• 제목/요약/키워드: CORROSION

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TMCP 강의 부식열화 및 부식피로강도 평가 (Evaluation of Corrosion Fatigue Strength and Corrosion Degradation of TMCP Steel)

  • 박진형;배동호
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.241-246
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    • 2003
  • In order to develop a method of corrosion fatigue design and estimate reliability of TMCP steel using as the material of heavy industries and plants, its corrosion susceptibilities, corrosion fatigue strength, and determination of fatigue design criterion considering corrosion degradation were investigated. From the results, the corrosion characteristic of TMCP steel is very susceptible in 3.5wt.% NaCl solution. Its susceptibility was linearly increased with the solution temperature increase. The corrosion fatigue strength in $25${\circ}$, 3.5wt.% NaCl solution is very lower than that of in air. And also, it was decreased with the frequency decrease in the same environment. It is expected that the developed corrosion fatigue design method for TMCP steel is useful. However, it is necessary to verify its reliability for actual application.

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상수도관의 부식특성과 부식깊이 추정 모델 (Characteristics of Pit Corrosion and Estimation Models of Corrosion Depth in Buried Water Pipes)

  • 김재학;류태상;김주환;하성룡
    • 상하수도학회지
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    • 제21권6호
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    • pp.689-699
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    • 2007
  • The accurate estimation of water pipe deterioration is indispensable to prevent pipe breakage and manage in advance. In this study, corrosion of water pipe is adopted, which is relatively underestimated although it takes most part of deteriorating pipeline. Predicting corrosion rate and corrosion depth of a pipe can make an increase the life span of the pipeline, which is laid under the ground according to characteristics of soil and water corrosion. For the purpose, mathematical models that can presume nominal depth through estimation of pit corrosion and corrosion rate is introduced. As comparison of results with conventional methods in other foreign countries, it is evaluated that the external corrosion depth is estimated less than the models, proposed by other researchers and the internal corrosion rate was processed faster than the external corrosion rate.

선박용 디젤엔진 과급기 로터 접합체의 부식특성에 미치는 비틀림응력의 영향 (Effects of Torsional Stress on the Corrosion Characteristics in the Rotor Assembly of Marine Diesel Engine Supercharger)

  • 조상근;공유식;김영대
    • 동력기계공학회지
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    • 제9권1호
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    • pp.50-56
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    • 2005
  • The corrosion experiment was performed for 120 hours on the specimens in the natural seawater tank with four steps of the loaded torsional stress. The surface corrosion pattern of SCM440 area was showed global corrosion and narrow pitting, that was cause by galvanic corrosion between friction welded IN713LC and SCM440. But corrosion does not proceeded from IN713LC area. Initially, the average relative electrode potential and corrosion current were decreased suddenly, by and large, it was stabilized gradually tend to decreasing with the elapse of the immersion time. The corrosion rate was decreased by increasing the load stress, but 200 MPa specimen was showed most large value.

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Application of the Electrochemical Noise Method with Three Electrodes to Monitor Corrosion and Environmental Cracking in Chemical Plants

  • Ohtsu, Takao;Miyazawa, Masazumi;Ebara, Ryuicluro
    • Corrosion Science and Technology
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    • 제7권3호
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    • pp.173-178
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    • 2008
  • Recently an electrochemical noise method (ENM) with three electrodes has gained attention as a corrosion monitoring system in chemical plants. So far a few studies have been carried out for localized corrosion and environmental cracking of chemical plant materials. In this paper the ENM system is briefly summarized. Then an application of ENM to general corrosion for chemical plant materials is described. The emphasis is focused upon the analysis of stress on the corrosion cracking process of austenitic stainless steel in 30% $MgCl_2$ aqueous solution and the corrosion fatigue crack initiation process of 12 Cr stainless steel in 3% NaCl aqueous solution by ENM. Finally future problems for ENM to monitor regarding corrosion and environmental cracking in chemical plants are discussed.

A5083-H116 알루미늄 합금재 용접부의 부하응력에 따른 부식특성의 영향 (Effect of Corrosion Characteristics in Relation to Loaded Stress in the Welded Zone of A5083-H116 Aluminum Alloy)

  • 조상근;공유식;김영대
    • 동력기계공학회지
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    • 제8권3호
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    • pp.44-51
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    • 2004
  • Effect of corrosion characteristics in relation to loaded stress in the welded zone of A5083-H116 aluminum alloy, in the seawater was studied. The corrosion experiment was performed for 120 hours on the specimens in the natural seawater tank with four steps of the loaded stress. The corrosion crack, corrosion rate, electrode potential, current, and corrosion pattern, etc. were examined for the specimens with the elapse of the immersion time. The main result derived from this study is the crack growth length is increased with the increasing loaded stress. The electrode potential and the corrosion current are decreased rapidly in the early stage of the corrosion, and then decreased gradually and stabilized eventually with the elapse of the immersion time. The test condition of the longer crack growth tends to show the higher corrosion rate. Corrosion pattern of the welded zone indicates that the depth and width of the pitting become increasing with the increasing loaded stress.

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해수환경중 캐비테이션 침식-부식 하에서의 응력부식균열 거동 (II) (Stress Corrosion Cracking Behavior under Cavitation Erosion-Corrosion in Sea Water-Part (II))

  • 안석환;임우조
    • 수산해양기술연구
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    • 제36권2호
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    • pp.139-146
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    • 2000
  • Cavitation can occur in pipes when liquid is moving at high velocity, especially at pittings where the smooth bore of the pipe is interrupted. The effect is usually to produce pitting on the downstream side of the turbulence. However, stress corrosion cracking behavior under cavitation erosion-corrosion was neatly unknown. In this study, therefore, some were investigated of stress corrosion cracking behavior, others were stress corrosion cracking behavior under cavitation erosion-corrosion of water injection. And datas obtained as the results of experiment were compared between the two. Mainresult obtained are as follows: 1) Stress corrosion cracking growth rate of heat affected zone under cavitation erosion-corrosion becomes most rapid, and stress intensity factor $K_1$becomes most high. 2) Stress corrosion cracking growth mechanism by cavitation erosion-corrosion is judgement on the strength of the film rupture model and the tunnel model. 3) The range of potential as passivation of heat affected zone is less noble than that of base metal, and that value is smaller. 4) Corrosion potential under cavitation erosion-corrosion in loaded stress is less noble than that of stress corrosion, and corrosion current density is higher.

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IN713LC-SCM440 이종재 마찰용접부의 부식특성에 미치는 pH의 영향 (The Effects of pH on the Corrosion Characteristics in Dissimilar Friction Welded Zone of IN713LC-SCM440)

  • 조상근;공유식;김영대
    • 한국해양공학회지
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    • 제19권2호
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    • pp.53-59
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    • 2005
  • The effect of pH on the corrosion characteristics in the dissimilar friction welded zone of IN713LC-SCM440 in the loaded torsional stress was studied. The corrosion experiment was performed for 120 hours on the specimens with five steps of pH. The surface corrosion pattern of the SCM440 area showed global corrosion and narrow pitting, which was caused by galvanic corrosion between friction welded IN713LC and SCM440, but corrosion did not proceeded from the IN713LC area. The average relative electrode potential gradually tends to decrease with the elapse of the immersion time in the acidity area. The average corrosion current also gradually tend to decrease The corrosion rate showed a larger value when the average relative electrode potential was higher and the average relative current was lower. The corrosion rate showed a larger value when the average relative electrode potential was higher in the acidity area, and it showed large when the average relative electrode potential was lower in the alkalinity area.

스테인리스 강의 부식 측정방법의 이용과 전망 (Prospects on the Use of Corrosion Rate Measurement Method for Stainless Steel)

  • 최용선;이재원;박은옥;이기영
    • 한국표면공학회지
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    • 제54권6호
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    • pp.294-301
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    • 2021
  • As the number of cases of performance degradation owing to corrosion of plant during processing in industries increases, the cost of maintaining industrial factory is increasing year by the year. Most of the materials of the facilities are consist of stainless steel (SS) such as austenite SS, ferrite SS, martensite SS, and duplex SS. Among them austenite SS is cheap and has excellent corrosion resistance and heat resistance. Corrosion is the consumption and change of metals by altering chemical and electrical reactions. The types of SS corrosion include pitting corrosion, crevice corrosion, galvanic corrosion, stress corrosion cracking, and thermal corrosion. The corrosion of SS is not only investigated various environmental factors but also the measurement of the corrosion rate. Therefore, it aims to understand comprehensive corrosion rates in various environments using qualitative, quantitative and electrochemical methods.

머플러용 스테인리스강의 내식성에 미치는 열적 산화의 영향 (Effects of Thermal Oxidation on Corrosion Resistance of Stainless Steels for Muffler Materials)

  • 김동우;김희산
    • 대한금속재료학회지
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    • 제46권10호
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    • pp.652-661
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    • 2008
  • Reduction of NOx in emission gas, improvement of engine efficiency, and extension of warranty period has made demands for developing materials more corrosively resistant to the inner-muffler environments or predicting the lifetime of materials used in muffler more precisely. The corrosion inside muffler has been explained with condensate corrosion mainly though thermal oxidation experiences prior to condensate corrosion. Hence, the aim of this study is to describe how the thermal oxidation affects the corrosion of stainless steel exposed to the inner-muffler environments. Auger electron spectroscopy and electrochemical tests were employed to analyze oxide scale and to evaluate corrosion resistance, respectively. Thermal oxidation has different role of condensate corrosion depending on the temperature: inhibiting condensate corrosion below $380^{\circ}C$ and enhancing condensate corrosion above $380^{\circ}C$. The low temperature oxidation causes to form compact oxide layer functioning a barrier for penetrating condensate into a matrix. Although though thermal oxidation caused chromium-depleted layer between oxide layer and matrix, the enhancement of the condensate corrosion in high temperature oxidation resulted from corrosion-induced crevice formed by oxide scale rather than corrosion in chromium-depleted layer. It was proved by aids of anodic polarization tests and measurements of pitting corrosion potentials. By the study, the role of high temperature oxidation layer affecting the condensate corrosion of stainless steels used as muffler materials was well understood.

Atmospheric Corrosion Behavior of Weathering Steel Exposed to the Outdoors for 10 Years in Korea

  • Yoo, Y.R.;Choi, S.H.;Kim, Y.S.
    • Corrosion Science and Technology
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    • 제21권4호
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    • pp.258-272
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    • 2022
  • Steel structures exposed to the outdoors experienced several types of corrosion, which may reduce their thickness. Since atmospheric corrosion can induce economic losses, it is important to consider the atmospheric corrosion behavior of a variety of metals and alloys. This work performed outdoor exposure tests for 10 years at 14 areas in Korea and calculated the atmospheric corrosion rate of weathering steel. This paper discussed the atmospheric corrosion behavior of weathering steel based on various corrosion factors. The average corrosion rates in coastal, industrial, urban, and rural areas were found to range from (2.83 to 4.23) ㎛/y, (2.99 to 4.23) ㎛/y, (1.72 to 3.14) ㎛/y, and (1.57 to 2.85) ㎛/y respectively. It should be noted that the maximum corrosion rate was about 6.0 times greater than the average corrosion rate. Regardless of the exposure sites, the color differences were increased, but the glossiness was reduced and there was no relationship between the corrosion rate and environmental factors and the glossiness.