• 한국산업안전학회:학술대회논문집
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• 한국안전학회 1998년도 추계 학술논문발표회 논문집
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• pp.329-334
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• 1998

난연성을 지닌 고분자 물질중 Chlorosulfonated Polyethylene(CSPE; Hypalon)은 Polyethylene에 염소와 황을 첨가한 것으로 염소를 첨가함으로써 기름과 화염에 대한 저항성을 향상시키고, 황 또한 기름, 화염에 대한 저항을 향상시킬 뿐 아니라 인장강도를 크게 해서 기계적 강도를 향상시킨 것이다. CSPE는 염소량의 등급에 따라 Coating재료, 호스 구조재, Wire와 Cable의 피복재료등 여러 가지 용도로 많이 쓰이고 있으며 특히 염소함량이 35%인 CSPE(Hypalon-40)의 경우 열저항과 압출 특성이 우수하기 때문에 Cable의 피복재료로 많이 쓰이고 있다.

• Macromolecular Research
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• 제11권6호
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• pp.506-510
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• 2003

A Zn ion-coated nanosilica filler has been developed and tested, in chlorosulfonated polyethylene (CSPE) and polychloroprene (CR), as a vulcanizing activator, cum was reinforcing filler. In this study, ZnO was replaced by the Zn ion-coated nanosilica filler with an aim of studying the dual role of this nanofiller in CSPE and CR. In the case of CSPE vulcanizates, the presence of MgO deteriorated the state and rate of cure when the Zn ion-coated nanosilica filler was used, but in the case of CR it improved the state of cure and enhanced the modulus and tensile strength. The Zn ion-coated filler proved to be a better reinforcing-cum-curing agent than was externally added ZnO and NA-22 also proved to be a better curative in the presence of the Zn ion-coated nanosilica filler for both CSPE and CR.

• 방사선산업학회지
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• 제5권3호
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• pp.237-242
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• 2011

In this research, the radiation resistance of ethylene propylene rubber (EPR) and chlorosulfonated polyethylene (CSPE) which can be used as a insulating materials of for electrical cable in the nuclear power plant were investigated. EPR and CSPE were irradiated by ${\gamma}$-ray at various doses ranging from 50 to 500 kGy at room temperature in air. The irradiated EPR and CSPE was investigated in terms of activation energy, mechanical properties, and oxidation stability. The experimental results revealed that CSPE exhibited the higher radiation resistance in comparison to that of EPR.

• 한국전기전자재료학회논문지
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• 제26권8호
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• pp.597-601
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• 2013

The accelerated thermal aging of a CSPE were carried out for 0, 80.82, 161.63 days at $100^{\circ}C$, which are equal to 0, 40 and 80 years of aging at $50^{\circ}C$, respectively. The volume electrical resistivities of the seawater and freshwater flooding were measured through 3-terminal circuit diagram. The volume electrical resistivities of the 0y, 40y and 80y were $2.454{\times}10^{13}{\sim}1.377{\times}10^{14}{\Omega}{\cdot}cm$, $1.121{\times}10^{13}{\sim}7.529{\times}10^{13}{\Omega}{\cdot}cm$ and $1.284{\times}10^{13}{\sim}8.974{\times}10^{13}{\Omega}{\cdot}cm$ at room temperature, respectively. The dielectric constant of the 0y, 40y and 80y were 2.922~3.431, 2.613~3.285 and 2.921~3.332 at room temperature, respectively. It is certain that the ionic ($Na^+$, $Cl^-$, $Mg^{2+}$, ${SO_4}^{2-}$, $Ca^{2+}$, $K^+$) conduction current was formed by the salinity of the seawater. The volume electrical resistivity of the cleaned CSPE via freshwater trends slightly upward with the number of dried days at room temperature. As a result, the $CH_2$ component of thermally accelerated aged CSPE decreased after seawater and freshwater flooding for 5 days respectively, whereas the atoms such as Cl, O, Pb, Al, Si, Sb, S related with the conducting ion ($Na^+$, $Cl^-$, $Mg^{2+}$, ${SO_4}^{2-}$, $Ca^{2+}$, $K^+$) component increased relatively.

• 전기학회논문지
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• 제64권12호
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• pp.1724-1729
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• 2015

Chlorosulfonated polyethylene (CSPE) was not flooded seawater and flooded seawater & freshwater for 5 days, respectively, and these samples are referred to as BSF(before seawater flooding) and ASFF(after seawater & freshwater flooding), respectively. The apparent density, dissipation factor, relative permittivity, melting temperature, dielectric breakdown time and increased time of applied voltage are higher than those of BSF, but the insulating resistance, dielectric strength, percent elongation and glass transition temperature of ASFF are lower than those of BSF. The differential temperature of those is $0.026{\sim}0.028(^{\circ}C)$ after AC and DC voltage is applied to ASFF, respectively, and the differential temperature of those is $0.013{\sim}0.037(^{\circ}C)$ after AC and DC voltage is applied to BSF, respectively. In the case AC and DC voltage is applied to ASFF as well as BSF, the variations in temperature of AC voltage are higher than those of DC voltage. It is investigated that dielectric loss due to dissipation factor ($tan{\delta}$) is related to electric dipole conduction current. It is certain that the ionic (electron or hole) leakage current was increased by conducting ions such as $Na^+$, $Cl^-$, $Mg^{2+}$, $SO_4^{2-}$, $Ca^{2+}$ and $K^+$, those are related to cured atoms of O and S that relatively increased after seawater flooding.

• 한국전기전자재료학회논문지
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• 제32권6호
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• pp.490-495
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• 2019

This study performs the thermal aging of chlorosulfonated polyethylene (CSPE) for 807.36 and 1,614.48 hours at $110^{\circ}C$, which is equivalent to 40 and 80 years of aging at $50^{\circ}C$ in nuclear power plants, respectively. Flat-type CSPEs were soaked in seawater for five days and then dried for five days at room temperature. Furthermore, the soaked CSPEs were cleaned for 5 days with fresh water and dried for 1,100 days at room temperature. Through this process, the log IV of the CSPEs decreases, whereas the dissipation factor of the CSPEs increases as thermally accelerated aged years increase at the measured frequency. Although the phase degree of the response voltage versus excitation voltage of the CSPEs increases, that of the response current versus excitation voltage decreases with the thermally accelerated aging. The thermal conductivity of the CSPEs increases slightly, but the thermal diffusivity does not vary with the thermally accelerated aged year increase. The displacement of the compressive strength of the CSPEs decreases gradually as the thermally accelerated aged years increase.