide increase. At below pH 9.5, chain-like calcite separates into individual particles to form precipitated calcium carbonate. The formation and synthetic temperature range of amorphous calcium carbonate is most suitable a primary decreasing step(a-step) at $15^{\circ}C$ in the electrical conductometry.

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Distributed Certificate Authority under the GRID-Location Aided Routing Protocol (Ad hoc 네트워크에서 GRID-Location Aided Routing 프로토콜을 이용한 분산 CA 구성)

  • Lim, Ji-Hyung;Kang, Jeon-Il;Koh, Jae-Young;Han, Kwang-Taek;Nyang, Dae-Hun
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.15 no.6
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    • pp.59-69
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    • 2005
  • Ad hoc network is the network which can be considered without a pre-constructed infrastructure, and a mobile node can join the network freely. However, the participation of the mobile nodes to the ad hoc network brings up much burden of re-computation for new routes, because it leads to losing the connection frequently. And, also, it causes serious security problem to be broadcasted wrong information by the malicious user. Therefore, it needs authentication against the mobile nodes. To make that Possible, we have two methods: single CA and distributed CA. In the case of CA method, the wireless network can be collapsed owing to expose the CA, but still the distributed CA method is a little more safe than previous one because it needs attacks toward a lot of CAs to collapse the network We can consider Secret Share scheme as the method that constructs the distributed CA system, but it is weak when the network size is too large. In this paper, we suggest hierarchical structure for the authentication method to solve this problem, and we will show the results of simulation for this suggestion.

Studies on the Change of Mineral Nutrients Content in Rice Plant in the Ripening Process I. Translocation and Cumulation of Mineral Nutrients in Different Parts of Rice Plant in the Ripening Process (등숙 진전에 따른 도체내 부위별 양분 동태에 관한 연구 I. 도체내 부위별 무기양분의 동태)

  • Lee, Yang-Ku;Lim, Moo-Sang;Im, Byeong-Gi
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.31 no.2
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    • pp.195-203
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    • 1986
  • In order to clarify the trend of change in mineral nutrients in rice plant on various ripening process, P$_2$O$\sub$5/, K$_2$O, MgO, CaO, SiO$_2$ and ash contents were determined for the grain, internode, leaf-5heath and leaf blade respectively for 9 times at an week interval after heading. Four rice cultivars with different maturity and ecotype were grown under normal cultural conditions for the trial. The contents of mineral nutrients in the brown rice were in the order of Ash, P$_2$O$\sub$5/, K$_2$O and MgO. CaO and SiO$_2$ were found in minute quantity in the brown rice. The hull contained SiO$_2$ in large quantity, and it also contained the mineral nutrients in the order of K$_2$O, P$_2$ O$\sub$5/O. The CaO content of hull was extremely minute.

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Characteristics of thick film Co2 sensors attached with Na2CO3-CaCO3 auxiliary phases (Na2CO3-CaCO3 보조상을 사용한 후막형 Co2 센서의 특성연구)

  • Shim, H.B.;Choi, J.W.;Kang, J.H.;Yoo, K.S.
    • Journal of Sensor Science and Technology
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    • v.15 no.3
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    • pp.168-172
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    • 2006
  • Potentiometric $CO_{2}$ sensors were fabricated using a NASICON ($Na_{1+x}Zr_{2}Si_{X}P_{3-X}O_{12}$, 1.8 < x < 2.4) thick film and auxiliary layers. The powder of a precursor of NASICON with high purity was synthesized by a sol-gel method. By using the NASICON paste, an electrolyte was prepared on the alumina substrate by screen printing and then sintered at $1000^{\circ}C$ for 4 h. A series of $Na_{2}CO_{3}-CaCO_{3}$ auxiliary phases were deposited on the Pt sensing electrode. The electromotive force (emf) values were linearly dependent on the logarithm of $CO_{2}$ concentration in the range between 1,000 and 10,000 ppm. The device attached with $Na_{2}CO_{3}-CaCO_{3}$ (1:2 in mol.%) showed good sensing properties in the low temperatures.

Crystal growth $Ca_{3}NbGa_{3}Si_{2}O_{14}$ compound for the piezoelectric application (압전응용을 위한 $Ca_{3}NbGa_{3}Si_{2}O_{14}$ 화합물의 단결정 성장)

  • 강용호;정일형;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.4
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    • pp.148-153
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    • 2001
  • New piezoelectric $Ca_{3}NbGa_{3}Si_{2}O_{14}$ (CNGS) single crystal was grown using the Czochralski technique. The crystal structure of CNGS was found to be isostructural with $A_{3}BC_{3}D_{2}O_{14}$. The unit cell parameters were a=8.087 and c=4.983 and the space group was P321. The distribution of each cation was found to be ordered in each site. Some piezoelectric properties of CNGS are showed.

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The Solidification of $CO_2$ by Using Waste Cement and Inorganic Waste By-Products (폐(廢)콘크리트 미분말(微粉末)과 무기성(無機性) 폐부산물(廢副産物)을 이용(利用)한 $CO_2$ 고형화(固形化))

  • Ahn, Ji-Whan;Yoo, Kwang-Suk
    • Resources Recycling
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    • v.18 no.3
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    • pp.3-10
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    • 2009
  • This paper will introduce the study which is the solidification and reduction of $CO_2$ green house gas, by using inorganic industrial wastes such like waste cement, steel making slag, incineration ash and so on. These inorganic wastes contain a large quantity of CaO content in common, which is easily reacted with CaO resulting in formation of $CaCO_3$. It will be suggested in this study that the necessary of the reduction and solidification of $CO_2$ gas with using industrial inorganic wastes is for building the Korea carbon storage model in this study.

Fabrication of ISFETs for Measuring Ion-Activities in Blood (혈액내의 이온활동도 측정을 위한 ISFETs의 제조)

  • Son, Byeong-Gi;Lee, Jong-Hyeon;Sin, Jang-Gyu
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.22 no.6
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    • pp.28-33
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    • 1985
  • ISFETS for physiological applications have been developed using the techniques for integrated circuit fabrication. The silicon nitride layer was used as a H+ sensing membrane. However, K+, Na+ and Ca++ sensing ISFETS were fabricated by forming tach specification sensing membranes over the silicon nitride gate insulator. The sensitivities of the fabricated devices were very good. The typical values of measured sentivities were iEmV/pH, 42mv1, pH,5 gmV/pNa and 28mv1p0a. However, the selectivity and stability should be somewhat improved for practical physiological uses with good reliability. The response times were, less than one second, short enough for the practical uses in physiological applications.

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Effect of Seed Mixture on Forage Yields and Botanical Composition at an Altitude of 400 m in Jeju island (표고 400m 제주 중산간 지역에서 혼합조합별 초지 생산성 및 식생구성)

  • Chae, Hyun Seok;Kim, Nam Young;Woo, Jae Hoon;Shin, Moon Cheol;Son, Jun Kyu;Seong, Pil Nam;Lee, Wang Shik;Kim, Si Hyun;Hwang, Kyung Jun;Kim, Young Jin;Park, Nam Gun
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.37 no.1
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    • pp.19-27
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    • 2017
  • The objective of this study was to determine the growth characteristics of cool (C1) and warm season grasses (C2) in pastures mixed with C1 and C2 at an altitude of 400 m in Jeju island to establishing pasture suitable for grazing horses and to evaluate the effect of pastures mixed with tall and short type grasses on the intake characteristics of horses. C1 used in this study was Kentucky bluegrass, redtop (short type grass) and tall type grasses were orchardgrass and tall fescue, respectively. Treatments of this study were consisted of four groups and the short type grass used in pastures mixed with C1 and C2 was mainly bermudagrass. Four treatment groups were follow as; Treatment 1 (bermudagrass + Kentucky bluegrass + redtop) 2) Treatment 2 (bermudagrass + tall fescue + orchardgrass) 3) Treatment 3 (Kentucky bluegrass + redtop) 4) Treatment 4 (tall fescue + orchardgrass). Bermudagrass was a little winter killing and inhibition of plant growth at an altitude of 400 m. Plant heights in pastures mixed with C1 and C2 were grown better than that in pastures mixed with C1. Especially, plant height in Treatment 4 was higher than other treatments. Dry matter yield was in the following order: Treatment 4> Treatment 3> Treatment 2> Treatment 1. Dry matter yield in pastures mixed with C1 increased as compared with pastures mixed with C1 and C2. Dry matter yield in Treatment 3 was higher than other treatments. In the first investigation regarding vegetation distribution, bermudagrass ratios among grasses in Treatment 1 and Treatment 2 were 11.7 and 13.3%, respectively. The growth of bermudagrass in winter was low due to the cold damage. However the growth of Kentucky bluegrass, redtop, tall fescue and orchardgrass was good. In the second investigation, bermudagrass ratios among grasses in Treatment 1 and Treatment 2 were 5.0 and 11.7%, respectively. Growth of forage in the second investigation was poor as compared to the first investigation. nutritive values(crude protein content, neutral detergent fiber content, acid detergent fiber content, digestibility) were good in pastures mixed with C1 Especially, nutritive values in pastures mixed with tall was higher than those of pastures mixed short grasses. P content among minerals in Treatment 1 was higher than other groups. However, the content of Ca, Mg and Mn were lower. The contents of Ca, K, Mg, Na, Cu, Zn and Fe in Treatment 2 were higher. However, the contents of K, Mg, Na, Cu, Zn and Fe in Treatment 3 were lower. Therefore, we suggest that cool season grasses with short grasses were sowed to establishing pasture suitable for grazing horses at an altitude of 400 m in Jeju island.

Phosphorus Removal in Wastewater Using Activated Ca-Loess Complex

  • Kang, Seong Chul;Lee, Byoung Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.5
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    • pp.713-721
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    • 2012
  • In many instances phosphorus is a limiting factor for eutrophication in streams, and lakes. Because wastewater treatment plant itself may be the main phosphorus source in a natural water body, removal of phosphorus in final effluent of wastewater treatment processes is required. Amongst various technologies for phosphorus removal in wastewater, adsorption technology was investigated using activated Ca-loess complex. Ca was added in loess to enhance adsorption capacity and intensity of phosphorus. Ca added loess was activated at a high temperature of $400^{\circ}C$ which turned out to be the optimum temperature. Activated Ca-loess complex below $400^{\circ}C$ had not enough strength to be applied as an activated Ca-loess pallet column in wastewater treatment process. Ca-loess complex which activated above $400^{\circ}C$ lost its adsorption capacity as the loess surface was glassified when the activation temperature reached above $400^{\circ}C$20. Even if adsorption capacity of activated Ca-loess was not very high due to the lack of abundant pores on its surface, adsorption intensity was still high because it was activated with added Ca in loess. Activated loess was made by pallets. The activated loess pallets were filled in a column, and were applied in wastewater treatment process. Using an activated Ca-loess pallet column, total phosphorus (T-P) was reduced from about 0.5 mg/l to lower than 0.1 mg/l in wastewater treatment, and ionic phosphorus (phosphate) was completely removed for the four months of pilot plant operation.

Transient Liquid Phase Sintering of LCCC(La0.8Ca0.2Cr0.9Co0.1O3-δ) with the Addition of CaCrO4 (CaCrO4 첨가에 따른 LCCC(La0.8Ca0.2Cr0.9Co0.1O3-δ)의 전이액상소결거동)

  • Lee, Ho-Chang;Kang, Bo-Kyung;Lee, Joon-Hyung;Heo, Young-Woo;Kim, Jae-Yuk;Kim, Jeong-Joo
    • Journal of the Korean Ceramic Society
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    • v.49 no.2
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    • pp.197-203
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    • 2012
  • In this study, in order to improve densification of $La_{0.8}Ca_{0.2}Cr_{0.9}Co_{0.1}O_{3-\delta}$ (LCCC), which is known for one of the most proper candidate interconnector materials in the solid oxide fuel cells, $CaCrO_4$ was prepared via solid oxide synthesis route and added to the LCCC with different amount and particle sizes. As the amount of the $CaCrO_4$ increased, porosity of the sintered samples increased, and the pore size was proportional to the particle size of the $CaCrO_4$. This supports the fact that the $CaCrO_4$ phase forms liquid during sintering and permeate into the matrix leaving behind large pores. Then the liquid reacts with the matrix through the solid solution. However, when the samples were sintered with a slow ramp up rates, the porosity decreased. This is thought to be caused by the progressive solid solution of $CaCrO_4$ before the temperature reach to the melting temperature and forms a fluent amount of liquids. The sintering behavior of the LCCC with the addition of $CaCrO_4$ was analyzed through the transient liquid phase sintering on the basis of the microstructure observation and phase identification by x-ray diffraction.