• Journal of environmental and Sanitary engineering
• /
• v.15 no.2
• /
• pp.34-40
• /
• 2000

In the tungsten industry, molybdenum wire which used as the center supporter for coil shape tungsten wire was removed. Nitric acid dissolution method which used prevalently up to the present, takes nitric acid as major component and use noxious material such as sulfuric acid and hydrochloric acid remove molybdenum wire which used as center supporter by dissolve selectively within the range of no damage on tungsten wire. Mixed acid waste water occurred to the process were difficult to be decomposed by the conventional methords. This mixed acid waste water was treated by ozone, and It was obtained using possible by-product through the treatment waste water. For the three reactors with the same volume ; Blank reactor, Disturbance plate reactor, Packed-bed reactor ; the results were as follows : For the blank reactor COD removal efficiency in the pH = 4 (HRT : 6hr) was 28.5%, COD removal efficiency in the pH = 7 (HRT : 6hr) was 28.6%, and COD removal efficiency in the pH = 10 (HRT : 6hr) was 27.8%. For the disturbance plate reactor COD removal efficiency in the pH = 4 (HRT : 6Min.) was 86.5%, COD removal efficiency in the pH =7 (HRT : 6Min.) was 84.4%, and COD removal efficiency in the pH = 10 (HRT : 60Min.) was 86.8%. For the packed-bed reactor COD removal efficiency in the pH = 4 (HRT : 40Min.) was 76.0%, COD removal efficiency in the pH = 7 (HRT : 40Min.) was 81.3%, and COD removal efficiency in the pH = 10 (HRT : 40Min.) was 84.6%. After O3 treatment using possible by-product(Na2SO4) was 150g/ℓ.

• Journal of Environmental Science International
• /
• v.5 no.4
• /
• pp.513-524
• /
• 1996

Laboratory investigation was conducted to evaluat the mixing effects on organic removal efficiency to treat low-strength synthetic wastewater using modified anaerobic - filter reactor combining anaerobic filter and upflow anaerobic sludge blanket. Using the modified process the low-strength wastewater like municipal sewage could be treated with 85% T-COD removal efficiency at hydraulic retention time of 6 hours. At the constant organic loading of 0.5 kg COD/m 3-day, the organic removal efficiency and effluent COD concentration are increased as influent COD concentration increased from 125 mg/l to 500 mg/l. Mixing effects on organic removal efficiency are evident and optimum mixing speed is found as 50RPM. Placing the granular sludge and media on which slime layer was pre-formed into the reactor seemed to be very effective In achieving short start-up period. Therefore, the steady state was achived after 4 weeks and 1 week based on T-COD and S-COD, respectively.

• KSBB Journal
• /
• v.6 no.4
• /
• pp.345-350
• /
• 1991

The purpose of this study is to investigate biomass characteristics and organic removal efficiency by changing superficial upflow velocity and organic loading rate in treating alcoholic distillery wastewater. Since the biomass concentration and the thickness of biofilm are very sensitive to superficial upflow velocity, a high concentration of biomass could be achieved by decreasing superficial upflow velocity that lowered the organic removal efficiency. Therefore, superficial upflow velocity should be controlled as to give optimum conditions and removal efficiency. Generally, activated sludge system shows 70% COD removal efficiency at$1.5kgCOD/m^3{\cdot}day$, but the fluidized-bed biofllm reactor shows 80% COD removal efficiency even at 6kgCOD/$m^2{\cdot}day$.

• Journal of Environmental Health Sciences
• /
• v.20 no.2
• /
• pp.22-27
• /
• 1994

This study is to discuss the factors influenced on the removal efficiency of a high-strength organic wastewaters investigated using the polypropyrene media which appropriate to attach microorganism in the tube type fixed biofilter reactor. The results obtained in the experiment were as follows: 1. The kinetics of reaction rate (k') were 0.125, 0.135, 0.155 varing initial COD 720, 1280, 1630 mg/l in batch reactor. 2. In the range of pH 4.0 ~12.0 was obtained the removal efficiency of COD higher than 85%. It was proved that variation of pH (4.0 ~12.0) was nothing to do with the removal efficiency of substrate in continuous reactor. 3. Temperature to obtain removal efficiency of COD higher than 85% was 10 ~ 40$\circ$C. Removal efficiency of COD was no less than those at high temperature. 4. In the continuous reactor, the volumetric loading of COD for removal efficiency higher than 95% had to be 0.5~1.5 kg COD/m$^3$.d below. And then the HRT was 8 hrs. 5. In comparison with the activated sludge process, the tube type fixed biofilter process was excellent in removal efficiency of substrate and sludge production rate.

• Journal of environmental and Sanitary engineering
• /
• v.8 no.1
• /
• pp.107-116
• /
• 1993

This study is conducted to investigate treatability by activated sludge process for wastewater from acetaldehyde manufacturing plant. The optimum hydraulic retention time in aeration tank for removal of high strength substrate were measured. The removal efficiency were checked out by hydraulic retention time : 35hr., 40hr. and 45hr., respectively. $COD_{Cr}$, like substances were removed in all hydraulic retention time zone directed for efficiency, but non-biodegradable substances were remained. $COD_{Cr}$ biomass loading was 0.81kg $COD_{Cr}/kgMLVSS$ . day at 35hr. of retention time, 0.34 kg$COD_{Cr}$/kg MLVSS . day at 40hr., and O.l9kg$COD_Cr$/kgMLVSS . day at 45hr. And the mean $COD_{Cr}$, removal efficiency was 65.5%, 81.6% and 83.0%, respectively. And also $COD_{Cr}$, volume loading was 1.01kg$COD_{Cr}/m^3$ day, 0.87kg$COD_{Cr}/m^3$ - day, and 0.79kg$COD_{Cr}/m^3{\cdot }$day, respectively. The basic design parameter obtained is as fallows. The value of Specific substrate removal rate coefficient (k), Yield coefficient(Y) and Decay coefficient($k_d$) was $0.0013day^{-1}$, $0.505kgMLVSS/kgCOD_{Cr}$ and $0.040day^{-1}$, respectively.

• Korean Journal of Environmental Agriculture
• /
• v.25 no.3
• /
• pp.195-201
• /
• 2006

The operational characteristics of anaerobic bioreactors in treating swine wastewater were evaluated upto hydraulic retention time (HRT) of 1 day and organic loading rate (OLR) of $5.1kg-COD/m^3{\cdot}d$ for 200 days. The bioreactors were effective in treating swine wastewaters with COD removal efficiency of $78.9{\sim}81.5%$ and biogas generation of $0.39{\sim}0.59m^3/kg-COD_r$ at OLR of $1.1{\sim}2.2kg-COD/m^3{\cdot}d$. The two-stage ASBF anaerobic bioreactors was effective in treating different characteristics of swine wastewaters since they showed high and stable COD removal efficiency at high OLR due to effective retention of biomass by media and staging. The effects of ammonia on anaerobic digestion were investigated by operating two-stage ASBF reactors using swine wastewaters as influent without and with ammonia removal at HRT of $1{\sim}2$ days and OLR of $2.2{\sim}9.6kg-COD/m^3{\cdot}d$ for 250 days. The COD removal efficiency and biogas generation of two-stage ASBF reactors was decreased by increasing influent ammonia concentrations to 1,580 mg (T-N)/L with increasing OLR to $6.3kg-COD/m^3{\cdot}d$, while those were increased by maintaining influent ammonia concentrations below 340 mg (T-N)/L by MAP precipitation with increasing OLR to $9.6kg-COD/m^3{\cdot}d$. Initial inhibition of ammonia on anaerobic processes was observed at a concentration of 760 mg (T-N)/L and the COD removal efficiency and biogas generation dropped to 1/2 at ammonia concentration ranges of $1,540{\sim}1,870mg$ (T-N)/L. It is essential to remove ammonia in swine wastewaters to an initial inhibition level before anaerobic processes for the effective removal of COD.

• Journal of environmental and Sanitary engineering
• /
• v.12 no.1
• /
• pp.39-48
• /
• 1997

The study was conducted to know the possibility that the removal efficiency of organic and suspended solids(SS) could be increased by suppling of sea water and the optimum amount of sea water to be supplied treat bleaching waste water by lime coagulation settlement at pulp mill process. When the lime dosage was increased, the removal efficiency of COD and SS in the waste water was increased based on the removal efficiency of COD and SS. The lime dosage and removal efficiency was increased proportionally with the lime concentration of 4,000 mg/l, but the increase of removal efficiency was presented slightly above the 4,000mg/l. It was evaluated that the removal efficiencies of COD and SS could be increased and the requirement of lime dosage could be decreased by the sea water supplement. The removal efficiency of SS was most increased when the sea water supplement was 10% or more in the waste water. The removal efficiencies of COD was the best at 4% sea water excepting the dilution efficiency by sea water supplement.

• Journal of environmental and Sanitary engineering
• /
• v.13 no.2
• /
• pp.139-146
• /
• 1998

The characteristics of color and COD removal for dyeing-wastewater using electrochemical reaction were investigated. >From the result, the removal efficiency of color and COD were increased with increase of temperature, decrease of electrode distance, increase of electrolyte concentration and increase of potential and these were obtained above 99%, above 75% within 30 min, individually. Cause of higher COD removal efficiency, it is more suitable that dyeing-wastewater is treated by electrolytic treatment prior to biological treatment. It is concluded that the electrolytic treatment of dyeing-wastewater can be used as the effective and economical method in practical treatment.

• Journal of Environmental Science International
• /
• v.2 no.4
• /
• pp.331-336
• /
• 1993

A mathematical model for organic removal efficiency was investigated in a fluidized bed biofilm reactor by changing the feed flow rate, the residence time and the recycle flow rate. In batch experiment, organic removal could be assumed as first order and an intrinsic first order rate constant(k1) was found $6.4{\times}^{-6}cm^3/mg{\cdot}sec$ at influent COD range of 3040 - 6620 mg/L. In continuous experiment, at the condition of the influent COD, 3040 mg/L, the superficial upflow velocity, 0.47 cm/sec, the biofilm thickness 336 ${\mu}m$ and the biofilm dry density 0.091 g/mL, the calculated COD removal efficiency from the mathematical model gave 60% which was very close to the observed value of 66 %. As the feed flow rate was increased, the COD removal efficiency was sharply decreased and at constant feed flow rate, the COD removal efficiency was decreased also as the residence time being decreased.

• Journal of environmental and Sanitary engineering
• /
• v.5 no.2
• /
• pp.45-52
• /
• 1990

This study is to discuss limiting factors influenced on the removal efficiency of organic materials investigated using the polypropyrene biofilter which appropriate to attach micro-organism in order to apply the contact oxidation proce,:5. The results obtained in the experiment were as follows : 1. In the range o: pH 4.0~ 12.0 was obtained the removal efficiency of COD higher than 85% It was proved that variation of pH(4.0 ~ 12.0) was nothing to do with the removal efficiency of substrate in continuous reactor. 2. Temperature to obtain removal efficiency of COD higher than 85% was $10^{\circ}$ ~$40^{\circ}$. Removal efficiency of COD was no less than those at high temperature if MLVSS concentration was maintained 8,000~ 15,000 m/1. 3. In the continuous reactor, the volumetric loading of COD for removal efficiency higher than 95% had to be 0.5~1.5 kg COD/.d below. And then the HRT was Bhrs. 4. In comparison with the conventional activate sludge process, the contact oxidation process was excellent in removal efficiency, sludge production rate and maintenance.