• 제목/요약/키워드: CO removal

검색결과 1,580건 처리시간 0.028초

토양세정 기술을 활용한 윤활유와 아연 복합오염 철도토양의 정화 연구 (Feasibility Study on Soil Flushing for Railway Soil Contaminated with Lubricant Oil and Zinc)

  • 박성우;조정민;이재영;박준규;백기태
    • 한국지하수토양환경학회지:지하수토양환경
    • /
    • 제16권4호
    • /
    • pp.31-37
    • /
    • 2011
  • The feasibility study of soil flushing was investigated to remediate lubricant oil and zinc contaminated railway soil. In this study, mixed washing agents of surfactant and inorganic acid/base were used for the simultaneous removal. The mixed washing agent of non-ionic surfactant and HCl removed 15% of the lubricant oil and 40% of zinc, respectively. Alkaline-enhanced soil washing process increased the removal of lubricant oil up to 40%. This is because alkaline solution reduced the interfacial tension between water phase and lubricant oil phase due to the soap formation reaction. To simulate in-situ soil flushing for the remediation of railroad-related contamination, two dimensional soil flushing was carried out based on the results of batch soil washing. In the soil flushing, the removal efficiencies of lubricant oil and zinc were 34% and 16%, respectively. Even though the removal efficiency was low, the mixed washing agent can remove metal and lubricant oil simultaneously.

실험실 규모에서 고온 섬유 여과재를 이용한 방향족 유기화합물 제거 특성 조사 (Removal Efficiency Study of Aromatic Hydrocarbons Using a High-Temperature Fiber Filter on a Laboratory Scale)

  • 이학성;강병욱;이상권;한영욱;한범
    • 한국환경과학회지
    • /
    • 제8권4호
    • /
    • pp.473-477
    • /
    • 1999
  • The purpose of this study was to investigate the characteristics of removal efficiency for aromatic hydrocarbons using a high-temperature fiber filter on a laboratory scale. The main elemental compositions of a high-temperaure fiber filter are aluminium and silica, which can act as the catalysts. Benzene, toluene and o-xylene among aromatic hydrocarbons were used in this experiment. For 3cm thickness of fiber filter, these compounds were removed more than 90% at the face velocities of 3cm/sec and 5cm/sec above 45$0^{\circ}C$. For 4cm thickness of it, the removal efficiencies of these compounds were almost 90% from 40$0^{\circ}C$ at the same face velocities, suggesting that it may be due to increasing the contact time between the fiber filter and aromatic hydrocarbons. The pressure droop ranged from 22 to 48mmH2O for 3cm thickness of fiber filter. However, for 4cm thickness of it, it was about two times(41~89mm$H_2O$) higher than that for 3cm fiber thickness.

  • PDF

초저이온농도에서 이온교환수지에 의한 실리카제거 평형특성 (Equilibrium Property of Ion Exchange Resin for Silica Removal at Ultralow Concentration)

  • 윤태경;이강춘;노병일
    • 한국환경과학회지
    • /
    • 제16권8호
    • /
    • pp.907-912
    • /
    • 2007
  • Ion exchange resin was used to remove silica ion at ultralow concentration. The effects of temperature, type of ion exchange resin and single/mixed-resin systems on removal efficiency were estimated. As temperature increased, the slope of concentration profile became stiff, and the equilibrium concentration was higher. In the single resin system, the removal of silica was continued up to 400 min, but the silica concentration was recovered to initial concentration after 400 min due to the effect of dissolved $CO_2$. In the mixed-resin system it took about 600 min to reach equilibrium. Because of faster cation exchange reaction than anion exchange reaction, the effect of $CO_2$ could be removed. Based on the experimental results carried out in the mixed-resin system, the selectivity coefficients of silica ion for each ion exchange resin were calculated at some specific temperatures. The temperature dependency of the selectivity coefficient was expressed by the equation of Kraus-Raridon type.

재생 알루미늄 산화물과 $TiO_2$의 복합성형체를 이용한 비소 흡착 특성 (Adsorption Characteristics of Arsenic on Composite Adsorbents using Recycled Aluminium Oxides and $TiO_2$)

  • 민경철;이승목;김근한;이희용;양재규;박연종
    • 한국물환경학회지
    • /
    • 제28권2호
    • /
    • pp.197-201
    • /
    • 2012
  • The objective of this study was to evaluate the removal efficiency of arsenite and arsenate using composite adsorbents with various mixing ratio of recycled aluminum oxides and $TiO_2$. From batch adsorption experiments, while the removal of As(III) was almost same with 4 different composite samples in the entire pH range, the removal of As(V) was substantially increased as the weight ratio of $TiO_2$ in composite samples reduced and showed anionic adsorption characteristics. Both adsorption of As (III) and As(V) on composite samples followed pseudo-second-order adsorption equation and C-3 showed faster reaction rate for the removal of arsenic. From the adsorption isotherm experiments, Langmuir isotherm explained well and the maximum adsorption capacities of arsenic were obtained with C-1.

Evaluation of dynamic behavior of coagulation-flocculation using hydrous ferric oxide for removal of radioactive nuclides in wastewater

  • Kim, Kwang-Wook;Shon, Woo-Jung;Oh, Maeng-Kyo;Yang, Dasom;Foster, Richard I.;Lee, Keun-Young
    • Nuclear Engineering and Technology
    • /
    • 제51권3호
    • /
    • pp.738-745
    • /
    • 2019
  • Coprecipitation using hydrous ferric oxide (HFO) has been effectively used for the removal of radionuclides from radioactive wastewater. This work studied the dynamic behavior of HFO floc formation during the neutralization of acidic ferric iron in the presence of several radionuclides by using a photometric dispersion analyzer (PDA). Then the coagulation-flocculation system using HFO-anionic poly acrylamide (PAM) composite floc system was evaluated and compared in seawater and distilled water to find the effective condition to remove the target nuclides (Co-60, Mn-54, Sb-125, and Ru-106) present in wastewater generated in the severe accident of nuclear power plant like Fukushima Daiichi case. A ferric iron dosage of 10 ppm for the formation of HFO was suitable in terms of fast formation of HFO flocs without induction time, and maximum total removal yield of radioactivity from the wastewater. The settling time of HFO flocs was reduced by changing them to HFO-PAM composite floc. The optimal dosage of anionic PAM for HFO-anionic PAM floc system was approximately 1-10 ppm. The total removal yield of Mn-54, Co-60, Sb-125, Ru-106 radionuclides by the HFO-anionic PAM coagulation-flocculation system was higher in distilled water than in seawater and was more than 99%.

Synthesis and Characterization of Calcium Derivative Combined with High-Surface-Area Activated Carbon Composites for Fine Toxic Gas Removal

  • Areerob, Yonrapach;Nguyen, Dinh Cung Tien;Dowla, Biswas Md Rokon;Kim, Hyuk;Cha, Je-Woo;Oh, Won-Chun
    • 한국세라믹학회지
    • /
    • 제55권5호
    • /
    • pp.473-479
    • /
    • 2018
  • Highly toxic gases such as hydrogen sulfide ($H_2S$), carbon dioxide ($CO_2$), and ammonia ($NH_3$) are generated by both nature and human activities and affect human health. In this research, activated carbon combined with $Ca(OH)_2$ and $CaCO_3$ (AC-CO and AC-CC, respectively) were fabricated and applied in absorbing toxic gases from air pollutants. Activated charcoal powder was compressed in the form of pellets and used in the designated conditions. The optimum operating conditions and material properties, such as adsorption capacity, effect of weight ratio of the mixture, and hardness, have been investigated after combining with the calcium derivative. The good performance exhibited in this study suggests that this material is expected to be an effective and economically viable adsorbent for $NH_3$, $CO_2$, and $H_2S$ removal from the air system.

수냉식 방열을 이용한 연료전지용 PROX 반응기의 성능에 관한 실험적 연구 (Experimental Study on the Preferential Oxidation Reactor Performance Using a Water Cooling Heat Removal for Polymer Electrolyte Membrane Fuel Cell)

  • 김진산;조태현;구본찬;이도형
    • 한국수소및신에너지학회논문집
    • /
    • 제27권5호
    • /
    • pp.503-509
    • /
    • 2016
  • Fuel cell is a device for producing electricity by using the hydrogen produced by the fuel processor. At this time, CO is also created by the fuel processor. The resulting CO enters the stack where is produce electricity and leads to the adsorption of anode catalyst, finally the CO poisoning occurs. Stack which occurred CO poisoning has a reduction in performance and shelf life are gradually fall because they do not respond to hydrogen. In this paper, experiments that using a PROX reactor to prevent CO poisoning were carried out for removing the CO concentration to less than 10ppm range available in the fuel cell. Furthermore experiments by the PROX reaction was designed and manufactured with a water-cooling heat exchange reactor to maintain a suitable temperature control due to the strong exothermic reaction.

$CO_2$ 직접 제거를 통한 다중이용시설의 에너지 절감 및 경제적 효과에 대한 실험적 연구 (Experimental studies of energy savings and economic effects by direct removal of carbon dioxide in the multi-use facility)

  • 김요섭;이주열;최진식;신재란;임윤희;박병현;김윤신
    • 한국응용과학기술학회지
    • /
    • 제31권3호
    • /
    • pp.466-471
    • /
    • 2014
  • It is important to develop the smart ventilation system in order to minimize a building energy consumption using ventilation. In this study, We evaluated the efficiency of the smart ventilation system being developed at the nursery. To evaluate the energy savings and carbon dioxide removal efficiency, two kinds of experimental conditions were compared. First, air conditioner and Smart HVAC system were operated. Second, air conditioner was operating and external air was put into the inside by rate of air circulation. It was more effective when working with air conditioning and ventilation system at the same time. If the Smart HVAC system is applied in a multi-use facility, indoor air quality will be comfortable and the social cost will be reduced.

녹조류와 적니의 이산화탄소환경 공동열분해를 통한 탄소-철 복합체 생성 및 과황산염 활성화를 통한 수중 염료 제거 (Fabrication of Metal-biochar Composite through CO2 Assisted Co-pyrolysis of Chlorella and Red Mud and Its Application for Persulfate Activation)

  • 장희진;권기훈;윤광석;송호철
    • 한국지하수토양환경학회지:지하수토양환경
    • /
    • 제27권1호
    • /
    • pp.31-38
    • /
    • 2022
  • The common algae and industrial waste, chlorella and red mud, were co-pyrolyzed in carbon dioxide condition to fabricate iron-biochar composite. In order to investigate the direct effect of chlorella and red mud in the syngas generation and the property of biochar, experiments were performed using mixture samples of chlorella and red mud. The evolution of flammable gasses (H2, CH4, CO) was monitored during pyrolysis. The produced biochar composite was employed as a catalyst for persulfate activation for methylene blue removal. BET analysis indicated that the iron-biochar composite mainly possessed meso- and macropores. The XRD analysis revealed that hematite (Fe2O3) contained in red mud was transformed to Fe3O4 during co-pyrolysis. The composite effectively activated persulfate and removed methylene blue. Among the composite samples, the composite fabricated from the mixture composed of 1:2 chlorella:red mud showed the best performance in syngas generation and methylene blue removal.