• Title/Summary/Keyword: COD Test

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Control of Contaminants Elution by Solidification of Contaminated Soil (오염토양의 고형화에 따른 오염물질 용출제어)

  • Chung, Ha-Ik;Cho, Jin-Woo;Yu, Jun;Lee, Yong-Su
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.739-742
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    • 2002
  • Immobilization of contaminants in contaminated soils by solidification processes is an attractive potential remediation process. In this study, the treatability of lead, copper, toluene, and COD was investigated by leaching test. Industrial sand was adopted as the test material and was contaminated with lead copper, and toluene to 100mg/kg, 500mg/kg, 200mg/kg respectively. P solidifying agent was used as the binder(20% by weight of contaminated soil) in the solidification treatment. The leachability of contaminants leached from the solidified soil was evaluated using column test. The percentage of contaminants leached from the solidified soil was significantly reduced by reaction of waste species with cement components and encapsulation reaction of binder. Based on the tests, it is ascertained solidification process can be a very effective method to control the elution of contaminants from the contaminated soil.

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Analysis of Methane from Screened Soil of Closed Landfill and Application of Landfarming for the Reduction of the Methane (사용종료 매립지 선별토양의 메탄 발생 분석 및 토양경작기술 적용 효과 연구)

  • Kim, Kyung;Yang, Jae-Kyu;Chang, Yoon-Young
    • Journal of Soil and Groundwater Environment
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    • v.15 no.5
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    • pp.40-45
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    • 2010
  • In this study, methane production by reuse of screened soil of landfill was estimated and the effect of application of landfarming for the reduction of methane was investigated. The study soil sampled from S closed landfill contains VS 9.8~12.8% and its BOD/COD is 0.31~0.33 which is more than three times over 0.1, the BOD/COD stabilization criteria of Ministry of Environment. The effective remediation technology for the reduction of organics of soil, landfarming was applied to the screened soil for 60 days. VS and TPH removal showed 5.2~8.3% and 67~74% respectively, and the reduction of VS until 30 day charged 70% of the total reduction. BMP test showed 27.77~30.46 mL $CH_4$/g VS and total methane production from total screened soil for remediation is expected about 260.4 $CH_4$ ton. Expected amount of methane production of the screened soil by landfarming application is 12.9 $CH_4$ ton, which shows 95% gas reduction effect and landfarming is effective for the reduction of methane production from screened soil of landfill.

Effect of Digestion Temperature on the Solid-Liquid Separation Characteristics of Anaerobically Digested Municipal Sewage Sludge (도시하수슬러지의 혐기성소화시 고액분리 특성에 미치는 소화온도의 영향)

  • Han, Jang Woon;Chang, Duk;Kim, Sung Soon
    • Journal of Korean Society of Water and Wastewater
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    • v.8 no.1
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    • pp.1-8
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    • 1994
  • Laboratory experiments were conducted to investigate the effect of digestion temperature on the settleability and dewaterability of anaerobically digested sludge. The digesters were operated at a hydraulic retention time of 20 days with a loading rate of 0.63~0.66kg volatile solids per cubic meter per day at the temperature of $35^{\circ}C$ and $55^{\circ}C$. A mixed primary and secondary municipal sludge was used as a feed. The interface height of the sludge during settling test was recorded to identify settleability. As a measure of dewaterability of the sludge, specific resistance and capillary suction time were also measured with and without chemical conditioning. Higher digestion efficiency was obtained at $55^{\circ}C$ than $35^{\circ}C$. However, the settleability and dewaterability of the sludge at $35^{\circ}C$ were quite higher than those of the sludge digested at $55^{\circ}C$. The optimum dosages of ferric chloride for sludge conditioning were 0.4% and 0.6% at $35^{\circ}C$ and $55^{\circ}C$, respectively. The filtrate COD of the sludge digested at $55^{\circ}C$ was higher than at $35^{\circ}C$, which means that poor dewaterability of the sludge result in high filtrate COD.

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Characteristics of Phenolic Wastewater Treatment using Moving Bed Biofilm Reactor in the MLE Process (MLE type MBBR을 이용한 페놀화합물 함유폐수의 처리특성)

  • Kim, Moon Ho;Oh, Sung Mo;Bae, Yoon Sun;Park, Chul Hwi
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.5
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    • pp.521-529
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    • 2007
  • Nutrient removal from synthetic wastewater was investigated using a MLE (Modified-Ludzack Ettinger) type MBBR (Moving Bed Biofilm Reactor), with different phenol ($C_6H_5OH$) concentrations, in order to determine the inhibition effects of phenol on biological nutrient removal and the biodegradation of phenolic wastewater. The wastewater was prepared by mixing a solution of molasses with known amounts of phenol and nutrients. The experiments were conducted in a lab-scale MLE type MBBR, operated with four different phenol concentrations (0, 67, 100 and 168mg/L) in the synthetic feed. Throughout the experiments, the ratio of the phenolic COD concentration to the total COD was varied from 0 to 1. Throughout batch test, the SNR (Specific Nitrification Rate) and SDNR (Specific Denitrification Rate) were significantly influenced by changes of the phenol concentration. Phenol was inhibitory to the nitrification/denitrification process, and showed greater inhibition with higher initial phenol concentrations. The SNR observed with 0, 67, 100 and 168mg phenol/L were very different like 10.12, 6.95, 1.51 and $0.35mg\;NH_{3^-}N/gMLVSS$ hr, respectively. Similarly, the SDNR observed at 0, 67, 100 and 168mg phenol/L were different like 0.322, 0.143, 0.049and 0.006mgN/gMLVSS day, respectively.

A Study on the Substrate Removal Efficiency with Varing SRT in Anaerobic Treatment of High Organic Wastewater (고농도 유기성폐수의 혐기성처리시 SRT변화에 따른 유기물질 제거효율에 관한 연구)

  • Kim Byeong Ho;Kim Dong Min
    • Journal of environmental and Sanitary engineering
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    • v.4 no.1 s.6
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    • pp.43-52
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    • 1989
  • A synthetic wastewater composed of powdered baby food and inorganic nutrients was treated by five 3.6L anaerobic reactors in order to test the relationship between solids retention time (SRT) and media surface ratio, and the removal efficiencies of organic substrate. Of the five reactors, four were semi-continuously fed stirred-tank reactors and one continuously-stirred batch reactor. The influent was 7430mg/L in COD, 7120 mg/L $BOD_L$ and 6350mg/L in $BOD_5$, respectively. Operating temperature was $35{\pm}1^{\circ}C$ and pH in the range 6.9 to 7.2. In this experimental study it was found that a linear relationship existed, within the experiment range, between SRT and media surface ratio, and that SRT and removal efficiency increased with increasing media surface ratio. The substrate removal efficiencies were 82.7 to $88.2\%$ in COD, 82.9 to $88.4\%$ in $BOD_L$ and 83.3 to $88.7\%$ in $BOD_5$, respectively.

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Saturation curves for chemical coagulation of wastewater treatment (화학 응집제 투입에 따른 수질항목별 하수처리 반응곡선)

  • Ryu, Jae-Na;Oh, Je-Ill;Lee, Kyeoung-Jong
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.5
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    • pp.537-548
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    • 2010
  • Recently the Government has announced updated water quality standards for wastewater treatment effluent (become effective in 2012). That includes highly enforced regulations for T-P, BOD and COD, and a large budget, in particular for phosphorus removal, was set by the Ministry of environment. Chemical coagulation destabilizes colloidal particles so that particles grow to larger flocs, and solid particles are removed by solid-liquid separation. The efficiency of chemical coagulation depends on a various factors, including coagulant types and costs, construction and operation costs for the treatment facilities and so on. The proper selection should be based on the treatment efficiency of coagulants and underlying costs. The current research was to evaluate the treatment efficiencies of coagulants on a variety of wastewater influents and to develop saturation curves for several water quality parameters. Typical $Al_2(SO_4)_3$ and $FeCl_3$ were tested under a range of coagulant concentrations. The pollutant removal efficiencies of chemical treatment both for the $Al_2(SO_4)_3$ and $FeCl_3$ were especially high for T-P, followed by SS, BOD and COD. Correlation test also proved the highest relationship between SS and T-P.

Effects of the Redox Potential of the Acidogenic Reactor on the Performance of a Two-Stage Methanogenic Reactor

  • Phae, Chae-Gun;Lee, Wan-Kyu;Kim, Byung-Hong;Koh, Jong-Ho;Kim, Sang-Won
    • Journal of Microbiology and Biotechnology
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    • v.6 no.1
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    • pp.30-35
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    • 1996
  • Distillery wastewater was used in a thermophilic laboratory-scale two stage anaerobic digester to test the effects of the redox potential of the first acidogenic reactor on the performance of the system. The digester consisted of first a acidogenic reactor and the an upflow anaerobic sludge blanket (UASB) reactor. The digestor was operated at a hydraulic retention time (HRT) of 48 h. Under these conditions, about 90% of the chemical oxygen demand as measured by the chromate method ($COD_{cr}$) was removed with a gas production yield of 0.4 l/g-COD removed. The redox potential of the acidogenic reactor was increased when the reactor was purged with nitrogen gas or agitation speed was increased. The increase in reduction potential was accompanied by an increase in acetate production and a decrease in butyrate formation. A similar trend was observed when a small amount of air was introduced into the acidogenic reactor. It is believed that the hydrogen partial pressure in the acidogenic reactor was decreased by the above mentioned treatments. The possible failure of anaerobic digestion processes due to over-loading could be avoided by the above mentioned treatments.

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Property of Water Environment and Evaluation of Zooplankton as Predators for the Control of Algal Bloom in the Agricultural Reservoir (농업용저수지의 녹조제어를 위한 수환경 특성과 포식성 천적생물의 분리 및 효과분석)

  • Nam, Gui-Sook;Song, Young-Hee;Lee, Eui-Haeng;Hong, Dae-Byuk;Han, Myung-Soo
    • KCID journal
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    • v.18 no.1
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    • pp.33-43
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    • 2011
  • Jundae reservoir has basin area of 234ha, average depth of 3.77m and total storage of $619{\times}10^3m^3$, and is located in Dangin-gun, Chungcheongnam-do. The water quality of Jundae reservoir exceeded the IV grade of water quality standard as available for irrigation water in COD, TN, TP, Chl-a. COD and Chl-a were higher in spring season, because the algal bloom by phytoplankton increased. And the algal blooms in October by inflow non-point pollution during summer rainy season. The most dominant zooplankton was rotifers during study period at all stations. Dominant species were Keratella cochlearis, Polyarthra spp., and Trichocerca spp. We successfully established 2 isolated clone cultures as predator. One is Rotifer, Euchlanis sp. and another is cladocerans, Bosmina sp. To test the removal rate of 2 cultures against Microcystis aeruginosa, we inoculated Euchlanis sp. and Bosmina sp. separately when the abundance reached at $1.0{\times}10^6$cells/ml. Euchlanis sp. removed M. aeruginosa around 98.9% and Bosmina sp. removed it around 98.4%. They are useful grazers for controling algae blooms, Euchlanis sp. and Bosmina sp. feeding on M. aeruginosa highly.

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A Study on the Degradation of PAH in Organic and Aqueous Phases by Ozone (다환방향족탄화수소에 대한 오존처리의 방법에 관한 연구)

  • Choi, Young Ik;Son, Hee-Jong;Jung, Chul-Woo
    • Journal of Korean Society on Water Environment
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    • v.22 no.6
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    • pp.1123-1129
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    • 2006
  • Pyrene of natural and anthropogenic sources is one of the toxic, mutagenic polycyclic aromatic hydrocarbons (PAHs) listed as priority pollutants. The objectives of this research are to break down pyrene by using ozonation, identify the intermediates and byproducts of pyrene, and test the biodegradability of intermediates and byproducts of pyrene in the aqueous phase. Since pyrene is non-polar, hexane was chosen as a solvent to effectively dissolve pyrene. Pyrene solutions were treated with ozone, as it has high oxidation capacity and electrophilic characteristic. After different ozonation pretreatment times (2, 3, and 10 minutes), intermediates of pyrene in the form of yellowish solid were collected from the hexane solution using a centrifuge. They were identified by gas chromatography/mass spectrometer (GC/MS). $BOD_5$, COD, and E-coli toxicity tests have been performed to assess the ozonation products.

The Charateristics of Melting Slag from MSWI and Sewage Water Filter Application (소각용융슬래그의 특성 및 수처리 여과재 활용에 관한 연구)

  • Park, Sang-Goo;Kim, Gun-Heung
    • Journal of Wetlands Research
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    • v.14 no.4
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    • pp.471-478
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    • 2012
  • The objective of the study is to find a way to utilize MSWI slag as filter material and to verify it. To do so, stability as filter material was tested, and used Ju-Munjin filter sand as control group to run actual filtering experiment to analyze filtering efficiency. According to result, MSWI slag is usable within designated waste acceptable standards. Also, it showed similar level of filtering capability to filter sand. Thus, MSWI slag could help to save and recycle resources if used as filtering material instead of filter sand As result of filtering test, SS and COD showed about same level of filtering capability similar to standard filter sand. MSWI slag has shown 26.96% higher with T-N, and 6.55% higher with T-P compared to standard filter sand. Also, remove efficiency comparison result with No. 40#(0.43mm) and mixed diameter showed equal or greater filtering capability.