• Journal of the Korean Chemical Society
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• v.24 no.1
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• pp.8-14
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• 1980

Solvolysis rate constants for methylchloroformate, $CH_3O$(CO)Cl, methylthiono-chloroformate, $CH_3O$(CS)Cl, and methylthiolchloroformate, $CH_3S$(CO)Cl, have been determined conductometrically in acetone-water and acetonitrile-water mixtures, and activation parameters, ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$, have been derived. Results show that in water-rich regions the order of rate increases as $$CH_3O(CO)Cl while in dipolar aprotic solvent-rich region this order reverses. The plots of log k vs. solvent parameters, Y, $\frac{D-1}{2D+1}$ and log($H_2$) show that the order of rate increase in water-rich region is the results of increase in $S_N1$ character. It is concluded that $CH_3S$(CO)Cl solvolyzes via $S_N1$ mechanism whereas $CH_3O$(CO)Cl reacts via $S_N2$ and $CH_3O$(CS)Cl via intermediate mechanism in water-rich region.

• Journal of Welding and Joining
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• v.13 no.1
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• pp.127-137
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• 1995

The possibility of new GMAW process using economic shielding gases including CO$_{2}$ gas was investigated on the effect of shielding gas on weldabilty. In the optimum welding condition using 600A power source, FCAW process showed low depositions rate, 114 g/min at 300A, but new GMAW using other mixed shielding gases exhibited high deposition rate, 208-224 g/min at 450A. TIME gas, Ar+CO$_{2}$ gas and Ar+CO$_{2}$+O$_{2}$ gas as a shielding gas were able to be used to the very high welding current(450A), moreover TIME gas and Ar+CO$_{2}$ gas showed the highest arc stability among shielding gases studied in this experiments. The weld penetration was performed by axial spray transfer mode of weld droplet. On the basis of workability, weldability and economic point of view, Ar mixture (80%Ar+20%CO$_{2}$) gas was recommended as a shielding gas for the development and application of new GMAW process. This shielding gas showed the low spatter, good weld quality, stable arc and low cost at the region of high welding current.

• Membrane and Water Treatment
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• v.7 no.5
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• pp.463-476
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• 2016

In this study, application of polypropylene hollow fiber membrane contactors for $CO_2$ removal from water in liquid-liquid extraction (LLE) mode was simulated. For this purpose, a steady state 2D mathematical model was developed. In this model axial and radial diffusion was considered to $CO_2$ permeation through the hollow fibers. $CO_2$ laden water is fed at a constant flow rate into the lumen side, permeated through the pores of membrane and at the end of this process, $CO_2$ solution in the lumen side was extracted by means of aqueous diethanolamine (DEA) and chemical reaction. The simulation results were validated with the experimental data and it was found a good agreement between them, which confirmed the reliability of the proposed model. Both simulation and experimental results confirmed the reduction in the percentage of $CO_2$ removal by increment of feed flow rate.

• Journal of Ecology and Environment
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• v.37 no.2
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• pp.61-67
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• 2014

Mankyua chejuense is a native endangered plant distributed only in Gotzawal, a forested wetland, in Jeju Province, Korea. In order to determine the optimal environmental conditions for the growth and development of M. chejuense, we investigated the above- and below-ground growth responses and survival rate to various soil texture (sand and clay), water regimes (flooding and non-flooding), and $CO_2+T$ (ambient and elevated) conditions. All of the treatments had significant effects on aboveground growth parameters, while only the water regime and $CO_2+T$ treatments influenced belowground growth. The survival rate of M. chejuense was about twice higher under the sand, non-flooding and elevated $CO_2+T$ conditions than clay, flooding and ambient $CO_2+T$ conditions. These results indicate that M. chejuense grows in well-drained sandy soil conditions and elevated $CO_2$ concentration and temperature situations. Thus, there is a need to maintain M. chejuense under constant non-flooding soil conditions by implementing appropriate soil drainage strategies.

• Journal of the Korean Chemical Society
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• v.38 no.4
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• pp.265-270
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• 1994

The aquation and base hydrolysis of [Co(en)$_2$NH$_3$Cl]$^{2+}$ were studied by UV spectroscopic method in various SDS aqueous solution. The base hydrolysis of [Co(en)$_2$NH$_3$Cl]$^{2+}$ with the addition of 0, 0.05, 0.1 mol dm$^{-3}$ sodium chloride was studied. For the aquation of the complex, the rate constant in the micellar phase(kH$^M$) was a little larger than that in the aqueous phase(kH$^W$). With the increase of SDS concentration, the second order rate constant(kOH) for the base hydrolysis unchanged below the CMC and sharply decreased down to a limiting value after the CMC was reached. The effect of added NaCl on the rate behavior of the complexes in the micellar solution were investigated by using an ion-exchanged model.

• Korean Journal of Environmental Agriculture
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• v.42 no.3
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• pp.231-238
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• 2023

We analyzed the variations in the CO₂ concentration and temperature between a CO₂-enriched and control greenhouse. We cultivated Alstroemeria 'Hanhera' in the two greenhouses and assessed the growth parameters (stem length, stem thickness, and the number of flowers) and yield. The CO₂-enriched greenhouse had a CO₂ generator that produced CO₂ at rate of 0.36 kg/h and its windows were programmed to open when the temperature exceeded 20℃ and close when it dropped below 15℃. The control greenhouse had no additional CO₂ supplementation, and its windows were programmed to open when the temperature exceeded 20℃ and close at approximately 17:00. In the morning, CO₂ concentration remained above 500 ppm in the CO₂-enriched greenhouse, which was higher than that in the control greenhouse (approximately 370 ppm). The ventilation effect only through the side windows to reduce the temperature in both greenhouses did not appear dynamically. CO₂ supplementation promoted plant growth, resulting in a significant increase in plant yield of over 60% compared to that of the control greenhouse. Our findings suggest that elevated CO₂ concentration in the morning can significantly promote the growth and development of Alstroemeria during the winter.

• Korea-Australia Rheology Journal
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• v.20 no.1
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• pp.1-6
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• 2008

Absorption rate of carbon dioxide was measured in the aqueous xanthan gum (XG) solution in the range of 0-0.15 wt% containing 2-amino-2-methyl-1-propanol (AMP) of $0-2\;kmol/m^3$ in a flat-stirred vessel with an impeller of 0.05m and agitation speed of 50rpm at $25^{\circ}C$ and 0.101 MPa. The volumetric liquid-side mass transfer coefficient ($k_La$) of $CO_2$, which was correlated with the viscosity and the elastic behavior of XG solution containing Deborah number as an empirical formula, was used to estimate the chemical absorption rate of $CO_2\;(R_A)$. $R_A$, which was estimated by mass transfer mechanism based on the film theory using the physicochemical properties and the kinetics of reaction between $CO_2$ and AMP, was compared with the measured rate. The aqueous XG solution with elastic property of non-Newtonian liquid made $R_A$ increased compared with Newtonian liquid based on the same viscosity of the solution.

• Journal of Hydrogen and New Energy
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• v.10 no.3
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• pp.185-189
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• 1999

Effects of alloy modification with the $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.4}$ alloy for an electrode use have been investigated. For the alloy composition, a part of Mn was substituted by Co, Cr and Fe. The experimental results showed that Co accelerated activation of alloy, and Fe and Cr improved the discharge capacity. These results agree with P-C-T curves of each alloy. But substituting Fe for Mn showed the decrease of the discharge capacity when discharged at high rate (60mA, about 1C rate). Considering both the discharge capacity and the high rate discharge property, $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.3}Cr_{0.1}$ alloy was found to be the best alloy among the alloys subjected to the test.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.4
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• pp.459-469
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• 2005

In recent years, concerns have been growing globally regarding greenhouse gases. Open burning of biomass causes emission of a number of greenhouse and other gases and substances. This paper studied an analysis on the characteristics of four types of biomass using duel type cone calorimeter. Cone calorimeter is widely used for assessing combustibility of materials in Europe. As a result, we evaluated several characteristics of biomass, such as heat released rate, smoke production rate, CO, $CO_2$ production and mass loss rate, and so on. $CO_2$ is currently responsible for over $60\%$ of the enhanced greenhouse effect, and may be the most important contributor to future. $CO_2$ production for biomass in the range of $1.74\~1.99kg/kg$ is similar to previous research conducted by Bhattacharya et al. (2002a).

• Applied Chemistry for Engineering
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• v.27 no.1
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• pp.56-61
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• 2016

In this study, the effect of natural minerals on the reaction kinetics for lignite-$CO_2$ gasification was investigated. After physical mixing of lignite from Meng Tai area with 5 wt% of each natural mineral catalysts among Dolomite, Silica sand, Olivine and Kaolin, $CO_2$ gasification was performed using TGA at each 800, $850^{\circ}C$ and $900^{\circ}C$. The experimental data was analyzed with volumetric reaction model (VRM), shrinking core model (SCM) and modified volumetric reaction model (MVRM). MVRM was the most suitable among three models. As increasing the reaction temperature, the reaction rate constant became higher. With natural mineral catalysts, the reaction rate constant was higher and activation energy was lower than that of without catalysts. The lowest activation energy, 114.90 kJ/mol was obtained with silica sand. The highest reaction rate constant at $850^{\circ}C$ and $900^{\circ}C$ and lower reaction rate constant at $800^{\circ}C$ were obtained with Kaolin. Conclusively, the better catalytic performance could be observed with Kaolin than that of using other catalysts when the reaction temperature increased.