• Title/Summary/Keyword: CS model

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Adsorption Characteristics of Ammonia-Nitrogen by Zeolitic Materials Synthesized from Jeju Scoria (제주 스코리아로부터 합성한 제올라이트 물질에 의한 암모니아성 질소의 흡착 특성)

  • Lee, Chang-Han;Hyun, Sung-Su;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.29 no.12
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    • pp.1261-1274
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    • 2020
  • The characteristics of ammonia-nitrogen (NH4+-N) adsorption by a zeolitic material synthesized from Jeju scoria using the fusion and hydrothermal method was studied. The synthetic zeolitic material (Z-SA) was identified as a Na-A zeolite by X-ray diffraction, X-ray fluorescence analysis and scanning electron microscopy images. The adsorption of NH4+-N using Jeju scoria and different types of zeolite such as the Z-SA, natural zeolite, and commercial pure zeolite (Na-A zeolite, Z-CS) was compared. The equilibrium of NH4+-N adsorption was reached within 30 min for Z-SA and Z-CS, and after 60 min for Jeju scoria and natural zeolite. The adsorption capacity of NH4+-N increased with approaching to neutral when pH was in the range of 3-7, but decreased above 7. The removal efficiency of NH4+-N increased with increasing Z-SA dosage, however, its adsorption capacity decreased. For initial NH4+-N concentrations of 10-200 mg/L at pH 7, the adsorption rate of NH4+-N was well described by the pseudo second-order kinetic model than the pseudo first-order kinetic model. The adsorption isotherm was well fitted by the Langmuir model. The maximum uptake of NH4+-N obtained from the Langmuir model decreased in the order of Z-CS (46.8 mg/g) > Z-SA (31.3 mg/g) > natural zeolite (5.6 mg/g) > Jeju scoria (0.2 mg/g).

The Analytical Radioactive Waste Repository Source Term REPS Model (방사성폐기물 처분장 선원항 REPS 모델)

  • Kim, Chang-Lak;Cho, Chan-Hee;Park, Kwang-Sub;Kim, Jinwung
    • Nuclear Engineering and Technology
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    • v.22 no.4
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    • pp.315-325
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    • 1990
  • The analytical repository source term (REPS) computer code is developed for the safety assessment of radioactive waste geologic repository. For reliable prediction of the leach rates for various radionuclides, degradation of concrete structures, corrosion rate of waste container, degree of corrosion on the container surface, and the characteristics of radionuclides are considered in this REPS code. For the validation of the radionuclide leach rates predicted by the REPS model, the calculated leach rates of Cs-137, Sr-85, and Co-60 are compared with two reported leaching test results. Cesium and strontium leach congruently, and the leaching test results of these species can be reproduced by the congruent leaching model included in the REPS model. In case of cobalt, the solid diffusion model is in good agreement with the leaching test results.

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Accuracy of 14 intraoral scanners for the All-on-4 treatment concept: a comparative in vitro study

  • Gozde, Kaya;Caglar, Bilmenoglu
    • The Journal of Advanced Prosthodontics
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    • v.14 no.6
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    • pp.388-398
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    • 2022
  • PURPOSE. This in vitro study aimed to evaluate the accuracy of 14 different intraoral scanners for the All-on-4 treatment concept. MATERIALS AND METHODS. Four implants were placed in regions 13, 16, 23, and 26 of an edentulous maxillary model that was poured with scannable Type 4 gypsum to imitate the All-on-4 concept. The cast was scanned 10 times for each of 14 intraoral scanners (Primescan, iTero 2, iTero 5D, Virtuo Vivo, Trios 3, Trios 4, CS3600, CS3700, Emerald, Emerald S, Medit i500, BenQ BIS-I, Heron IOS, and Aadva IOS 100P) after the polyether ether ketone scanbody was placed. For the control group, the gypsum model was scanned 10 times with an industrial scanner. The first of the 10 virtual models obtained from the industrial model was chosen as the reference model. For trueness, the data of the 14 dental scanners were superimposed with the reference model; for precision, the data of all 14 scanners were superimposed within the groups. Statistical analyses were performed using the Kolmogorov-Smirnov, Shapiro-Wilks, and Dunn's tests. RESULTS. Primescan showed the highest trueness and precision values (P < .005), followed by the iTero 5D scanner (P < .005). CONCLUSION. Some of these digital scanners can be used to make impressions within the All-on-4 concept. However, the possibility of data loss due to artifacts, reflections, and the inability to combine the data should be considered.

Inhibition of Citrate Synthase Thermal Aggregation In Vitro by Recombinant Small Heat Shock Proteins

  • Gong, Weina;Yue, Ming;Xie, Bingyan;Wan, Fanghao;Guo, Jianying
    • Journal of Microbiology and Biotechnology
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    • v.19 no.12
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    • pp.1628-1634
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    • 2009
  • Small heat shock proteins (sHSPs) function as molecular chaperones that protect cells against environmental stresses. In the present study, the genes of hsp17.6 and hsp17.7, cytosolic class I sHSPs, were cloned from a tropical plant, Ageratina adenophorum. Their C-terminal domains were highly conserved with those of sHSPs from other plants, indicating the importance of the C-terminal domains for the structure and activity of sHSPs. The recombinant HSP17.6 and HSP17.7 were applied to determine their chaperone function. In vitro, HSP17.6 and HSP17.7 actively participated in the refolding of the model substrate citrate synthase (CS) and effectively prevented the thermal aggregation of CS at $45^{\circ}C$ and the irreversible inactivation of CS at $38^{\circ}C$ at stoichiometric levels. The prior presence of HSP17.7 was assumed to suppress the thermal aggregation of the model substrate CS. Therefore, this report confirms the chaperone activity of HSP17.6 and HSP17.7 and their potential as a protectant for active proteins.

Object Tracking Using Particle Filters in Moving Camera (움직임 카메라 환경에서 파티클 필터를 이용한 객체 추적)

  • Ko, Byoung-Chul;Nam, Jae-Yeal;Kwak, Joon-Young
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.37 no.5A
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    • pp.375-387
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    • 2012
  • This paper proposes a new real-time object tracking algorithm using particle filters with color and texture features in moving CCD camera images. If the user selects an initial object, this region is declared as a target particle and an initial state is modeled. Then, N particles are generated based on random distribution and CS-LBP (Centre Symmetric Local Binary Patterns) for texture model and weighted color distribution is modeled from each particle. For observation likelihoods estimation, Bhattacharyya distance between particles and their feature models are calculated and this observation likelihoods are used for weights of individual particles. After weights estimation, a new particle which has the maximum weight is selected and new particles are re-sampled using the maximum particle. For performance comparison, we tested a few combinations of features and particle filters. The proposed algorithm showed best object tracking performance when we used color and texture model simultaneously for likelihood estimation.

Effects of a Caragana sinica Water Extract on Lipid and Glucose Metabolism in Ovariectomized Rats (골담초 열수 추출물의 갱년기 이후 지질 및 당질 대사 개선 효능)

  • Lee, Sang Chul;Chung, Soo Im;Kang, Mi Young
    • Korean Journal of Plant Resources
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    • v.29 no.5
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    • pp.532-538
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    • 2016
  • Menopause is characterized by a decrease in estrogen production by the ovaries. Furthermore, the risk of developing chronic diseases including cardiovascular disease, obesity, and diabetes increases in menopausal women. In this study, we evaluated the ability of Caragana sinica (CS) to affect lipid and glucose metabolism in an ovariectomized Sprague-Dawley rat model of induced menopause. The animals were divwided randomly into three groups: sham-operated rats (SHAM), ovariectomized rats (OVX), and ovariectomized rats treated with 1% water extract of CS (OVX-CS). The OVX-CS treated mice showed a significant decrease in body weight, adipose tissue, triglyceride, and total cholesterol. Improved lipid and glucose profiles were also observed, and were attributed to suppression of hepatic lipogenesis and adipokine production and regulation of glucose-regulating enzyme activity. Therefore, these findings indicate a potential use for CS as a functional food for menopause-induced hyperlipidemia and hyperglycemia.

The Removal Characteristics of Cs$^{+}$ and Co$^{++}$ from Aqueous Wastes by Ultrafiltration in Combination with Chemical Treatment Techniques(II) (화학처리와 한외여과막의 결합공정에 의한 Cs 및 Co의 제거특성 (II))

  • 이근우;정경환;김길청;김준형
    • Journal of Energy Engineering
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    • v.5 no.1
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    • pp.56-64
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    • 1996
  • The objective of this investigation is to establish the rejection characteristics of caesium and cobalt from radioactive liquid waste by chemical/ultrafiltration process. An extensive experimental investigation was conducted with inactive caesium and cobalt ions, utilizing ultrafiltration stirred cell. Caesium and cobalt could be effectively removed from waste solution using copper ferrocyanide and polyarcylic acid(PAA). The rejection dependence of the caesium was found to be a function of caesiun to potassium copper ferrocyanide feed molar ratio. The binding behavior of caesium on K$_2$Cu$_3$(Fe(CN)$\sub$6/)$_2$, particles was explained in terms of a Langmuir adsorption isotherm. When Cs/K$_2$Cu$_3$(Fe(CN)$\sub$6/)$_2$molar ratio was 1.5, the removal of caesium was the most efficient. The rejection efficiency of cobalt is dependent upon various parameters such as pH, cobalt concentration and PAA concentration. The rejection behavior of cobalt was explained in term of a equilibrium model taking into account the reaction between the ligand group, the proton and the cobalt ion. At the conditions of PAA/Co ratio of 2 and pH of 5.6, the removal of cobalt was over 90%. Also, the effect of chemical addition sequence for the simultaneously removal of caesiun and cobalt was discussed.

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Effects of Temperature on the Uptake and Retention of Cesium-137 by the Clam Cyclina sinensis (가무락조개에 의한 세슘-137 의 농축(濃縮)과 잔류(殘留)에 미치는 온도(溫度)의 영향)

  • Yoo, Byung-Sun;Lee, Jeong-Ho;Lee, Su-Rae
    • Korean Journal of Environmental Agriculture
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    • v.2 no.1
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    • pp.24-29
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    • 1983
  • The effects of temperature on the uptake of $^{137}Cs$ from seawater and on the retention after its uptake by the clam Cycling sinensis was investigated under laboratory conditions. The clams exhibited a greater bioaccumulation of $^{137}Cs$ in $25^{\circ}C$-acclimated animals than those acclimated at $15^{\circ}C$. The viscera of the clams reached the highest bioconcentration factor after 14 days uptake from seawater, but the tissue distribution pattern of $^{137}Cs$ was little influenced, if any, by the uptake temperature. The uptake rate slightly decreased with an increase of temperature in order of $10^{\circ}C$. The radionuclide accumulated in clams was released again in a radionuclide-free seawater according to a two-exponential compartment model. A temperature increase of $10^{\circ}C$ reduced the biological half-life of the long-lived component with a factor of about two, whereas it caused no change in the short-lived component.

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Reduction of Oxidative Stress by Chondroitin Sulfate in the Ovariectomy-Induced Aging Rat (난소절제로 유도한 노화쥐에서 chondroitin sulfate에 의한 산화 스트레스의 감소효과)

  • 이진영;하배진
    • Journal of Life Science
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    • v.14 no.2
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    • pp.280-285
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    • 2004
  • The ovarian hormone-deficiency induced ovariectomy rat is widely used as an aging model due to its practicality, convenience, and cost effectiveness. The surgically ovariectomized rat induces reactive oxygen species (ROS) generation like aging phenomena. Free oxygen radicals have been proposed as important causative agents of aging. The purpose of this study was to investigate the effect of chondroitin sulfate (CS) to prevent ovariectomy (OVX)-induced oxidative stress. The OVX rats were given intraperitoneally CS at doses of 100 mg/kg and 200 mg/kg daily for fifteen weeks. Malondialdehyde (MDA) levels were determined as well as the activities of superoxide dismutase (SOD), catalase (CAT), reduced-glutathione (GSH), oxidized-glutathione (GSSG), glutathione peroxidase (GPx) in the liver. The liver antioxidative enzyme activity was elevated while MDA concentration decreased in all CS treated animals. The results demonstrated that CS reduced oxidative stress in a dose dependent manner. These results suggest that CS might be a useful candidate for antioxidative reagent.

Sorption Efficiency of the Bamboo Charcoal to Remove the Cesium in the Contaminated Water System (오염수계 내 세슘 제거를 위한 대나무 활성탄의 흡착효율 규명)

  • Ahn, Joungpil;Lee, Minhee
    • Economic and Environmental Geology
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    • v.51 no.2
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    • pp.87-97
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    • 2018
  • The cesium (Cs) removal from the contaminated water system has been considered to be difficult because the cesium likes to exist as soluble phases such as ion and complexes than the solid in water system. Many researches have focused on developing the breakthrough adsorbent to increase the cesium removal efficiency in water. In this study, the laboratory scale experiments were performed to investigate the feasibility of the adsorption process using the bamboo charcoal for the Cs contaminated water system. The Cs removal efficiency of the bamboo charcoal were measured and the optimal adsorption conditions were determined by the adsorption batch experiments. Total 5 types of commercialized bamboo charcoals in Korea were used to identify their surface properties from SEM-EDS and XRD analyses and 3 types of bamboo charcoals having large specific surface areas were used for the adsorption batch experiment. The batch experiments to calculate the Cs removal efficiency were performed at conditions of various Cs concentration (0.01 - 10 mg/L), pH (3 - 11), temperature ($5-30^{\circ}C$), and adsorption time (10 - 120 min.). Experimental results were fitted to the Langmuir adsorption isotherm curve and their adsorption constants were determined to understand the adsorption properties of bamboo charcoal for Cs contaminated water system. From results of SEM-EDS analyses, the surfaces of bamboo charcoal particles were composed of typical fiber structures having various pores and dense lamella structures in supporting major adsorption spaces for Cs. From results of adsorption batch experiments, the Cs-133 removal efficiency of C type bamboo charcoal was the highest among those of 3 bamboo charcoal types and it was higher than 75 % (maximum of 82 %) even when the initial Cs concentration in water was lower than 1.0 mg/L, suggesting that the adsorption process using the bamboo charcoal has a great potential to remove Cs from the genuine Cs contaminated water, of which Cs concentration is low (< 1.0 mg/L) in general. The high Cs removal efficiency of bamboo charcoal was maintained in a relatively wide range of temperatures and pHs, supporting that the usage of the bamboo charcoal is feasible for various types of water. Experimental results were similar to the Langmuir adsorption model and the maximum amount of Cs adsorption (qm:mg/g) was 63.4 mg/g, which was higher than those of commercialized adsorbents used in previous studies. The surface coverage (${\theta}$) of bamboo charcoal was also maintained in low when the Cs concentration in water was < 1.0 mg/L, investigating that the Cs contaminated water can be remediated up with a small amount of bamboo charcoal.