• Title/Summary/Keyword: COD Test

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Effect of Heat Treatment of Sewage Sludge on Solubilization and Thermophilic Acid fermentation efficinecy (하수슬러지의 열처리에 의한 가용화효과 및 고온산발효의 분해효율에 미치는 영향 평가)

  • Park, Yongjin;Tsuno, Hiroshi;Hidaka, Taira;Kim, SeogKu
    • Journal of the Korea Organic Resources Recycling Association
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    • v.15 no.2
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    • pp.89-97
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    • 2007
  • In this study, thermalpretreatment was used to solubilize organic matter contained in sewage sludge before acid fermentation. By thermal pretreatment, solubilization of particulate CODcr, carbohydrate and protein increased. By thermal treatment at $120^{\circ}C$ for 30 minutes, CODcr solubilization efficiency of the primary sludge reached 8.3%. Meanwhile, for the secondary sludge, CODcr solubilization efficiency reached 16.5% because of high solubilization ratio of protein under the same pretreatment conditon. The results of anaerobic biodegradability test showed that both VFAs conversion ratio and hydrolysis rate of organic compounds in sewage sludge were improved by thermal pretreatment. Meanwhile, the optimum thermal pretreatment condition was varied with composition of organic compounds in sludge. In this study, the optimun thermal pretreatment condition of the primary sludge, containing high concentration of carbohydrate, was $80^{\circ}C$ for 30 minutes. Meanwhile, for the secondary sludge, mainly composed of protein, the sludge treated at $120^{\circ}C$ for 30 minutes showed the effective organic removal and VFAs production.

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Analyses on Environment-friendliness of Waterproof Materials Based on Fish Toxicity Test (어독성 실험에 따른 방수재 친환경 특성 분석)

  • Kim, Sung-Kyun;Woo, Ji-Keun;Lee, Im-Gyu;Yoo, Hy-Ein;Jeong, Jae-Wook
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.13 no.1
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    • pp.57-68
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    • 2010
  • The purpose of this study is to analyze the characteristics of environment-friendliness of waterproof materials based on comprehensive experiments on waterproofness in terms of coefficients of permeability, harmfulness of waterproof materials and fish toxicity of Oryzias latipes mortality to verify eco-toxicity of each method of construction and waterproof material, which are to be applied by taking eco-toxicity into account when building ecological flows in upper areas on natural and artificial grounds. As a result, the following conclusions have been reached in this study: 1. In regard of the harmfulness analyzed, each material showed a different result of analytical value in each lab tank. Compared to input water, pH, COD, SS, T-P, and T-N values increased a little, but DO value decreased. The value of turbidity analyzed independent of the water quality standard of aquatic ecosystem set forth by the Ministry of Environment increased a little compared to the value in input water. 2. In the experiment of fish toxicity, compacted quicklime, cement fluid waterproof material, cement mortar waterproof material and bentonite powder were found to have 100% of fish mortality, respectively, and membrane waterproof material showed 83.3% of mortality, indicating strong fish toxicity. Improved asphalt sheet (63.3%) and synthetic rubber sheet (53.3%) were analyzed to have medium fish toxicity, while bentonite sheet (6.7%), Hwang-toh (6.7%) and clay (3.3%) showed relatively lower mortality and fish toxicity. 3. Regarding the analysis on waterproofness in terms of the coefficient of permeability of each waterproof material, improved asphalt sheet, synthetic rubber sheet, membrane waterproof material, cement fluid and mortar waterproof material and bentonite sheet were found impervious in case no leakage takes place in construction. Bentonite powder was found practically impervious based on the analytical results from the experiment done in compliance with weight ratios. So were the clay and Hwang-toh from the experimental results. To sum up such results as found in the experiment mentioned so far, the values of harmfulness and waterproofness analyzed were different in each lab tank, but there was absolutely little correlation with the mortality gained from the experiment on fish toxicity. In the experiment of fish toxicity, environment-friendly waterproof materials were analyzed, and it was found that clay, Hwang-toh and bentonite sheet are highly environment-friendly. In contrast, synthetic rubber and improved asphalt sheets were found to have medium-level environment-friendliness. Also, membrane water-proof materials, compacted quicklime, cement fluid and mortar waterproof material and bentonite powder were analyzed to have low environment-friendliness.

Influence of Electrochemical Oxidation Potential on Biofilm Structure and Bacterial Dissimilation in Wastewater Treatment Bioreactor (오수처리 반응기에서 생물막 매개체에 부과한 전기화학적 산화전위가 생물막의 구조와 미생물의 대사에 미치는 영향)

  • Na, Byung-Kwan;Park, Doo-Hyun
    • Microbiology and Biotechnology Letters
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    • v.35 no.1
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    • pp.73-80
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    • 2007
  • Biofilm media was equipped in two-compartmented wastewater treatment bioreactor which was separated by porcelain septum. DC 2.0 volt of electric potential was charged to anodic (oxidative) biofilm media (ABM) to induce oxidation potential but not to that of carbon (neutral) biofilm media (CBM) that was used for control test. Biofilm structure, biomass variation, Off variation and wastewater treatment efficiency in the bioreactor equipped with ABM (ABM-bioreactor) and CBM (CBM-bioreactor). Time-coursed variation of biofilm structure forming on surface of ABM and CBM was observed by scanning electron microscopy. The biofilm growing on ABM was dispersed on surface and was not completely covered the media but the biofilm growing on CBM was continuously increased and finally covered the media. The ORP of CBM was decreased to 100 mV, which was reciprocally proportional to the biomass growth. However, the ORP of ABM was about 800 mV, which was maintained during operation for about 60 days. The treatment efficiency of COD in the ABM bioreactor was 2 times higher than those in the CBM bioreactor. From these results, we proposed that electrochemical oxidation potential charged to biofilm media may inhibit formation of biofilm extremely condensed and activate bacterial cell metabolism.

Effect of Alkaline Pretreatment on Sludge Aerobic Digestion and Fertilizer Value (알칼리 전처리에 의한 슬러지 호기성 소화 및 액비 특성 변화)

  • Hwang, Eung-Ju
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.1
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    • pp.90-96
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    • 2008
  • In order to meet the stringent requirement of sludge disposal and to find ecological alternative, aerobic digestion coupled with alkaline pretreatment was studied. The treated sludge was tested for the potential of liquid fertilizer. In the aerobic digestion, it was obvious that the performance of digester B(fed with the sludge pretreated by NaOH) was better than that of digester A(fed with raw sludge) in terms of COD and SS removal. SS and VSS removal rates in digester B were 66% and 69%, respectively. At 5 days, TSS removal rate reached 47% in the digester B, which was 71% of final TSS removal rate. It revealed that the pretreatment process can shorten the retention time of aerobic digestion. 94.1% of TCOD in the raw sludge was reduced by alkaline pretreatment and aerobic digestion. Final SCOD was in the range of 220$\sim$230 mg/L implying the sludge was stabilized. Nitrification and pH drop were observed in the aerobic digestion. Final nitrate concentrations in digester A and B were 445.4 and 223.1 mg/L and final pH in digester B was 3.0. Biological assays reported that leaf size of cucumber seedling increased with nitrate concentration and sludge to soil ratio. The sludge treated by alkaline and aerobic digestion promoted the growth of seedling leaf and stem remarkably compared to raw sludge. In contrast, the aerobically digested sludge without pretreatment improved leaf growth and inhibited stem growth.

Catch and cluster analysis according to net materials of gillnet for the Pacific herring in the coastal waters of Samcheok, Korea (삼척 연안 청어자망의 그물 재질에 따른 어획과 군집 분석)

  • AN, Heui-Chun;BAE, Jae-Hyun;PARK, Jong-Myung;HONG, Sung-Eic;KIM, Seong-Hun;PARK, Hae-Hoon
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.51 no.3
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    • pp.348-354
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    • 2015
  • Experiments for catch and cluster analysis on the catch by gillnet for the Pacific herring were conducted using traditional nylon net (PA) and developing biodegradable net (PBS) with different monofilaments of #2 (=0.23 mm) and #3 (=0.28 mm) in diameter between 2011 and 2012, and of #2, #2.5 and #3 in 2013 in the eastern coastal waters of Samcheok, Korea. The total catch during the experiments was 3,337kg in weight and 16,757 individuals in number. Though the catch ratio of the Pacific herring in 2011 and 2012 was 97.4% and 98.7%, respectively, that of the Pacific herring in 2013 was 73.6% as the biggest and followed by goldeye rockfish (8.6%), black edged sculpin (8.4%), atka mackerel (7.2%) and Alaska cod (1.0%). The ANOVA analysis on the total catch in relation to net material showed that there was not statistically significant difference at the 5% level between nylon net (PA) and biodegradable net (PBS) (p=0.91). With the cluster analysis on the catch in relation to net material (PA, PBS) and twine thick (#2, #3), it showed the influence of net material on the catch was greater than that of twine diameter in this experiment. From the test of homogeneity on the catch by the gillnet with PA and PBS in which several species were caught in 2013, there was not statistically significant homogeneity in relation to net material (p<0.005). That meant the traditional gillnet of nylon (PA) was more efficient than the biodegradable (PBS) gillnet to catch several kinds of fish, however the PBS gillnet was better than the PA gillnet to catch the target Pacific herring.

Determination of Freshness of Fish Meat using Electric Conductivity Meter (전기전도도를 이용한 어육의 선도판정)

  • LEE Byeong-HO
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.22 no.5
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    • pp.219-227
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    • 1989
  • A new devised conductivity meter was used in the rapid and convinient determination of freshness of fish meats. Electric conductivity of frozen fishes like cod, tuna, flounder, Alaksa pollock were demonstrated about $6,100\pm200{\mu}u$ at the beginning of spoilage showed VBN content of $30\~35mg\%$ while that of fresh meat of yellow tail, rock trout, and mackerel were in the range of $5,100\~5,400{\mu}u$. The relationship between electric conductivity and freshness as measured by VBN content was direct proportion during the deterioration of fish meat. It was presumed that electric conductivity change of red muscled fish was more temperature dependence than that of white muscled fishes. $Q_{10}$ value of mackerel meat was about 2.34 at the temperature ranged from 15 to $30^{\circ}C(\pm1^{\circ}C)$). The electric conductivity obtained with conductivity meter could be a valuable criteria for the freshness test of fish meat determining in 10 seconds by handy compact portable meter.

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Enhancement of Denitrification Capacity of Pseudomonas sp. KY1 through the Optimization of C/N ratio of Liquid Molasses and Nitrate (액상 당밀과 질산성 질소의 C/N 비율에 따른 Pseudomonas sp. KY1의 탈질 능력 및 그 최적비율에 관한 연구)

  • Lee, Kyuyeon;Lee, Byung Sun;Shin, Doyun;Choi, Yongju;Nam, Kyoungphile
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.9
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    • pp.654-659
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    • 2013
  • This study was conducted to identify an optimal ratio of carbon to nitrogen (C/N ratio) for denitrification of nitrate using molasses as an external carbon source. A series of batch and column tests was conducted using an indigenous bacterium Pseudomonas sp. KY1 isolated from a nitrate-contaminated soil. For the initial nitrate-nitrogen concentration of 100 mg-N/L, batch test results indicated that C/N ratio of 3/1 was the optimal ratio with a relatively high pseudo-first-order reaction constant of $0.0263hr^{-1}$. At C/N ratio of 3/1, more than 80% of nitrate-nitrogen concentration of 100 mg-N/L was removed in 100 hrs. Results of column tests with a flow velocity of 0.3 mL/min also indicated that the C/N ratio of 3/1 was optimal for denitrification with minimizing remaining molasses concentrations. After 172 hrs of column operation (35 pore volumes) with an influent nitrate-nitrogen concentration of 100 mg-N/L, the effluent met the drinking water standard (i.e., 10 mg $NO_3$-N/L).

A Study on the Stability of Uncontinuous Plate Structures with Cracks (결함을 갖는 불연속평판 구조물의 안정성 연구)

  • Lee, Seon-U;Kim, Si-Yeong;Hong, Bong-Gi
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.20 no.1
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    • pp.37-42
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    • 1984
  • This paper deals with the characterics of the stability of uncontinuous plate structures with cracks. The relation between the J-intergal of the cracks existing in the stress-concentrated regions and local strain are investigated experimentally and theoretically. The BEM(boundary element method)analysis and test results lead to the follow conclusions: 1. A non-dimensional J was computed in a plate stress and strain condition for several kind of loads and crack types. The J design curves are defined as follows: J sub(E)/$\sigma$ sub(y) super(2) a=3.345(e/e sub(y) ) super(2) at e/e sub(y)$\leq$1 J sub(E)/$\sigma$ sub(y) super(2) a=3.345(e/e sub(y) ) at e/e sub(y)$\geq$1 2. Use of this curve provides a good estimation for the uncontinuous plate structures with cracks existing in the stress and strain concentrated region. 3. The stability of the characteristics is mainly depenent upon not the length of cracks but the type of the cracks.

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Developmemt of Rice Husk Pellets as Bio-filter Media of Bio Scrubber Odor Removal System (왕겨펠렛 생물담체 개발 및 이를 이용한 bio scrubber형 악취제거 시스템 성능평가)

  • Bae, Jiyeol;Han, Sangjong;Park, Ki Ho;Kim, Kwang-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.4
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    • pp.554-566
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    • 2018
  • The rice husk contains nutrients which can be easily utilized by microorganisms, and also has a water retaining ability, which played a crucial part in enabling it to become a biofilter media. In this study, we evaluated the applicability of rice husk pellet bio-scrubber as a microbiological carrier. The pelletization experiment of rice husk as a biological media was performed using PVA and EVA binder. Also, the feasibility tests of rice husk as a biological media for odor removal were carried out in order to know whether rice-husk contains useful components as a media for microbiological growth or not. Lastly, a combined test for odor gas absorption and biological oxidation was conducted using a lab scale bio-filter set-up packed with rice-husk pellets as wet-scrubber. The major components of the rice husk were carbon, hydrogen, nitrogen, and oxygen, while carbon acted as the main ingredient which comprised up to 23.00%. The C : N : P ratio was calculated as 45 : 1 : 2. Oxygen uptake rate, yield and decay rate of the rice husk eluent was calculated to be $0.0049mgO_2/L/sec$, 0.24 mgSS/mgCOD and 0.004 respectively. The most stable form of rice husk pellets was produced when the weight of the rice husk, EVAc, PVAc, and distilled water was 10 : 2 : 0.2 : 10. The prepared rice husk pellets had an apparent density of 368 g/L and a porosity of 59.00% upon filling. Dry rice husks showed high adsorption capacity for ammonia gas but low adsorption capacity for hydrogen sulfide. The bio-filter odor removal column filled with rice husk pellets showed more than 99.50% removal efficiency for NH3 and H2S gas. Through the analysis of circulation water, the prime removal mechanism is assumed to be the dissolution by water, microbial nitrification, and sulfation. Finally, it was confirmed that the microorganisms could survive well on the rice husk pellets, which provided them a stable supply of nutrients for their activity in this long-term experiment. This adequate supply of nutrients from the rice husk enabled high removal efficiency by the microorganisms.

Development of Sandwich ELISA for the Detection of Mackerel in Processed Foods (가공식품 중 고등어의 검출을 위한 ELISA의 개발)

  • Shon, Dong-Hwa;Kim, Mi-Hye
    • Korean Journal of Food Science and Technology
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    • v.44 no.1
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    • pp.1-7
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    • 2012
  • There have been few studies related to ELISA for mackerel. In this study we developed a sandwich ELISA for mackerel in processed foods using rabbit polyclonal antibodies against mackerel parvalbumin, the major allergen of mackerel and heat-stable protein. The parvalbumin was purified by ammonium sulfate precipitation and Sephadex G-50 column chromatography. From the standard ELISA curves, the detection limit of parvalbumin was 3 ng/mL and the detection range of mackerel was 5-5,000 ${mu}g/mL$. We further investigated the cross-reactivity of the antibodies toward mackerel, mackerel pike, salmon, flatfish, armorclad rockfish, cod fish, squid, shrimp, blue crab, and lobster. The antibodies were specific for mackerel only. The mean assay recoveries in cooked cream soup, baby food, sausage, and sauce spiked with 0.01 to 0.3% mackerel were 104, 101, 54, and 0%, respectively. In sample tests of 16 commercial items, the qualitative coincidence ratio of assay result and indication was 75%.