• Title/Summary/Keyword: CS model

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Comparison of Cs and Sr Ion Adsorption Capacities with Crystallinity of Zeolitic Materials Synthesized from Coal Fly Ash under Low-Alkaline Conditions (석탄 비산재로부터 저알칼리 조건에서 합성된 제올라이트 물질의 결정화도에 따른 Cs 및 Sr 이온의 흡착 용량 비교)

  • Choi, Jeong-Hak;Lee, Chang-Han
    • Journal of Environmental Science International
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    • v.31 no.2
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    • pp.171-180
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    • 2022
  • Zeolitic material, Z-Y3, was synthesized from coal fly ash (CFA) under low-alkaline conditions (NaOH/CFA ratio = 0.3 and NaOH solution concentrations of 0.0, 0.5, and 1.0 M) using a fusion/hydrothermal method. The adsorption capacities of the fabricated Z-Y3 samples for Cs and Sr ions and the desorption capacity of Na ions were evaluated. The XRD patterns of the Z-Y3 sample fabricated using a 1.0 M NaOH solution (Z-Y3 (1.0 M)) indicated the successful synthesis of a zeolitic material, because the diffraction peaks of Z-Y3 coincided with those of the Na-A zeolite in the 2θ range of 7.18-34.18. Moreover, the SEM images revealed that morphology of the Z-Y3 (1.0 M) sample, which presented zeolitic materials characteristics, consisted of sharp-edged cubes. The adsorption isotherms of Cs and Sr ions on all the fabricated Z-Y3 samples were described using the Langmuir model, and the maximum adsorption capacities of Cs and Sr were calculated to be 0.14-0.94 mmol/g and 0.19-0.78 mmol/g, respectively. The desorption of Na ions from the Cs and Sr ions adsorbed Z-Y3 samples followed the Langmuir desorption model. The maximum desorption capacities of Na ions from the Cs and Sr ions adsorbed Z-Y3 (1.0 M) samples were 1.28 and 1.49 mmol/g, respectively.

An analysis on enhancement of customer satisfaction for conversion farm with $2^{nd}$ and $3^{rd}$ industry (2.3차 산업 융합 농장의 고객 만족 요인 분석)

  • Jang, Hyun-Dong;Kim, Soung-Hun
    • Korean Journal of Agricultural Science
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    • v.38 no.4
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    • pp.769-774
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    • 2011
  • This study aimed at finding the factors impacting customer satisfaction (CS) for conversion farm with $2^{nd}$ and $3^{rd}$ industry, because the most important thing in the conversion farm is enhancing customer satisfaction. The data on CS from 173 pumpkin farm's customers by on-line survey were gathered. The analysis using structural equation model with Amos was carried out. Product, service and purchasing were determined as 3 factors impacting to CS. The result showed that purchasing is the biggiest contributor to CS. It means the customers using on-ine market are very sensitive to farm's brand and logistics. It is also found that conversion with processing and farm experience activity is definitely affecting to building customer's trust. In conclusion, making efforts on enhancing CS in conversion farm is the key to success.

A Study on the Assessment of Derived Intervention Levels in Foodstuffs Using the Dynamic Ingestion Pathway Model (동적 섭식경로모델을 이용한 음식물에 대한 유도 방사능 개입준위의 산정에 관한 연구)

  • Hwang, Won-Tae;Han, Moon-Hee;Kim, Byung-Woo
    • Journal of Radiation Protection and Research
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    • v.19 no.3
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    • pp.199-208
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    • 1994
  • The derived intervention levels in Korean foodstuffs were estimated using the dynamic ingestion pathway model which was developed considering Korean environment. The derived intervention levels were estimated from the intervention level of dose based on the thyroid committed dose equivalent of infant in the case of I-131, and the whole body committed dose equivalent for age groups and 13 kinds foodstuffs in the cases of Cs-137 and Sr-90. The derived intervention levels were shown as a considerable variation with deposition time and radionuclide. The adult was the most important age group in the estimation of derived intervention levels for Cs-137 and Sr-90. In the adult, the derived intervention levels for rice were 2390 and 47 Bq/kg for Cs-137 and Sr-90 in the case of deposition in summer, respectively, and 198 and 79 Bq/kg in the case of deposition in winter, respectively.

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Triple-layer Surface Complexation Modeling on the Adsorption of cs-137 and Sr-90 onto Kaolinite: Effect of Groundwater Ions and pH (캐올리나이트의 셰슘-137 및 스트론튬-90 흡착에 대한 삼중층 표면복합반응 모델링: 지하수 이온성분 및 pH의 영향)

  • 정찬호;박상원;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.11 no.2
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    • pp.106-116
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    • 1998
  • The adsorption of Cs-137 and Sr-90 onto kaolinite in prescence of major groundwater cations (Ca2+, K+, Na+) with different concentrations was simulated by using triple-layer surface complexation model (TL-SCM). The site density (8.73 sites/nm2) of kaolinite used for TL-SCM was calculated from it's CEC and specific surface area. TL-SCM modeling results indicate that concentrations dependence on 137Cs and 90Sr adsorption onto kaolinite as a function of pH is best modeled as an outer-sphere surface reaction. This suggests that Cs+ and Sr2+ are adsorbed at the $\beta$-layer in kaolinite-water interface where the electrolytes, Nacl, KCl and CaCl2, bind. However, TL-SCM results on Sr adsorption show a discrepancy between batch data and fitting data in alkaline condition. This may be due to precipitation of SrCO3 and complexation such as SrOH+. Intrinsic reaction constants of ions obtained from model fit are as follows: Kintcs=10-2.10, KintSr=10-2.30, KintK=10-2.80, KintCa=10-3.10 and KintNa=10-3.32. The results are in the agreement with competition order among groundwater ions (K+>Ca2+>Na+) and sorption reference of nuclides (Cs-137>Sr-90) at kaolinite-water interface showed in batch test.

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Anti-diabetic Effect of the Exopolysaccharides (EPS) Produced from Cordyceps sinensis on ob/ob Mice (제 2형 당뇨쥐에서 동충하초로부터 생산된 세포외 다당류의 항당뇨 효과)

  • Choi, Jang-Won
    • KSBB Journal
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    • v.26 no.1
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    • pp.33-40
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    • 2011
  • Anti-diabetic effect of the exopolysaccharides (EPS) produced from submerged mycelial culture of Cordyceps sinensis (Cs) was studiedin a type II diabetic animal model (C57BL/6J ob/ob). This study was designed to determine whether Cs-EPS improves clinical symptoms of type II diabetes in ob/ob mice. After Cs-EPS treatment at doses of 200 mg/kg body weight, the fasting blood glucose levels decreased by 47% after 7 weeks compared with those of the control mice. According to the oral glucose tolerance test, the glucose levels recovered its baseline after 120 min in Cs-EPS-treated mice, although the blood glucose levels increased significantly after 30 min. On the other hand, the control group (not-treated) did not recovered its initial level of glucose after 120 min. Furthermore, food intake, body weight, total plasma cholesterol and triglyceride concentrations in ob/ob mice treated with Cs-EPS were significantly decreased, compared with those in control ob/ob mice. Cs-EPS treatment increased significantly the plasma insulin level and the expression of leptin mRNA in adipose tissue of Cs-EPS-treated ob/ob mice. From these results, it is demonstrated that Cs-EPS could be effective for regulating normal blood glucose levels by increasing the amounts of plasma insulin and leptin expression in ob/ob mice, indicating that this compound could be a candidate material as a dietary supplement to control hyperglycemia in patients suffering from type II diabetes.

Desorption Characteristics of Cobalt, Strontium, and Cesium in Natural Soil and Kaolin Using CMCD (CMCD를 이용한 자연토양 및 카올린에서의 코발트, 스트론튬, 세슘의 탈착 특성)

  • Choi, Jeonghak;Cheon, Kyeongho
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.12
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    • pp.61-69
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    • 2014
  • Carboxymethyl-${\beta}$-cyclodextrin (${\beta}$-CMCD), as a biodegradable surfactant with hydrophobic and hydrophilic properties, has potential advantages of being applicable to the simultaneous treatment of multiple contaminated soils. In this study, the desorption behaviors of r adionuclides such as cobalt (Co), strontium (Sr), and cesium (Cs) from the soil contaminated with them were experimentally investigated and the effectiveness of CMCD as a desorbent was evaluated. The desorption equilibrium of used radionuclides could be achieved within 1~3 hr and the desorption ratio from kaolin was higher than that from natural soil. The addition of CMCD of 2 g/L increased the desorption ratio by 5~20 % and the desorption ratio of used r adionuclides was shown in the order of Co > Cs > Sr. The experimental desorption data were fitted successfully by pseudo-second order kinetic model and the desorption rate of the r adionuclides was shown in the order of Cs > Co > Sr. Hysteresis between adsorption and desorption of the r adionuclides, as shown in the order of Sr > Co > Cs, increased as the desorption rate decreased. Consequently, it could be considered that the desorption rate was one of the significant factors of the hysteresis. The addition of CMCD as desorbent increased the amount of desorbed radionuclides and decreased the hysteresis. However, the CMCD could not completely desorb the radionuclides from soils even though the excess of CMCD was added.

Selective adsorption of Cs+ by MXene (Ti3C2Tx) from model low-level radioactive wastewater

  • Jun, Byung-Moon;Jang, Min;Park, Chang Min;Han, Jonghun;Yoon, Yeomin
    • Nuclear Engineering and Technology
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    • v.52 no.6
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    • pp.1201-1207
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    • 2020
  • This study explored whether MXene (Ti3C2Tx) could remove radioactive Cs+ from model nuclear wastewater. Various adsorption tests were performed and the physical aspects of the interaction were investigated. We varied the MXene dosage, Cs+ initial concentration, solution pH, solution temperature and exposure time. MXene adsorption exhibited very fast kinetics, based on the fact that equilibrium was achieved within 1 h. MXene exhibited an outstanding adsorption capacity (148 mg g-1) at adsorbent and adsorbate concentrations of 5 and 2 mg L-1, respectively, at neutral pH condition (i.e., pH 7). We explored Cs+ adsorption by MXene in the presence of four different ions (NaCl, KCl, CaCl2 and MgCl2) and three different organic acids (sodium oleate, oxalic acid, and citric acid). The Cs+ removal rate changed in the presence of these components; adsorption of Cs+ by MXene thus involved ion exchange, supported by both Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy. We confirmed that MXene was re-usable for at least four cycles. MXene is cost-effective and practical when used to adsorb radionuclides (e.g., Cs+) in nuclear wastewater.

Gene expression analysis related to ethylene induced female flowers of cucumber (Cucumis sativus L.) at different photoperiod

  • Ikram, Muhammad Maulana Malikul;Esyanti, Rizkita Rachmi;Dwivany, Fenny Martha
    • Journal of Plant Biotechnology
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    • v.44 no.3
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    • pp.229-234
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    • 2017
  • Photoperiod is one of the factors affecting productivity of cucumber plant by inducing ethylene hormone production and so triggering flower sex differentiation into female flower. However, only few studies have been perfomed in order to reveal the effect of photoperiod in molecular level in relation to the flower differentiation. Therefore, in this study, Mercy cultivar of cucumber (andromonoecious) was treated with photoperiod of 8, 12, 16 hours of light, while control received no treatment of additional light. Photoperiod of 8 hours was achieved by blocking the sunlight with shade net and 16 hours by giving longer light exposure using white LEDs. Cucumber's flowers were quantified and the apical and lateral shoots were extracted to evaluate the gene profile related to the photoperiod, ethylene production, and female flower differentiation, which were CsACS2, CsETR1, CsCaN, and CsPIF4 using PCR method. Photoperiod of 8 hours affected the production of female flower with average number of 6.7 flowers in main stem and 8.0 flowers in lateral stem, compared to photoperiod of 12 and 16 hours which produced 3.7 and 2.0 flowers in main stem with 7.0 and 11.3 in lateral stem, respectively. In silico studies in this experiment resulted in proposed model of signal transduction that showed the connection between ethylene production and flower differentiation. PCR analysis confirmed the expression of CsACS2, CsETR1, and CsCaN, that was positively correlated with numbers of female flowers in cucumber, but the expression of CsPIF4 that represent photoperiod haven't been confirmed correlated with the ethylene production and flower differentiation.

Development of a Mass Transfer Model and Its Application to the Behavior of the Cs, Sr, Ba, and Oxygen ions in an Electrolytic Reduction Process for SF

  • Park ByungHeung;Kang Dae-Seung;Seo Chung-Seok;Park Seong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.2
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    • pp.85-93
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    • 2005
  • Isotopes of alkali and alkaline earth metals (AM and AEM) are the main contributors to the heat load and the radiotoxicity of spent fuel (SF) . These components are separated from the SF and dissolved in a molten LiCl in an electrolytic reduction process. A mass transfer model is developed to describe the diffusion behavior of Cs, Sr, and Ba in the SF into the molten salt. The model is an analytical solution of Fick's second law of diffusion for a cylinder which is the shape of a cathode in the electrolytic reduction process. And the model is also applied to depict the concentration profile of the oxygen ion which is produced by the electrolysis of Li$_{2}$O. The regressed diffusion coefficients of the model correlating the experimentally measured data are evaluated to be greater in the order of Ba, Cs, and Sr for the metal ions and the diffusion of the oxygen ion is slower than the metal ions which implies that different mechanisms govern the diffusion of the metal ions and the oxygen ions in a molten LiCl.

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Prediction of compressive strength of concrete modified with fly ash: Applications of neuro-swarm and neuro-imperialism models

  • Mohammed, Ahmed;Kurda, Rawaz;Armaghani, Danial Jahed;Hasanipanah, Mahdi
    • Computers and Concrete
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    • v.27 no.5
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    • pp.489-512
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    • 2021
  • In this study, two powerful techniques, namely particle swarm optimization (PSO) and imperialist competitive algorithm (ICA) were selected and combined with a pre-developed ANN model aiming at improving its performance prediction of the compressive strength of concrete modified with fly ash. To achieve this study's aims, a comprehensive database with 379 data samples was collected from the available literature. The output of the database is the compressive strength (CS) of concrete samples, which are influenced by 9 parameters as model inputs, namely those related to mix composition. The modeling steps related to ICA-ANN (or neuro-imperialism) and PSO-ANN (or neuro-swarm) were conducted through the use of several parametric studies to design the most influential parameters on these hybrid models. A comparison of the CS values predicted by hybrid intelligence techniques with the experimental CS values confirmed that the neuro-swarm model could provide a higher degree of accuracy than another proposed hybrid model (i.e., neuro-imperialism). The train and test correlation coefficient values of (0.9042 and 0.9137) and (0.8383 and 0.8777) for neuro-swarm and neuro-imperialism models, respectively revealed that although both techniques are capable enough in prediction tasks, the developed neuro-swarm model can be considered as a better alternative technique in mapping the concrete strength behavior.