• Title/Summary/Keyword: CORROSION

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Corrosion Performance of Cu Bonded Grounding-Electrode by Accelerated Corrosion Test

  • Choi, Sun Kyu;Kim, Kyung Chul
    • Corrosion Science and Technology
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    • v.17 no.5
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    • pp.211-217
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    • 2018
  • Natural degradation of grounding-electrode in soil environment should be monitored for several decades to predict the lifetime of the grounding electrode for efficient application and management. However, long-term studies for such electrodes have many practical limitations. The conventional accelerated corrosion test is unsuitable for such studies because simulated soil corrosion process cannot represent the actual soil environment. A preliminary experiment of accelerated corrosion test was conducted using existing test standards. The accelerated corrosion test that reflects the actual soil environment has been developed to evaluate corrosion performances of grounding-electrodes in a short period. Several test conditions with different chamber temperatures and salt spray were used to imitate actual field conditions based on ASTM B162, ASTM B117, and ISO 14993 standards. Accelerated degradation specimens of copper-bonded electrodes were made by the facile method and their corrosion performances were investigated. Their corrosion rates were calculated to $0.042{\mu}m/day$, $0.316{\mu}m/day$, and $0.11{\mu}m/day$, respectively. These results indicate that accelerated deterioration of grounding materials can be determined in a short period by using cyclic test condition with salt spray temperature of $50^{\circ}C$.

Corrosion control of drinking water pipes by corrosion inhibitor (부식억제제에 의한 상수도관의 부식제어)

  • Hwang, Byung-Gi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.6
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    • pp.2306-2310
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    • 2010
  • Corrosion is a complex series of oxidation/reduction reactions between at the water-metal surfaces and materials in which the water is stored or transported. With respect to the corrosion potential of drinking water, the primary concerns include the potential presence of toxic metals, such as lead and copper; deterioration and damage to the household plumbing, and aesthetic problems such as stained laundry, and bitter taste. This study was performed to evaluate the effects of corrosion inhibitors on corrosion rates, Fe and Cu release concentration in water distribution pipes. Decrease of corrosion rates were strongly related to phosphate corrosion inhibitors. Considering that typical corrosion processes consists of a series of electrochemical reaction at the metal surface in contact with water, corrosion rates were positively correlated with Fe release.

Atmospheric Corrosion of Hot Dip Zinc Coated Steel in Coastal and Rural Areas of Vietnam

  • Tru, Nguyen Nhi;Duyen, Le Khac;Han, Tran Mai
    • Corrosion Science and Technology
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    • v.16 no.5
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    • pp.241-246
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    • 2017
  • The comparative results of corrosion testing in humid tropical atmosphere in rural and coastal areas for hot dipped zinc coatings are presented below. The test was conducted in outdoor conditions over a period of five years. The mass loss and other performance characteristics of two types of zinc coatings were evaluated, analysed and discussed in relation to the climatic and environmental parameters. The corrosion rates of the coatings exposed to coastal conditions were about three times higher than the corrosion rates appreciated in rural conditions. The data demonstrates that the corrosion process obeys an equation of the form $M=At^n$, where M is the loss of metal and t is the time of exposure. A and n are constants which values depend on the environmental characteristics and the physicochemical behavior of the corrosion products respectively. Corrosion is strongly influenced by atmospheric time of wetness (TOW) and airborne salinity. The nature and composition of corrosion products are also considered. Simonkolleite, a major crystalline phase, was found in the zinc corrosion products exposed to coastal conditions, while zinc hydroxide and zinc hydrosulfate are easily found in rural settings.

Use of Hydrazine for Pitting Corrosion Inhibition of Copper Sprinkler Tubes: Reaction of Hydrazine with Corrosion By-Products

  • Suh, Sang Hee;Kim, Sohee;Suh, Youngjoon
    • Corrosion Science and Technology
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    • v.16 no.5
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    • pp.247-256
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    • 2017
  • The feasibility of using hydrazine for inhibiting pitting corrosion in copper sprinkler tubes was investigated by examining microscopical and structural evolution of corrosion by-products with SEM, EDS, and XRD. Hydrazine removed dissolved oxygen and reduced CuO and $Cu_2O$ as well. The stable phase was changed from CuO to $Cu_2O$ or Cu depending on hydrazine concentration. Hydrazine concentration of 500 ppm could convert all CuO corrosion by-products to $Cu_2O$. In a tightly sealed acryl tube filled with aqueous solution of 500 ppm hydrazine, octahedral $Cu_2O$ particles were formed while plate-like structures with high concentration of Cu, O, N and C were formed near a corrosion pit. The inside structure of a corrosion pit was not altered by hydrazine aqueous solution. Uniform corrosion of copper was almost completely stopped in aqueous solution of 500 ppm hydrazine. Corrosion potential of a copper plate was linearly dependent on log (hydrazine concentration). The concept of stopping pitting corrosion reaction by suppressing oxygen reduction reaction could be verified by applying this method to a reasonable number of real sprinkler systems before full-scale application.

An Electrochemical Study on the Corrosion Property of Materials for Sea Water Heat Exchange System (해수 열교환기용 재료의 부식특성에 관한 전기 화학적 연구)

  • 김진경;김강희;김성종;박근현;문경만
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.1
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    • pp.99-107
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    • 2002
  • Recently all kinds of structural materials are subjected to the severe corrosive environment. Especially corrosion problems of heat exchanger such as galvanic corrosion, erosion and cavitation raised by both contaminated solution and high velocity of fluid to increase cooling effect of heat exchanger have been frequently reported in these days. In this study two kinds of sheet materials and five kinds of tube materials are used for galvanic corrosion characteristics and their corrosion current density calculation. The tube materials having the most galvanic corrosion resistance between tube and sheet of heat exchanger were Al Brass(68700) and Al Brass(C6872TS) and although Ti tube predominantly indicated the highest individual corrosion resistance among those five tube materials. it appeared that Ti tube can be allowed as sheet materials to get galvanic corrosion easily. However it is considered that Cu-Ni tube materials is not only easy to produce galvanic corrosion significantly between tube and sheet regardless of kinds of sheet materials but also is appeared considerably its own high corrosion current density

A Study on the Fatigue Life Prediction of Al-2024 with Corrosion (부식을 고려한 항공기재료의 부식피로수명예측 연구)

  • Kim, Wie-Dae
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.1
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    • pp.46-51
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    • 2007
  • In this study, test results for fatigue crack propagation of Al-2024-T3511 are presented considering corrosion effects, and fatigue lifes are compared for the cases of corrosion and non-corrosion. Higher corrosion environments show lower fatigue life and faster crack growth. To predict the corrosion fatigue life, a corrosion factor concept is newly introduced and applied in Paris' law. The predicted results show good agreement with experimental data and this corrosion fatigue model can be successfully used for the prediction of fatigue life of aluminum structure with corrosion effects.

Survey of Corrosion Cost in China and Preventive Strategies

  • Ke, Wei;Li, Zhiqiang
    • Corrosion Science and Technology
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    • v.7 no.5
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    • pp.259-264
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    • 2008
  • A national consultative project entitled "corrosion cost survey in China and preventive strategies" was funded by the Chinese Academy of Engineering in 1998. Soon afterwards, an expert group was organized jointly by the Institute of Metal Research, CAS and Chinese Society of Corrosion and Protection. The report on corrosion cost survey in China was published in 2003. According to this report the overall annual corrosion cost in China estimated by the Uhlig Method and Hoar Method at 1997-2001 was found to be 200.7 billion Yuan RMB and 228.8 billion Yuan RMB respectively, which is equivalent to 2% of the gross national product of China. However the total cost of corrosion including the direct and indirect cost was estimated to be more than 500 billion Yuan RMB per year in China. Among them, corrosion cost of infrastructure ranked in first comparing with other sectors. Although corrosion costs in some sectors, such as electric power, petrochemical, oil pipeline and railway in China has reduced in the past years, significant losses are still being encountered in most sectors of industries and cost-effective methods have not always been implemented. Both successful and unsuccessful cases in corrosion control and corrosion management were collected. As the investment in capital construction continues increasing rapidly in China, the maintenance and life extension of the infrastructures will become a big issue. The preventive strategies have been suggested

Intergranular Corrosion of Stainless Steel (스테인리스강 입계부식)

  • Kim, Hong Pyo;Kim, Dong Jin
    • Corrosion Science and Technology
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    • v.17 no.4
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    • pp.183-192
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    • 2018
  • Stainless steel can be classified into three categories depending on the microstructure as austenitic stainless steel, ferritic stainless steel and martensitic stainless steel. Generally, stainless steel is extremely resistant to corrosion as the name implies. However, under specific environments, susceptibility to localized corrosion such as pitting, intergranular corrosion and stress corrosion cracking increases. This paper reviewed the state of arts on intergranular corrosion mechanisms, countermeasures on intergranular corrosion and intergranular corrosion test methods. Intergranular corrosion is mostly related with chromium depletion at the grain boundary and sometimes with segregation of electroactive elements in solution annealed stainless steel. Countermeasures on intergranular corrosion include avoiding chromium depletion by heat treatment and the addition of alloying elements. Sensitization evaluation of stainless steel was performed either through acid immersion test or electrochemical test. The methods were standardized in (Japanese Industrial Standards). Even though are useful in evaluating the degree of sensitization for industrial purpose but do not provide detailed information about sensitization mechanism, cause and chromium profile.

Influence of pH in 3.5% NaCl aqueous solution on corrosion fatigue-fracture of dual phase steel (3.5% NaCl 수용액의 pH변화가 복합조직강의 부식피로파괴에 미치는 영향)

  • 오세욱;안호민;도영문
    • Journal of Ocean Engineering and Technology
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    • v.1 no.2
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    • pp.123-129
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    • 1987
  • Corrosion fatigue fracture of dual phase steel(SS41) and raw material steel(SS41) were investigated in 3.5% NaCl aqueous solution at PH 4,6,9 and 11. The fatigue limit of dual phase steel is increased approximately 1.8 times larger than that of raw material in air. The corrosion fatigue life of dual phase steel is about 5-10 times larger than that of raw material in 3.5% NaCl aqueous solution. The reduction of fatigue life is larger for the acidsalt solution than for the alkali salt solution. The reduction of stress level on the reduction ratio of corrosion fatigue life is large as pH 6-11. The reduction ratio of corrosion fatigue life of dual phase steel and raw material is nearly coincided at pH 2. While at pH4-2 the reduction ratio of corrosion fatigue life only depends on the corrosion effect. It has been found that the corrosion resistance effect of dual phase steel is smaller than that of raw material in corrosion fatigue crack propagation rate. As pH below 6 is changed, it can be clearly observed from raw material that the brittle intergranular fracture is characterized, and from the above result, the influence of corrosion of dual phase steel is small.

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High Temperature Salt Corrosion Property of Ferritic Stainless Steels (페라이트계 스테인리스강의 고온염 부식특성에 관한 연구)

  • Song, Jeon-Young;Park, Joong-Cheol;Ahn, Yong-Sik
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.6
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    • pp.860-866
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    • 2009
  • It is very important to choose optimal material having good corrosion resistance and capabilities for the part materials such as the automotive exhaust system under a hot salt corrosion atmosphere. Generally, two types of corrosion come into the automotive exhaust system. One is 'Condensate Corrosion', which is occurred by exhaust gas condensate formed at the inner surface of exhaust system heated up during driving, which results in the acid condensate pitting. The other is 'High Temperature Salt Corrosion' occurring from the interaction between the chloride ion coming from salt at the seaside district or snow salt and the outer surface of exhaust system. By the corrosion attack, the main muffler is firstly damaged and the life cycle of an automobile is significantly decreased. It has been investigated that the hot salt corrosion properties of a STS 409L and 436L ferritic stainless steels which are well-known for the materials of the automotive exhaust system. In addition, the corrosion properties of hot dip aluminum coated STS 409L have been compared with uncoated steels. Aluminum coated STS 409L showed a superior corrosion resistance than uncoated STS 409L, and futhermore showed a better corrosion resistance than a STS 436L, which is an expensive ferritic stainless steel having a excellent corrosion resistance caused from more chromium content of an alloying element.