• Applied Chemistry for Engineering
• /
• v.10 no.8
• /
• pp.1129-1135
• /
• 1999

The reduction of $SO_2$ by CO over supported cobalt catalysts was investigated within the temperature range of $350{\sim}550^{\circ}C$, initial $SO_2$ concentration of 1000~10000 ppm, $CO/SO_2$ molar ratio of 1.0~3.0 and space velocity of $5000{\sim}15000h^{-1}$. Several types of supports such as ${\gamma}-Al_2O_3$, $TiO_2$ were tested. The $SO_2$ conversion and selectivity to elemental sulfur were investigated using a differential fixed bed reactor at atmospheric pressure. The catalyst prepared by wet impregration of 5 wt % cobalt on ${\gamma}-Al_2O_3$ showed $SO_2$ conversion higher than 90% and COS yield lower than 6% at temperature above $400^{\circ}C$. The optimum $CO/SO_2$ molar ratio was investigated as 2.0. At higher $CO/SO_2$ molar ratio, the $SO_2$ conversion became higher but the main product was COS. The effect of $SO_2$ concentration and space velocity over $SO_2$ conversion and COS yield was not appreciable in the experimental range. The activated cobalt phase was detected as $CoS_2$ and the $CoS_2$ phase unchanged even after reaction.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.11a
• /
• pp.533-536
• /
• 2009

The gasification technology is a very flexible and versatile technology to produce a wide variety products such as electricity, steam, hydrogen, Fisher-Tropsch(FT) diesels, Dimethyl Ether(DME), methanol and SNG(Synthetic Natural Gas) with near-zero pollutant emissions. Gasification converts coal and other low-grade feedstocks such as biomass, wastes, residual oil, petroleum coke, etc. to a very clean and usable syngas. Syngas is produced from gasifier including CO, $H_2$, $CO_2$, $N_2$, particulates and smaller quantities of $CH_4$, $NH_3$, $H_2S$, COS and etc. After removing pollutants, syngas can be variously used in energy and environment fields. The pilot-scale coal gasification system has been operated since 1994 at Ajou University in Suwon, Korea. The pilot-scale gasification facility consists of the coal gasifier, the hot gas filtering system, and the acid gas removal (AGR) system. The acid gas such as $H_2S$ and COS is removed in the AGR system before generating electricity by gas engine and producing chemicals like Di-methyl Ether(DME) in the catalytic reactor. The designed operation temperature and pressure of the $H_2S$ removal system are below $50^{\circ}C$ and 8 kg/$cm^2$. The iron chelate solution is used as an absorbent. $H_2S$ is removed below 0.1 ppm in the H2S removal system.

• Korean Chemical Engineering Research
• /
• v.48 no.3
• /
• pp.316-321
• /
• 2010

The $SO_2$ catalytic reduction was carried out under the condition of high pressure in this study. Sn-Zr based oxide and CO were used as the catalyst and reducing agent for the reduction of $SO_2$ to element sulfur, respectively. In order to compare the reactivity with the pressure on the catalytic process, the reactivity tests were performed under the conditions of atmospheric pressure and 20 atm. $SO_2$ conversion, the element sulfur yield and COS selectivity were also compared with changing the reaction temperature, $CO/SO_2$ mole ratio and the space velocity(GHSV). $SO_2$ conversion increased with increasing temperature and $CO/SO_2$ mole ratio under the condition of atmospheric pressure and element sulfur yield decreased due to the production of COS by the series reaction of CO and the produced sulfur. However, high $SO_2$ conversion and high element sulfur were obtained under the condition of 20 atm. It was concluded that COS decreased due to the condensation of the produced element sulfur under the condition of high pressure. Therefore, the high sulfur yield for $SO_2$ catalytic reduction could be profitably obtained under the condition of high pressure.

• 전기의세계
• /
• v.12
• /
• pp.6-11
• /
• 1963

철극형동기기를 무부하상태로 전환을 할때 갑지기 2상간에 단락이 돌발한 경우 다른 개로상단자에 유기되는 open-phase voltage의 과도상태를 구명하는데 본 논문의 목적이 있다. 우선 전기자전압의 직축분과 횡축분을 구하기 위하여 Blondel씨가 제창한 이론을 matrix form으로 전개하여 그의 기본전압방정식을 확립시키고 이어서 상간단락전류를 구해가지고 개로상단자에 유기되는 이상전압, 즉 open-phase voltage의 치를 e$_{a}$ =e$_{d}$cos.theta.-e$_{q}$ sin.theta.+e$_{0}$의 관계식에 의거해서 구해보자는 것이다. 논설상의 편의를 도모키 위해 몇가지 가정을 마련하는 것이 순서라고 본다. 제동권선이 없는 철극동기기를 취급하고 포화현상을 무시하며 직축상에 주계자가 존재하는것으로 간주하며, 전기자회로의 저항은 근소치임으로 시정수에 한애서만 영향을 주는 것 이외에는 계산상에서 이를 무시하고 역시 계산에 나오는 무든 양은 per-unit notation을 사용하고 영상분은 고려하지 않으며 대표적인 동기기정수를 x$_{d}$=0.78, x'$_{d}$=0.21, x$_{q}$ =0.48 및 E=1로 정해서 구명해보자는 것이다.

• 한국신재생에너지학회:학술대회논문집
• /
• 2007.11a
• /
• pp.457-460
• /
• 2007

석탄가스화 기술은 석탄을 고온/고압 조건에서 가스화 반응시켜 CO와 $H_2$가 주성분인 합성가스(syngas)로 전환시키는 기술이다. 그러나 가스화 반응으로 인해 합성가스 내에는 불순물인 $H_2S$, COS, $NH_3$ 등의 오염 물질이 발생하게 되며, 가스터빈의 부식, 촉매의 피독, 전극의 성능 저하 현상 등을 일으켜 효율을 저하시키게 된다. 이에 본 연구에서는 FeMgO 촉매를 제거용매로 사용하여 $H_2S$를 효과적으로 제거하기 위하여 Lab-scale 탈황 설비를 제작하였으며, 석탄 가스화 운전에 연계하여 합성가스 내 포함된 산성가스 정제 특성에 관한 연구를 진행하였다.

• Journal of vocational education research
• /
• v.30 no.4
• /
• pp.281-300
• /
• 2011

This study tried to look into what are happening in the 'class for the talented in invention' using COS-R developed by VanTassel-Baska. Teaching and learning activities within the classroom were observed and analyzed in terms of teacher's observation and teacher's observation, respectively. Based on results of this study, conclusions are as follows. First, it was founded that there are some commonalities between teacher observations and student observations. Based on teacher observations, differentiated teaching activities considering individual characteristics are rarely observed, and for students, it was true. Therefore, supplying a special training program for teachers are needed in order to make teachers and students engage in changing their teaching and learning behaviors. Second, on the side of teachers, they usually emphasize the importance of curriculum planning and implementation, problem solving, creative thinking et al. However, they barely stress the characteristics of research methods, critical thinking, and considering individual characteristics and the level of intellectual ability. Third, on the side of students, they frequently respond to solving problems and critical thinking at the same degree. On the other hand, systemic efforts of considering individual differences and adapting to them have been less regarded in both teaching and learning. In sum, for the successful 'Invention gifted classroom', establishing an educational environment to consider individually guided instruction and taking a balance among various factors embedded in teaching and learning situation should be required.

• The Korean Journal of Food And Nutrition
• /
• v.15 no.2
• /
• pp.112-118
• /
• 2002

Sporulation in the fission yeast Schizosaccharomyces pombe has been regarded as an important model of cellular development and differentiation. S. pombe cells proliferate by mitosis and binary fission on growth medium. Deprivation of nutrients especially nitrogen sources, causes the cessation of mitosis and initiates sexual reproduction by matting between two sexually compatible cell types. Meiosis is then followed in a diploid cell in the absence of nitrogen source. DNA fragment complemented with the mutations of sporulation gene was isolated from the S. pombe gene library constructed in the vector, pDB 248' and designated as pDB(spo5)1. We futher analyzed six recombinant plasmids, pDB(spo5)2, pDB(spo5)3, pDB(spo5)4, pDB(spo5)5, pDB (spo5)6, pDB(spo5)7 and found each of these plasmids is able to rescue the spo5-2, spo5-3, spo5-4, spo5-5, spo5-6, spo5-7 mutations, respectively. Mapping of the integrated plasmid into the homologous site of the S. pombe chromosomes demonstrated that pDB(spo5)1, and pDB(spu5)Rl contained the spo5 gene. Transcripts of spo5 gene were analyzed by Northern hybridization. Two transcripts of 3.2 kb and 2.5kb were detected with 5kb Hind Ⅲ fragment containing a part of the spo5 gene as a probe. The small mRNA(2.5kb) appeared only when a wild-type strain was cultured in the absence of nitrogen source in which condition the large mRNA (3.2kb) was produced constitutively. Appearance of a 2.5kb spo5-mRNA depends upon the function of the meil, mei2 and mei3 genes.