• Title/Summary/Keyword: CR geometry

Search Result 55, Processing Time 0.027 seconds

Crystal and Molecular Structure of Hexaimidazolidone Chromium(III) Nitrate, $[Cr(OC_3H_6N_2)_6](NO_3)_3\cdot4H_2O$ (Hexaimidazolidone Chromium(III) Nitrate, $[Cr(OC_3H_6N_2)_6](NO_3)_3.4H_2O$의 결정 및 분자 구조)

  • Suh, Jung-Sun;Lee, Kyu-Wang;Suh, Il-Hwan
    • Korean Journal of Crystallography
    • /
    • v.11 no.2
    • /
    • pp.71-74
    • /
    • 2000
  • The title compound, [Cr(OC3H6N2)6](NO3)3·4H2O, was crystallized in the centrosymmetric space group P with two half molecules in an asymmetric unit, and the two complete molecules are generated by inversion symmetry located at Cr atoms. Therefore, the Cr atoms are coordinated to six imidazolidone ligands through the oxygen atoms, and both CrO6 units have a slightly distorted octahedral geometry.

  • PDF

LOXODROMES AND TRANSFORMATIONS IN PSEUDO-HERMITIAN GEOMETRY

  • Lee, Ji-Eun
    • Communications of the Korean Mathematical Society
    • /
    • v.36 no.4
    • /
    • pp.817-827
    • /
    • 2021
  • In this paper, we prove that a diffeomorphism f on a normal almost contact 3-manifold M is a CRL-transformation if and only if M is an α-Sasakian manifold. Moreover, we show that a CR-loxodrome in an α-Sasakian 3-manifold is a pseudo-Hermitian magnetic curve with a strength $q={\tilde{r}}{\eta}({\gamma}^{\prime})=(r+{\alpha}-t){\eta}({\gamma}^{\prime})$ for constant 𝜂(𝛄'). A non-geodesic CR-loxodrome is a non-Legendre slant helix. Next, we prove that let M be an α-Sasakian 3-manifold such that (∇YS)X = 0 for vector fields Y to be orthogonal to ξ, then the Ricci tensor 𝜌 satisfies 𝜌 = 2α2g. Moreover, using the CRL-transformation $\tilde{\nabla}^t$ we fine the pseudo-Hermitian curvature $\tilde{R}$, the pseudo-Ricci tensor $\tilde{\rho}$ and the torsion tensor field $\tilde{T}^t(\tilde{S}X,Y)$.

Cr(III)-Tetraaza Macrocyclic Complexes Containing Auxiliary Ligands (Part II); Synthesis and Characterization of Cr(III)-Citrato Macrocyclic Complex

  • Byun, Jong-Chul;Park, Yu-Chul;Youn, Jeung-Su;Han, Chung-Hun;Lee, Nam-Ho
    • Bulletin of the Korean Chemical Society
    • /
    • v.26 no.4
    • /
    • pp.634-640
    • /
    • 2005
  • The reaction of cis-[Cr([14]-decane)(OH$_2)_2]^+$ ([14]-decane = rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-teraazacyclotetradecane) with auxiliary ligands {$L_a$ = citrate(cit)} leads to a new dimeric complex cis-[{Cr([14]-decane)($\mu$-cit)}$_2](ClO_4)_2$. This binuclear complex has been structurally characterized by a combination of elemental analysis, conductivity, IR and Vis spectroscopy, mass spectrometry, and X-ray crystallography. Analysis of the crystal structure of cis-[{Cr([14]-decane)($\mu$-cit)})($_2]^+$ reveals that each chromium has a distorted octahedral coordination environment and citrato ligands are monodentate to the two chromium atoms via the carboxyl groups. For dimeric complex the bridging geometry is as follows: Cr$\ldots$Cr = 7.361 $\AA$; Cr-O(average) = 1.958 (8) $\AA$; Cr-N range = 2.108 (9)-2.147(9) $\AA$; N(1)-Cr-N(3) (equatorial position) = 98.0(4)$^{\circ}$; N(2)-Cr-N(4) (axial position) = 166.4(4)$^{\circ}$; O(1)-Cr-N(2) = 98.1(4)$^{\circ}$; O(3)-Cr-N(4) = 96.6(3)$^{\circ}$; O(1)-Cr-O(3) = 90.4$^{\circ}$. The FAB mass spectrum of the dimeric complex displays peak due to the molecular ions cis-[{Cr([14]-decane)($\mu$-cit)})($_2]^+$ at m/z 1053.

SYMMETRIES OF PARTIAL DIFFERENTIAL EQUATIONS

  • Gaussier, Herve;Merker, Joel
    • Journal of the Korean Mathematical Society
    • /
    • v.40 no.3
    • /
    • pp.517-561
    • /
    • 2003
  • We establish a link between the study of completely integrable systems of partial differential equations and the study of generic submanifolds in $\mathbb{C}$. Using the recent developments of Cauchy-Riemann geometry we provide the set of symmetries of such a system with a Lie group structure. Finally we determine the precise upper bound of the dimension of this Lie group for some specific systems of partial differential equations.

Structural and Spectral Characterization of a Chromium(III) Picolinate Complex: Introducing a New Redox Reaction

  • Hakimi, Mohammad
    • Journal of the Korean Chemical Society
    • /
    • v.57 no.6
    • /
    • pp.721-725
    • /
    • 2013
  • Reaction between 2-pyridinecarboxylic acid (Hpic) and $K_3[Cr(O_2)_4]$ give complex $[Cr(pic)_3].H_2O$ (1) which is characterized by elemental analysis and spectroscopic methods (FT-IR, Raman) and X-ray crystallography. In the crystal structure of 1, chromium atom with coordinated by three nitrogen and three oxygen atoms has a distorted octahedral geometry. Also a water molecule is incorporated in crystal network. Each water molecule acts as hydrogen bond bridging and connects two adjacent complexes by two $O-H{\cdots}O$ hydrogen bonds.

SEIBERG-WITTEN-LIKE EQUATIONS ON THE STRICTLY PSEUDOCONVEX CR-3 MANIFOLDS

  • Eker, Serhan
    • Bulletin of the Korean Mathematical Society
    • /
    • v.56 no.6
    • /
    • pp.1551-1567
    • /
    • 2019
  • In this paper, Seiberg-Witten-like equations are written down on 3-manifolds. Then, it has been proved that the $L^2$-solutions of these equations are trivial on ${\mathbb{R}}^3$. Finally, a global solution is obtained on the strictly pseudoconvex CR-3 manifolds for a given constant negative scalar curvature.

Effect of Microstructure and Unit Cell's Geometry on the Compressive Mechanical Response of Additively Manufactured Co-Cr-Mo Sheet I-WP Lattice

  • So-Yeon Park;Kyu-Sik Kim;Bandar Almangour;Kee-Ahn Lee
    • Archives of Metallurgy and Materials
    • /
    • v.67 no.4
    • /
    • pp.1525-1529
    • /
    • 2022
  • Co-Cr-Mo based sheet I-WP lattice was fabricated via laser powder bed fusion. The effect of microstructure and the I-WP shape on compressive mechanical response was investigated. Results of compression test showed that yield strength of the sheet I-WP was 176.3 MPa and that of bulk Co-Cr-Mo (reference material) was 810.4 MPa. By applying Gibson-Ashby analytical model, the yield strength of the lattice was reversely estimated from that of the bulk specimen. The calculated strength of the lattice obtained was 150.7 MPa. The shape of deformed lattice showed collective failure mode, and its microstructure showed that strain-induced martensitic transformation occurred in the overall lattice. The deformation behavior of additively manufactured sheet I-WP lattice was also discussed.

Measurement of excitation efficiency and passively Q-switched characteristics of laser diode end-pumped Nd:YAG laser by using $Cr^{4+}$:YAG as a saturable absorber ($Cr^{4+}$:YAG 포화 흡수체를 이용한 레이저 다이오드 뒷면 여기 Nd:YAG 레이저의 들뜸 효율 및 Q-switching 특성 연구)

  • 정태문;김광석;문희종;이종훈;김철중;이종민
    • Korean Journal of Optics and Photonics
    • /
    • v.9 no.4
    • /
    • pp.231-235
    • /
    • 1998
  • Passively Q-switched, laser diode(LD) end-pumped Nd:YAG laser was demonstrated by using $Cr^{4+}$:YAG as a saturable absorber. In addition , we could calculate an excitation efficiency, which is an important parameter to evaluate the pumping geometry, directly by measuring the absorbed power in Nd:YAG at threshold condition. We found that output parameters such as average power, pulse duration, and repetition rate strongly depended on the low intensity transmission of $Cr^{4+}$:YAG and driving current of lase diode. The maximum Q-switched output power of 1 W was obtained with 40 kHz repetition rate. The pulse duration was varied from 50 ns to 200 ns.

  • PDF

A study on the characteristics of acoustic emission signal in dynamic cutting process (동적 절삭과정에서 AE 신호의 특성에 관한 연구)

  • Kim, Jeong-Suk;Kang, Myeong-Chang;Kim, Duk-Whan
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.11 no.4
    • /
    • pp.69-76
    • /
    • 1994
  • AE(Acoustic Emission) signal is correlated to workpiece material, cutting conditions and tool geometry during metal cutting. The relationship between AE signal and cutting parameters can be obtained by theoretical model and experiments. The value of CR(Count Rate) is nearly constant in stable cutting, but when the chatter vibration occours, the value of CR is rapidly increased due to the vibration deformation zone. By experimental signal processing of AE, it is more effective than by RMS(Root Mean Square) measurement to detect the threshold of chatter vibration by CR measurement.

  • PDF