• Title/Summary/Keyword: CO2 Rate

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A Study on Optimization of Manufacturing Condition for LiNi1/3Mn1/3Co1/3O2-based Cathode Electrode (LiNi1/3Mn1/3Co1/3O2계 정극활물질을 적용한 전극 제조조건 최적화 연구)

  • Kim Hyun-Soo;Kim Sung-Il;Lee Chang-Woo;Moon Seong-In;Kim Woo-Seong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.2
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    • pp.139-144
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    • 2006
  • A fabrication condition of the cathode electrode was optimized in a lithium secondary battery. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ powders were used as a cathode material. The $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$/Li cells were prepared with a certain formulation and their cycleability and rate-capability were evaluated. Optimum electrode composition simulated from the evaluated value was 86.3: 5.6: 8.1 in mass $\%$ of active material: binder: conducting material. Discharge capacity decreased markedly as the press ratio exceeded $30\%$ during preparation of the electrode. Discharge performance at a high current rate deteriorated abruptly as the electrode thickness was over $120{\mu}m$.

Co-expression of Survivin and Bcl-2 in Primary Brain Tumors : Their Potential Effect on Anti-apoptosis

  • Ryu, Je-Il;Kim, Choong-Hyun;Cheong, Jin-Hwan;Bak, Koang-Hum;Kim, Jae-Min;Oh, Suck-Jun
    • Journal of Korean Neurosurgical Society
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    • v.40 no.1
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    • pp.1-5
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    • 2006
  • Objective : Survivin is an inhibitor of apoptosis protein[IAP], which inhibits apoptosis through a pathway distinct from the Bcl-2 family members. Overexpression of survivin and Bcl-2 have been commonly reported in human neoplasms. The authors investigate whether there is a synergistic effect on the anti-apoptosis rate of primary brain tumors "in situ" based on the co-expression of survivin and Bcl-2. Methods : One hundred and two brain tumor patients who had been resected were included in this study. Survivin tin and Bcl-2 were detected by Western blotting analysis, while apoptosis was examined by DNA fragmentation analysis. An anti-apoptotic rate was assessed in these brain tumor samples based on the expression of survivin and Bcl-2 or co-expression of both. Results : Survivin and Bcl-2 were expressed in 57[55.9%] and 53[52.0%] of 102 brain tumor samples studied respectively, and co-expressed in 31[30.4%]. The percentage of astrocytic and meningeal tumors expressing survivin was significantly correlated with histological grades; however, Bcl-2 was not correlated [p=0.106]. The anti-apoptotic rate in primary brain tumors with survivin, Bcl-2, and both was detected in 49[86.0%] of 57 samples, 42[79.9%] of 53 samples, and 27[87.1%] of 31 samples, respectively. Their difference in the frequency of anti-apoptosis was not significant. Conclusion : Survivin or Bcl-2 is involved in the anti-apoptosis. However, it suggests that co-expression of survivin and Bcl-2, together, have no synergistic effect on the anti-apoptotic properties of the primary brain tumors.

Application of the Combination of Soybean Lecithin and Whey Protein Concentrate 80 to Improve the Bile Salt and Acid Tolerance of Probiotics

  • Gou, Xuelei;Zhang, Libo;Zhao, Shiwei;Ma, Wanping;Yang, Zibiao
    • Journal of Microbiology and Biotechnology
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    • v.31 no.6
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    • pp.840-846
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    • 2021
  • To improve the bile salt and acid tolerance of probiotics against gastrointestinal stresses, we investigated the effects of soybean lecithin and whey protein concentrate (WPC) 80 on the bile salt tolerance of Lacticaseibacillus paracasei L9 using a single-factor methodology, which was optimized using response surface methodology (RSM). The survival rate of L. paracasei L9 treated with 0.3% (w/v) bile salt for 2.5 h, and combined with soybean lecithin or WPC 80, was lower than 1%. After optimization, the survival rate of L. paracasei L9 incubated in 0.3% bile salt for 2.5 h reached 52.5% at a ratio of 0.74% soybean lecithin and 2.54% WPC 80. Moreover, this optimized method improved the survival rate of L. paracasei L9 in low pH condition and can be applied to other lactic acid bacteria (LAB) strains. Conclusively, the combination of soybean lecithin and WPC 80 significantly improved the bile salt and acid tolerance of LAB. Our study provides a novel approach for enhancing the gastrointestinal tolerance of LAB by combining food-derived components that have different properties.

Source Emission Rate on Air Pollutants from Portable Gas Range and Optimal Ventilation Rate in Indoor Environment (휴대용 가스렌지 연소에 의한 공기오염물질의 발생량 및 실내환경의 필요 환기량)

  • Yim, Sung-Kuk;Kim, Young-Hee;Yang, Won-Ho
    • Journal of Environmental Health Sciences
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    • v.33 no.2 s.95
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    • pp.92-97
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    • 2007
  • A series of source tests were conducted to characterize emissions of nitrogen oxide(NOx, NO, $NO_2$), carbon mon oxide(CO), carbon dioxide$(CO_2)$ and total VOCs from portable combustion devices in steady-state using well-mixed chamber. Since use of portable gas range is widespread in houses and restaurants in Korea, it is important to characterize the emission of air pollutants and suggest optimum ventilation rate. Ranges of emission rates of air pollutants from portable gas ranges were $NO \;0.551\sim0.939mg/hr,\;NO_2\;0.354\sim1.080mg/hr,\;NO_x\;1.207\sim1.631mg/hr,\;CO\;1.389\sim4.21mg/hr,\;CO_2\;2426.823\sim2973.495mg/hr$, and VOCs $0\sim0.119mg/h$. Mean of personal exposure and indoor environment level of $NO_2$ by combustion of portable gas range were 74.7 ppb and 65.4 ppb, respectively, suggesting persons using portable gas range in houses and restaurants might be highly exposed. Required ventilation rate to control the air pollutants emitted from portable gas range was maximumly $3.131m^3/hr$ on the basis of $NO_2$ indoor air quality standard.

Growth, Photosynthesis and Zinc Elimination Capacity of a Sorghum-Sudangrass Hybrid under Zinc Stress (고농도 아연 조건에서 수수-수단그라스 교잡종의 생장, 광합성 및 아연 제거능)

  • Oh, Soonja;Koh, Seok Chan
    • Journal of Environmental Science International
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    • v.25 no.8
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    • pp.1143-1153
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    • 2016
  • Plant biomass, photosystem II (PSII) photochemical activity, photosynthetic function, and zinc (Zn) accumulation were investigated in a sorghum-sudangrass hybrid (Sorghum bicolor ${\times}$ S. sudanense) exposed to various Zn concentrations to determine the elimination capacity of Zn from soils. Plant growth and biomass of the sorghum-sudangrass hybrid decreased with increasing Zn concentration. Symptoms of Zn toxicity, i.e., withering and discoloration of old leaves, were found at Zn concentrations over 800 ppm. PSII photochemical activity, as indicated by the values of $F_v/F_m$ and $F_v/F_o$, decreased significantly three days after exposure to Zn concentrations of 800 ppm or more. Photosynthetic $CO_2$ fixation rate (A) was high between Zn concentrations of 100-200 ppm ($22.5{\mu}mol$ $CO_2{\cdot}m^{-2}{\cdot}s^{-1}$), but it declined as Zn concentration increased. At Zn concentrations of 800 and 1600 ppm, A was 14.1 and $1.8{\mu}mol$ $CO_2{\cdot}m^{-2}{\cdot}s^{-1}$, respectively. The patterns of stomatal conductance ($g_s$), transpiration rate (E), and water use efficiency (WUE) were all similar to that of photosynthetic $CO_2$ fixation rate, except for dark respiration ($R_d$), which showed an opposite pattern. Zn was accumulated in both above- and below-ground parts of plants, but was more in the below-ground parts. Magnesium (Mg) and iron (Fe) concentrations were significantly low in the leaves of plants, and symptoms of Mg or Fe deficiency, such as a decrease in the SPAD value, were found when plants were treated with Zn concentrations above 800 ppm. These results suggest that the sorghum-sudangrass hybrid is able to accumulate Zn to high level in plant body and eliminate it with its rapid growth and high biomass yield.

Comparison of Removal Capabilities among Several Aqueous Amine Absorbents for Sweeting Acid Gases Contained in Natural Gas (다양한 아민 흡수제를 이용한 천연가스 중에 포함되어 있는 산성가스 제거 성능 비교)

  • Cho, Du-hee;Kim, Dong-sun;Cho, Jung-ho
    • Plant Journal
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    • v.10 no.1
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    • pp.34-39
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    • 2014
  • Simulation works for comparing removal capabilities of acid gases contained in natural gas among several aqueous amine absorbents using commercial process simulator PROMAX(BR&E Co.) were carried out. Amine aqueous solution used in this study were 30 wt% MEA, 30 wt% DEA, 50 wt% MDEA, and 50 wt% MDEA with 3 wt% piperazine as additive. We obtained the simulated results that while MEA aqueous solution is relatively capable of more $CO_2$ gas, but DEA, MDEA, MDEA aqueous solutions with piperazine as additive are capable of more $H_2S$ gas. Also, we found that 30 wt% MDA aqueous solution is the smallest circulate rate of lean amine solution, and 50 wt% MDEA aqueous solution with 3 wt% piperazine as additive is the smallest heat duty in stripping unit. 50 wt% MDEA aqueous solution with 3 wt% piperazine as additive is found less amine circulation rate than 50 wt% MDEA due to the introduction of additive.

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Experimental Study of Char Oxidation and Kinetic Rate in O2/CO2 and O2/N2 Environments (O2/CO2조건과 O2/N2조건에서의 촤 연소특성 및 산화 반응성에 관한 실험적 연구)

  • Kim, Song-Gon;Lee, Cheon-Seong;Lee, Byoung-Hwa;Song, Ju-Hun;Chang, Young-June;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.12
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    • pp.1101-1109
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    • 2010
  • We investigated the combustion rate and kinetic rate of char when burning in oxygen-enriched atmospheres with either an $N_2$ or $CO_2$ bath gas in a drop tube furnace. The experiments were performed with sub-bituminous coal (Adaro) and bituminous coal (Coal valley) under atmospheric pressure conditions. Two different coals were investigated over 12 to 30 vol% oxygen and furnace temperatures of 900, 1100, and $1300^{\circ}C$. For both coals, the particle temperature and overall reaction rate are lower in the $CO_2$ bath gas. However, analysis of single-particle data shows that the surface-specific burning rate of char oxidation is similar in both gases. In addition, the kinetic rate and activation energy for each coal were similar for both gases. Generally, the particle temperature and overall reaction rate of sub-bituminous coal are higher than those of bituminous coal.

Evaluation of Continuously and Intermittently Aerated Hog Manure Compost Stability in a Pilot-scale Bin Composting System (파일럿 규모 빈 퇴비화 시스템에서 연속 및 간헐 통기 돈분 퇴비의 안정도 평가)

  • Hong, Ji-Hyung
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.40 no.5
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    • pp.100-108
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    • 1998
  • Compost stability represents the state of microbiological activity and measurements of respiration either through $CO_2$ evolution or $O_2$ uptake should provide the best indication of this state. Hog manure amended with sawdust was composted in a pilot-scale reactor vessels using continuous and intermittent aeration for 3 weeks. In this study we evaluated the $CO_2$ respiration rate effect of aeration method on the reduction of $CO_2$ evolution, and investigated the stability of fresh and finished compost for plant growth. The intermittently aerated composting is a practical proposition for a very stable compost making. The $CO_2$ respiration rate in the fresh and finished compost during intermittently aerated composting was maintained from 0.3 to 1.4 and was good for use in horticulture, while the continuously aerated composting was 7 to 23 and needed more time for compost curing.

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Optimization of BOG Reliquefaction Process of Carbon Dioxide Considering Nitrogen Content

  • Ijun Jeong;Youngsub Lim
    • Journal of Ocean Engineering and Technology
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    • v.38 no.5
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    • pp.245-256
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    • 2024
  • As the importance of carbon capture and storage (CCS) technology increases for greenhouse gas reduction, CO2 transportation technology is also becoming crucial. Efficiently handling boil-off gas (BOG) generated during voyages is particularly important. This paper proposes a process incorporating two-stage separation and mixed refrigerants to reliquefy CO2 BOG containing nitrogen efficiently. This process was optimized based on specific power consumption (SPC) criteria and compared with the conventional single-stage separation using an ammonia refrigerant. The two-stage separation allows the removal of non-condensable gases, such as nitrogen, before expansion, and the use of mixed refrigerants enables more efficient heat exchange than ammonia refrigerants, improving the reliquefaction rate. As a result, the proposed process reduced SPC by up to 8.8 % with a nitrogen content of 5 mol% and up to 74.7 % with a nitrogen content of 15 mol%. In addition, the proposed process achieved a reliquefaction rate of over 74.2 % across all nitrogen content ranges of 5-15 mol%.

Separation of $CO_2$ and $N_2$ with a NaY Zeolite Membrane under Various Permeation Test Conditions

  • Cho, Churl-Hee;Yeo, Jeong-Gu;Ahn, Young-Soo;Han, Moon-Hee;Hyun, Sang-Hoon
    • Korean Membrane Journal
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    • v.8 no.1
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    • pp.21-30
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    • 2006
  • A faujasite NaY zeolite membrane was prepared on a tubular ${\alpha}-Al_2O_3$ support by the secondary growth process, and effects of permeation test conditions on the $CO_2/N_2$ separation were investigated. A NaY zeolite membrane with good $CO_2/N_2$ separation was successfully synthesized by using the hydrothermal solution ($Al_2O_3:SiO_2:Na_2O:H_2O$ = 1:6:14:840 in a molar base): at a permeation temperature of $30^{\circ}C$, its $CO_2$ permeance and $CO_2/N_2$ separation factor were $2.5{\times}10^{-7}mol/m^2secPa$ and 34, respectively. The $CO_2$ and $N_2$ permeations were highly dependent on permeation test conditions (feed composition, feeding rate, feed pressure, He sweeping rate and permeation temperature). The results indicated that (i) $CO_2$ and $N_2$ permeations through NaY zeolite membrane are governed by surface and micropore diffusions, respectively, (ii) the preparation of NaY zeolite membrane with a large permeating area is one of the most difficult hurdles for its real applications, and (iii) the retardation of $N_2$ permeation is an effective key to improve $CO_2/N_2$ separation factor in NaY zeolite membrane.