• 한국정밀공학회지
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• 제29권9호
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• pp.931-937
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• 2012

In this study, we assessed environmental impacts of compound humidifiers using environmental life cycle assessment and presented the ways to improvements in energy consumption of them. We found eco-design parameters and $CO_2$-eq emissions in each stage of raw material acquisition, manufacturing, transportation, use and disuse in life cycle of the compound humidifiers. The highest $CO_2$ emission is found to be in the stage of use among all stages of life cycle, which is mainly due to power consumption in thermal heating of heating coil for sterilization during humidification. The power consumption and $CO_2$ emission in the stage of use can be reduced to 1/4 and 1/3 at the highest estimate through improvement of sterilization method, respectively. We suggested the replacement of conventional thermal heating coil by ultra violet light-emitting diodes (UV-LED) for sterilization and then presented the experimental results on the sterilization effects of UV-LEDs.

• 한국유기농업학회지
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• 제19권1호
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• pp.23-38
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• 2011

● The current world is suffering abnormal climate caused by global warming. The main cause of global warming is greenhouse gas such as carbon dioxide. The carbon labeling system and carbon traceability system being pushed ahead in the agricultural sector is the policy for responding to climate change to reduce greenhouse gas emissions. To make this policy more effective and enhanced, the amount of carbon emissions should be calculated based on the kind of crops or the various businesses in the agricultural sector. Therefore, in order to estimate the accurate amount of carbon emissions, it is necessary to establish carbon dioxide emission intensity of various agricultural materials added onto the agriculture, and to calculate the amount of carbon dioxide emission for each crop according to agricultural production. The purpose of this study is to establish the amount of emission, emission per agricultural materials, of agricultural materials being added for crop production as a basic step, and emission intensity which can be used in the future market in order to estimate accurate amount of carbon emission in all the policies being promoted in the agricultural sector. Therefore, in this study, in order to build LCI D/B about organic fertilizers among many organic materials added onto the organic agriculture sector, one leading company in organic fertilizer production was selected and LCA was conducted for this leading company. We had to build the intensity and integrated average concept of intensity upon the two cases once production farmers for their own consumption and farms besides organic fertilizer company were categorized even if it's little amount. But in this study, individually produced organic fertilizers were excluded. Calculated results are following. Carbon emission of mixed expeller cake fertilizer in organic fertilizer was 1,106,966.89kg-$CO^2$ and emission intensity was 0.01606kg-$CO^2$, respectively. Total emission of mixed organic fertilizers was 241,523.2kg-$CO^2$ and emission intensity was 0.01705kg-$CO^2$. And total emission of organic compound fertilizers was 94,592.66kg-$CO^2$ and emission intensity was 0.01769kg-$CO^2$, respectively.

• 한국대기환경학회지
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• 제29권6호
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• pp.713-721
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• 2013

This study is about emission characteristics of HAPs and particulate matters emitted by spray of paint and organic solvent usually used in vehicle paint facilities. To analyze emission characteristics of HAPs and particulate matters emitted from vehicle paint facilities are calculated based on the measuring emission quantity of pollutants based on the amount of paint used (kg) and unit area ($m^2$) by paint manufacturers (J company, K company, and R company). In cases of paint manufacturers (J, K, and R), average emission factors of VOCs, carbonyl compound, particulate matter, and PAHs per 1 kg of paint were 327.81 g/kg, 5.98 g/kg, 336.70 g/kg, and 0.0078 g/kg respectively. The average emission factors of VOCs, carbonyl compounds, particulate matters, and PAHs by unit area were $171.55g/m^2$, $3.10g/m^2$, $176.27g/m^2$, and $0.0036g/m^2$ respectively.

• 한국토양비료학회지
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• 제47권5호
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• pp.374-380
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• 2014

To estimate greenhouse gas (GHG) emission, the inventory of rice cultivation at the farming without agricultural chemicals was established from farmers in Gunsan, Jeonbuk province in 2011~2012. The objectives of this study were to calculate carbon footprint and analyse the major factor of GHGs. To do this, we carried out a sensitivity analysis using the analyzed main factors of GHGs and estimated the mitigation potential of GHGs. Also we suggested agricultural methods to reduce GHGs that can be appled by farmers at this region. At the farming system without agricultural chemicals, carbon footprint of rice production unit of 1 kg was 2.15 kg $CO_2.-eq.kg^{-1}$. Although the amount of carbon dioxide ($CO_2$) emission was the largest among GHGs, methane ($CH_4$) emission had the highest contribution to carbon footprint on rice production system when it was converted to carbon dioxide equivalent ($CO_2-eq.$) multiplied by the global warming potential (GWP). Main source of $CO_2$ emission in the rice farming system without agricultural chemicals was combustion of fossil fuels used by agricultural machinery. Most of the $CH_4$ was emitted during rice cultivation practice and its major emission factor was flooded paddy field in anaerobic condition. Also, most of the $N_2O$ was emitted from rice cultivation process. Major sources of the $N_2O$ emission was application of fertilizer such as compound fertilizer. As a result of sensitivity analysis in energy consumption, diesel had the highest sensitivity among the energy inputs. With the reduction of diesel consumption by 10%, it was estimated that $CO_2$ potential reduction was about 2.0%. With reducing application rate of compound fertilizer by 10%, the potential reduction was calculated that $CO_2$ and $N_2O$ could be reduced by 0.5% and 0.9%, respectively. At the condition of 10% reduction of silicate and compost, $CO_2$ and $CH_4$ could be reduced by 1.5% and 1.6%, respectively. With 8 days more drainage than the ordinary practice, $CH_4$ emission could be reduced by about 4.5%. Drainage and diesel consumption were the main sources having the largest effect on the GHG reduction at the farming system without agricultural chemicals. Based on the above results, we suggest that no-tillage and midsummer drainage could be a method to decrease GHG emissions from rice production system.

• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 2002년도 추계학술대회 논문집
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• pp.170-173
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• 2002

The object of this study is to investigate the effect of compounded welding through the AE (Acoustic Emission) characteristics on static tensile test. This study was carried out a SM 490A, high tension steel using the low hydrogen type E4316 of electronic shield metal arc welding and compound wire of $CO_2$gas arc welding. $CO_2$welding, weak in the intensity of HAZ (Heat Affected Zone), can be improved by being combined with coated arc welding, Coated arc welding, weak in the intensity of the bead, can be improved by being combined with $CO_2$welding. Especially, electronic coated arc welding and $CO_2$welding complement the mechanical intensity of HAZ and the bead with each other. So, compounded welding increases the intensity in the special parts and enhances the quality of goods.

• Bulletin of the Korean Chemical Society
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• 제33권6호
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• pp.1929-1933
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• 2012

Two cobalt(II) compounds $[Co(2,2{^\prime}-bipy)(H_2O)_2(SO_4)]_n$ (1) and $[Co_2(2,2^{\prime}-bipy)_2(btec)(H_2O)_6]{\cdot}2H_2O$ (2) (2,2'-bipy = 2,2'-bipyridine, $H_4btec$ = 1,2,4,5-benzenetetracarboxylic acid), have been simultaneously synthesized by a one-pot slow solvent evaporation reaction. Their structures were determined by single-crystal X-ray diffraction and further characterized by X-ray powder diffraction (XRPD), IR, elemental and thermogravimetric analysis (TGA). The structural analysis reveals that compound 1 exhibits an infinite 1D chain structure with the octahedral Co(II) centers bridging by the tetrahedral ${\mu}_2-SO{_4}^{2-}$ ligands, while compound 2 possesses a dinuclear $Co_2(2,2^{\prime}-bipy)_2(btec)(H_2O)_6$ unit and the two adjacent octahedral Co(II) ions are linked by the bismonodentately coordinated btec ligand. Additionally, compound 2 exhibits blue fluorescent emission in the solid state at room temperature.

• Bulletin of the Korean Chemical Society
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• 제32권9호
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• pp.3223-3228
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• 2011

To quantify the presence of mercuric ions in aqueous solution, double-stranded DNA (dsDNA) of poly(dT) was employed using a light switch compound, $Ru(phen)_2(dppz)^{2+}$ (1) which is reported to intercalate into dsDNA of a right-handed B-form. Addition of mercuric ions induced the dehybridization of poly(dT)${\cdot}$poly(dA) duplexes to form a hairpin structure of poly(dT) at room temperature and the metal-to-ligand charge transfer emission derived from the intercalation of 1 was reduced due to the dehybridization of dsDNA. As the concentration of $Hg^{2+}$ was increased, the emission of 1 progressively decreased. This label-free emission method had a detection limit of 0.2 nM. Other metal ions, such as $K^+$, $Ag^+$, $Ca^{2+}$, $Mg^{2+}$, $Zn^{2+}$, $Mn^{2+}$, $Co^{2+}$, $Ni^{2+}$, $Cu^{2+}$, $Cd^{2+}$, $Cr^{3+}$, $Fe^{3+}$, had no significant effect on reducing emission. This emission method can differentiate matched and mismatched poly(dT) sequences based on the emission intensity of dsDNA.

• Bulletin of the Korean Chemical Society
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• 제32권3호
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• pp.894-898
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• 2011

The first example of lead compound from $Pb(NO_3)_2$ and $H_3L$ N-heterocyclic ligand $(H_3L\;=\;(HO_2C)_2(C_3N_2)(C_3H_7)CH_2(C_6H_4)(C_6H_3)CO_2H)$, $[Pb_4(L')_4]{\cdot}5H_2O$ 1 (L' = OOC$(C_3H_7)(C_3N_2)CH_2(C_6H_4)(C_6H_3)COO)$, has been obtained under hydrothermal condition by decarboxylation, and characterized by elemental analysis, IR, TGDTA, and single-crystal X-ray diffraction. Compound 1 possesses a rare two-dimensional upper-lower offset terrace-like layer structure. In 1, crystallographic distinct Pb(II) ion adopts five-coordination geometry, and two lattice water molecules occupy the voids between 2-D layers. Results of solid state fluorescence measurement indicate that the emission band 458 nm may be assigned to $\pi^*-n$ and $\pi^*-\pi$ electronic transitions within the aromatic systems of the ligand L', however, the emission bands centred at 555 nm, 600 nm and 719 nm may be derived from phosphorescent emission ($\lambda_{excitation}$ = 390 nm).

• Journal of the Korean Wood Science and Technology
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• 제43권6호
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• pp.768-776
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• 2015

본 연구에서는 인도네시아 조림지에서 생장한 4수종의 효율적 활용방안을 마련하기 위해 콘칼로리미터법에 의해 연소특성을 조사하였다. 그 결과, 평균열방출량($HRR_{mean}$)은 비중에 비례하였으며, 총열방출량(THR) 및 연소시간(FT) 등열관련 계수도 같은 경향을 나타냈다. Albizia는 열방출 시간이 짧았고, Mindi는 4수종 중 점화시간(TTI)과 연소시간(FT)이 길어져 4수종 중 연소속도가 늦었고, 열방출 시간도 가장 길게 이어져 결국은 Mangium 수종과 비슷한 총열방출률을 나타내는 것을 확인할 수 있었다. Albizia는 공시수종 중 가장 높은 비소화면적 값을 나타내어 연기발생비율이 높았고, 반대로 Mindi는 가장 낮은 비소화면적 값을 나타내 연기발생비율이 낮았다. 초기 연기방출률은 Albizia가 높았으나 이후에는 Gmelina와 Mangium 의 연기방출률이 높아져 총연기발생량이 높게 나타났다. Gmelina는 불완전연소로 인해 연소기간 중 가장 많은 일산화탄소 연기를 생성하였고, $CO/CO_2$ 비율은 다른 수종에 비해 3배 이상 높았다.

• Bulletin of the Korean Chemical Society
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• 제33권4호
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• pp.1259-1263
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• 2012

Two metal compounds, $[Co(phen)_2(H_2O)_2]{\cdot}2H_2SIP{\cdot}2H_2O$ 1 and $[Ni(phen)_3]{\cdot}2H_2SIP{\cdot}3H_2O$ 2, have been obtained by incorporating 1,10-phenanthroline (phen) and 5-sulfoisophthalic acid monosodium salt ($NaH_2SIP$) ligands under hydrothermal conditions. Meanwhile, the two compounds were characterized by element analysis, IR, XRD, TG-DTA and single-crystal X-ray diffraction. Both 1 and 2 present 3D supramolecular structures via O-H${\cdots}$O hydrogen bond interactions. Luminescent properties for 1 and 2 were also studied. The compound 1 has two fluorescence emission peaks centered at 398 nm attributed to the intraligand emission from the SIP ligand and at 438 nm assigned to the combined interaction of intraligand ${\pi}^*-{\pi}$ transitions of the phen ligand and ligand-to-metal-charge-transfer (LMCT) transitions (${\lambda}_{ex}$ = 233 nm). The compound 2 shows one emission band centered at 423 nm with a shoulder peak at 434 nm which may be originated from the intraligand ${\pi}^*-{\pi}$ transitions of the phen ligand (${\lambda}_{ex}$ = 266 nm).