• Journal of the Mineralogical Society of Korea
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• 제21권1호
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• pp.67-83
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• 2008

The sericite ore deposits formed in the Precambrian granitic rock at the Bonghwa area, Kyungsangbuk-do, South Korea. The geochemical and mineralogical characteristics of sericite occurred in Daehyun and Seonghwang mine were analyzed using petrographic microscope, XRD, EPMA, XRF and ICP. An alteration mechanism was also studied. Sericitization occurred within the granitic rock by hydrothermal alteration. From the careful study on the occurrence and mineral assemblage, four alteration zone were clearly identified. These zones reflect progressive hydrothermal alteration process. All sericites belong to $2M_1$ polytype and their mineralogical and geochemical properties are close to illite. The sericite ores show various colors, but the characteristics of major element compositions and crystal structures are not different. The trace element analysis, however, indicates that the difference in color attribute to the abundance of Cr and Ti: bluish green colored sericite are enriched in Cr and blackish green colored sericite enriched in Ti. The formation of sericite ore deposit in the granitic rocks are closely relate to fracture system such as fault and joint. It is considered that the sericite ore deposits in this area were formed by very simple hydrothermal alteration occurred along the fracture zones in granitic rocks with absence of other hydrothermally altered minerals such as kaolin and pyrophyllite.

• Applied Chemistry for Engineering
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• 제22권4호
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• pp.367-375
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• 2011

Succinic acid ester derivatives have been used as additives for the base oil of metal working fluids and pressure working oils. In this paper, a series of succinic acid alkyl half-esters were synthesized with over 97% yields by ring-opening reaction of succinic anhydride and fatty alcohol and were soluble in 100 N base oil within 1 wt% concentration. The structures and purities of ester derivatives were confirmed by $^1H-NMR$ and FT-IR spectrum and GC analysis. Anti-corrosion properties of the esters in sea water were evaluated through ASTM D665 method and weight loss method and compared to that of succinic alkyl esters without carboxylic acid group in the molecule. As the results, anti-corrosion properties of succinic acid alkyl half-esters with carboxylic acid group were better than those of succinic acid alkyl esters without carboxylic acid group. And, Anti-corrosion properties of the esters with a shorter alkyl chain of high concentration showed better performance than those with longer alkyl chain of low concentration. Inhibition efficiency % (IE%) of the esters was over 95% in the concentration of 80 ppm and corrosion rate (CR) was below 0.3 mm/year at the same concentration. Thus, the corrosion properties of succinic acid alkyl half-esters result from the carboxylic acid groups in molecules.

• Journal of Ocean Engineering and Technology
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• 제13권3호통권33호
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• pp.92-99
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• 1999

High temperature and pressure materials in power plant are degraded by creep damage, if they are exposed to constant loads for long times, which occurs in load bearing structures of pressurized components operationg at elevated temperatures. Many conventional measurement techniques such as replica method, electric resistance method, and hardness test method for measuring creep damgage have been used. So far, the replica method is mainly used for the inspection of high temperature and pressure components. This technique is, however, restricted to applications at the surface of the testpieces and cannot be used to material inside. In this paper, ultrasonic evaluation for the detection of creep damage in the form of cavaties on grain boundaries or intergranular microcracks were carried out. And the absolute measuring method of quantitative ultrasonic velocity technique for Cr-Mo material degradation was analyzed. As a result of ultrasonic tests for crept for specimens, we founded that the sound velocity was decreased as increase of creep life fraction(${phi}c$) and also, confirmed that hardness was decreased as increase of creep life fraction(${phi}c$).

• Corrosion Science and Technology
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• 제14권3호
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• pp.113-119
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• 2015

Alloy 82/182 weld metals had been extensively used in joining the components of the PWR primary system. Unfortunately, there have been a number of incidents of cracking caused by PWSCC in Alloy 82/182 welds during the operation of PWR worldwide. To mitigate PWSCC, optimization of water-chemistry conditions, especially dissolved hydrogen (DH) and Zn contents, is considered as the most promising and effective remedial method. In this study, the PWSCC behaviours of Alloy 182 weld were investigated in simulated PWR environments with various DH content. Both in-situ and ex-situ oxide characterizations as well as PWSCC initiation tests were performed. The results showed that PWSCC crack initiation time was shortest in PWR water (DH: 30cc/kg). Also, high stress reduced crack initiation time. Oxide layer showed multi-layered structures consisted of the outer needle-like Ni-rich oxide layer, Fe-rich crystalline oxide, and inner Cr-rich inner oxide layers, which was not altered by the level of applied stress. To analyse the multi-layer structure of oxides, EIS measurement were fitted into an equivalent circuit model. Further analyses including TEM and EDS are underway to verify appropriateness of the equivalent circuit model.

• Wind and Structures
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• 제26권5호
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• pp.317-329
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• 2018

Wake characteristics of the flow over a finite square prism at different incidence angles were experimentally investigated using an open-loop wind tunnel. A finite square prism with a width D = 15 mm and a height H = 7D was vertically mounted on a horizontal flat plate. The Reynolds number was varied from $6.5{\times}10^3$ to $28.5{\times}10^3$ and the incidence angle ${\alpha}$ was changed from $0^{\circ}$ to $45^{\circ}$. The ratio of boundary layer thickness to the prism height was about ${\delta}/H=7%$. The time-averaged velocity, turbulence intensity and the vortex shedding frequency were obtained through a single-component hotwire probe. Power spectrum of the streamwise velocity fluctuations revealed that the tip and base vortices shed at the same frequency as that ofspanwise vortices. Furthermore, the results showed that the critical incidence angle corresponding to the maximum Strouhal number and minimum wake width occurs at ${\alpha}_{cr}=15^{\circ}$ which is equal to that reported for an infinite prism. There is a reduction in the size of the wake region along the height of the prism when moving away from the ground plane towards the free end.

• Journal of the Korean Magnetic Resonance Society
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• 제22권3호
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• pp.71-75
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• 2018

The CRISPR-Cas system is the adaptive immune system in bacteria and archaea against invading phages or foreign plasmids. In the type II CRISPR-Cas system, an endonuclease Cas9 cleaves DNA targets of phages as directed by guide RNA comprising crRNA and tracrRNA. To avoid targeting and destruction by Cas9, phages employ anti-CRISPR (Acr) proteins that act against host bacterial immunity by inactivating the CRISPR-Cas system. Here we report the backbone $^1H$, $^{15}N$, and $^{13}C$ resonance assignments of AcrIIA4 that inhibits endonuclease activity of type II-A Listeria monocytogenes Cas9 and also Streptococcus pyogenesis Cas9 using triple resonance nuclear magnetic resonance spectroscopy. The secondary structures of AcrIIA4 predicted by the backbone chemical shifts show an ${\alpha}{\beta}{\beta}{\beta}{\alpha}{\alpha}$ fold, which is used to determine the solution structure.

• Journal of Korea Foundry Society
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• 제15권6호
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• pp.604-615
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• 1995

Austenitic stainless steel castings using expandable polystylene(referred to hereafter as EPS) patterns are often affected by distinctive defects associated with incomplete decomposition of the EPS as the molds are filled with metal. The quality of the castings, with particular reference to carbon pick-up in austenitic stainless steel is further influenced to a significant extent by such factors as reduced pressure, the additive by adding $Na_2CO_3$ in coating. The steel composition and microstructure were examined at the surface layer of castings, at depths of 1mm, by taking successive layers of swarf and analysis. In experiments, the carburizing atmosphere was neutralized, showing that the coating performed efficiently by decomposing almost instantly on heating and liberating $CO_2$. The upper parts of castings obtained using EPS patterns were slightly higher in carbon pick-up than other parts. Comparing the 316L and 304 stainless steel castings, qualitative and quantative differences could be found between the carbon pick-up behaviours as influence of the carbon content and alloying elements. Carbide former such as Cr makes carbon more soluble in the steel. This must make carbon pick-up in the surface layer but at the same time richer in carbon especially in the 304 stainless steel castings.

• Proceedings of the KOR-KST Conference
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• 대한교통학회 2003년도 제43회 학술발표회논문집
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• pp.127-150
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• 2003

This research presents a novel application of static traffic assignment methods, but with a variable time value, for estimating the market share of a high-speed rail (HSR) in the NW-SE corridor of Korea which is currently served by the airline (AR), conventional rail (CR), and highway (HWY) modes. The proposed model employs the time-space network structure to capture the interrelations among all competing transportation modes, and to reflect their supply- and demand-sides constraints as well as interactions through properly formulated link-node structures. The embedded cost function for each network link offers the flexibility for incorporating all associated factors, such as travel time and fare, in the model computation, and enables the use of a distribution rather than a constant to represent the time-value variation among all transportation mode users. To realistically capture the tripmakers' value-of-time (VOT) along the target area, a novel method for VOT calibration has been developed with aggregate demand information and key system performance data from the target area. Under the assumption that intercity tripmakers often have nearly "perfect" travel information, one can solve the market share of each mode after operations of HSR for each O-D pair under the time-dependent demand with state-of-the-art traffic assignment. Aside from estimating new market share, this paper also investigated the impacts of HSR on other existing transportation modes.

• Macromolecular Research
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• 제13권5호
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• pp.435-440
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• 2005

This study describes a method where the match of two different length scales, i.e., the patterns from self-assembled block copolymer (<50 nm) and electron beam writing (>50 nm), allow the nanometer scale pattern mask. The method is based on using block copolymers containing a poly(methyl methacrylate) (PMMA) block, which is subject to be decomposed under an electron beam, as a pattern resist for electron beam lithography. Electron beam on self assembled block copolymer thin film selectively etches PMMA microdomains, giving rise to a polymeric nano-pattern mask on which subsequent evaporation of chromium produces the arrays of Cr nanoparticles followed by lifting off the mask. Furthermore, electron beam lithography was performed on the micropatterned block copolymer film fabricated by micro-imprinting, leading to a hierarchical self assembled pattern where a broad range of length scales was effectively assembled, ranging from several tens of nanometers, through submicrons, to a few microns.

• Proceedings of the Korean Geotechical Society Conference
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• 한국지반공학회 2008년도 추계 학술발표회
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• pp.196-203
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• 2008

Durability of geosynthetics for soil reinforcement is accounted for creep and creep rupture, installation damage and weathering, chemical and biological degradation. Among these, the long-term creep properties have been considered as the most important factors which are directly related to the failure of geosynthetic-reinforced soil(GRS). However, the creep test methods and strain limits are too various to compare the test results with each other. The most widely used test methods are conventional creep test, time-temperature superposition and stepped isothermal method as accelerated creep tests. Recently developed design guidelines recommend that creep-rupture curve be used to determine the creep reduction factor($RF_{CR}$) which is a conservative approach. In this study, the different creep test methods were compared and the creep reduction factors were estimated at different creep strain limits of 10% of total creep strain and creep rupture. In order to minimize the impact of creep strain to the GRS structures, the various creep reduction factors using different creep test methods should be investigated and then the most appropriated one should be selected for incorporating into the design.