• Title/Summary/Keyword: COD reduction

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Reduction of NPS pollution in the No-till field (무경운을 적용한 밭에서의 비점오염원 저감효과)

  • Lee, Su In;Won, Chul Hee;Shin, Min Hwan;Jeon, Je hong;Choi, Joong Dae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.426-426
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    • 2015
  • 무경운 농법은 경작지의 토양을 교란시키지 않고 작물을 재배하는 방법으로, 토양의 물리성 개선과 토양 침식 예방, 생산비 절감 등의 효과가 있어 전 세계적인 인정을 받고 있는 농업기술이다. 그러나 아직까지 무경운의 재배 지속 기간 등 많은 의문이 제기되고 있으며, 국내 환경조건에 맞는 실험적인 연구가 미흡한 실정이다. 이에 본 연구에서는 최적관리기법의 하나인 무경운(No-till)을 적용한 밭의 오염물질 저감효과를 장기적으로 살펴보고자 2011년부터 2014년까지 4년간의 모니터링을 실시하였다. 무경운 농법을 적용하기 위하여 동계피복작물(밀, 보리)을 재배작물 정식하기 전해 겨울에 파종하여 이듬해 6월 말 수확하였다. 이후 7월에서 8월 사이 재배작물(들깨, 무)을 정식하였다. 시비는 2011년에는 축산퇴비, 2012년에는 축산액비 그리고 2013년과 2014년에는 화학비료를 시비하였으며, 매년 경운과 무경운의 시비량은 동일하게 처리하였다. 유출 시험포의 면적은 $150m^2$(폭 5 m, 경사장 30 m)이며, 8개(경사도 3% 4개, 경사도 8% 4개)의 시험포를 조성하여 각각 2개씩 경운(관행)과 무경운을 적용하였다. 모니터링은 재배작물(들깨, 무) 정식 이후부터 작물 수확 전까지 강우사상에 대하여 이루어졌으며, 연구기간동안 총 13회의 강우 사상에 대하여 조사를 실시하였다. 경운대비 무경운 시험포의 평균 오염부하 삭감율을 분석한 결과 경사도 3% 시험포의 경우 BOD는 35.1%, $COD_{Cr}$은 37.4% 그리고 영양염류인 TN과 TP는 각각 36.9%와 33.5%가 삭감된 것으로 조사되었으며, 경사도 8% 시험포의 경우 BOD가 36.4%, $COD_{Cr}$은 45.8%, TN과 TP는 각각 45.5%와 40.6%가 삭감된 것으로 나타났다. 우리나라에서는 경운(관행) 농법이 영농관리 차원에서 대부분 이용되고 있으나, 본 연구 결과에 기초할 때 무경운 농법으로 영농할 경우 강우유출수 및 하천으로 유입되는 비점오염부하를 효과적으로 제어할 수 있을 것으로 기대된다.

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A Study on the Emission Characteristic and Improvement Plan of Domestic Sewage(NPS) in Rural Area (농촌지역 생활하수의 비점오염 유출특성 및 개선방안 연구)

  • SON, Jinkwan;KIM, Changhyun;Yun, Sungwook;KONG, Minjae;CHOI, Duckkyu;KANG, Donghyeon;Park, Minjung;KANG, Banghun
    • Journal of Korean Society of Rural Planning
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    • v.24 no.4
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    • pp.37-46
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    • 2018
  • The nonpoint pollution source (NPS) is irregular in the amount of generated and runoff. About 70% of the water pollution sources in Korea are NPS. Most of the rural areas are small towns with less than 50 families. This is where sewerage supply is poor. This is where the domestic swage of the house flows directly into the small stream. This study investigated the amount and concentration of domestic swage. And investigated NPS for public officials. We have suggested an improvement plan here. Local government officials lack the concept of NPS. Rural residents also do not know about NPS. Therefore, we proposed NPS public relations and education linked to public administration. This is an extension of the national budget and interest. The domestic swage is discharged at about 272 liters per day in a house. We proposed the introduction of small facilities. If the capacity remains, it is suggested to link to cattle shed, pigsty and so on. The BOD, COD, TN, TP, and SS concentrations were all high. This suggested a reduction in concentration in combination with natural water. Finally, NPS facilities were proposed to be put into rural areas. And it was determined that continuous monitoring was necessary. The results of this study were expected to be applied to NPS management.

Effect of Coagulant addition on Nutrient Removal Efficiency in a Submerged Membrane Bioreactor (응집제의 첨가에 따른 Membrane bioreactor 의 고도처리 효율 연구)

  • Park, Jong-Bu
    • Journal of Korean Society on Water Environment
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    • v.27 no.2
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    • pp.235-241
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    • 2011
  • This study was performed to investigate the characteristics of nutrient removal of municipal wastewater in the submerged membrane bioreactor by addition of alum directly into aerobic tank. Membrane bioreactor consists of three reactors such as two intermittent anaerobic tanks and the aerobic tank with hollow fiber membrane. The removal efficiencies of $COD_{cr}$, BOD, SS, TN and TP on the membrane bioreactor were 94.0%, 99.1%, 99.9%, 66.9%, and 58.9%, respectively. In addition, The removal efficiencies of $COD_{cr}$, BOD, SS, TN and TP on the membrane bioreactor with alum addition were 93.4%, 99.0%, 99.9%, 63.2%, and 96.8%, respectively. There was little difference between them on the nutrient removal efficiencies except phophorus removal. The estimated sludge production, specific denitrification rate, specific nitrification rate and phosphorus removal content on the membrane bioreactor were 1.76 kgTSS/d, $0.055mgNO_3-N/mgVSS{\cdot}d$, $0.031mgNH_4-N/mgVSS{\cdot}d$, and 0.095 kgP/d, respectively. And The estimated sludge production, specific denitrification rate, specific nitrification rate and phosphorus removal content on the membrane bioreactor with alum addition were 2.90 kgTSS/d, $0.049mgNO_3-N/mgVSS{\cdot}d$, $0.030mgNH_4-N/mgVSS{\cdot}d$, and 0.160 kgP/d, respectively. The alum content added was 1.7 molAl/molP on an average. The increasing ratio of tran-membrane pressure on the membrane bioreactor was $0.0056kgf/cm^2{\cdot}compared$ to $0.0033kgf/cm^2{\cdot}d$ on the membrane bioreactor with alum addition. There was a slightly reduction effect on membrane fouling by alum addition.

Comparative analysis of vegetation type LID's pollutant load reduction (식생형 LID 시설별 오염물질 유출저감효율 비교분석)

  • Gil, Kyungik;Kim, Sungryul
    • Proceedings of the Korea Water Resources Association Conference
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    • 2020.06a
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    • pp.209-209
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    • 2020
  • 환경부 자료에 따르면 1990년대부터 2000년대 후반까지 국내의 도시면적은 696,239㎢ 증가했다. 도시지역에서의 불투수면적이 차지하는 비율은 25% ~ 80%로 적지 않은 비율을 차지한다. 따라서 도시면적이 증가하면 이는 불투수면적의 증가로 이어지며 이로인한 지표유출로 오염물질의 유입이 늘어나게 되면, 수질오염중 비점오염원이 차지하는 비중의 증가한다. 비점오염원으로 인해 발생하는 환경문제를 해결하기 위해 LID(Low Impact Develpment)시설에 대한 연구가 많이 진행되었다. 본 연구에서는 7년간의 선행 연구결과를 바탕으로 LID 시설별 오염물질 저감효율을 비교분석하였다. 용인 삼계리에 위치한 식생수로 오염지표들의 유입, 유출EMC를 토대로 제거 효율에 대한 평가를 해보면 TSS는 46%, BOD는 48%, COD는 56%. TN은 42% 그리고 TP는 58%가 나왔다. 용인 해곡동에 위치한 식생여과대의 경우 TSS는 83%, BOD는 45%, COD는 43%, TN은 39%, 그리고 TP는 62%가 나왔다. 마지막으로 전주에 위치한 식생체류지의 경우 TSS는 100%, BOD는 75%, TOC는 62%, TN은 67% 그리고 TP는 83%가 나왔다. 이들 자료를 바탕으로 효율성 평가를 해보면 먼저 식생수로의 경우 TP 저감 효율이 58%로 가장 높았으며 TN 저감 효율이 42%로 가장 낮았다. 식생여과대의 경우 TSS 저감 효율이 83%로 가장 높았으며 TN 저감 효율이 39%로 가장 낮았다. 마지막으로 식생체류지의 경우 TSS 저감 효율이 100%에 가까운 양질의 제거효율을 보여주었으며, TOC의 경우 67%로 제일 낮은 제거효율을 보였다. 위 결과를 토대로 판단을 해보면 식생체류지가 전반적으로 좋은 지표를 보였으며 대부분의 상황에 양호한 제거효율을 기대할 수 있다고 생각된다. 식생 LID시설은 자연친화적이며 강우유출과 오염물질을 제거할 수 있다는 장점이 있는 반면, 장치형 LID시설에 비해 넓은 부지면적을 필요로 하므로 설치 지역의 특성에 맞게 LID 시설을 시공하는것이 적절하다고 판단된다. 해당 연구결과는 향후 식생형 LID시설을 설계하는데 있어서 기초자료로 반영될 것으로 기대된다.

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Reduction of Pollutant Load by Small Pond in a Rice Paddy Applied with Pig Manure Compost (돈분퇴비가 시용된 논의 양분유출 저감을 위한 저류지 효과)

  • Kim, Min-Kyeong;Kim, Myung-Hyun;Choi, Soon-Kun;Cho, Kwang-Jin;Hong, Seong-Chang;Jung, Goo-Bok;So, Kyu-Ho
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.4
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    • pp.21-27
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    • 2014
  • Pig slurry has been considered as environmental waste to be treated in an appropriate manner. Moreover, water-born pollution loads by agricultural non-point source(NPS) pollution are expected to become intensified due to ongoing precipitation change. This study was conducted to develop a best management practice to reduce NPS pollution load by agricultural activity with pig manure compost. An eco-friendly way, small drainage pond, was suggested in this study to avoid direct drainage of agricultural runoffs and eventually reduce the amount of pollutants discharged into the surrounding aqua-environment. A small pond($12m^2$) was constructed at the corner of a rice paddy field($17,15m^2$) located in Suwon, Korea. Water was allowed to drain only via a small drainage pond. Sampling was repeatedly made at two locations, one from an entrance and the other from an exit of a pond, during the rice cultivation period(May to October, 2013). Generally, sampling was made only when runoff water drained through a pond, such as during and/or after rain(irrigation). The water quality analysis showed that all quality parameters(SS, $COD_{Mn}$, T-N, and T-P) were improved as water passed through the pond. The amount of runoff water was reduced by 67.8%. Suspended solids and $COD_{Mn}$ concentrations were reduced by 79.8% and 71.9%, respectively. In case of T-N and T-P amounts, the reduction rates were 73.6% and 74.9%, respectively. Our data implies that agricultural NPS pollution from rice paddy fields with pig manure-based fertilizer can be effectively managed when an appropriate drainage water management practice is imposed.

The Use of Oyster Shell Powders for Water Quality Improvement of Lakes by Algal Blooms Removal

  • Huh, Jae-Hoon;Choi, Young-Hoon;Lee, Hyun-Jae;Choi, Woo Jeong;Ramakrishna, Chilakala;Lee, Hyoung-Woo;Lee, Shin-Haeng;Ahn, Ji-Whan
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.1-6
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    • 2016
  • In this year, Koreans have a shortage in agricultural and drinking water due to severe algal blooms generated in major lakes. Waste oyster shells were obtained from temporary storage near the workplace at which oysters were separated from their shells. Heating ($1000^{\circ}C$ for 1 h in air) was employed to convert raw oyster shell powders into calcium oxide powders that reacted efficiently with phosphorus and nitrogen to remove algal blooms from eutrophicated wastewater. As the dispersed amount of heated oyster shell powders was increased, water clarity and visual light penetration were improved. Coagulation, precipitation and carbonation process of the heated oyster shell powders in a water purifier facilitated removal of eutrophication nutrient such as phosphorus and nitrogen, which is both beneficial and economically viable. $CO_2$ implantation by carbonation treatment not only produced thermodynamically stable CaO in oyster shells to derive precipitated calcium carbonate (PCC) but also accelerated algal removal by activation of coagulation and precipitation process. The use of oyster shell powders led to a mean reduction of 97% in total phosphate (T-P), a mean reduction of 91% in total nitrogen (T-N) and a maximum reduction of 51% in chemical oxygen demand (COD), compared with the total pollutant load of raw algal solution. Remarkable water quality improvement of algal removal by heated oyster shell powders and PCC carbonation treatment will allow utilization as water resources to agricultural or industrial use.

Investigation of influence of nano H-ZSM-5 and NH4-ZSM-5 zeolites on membrane fouling in semi batch MBR

  • Sajadian, Zahra Sadat;Hazrati, Hossein;Rostamizadeh, Mohammad
    • Advances in nano research
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    • v.8 no.2
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    • pp.183-190
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    • 2020
  • The objectives of this research were the reduction of membrane fouling and improvement of sludge properties by using synthesized H-ZSM-5 and NH4-ZSM-5 zeolites. These two nano zeolites were synthesized and added to the membrane bioreactor (MBR). Three similar MBRs with the same operational condition were used in order to evaluate their effect on the mentioned matters. The evaluated parameters were trans-membrane pressure (TMP), Fourier-transform infrared spectroscopy (FTIR), particle size distribution (PSD), soluble microbial product (SMP), extracellular polymeric substances (EPS) and, excitation-emission matrix (EEM). The MBR0 was without any additional zeolite while 0.4 g/L of H-ZSM-5 and NH4-ZSM-5 were added to MBRHZSM-5 and MBRNH4ZSM-5, respectively. The COD removal of the MBR0, MBRH-ZSM-5 and MBRNH4-ZSM-5 were 87.5%, 93.3% and 94.6%, respectively. The TMP of the MBRH-ZSM-5 was 45% less than MBR0 whereas the reduction for MBRNH4-ZSM-5 was 65.5%. Also results showed that both H-ZSM-5 and NH4-ZSM-5 caused reduction in protein and polysaccharide related EPS but the NH4-ZSM-5 had better performance toward the elimination of organic compounds.

Evaluation of SRI Water Management on the Reduction of Irrigation Supply and NPS Pollution in Paddies (SRI 물관리 방법이 논의 관개용수량과 비점오염원 저감에 미치는 영향)

  • Seo, Jiyeon;Park, Baekyung;Park, Woonji;Yoon, Kwangsik;Choi, Dongho;Kim, Yongseok;Ryu, Jichul;Choi, Joongdae
    • Journal of Korean Society on Water Environment
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    • v.32 no.2
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    • pp.183-190
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    • 2016
  • Monitored data (rainfall runoff and water quality) from 4 different paddy sites over 3 years were compared to analyze the effect of irrigation water management on irrigation supply and rainfall runoff quality in Korea. The system of rice intensification water management was adopted at one site (SRI) while the conventional water management method was used for rice culture at the other three sites (CT, SD and HD). The soil texture at SRI, CT and SD was sandy loam while that at HD was silt loam. The average reduction of irrigation supply at SRI compared with CT, SD and HD during the 3 years studied was 49%, 51% and 55%, respectively. The average event mean concentration (EMC) at SRI compared with that at CT, SD and HD was decreased by 35% (BOD), 44% (COD), 47% (SS), 19% (TN) and 38% (TP). The correlation between rainfall runoff and the measured non-point source (NPS) pollutants was very good in general. The comparison revealed that SRI water management significantly reduced both irrigation supply and EMC in rainfall runoff. Paddy NPS pollution was closely related to factors that induce runoff such as rainfall and irrigation supply. It was concluded that SRI management could be an effective and practical option to cope with both water shortage due to climate change and water quality improvement in rural watersheds. However, further studies are recommended in large irrigation districts for use in the development and implementation of NPS pollution policies since the data was collected from field sized paddies.

Optimal Condition of Operation Parameter for Livestock Carcass Leachate using Fenton Oxidation Process (가축 사체 매몰지 침출수 처리를 위한 Fenton 산화공정의 최적조건)

  • An, Sang-Woo;Jeong, Young-Cheol;Yoo, Ji-Young;Min, Jee-Eun;Lee, Si-Jin;Park, Jae-Woo
    • Journal of Soil and Groundwater Environment
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    • v.18 no.1
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    • pp.26-35
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    • 2013
  • Outbreak of animal infectious diseases such as foot-and-mouth disease, avian influenza are becoming prevalent worldwide. For prevent the further infection, tremendous numbers of the infected or culled stocks are buried around farm. This burial method can generate a wide range of detrimental components such as leachate, nutrient, salt, and pathogenic bacteria, consequently. In this study, for the stabilization of livestock carcasses leachate, advanced oxidation processes utilizing the Fenton reaction was investigated in lab-scale experiments for the treatment for $COD_{Cr}$ of livestock carcass leachate. $COD_{Cr}$ reduction by the Fenton oxidation was investigated response surface methodology using the Box-Begnken methods were applied to the experimental results. A central composite design was used to investigate the effects of the independent variables of pH ($x_1$), dosage of $FeCl_2{\cdot}4H_2O$ ($x_2$) and dosage of $H_2O_2$ ($x_3$) on the dependent variables $COD_{Cr}$ concentration ($y_1$). A 1 M NaOH and $H_2SO_4$ was using for pH control, $FeCl_2{\cdot}4H_2O$ was used as iron catalyst and NaOH was used for Fenton reaction. The optimal conditions for Fenton oxidation process were determined: pH, dosage of $FeCl_2{\cdot}4H_2O$ and dosage of $H_2O_2$ were 3, 0.6 g (0.0151 M) and 7 mL(0.259 M), respectively. Statistical results showed the order of significance of the independent variables to be pH > initial concentration of ferrous ion > initial concentration of hydrogen peroxide.

ISOLATION, IDENTIFICATION AND CHARACTERIZATION OF AN IMMOBILIZED BACTERIUM PRODUCING N2 FROM NH4+ UNDER AN AEROBIC CONDITION

  • Park, Kyoung-Joo;Cho, Kyoung-Sook;Kim, Jeong-Bo;Lee, Min-Gyu;Lee, Byung-Hun;Hong, Young-Ki;Kim, Joong-Kyun
    • Environmental Engineering Research
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    • v.10 no.5
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    • pp.213-226
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    • 2005
  • To treat wastewater efficiently by a one-step process of nitrogen removal, a new bacterial strain producing $N_2$ gas from ${NH_4}^+$ under an aerobic condition was isolated and identified. The cell was motile and a Gram-negative rod, and usually occurred in pairs. By 16S-rDNA analysis, the isolated strain was identified as Enterobacter asburiae with 96% similarity. The isolate showed that the capacity of $N_2$ production under an oxic condition was approximately three times higher than that under an anoxic condition. Thus, the consumption of ${NH_4}^+$ by the isolate was significantly different in the metabolism of $N_2$ production under the two different environmental conditions. The optimal conditions of the immobilized isolate for $N_2$ production were found to be pH 7.0, $30^{\circ}C$ and C/N ratio 5, respectively. Under all the optimum reaction conditions, $N_2$ production by the immobilized isolate resulted in reduction of ORP with both the consumption of DO and the drop of pH. The removal efficiencies of $COD_{Cr}$, and TN were 56.1 and 60.9%, respectively. The removal rates of $COD_{Cr}$, and TN were the highest for the first 2.5 hrs with the removal $COD_{Cr}/TN$ ratios of 32.1, and afterwards the rates decreased as reaction proceeded. For application of the immobilized isolate to a practical process of ammonium removal, a continuous operation was executed with a synthetic medium of a low C/N ratio. The continuous bioreactor system exhibited a satisfactory performance at 12.1 hrs of HRT, in which the effluent concentrations of ${NH_4}^+$-N was measured to be 15.4 mg/L with its removal efficiency of 56.0%. The maximum removal rate of ${NH_4}^+$-N reached 1.6 mg ${NH_4}^+$-N/L/hr at 12.1 hrs of HRT(with N loading rate of $0.08\;Kg-N/m^3$-carrier/d). As a result, the application of the immobilized isolate appears a viable alternative to the nitrification-denitrification processes.