• Title/Summary/Keyword: CO Concentration

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Measuring CO Concentration in a Flame with Broadband CARS (광대역 CARS를 이용한 불꽃 내부의 CO 농도 측정)

  • 한재원
    • Korean Journal of Optics and Photonics
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    • v.4 no.2
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    • pp.212-219
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    • 1993
  • To reduce the mode noise induced from a multimode dye laser, a modeless laser generating amplified spontaneous emission was used as Stokes beam of the broadband CARS. A new technique for measuring species concentration from the modulation dip of nonresonant background of broadband CARS spectrum was proposed. The modulation dip was numerically calculated and fitted as a function of the concentration of the minor species and temperature of gas sample. We applied this technique in measuring CO concentration in a static cell and also the profile of CO concentration in a CHdair premixed flame of a counterflow burner.

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A Suggestion of indoor CO2 concentration prediction equation by operating KTX flap in Tunnel Sections (터널구간 운행시 KTX 플랩 작동에 따른 CO2 농도 예측식 제안)

  • So, Jin-Sub;Yoo, Seong-Yeon;Kim, Ick-Hee
    • Proceedings of the KSR Conference
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    • 2010.06a
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    • pp.2052-2057
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    • 2010
  • In December 2006, the Ministry of Environment in Korea established the "Indoor Air Quality Management Guidelines in Public Transportation." As the items of the guideline, $CO_2$(Carbon dioxide) and PM10(Particulate matter). Therefore, the air quality inside the train is supposed to be ruled by this guideline. This study calculated the increase or decrease rate of the $CO_2$ concentration by using the data measured in accordance with flap operation. In case of flap close or open, the calculated $CO_2$ concentration variation was 6.32ppm/min. The $CO_2$ concentration prediction equation was derived from the general equation and the actual measured value are compared with the predicted $CO_2$ concentration suggested during the KyungBu high speed railway construction. The predicted value show good agreement with the measured data.

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Local Concentration and Flame Temperature Characteristics of Combustion Product in Premixed LPG/Air Flames (예혼합 LPG/공기화염에서 연소생성물의 국소농도 및 화염온도특성)

  • 김태권;장준영
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.4
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    • pp.77-84
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    • 2001
  • Measurements of local CO, $CO_2$, $O_2$, $N_2$, $C_3$H$_{8}$, NOx concentrations and flame temperature are made for partially premixed flame with and without acoustic excitation. The CO, $CO_2$, $O_2$, $N_2$, and $C$_3$H_8$ concentrations are determined by thermal conductivity detection (Gas-chromatograph) and NOx concentrations are determined by chemiluminescent detection (NOx analyser). To measure local sample concentration, sampling probe was made by quartz with inlet diameter of 0.25mm. In the case of excitation, the visual shape of the flame is changed from laminar flame to turbulent-like flame. The flame length is also reduced, and the flame width becomes broad. In the observation of emission concentration without acoustic excitation, meanwhile, the $CO_2$ and NOx concentrations peak at flame front where the mixture meets with surrounding air, and the CO concentration is increasing at maximum position of CO2 concentration and peaks at the centerline of the burner. In the case of acoustic excitation, the $CO_2$ concentration is widely occurred at nozzle of the burner and is higher relative to unexcitation. The CO concentration is much reduced, but NOx concentration is more increasing. And flame temperature is higher relative to unexcitation. These are caused by enhancing of mixing with surrounding air due to excitation. However, in the case of acoustic excitation, the total NOx concentration is reduced because of the shortened flame length which affects residence time.e.

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Fabrication of Flake-like LiCoO2 Nanopowders using Electrospinning (전기 방사법을 이용한 플레이크형 LiCoO2 나노 분말의 제조)

  • Koo, Bon-Ryul;An, Geon-Hyoung;Ahn, Hyo-Jin
    • Journal of Powder Materials
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    • v.21 no.2
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    • pp.108-113
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    • 2014
  • Flake-like $LiCoO_2$ nanopowders were fabricated using electrospinning. To investigate their formation mechanism, field-emssion scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy were carried out. Among various parameters of electrospinning, we controlled the molar concentration of the precursor and the PVP polymer. When the molar concentration of lithium and cobalt was 0.45 M, the morphology of $LiCoO_2$ nanopowders was irregular and round. For 1.27 M molar concentration, the $LiCoO_2$ nanopowders formed with flake-like morphology. For the PVP polymer, the molar concentration was set to 0.011 mM, 0.026 mM, and 0.043 mM. Irregular $LiCoO_2$ nanopowders were formed at low concentration (0.011 mM), while flake-like $LiCoO_2$ were formed at high concentration (0.026 mM and 0.043 mM). Thus, optimized molar concentration of the precursor and the PVP polymer may be related to the successful formation of flake-like $LiCoO_2$ nanopowders. As a results, the synthesized $LiCoO_2$ nanopowder can be used as the electrode material of Li-ion batteries.

Correlations of Oil Concentration Prediction during In-line Flow of $CO_2/Oil$ Mixtures (유동중인 $CO_2$냉매와 오일 혼합물의 농도 예측을 위한 상관식)

  • Park, Keun-Seo;Kang, Byung-Ha;Park, Kyoung-Kuhn;Kim, Suk-Hyun
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.10
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    • pp.718-725
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    • 2007
  • In the general vapor-compression refrigeration system, refrigeration lubricant circulates in refrigeration system with refrigerant. Knowledge of the amount of circulating lubricant is very important to exactly calculate capacity of the refrigeration system. An experimental study was conducted to estimate the oil concentration of a flowing $CO_2/Oil$ mixtures. POE and PAG oil are considered as test lubricants in this study. Performance tests were conducted under simulated liquid conditions for $CO_2/POE$ oil mixture in oil concentration of 0 to 10 weight-percent and $CO_2/PAG$ oil mixture in oil concentration of 0 to 6 weight-percent in the temperature ranges of $-5^{\circ}C\;to\;15^{\circ}C$. The results obtained indicate specific gravity of $CO_2/Oil$ mixture is increased as oil concentration is increased and as temperature of mixture is decreased. Oil concentration correlation of $CO_2/POE$ oil mixture and $CO_2/PAG$ oil mixture is suggested, based on the measurement of specific gravity and temperature. This correlation enable to predict the oil concentration without extraction of the mixture and can be applied for $CO_2/POE$ mixtures and $CO_2/PAG$ mixtures.

Fire Patterns According to the Blood Hb-CO Concentration of Charred Bodies (소사체의 혈중 헤모글로빈-일산화탄소 농도에 따른 연소형태 연구)

  • Choi, Seung-Bok;Oh, Bu-Yeol;Choi, Don-Mook
    • Fire Science and Engineering
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    • v.26 no.3
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    • pp.40-48
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    • 2012
  • Fire patterns have been used to determine the origin and cause of fires in every setting imaginable. However, it is very difficult to identify fire patterns and causes from the fire-damaged remains of a devastated structure. If someone was killed by the fire, it is possible to identify fire patterns by analyzing the Hb-CO concentration in charred bodies of deceased as well as the pace of the fire. For example, a low level of Hb-CO concentration in the charred bodies indicate a rapid fire with accelerants and the death was caused by severe heat and thick toxic fumes. However, a high level of Hb-CO concentration in the charred bodies demonstrates that the fire was slow and/or there was a flameless form of combustion. Thus, it is possible to identify fire patterns through analyzing the level of Hb-CO concentration on the dead from the fire. In this study, the Hb-CO concentration in the charred bodies was from 3 % at the case of gas burning oneself to death to 93 % at the death caused by smoldering fire.

An Analysis on HCHO, TVOC, CO2 Concentration of Existing-Housing Indoor-Air in Summer (기존 주택의 하절기 실내 공기중 HCHO, TVOC, CO2 농도 실태 조사분석)

  • Nam, Ki-Cheul;Lee, Young-Han
    • KIEAE Journal
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    • v.16 no.6
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    • pp.115-122
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    • 2016
  • Purpose: The study is to measure indoor air pollutants concentration of existing housing and to analyze the causes and assess in accordance with the government's criteria. The research result could be used as data for public health through indoor air quality management of existing housing and more as a reference for new housing. Method: It was investigated 24 middle class housings of metropolitan area in summer which have been built for the past 30 years. Concentration of HCHO, TVOC was investigated in living room at morning and night and concentration of $CO_2$ was investigated in living room and master bedroom at morning and night. SKT100-X5 was used for concentration of HCHO, TVOC and ZGm053UK for concentration of $CO_2$. Result: Average concentration of TVOC was 1.31 times more than that of HCHO and standard deviation of that was 1.73 times higher. Average concentration of $CO_2$ was almost nearly close to 1,000ppm being criteria of the Ministry of Environment.

An Experimental Study on the Characteristics of Oxygen Combustion of Pulverized Coal and the $NO_x$ Formation using TGA/DSC and DTF (TGA/DSC, DTF를 이용한 미분탄의 산소 연소 및 $NO_x$ 배출 특성에 관한 실험적 연구)

  • Lee, Dae-Keun;Seo, Dong-Myung;Noh, Dong-Soon;Ko, Chang-Bog
    • 한국연소학회:학술대회논문집
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    • 2007.05a
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    • pp.54-59
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    • 2007
  • In a view of capturing $CO_2$ as a greenhouse gas, an experimental study was conducted on the combustion characteristics of pulverized coal in $O_2$/$CO_2$ environment using TGA/DSC and DTF facilities. The effects of gas composition and concentration on the processes of devolatilization and char burning experienced by coal particles in combustion furnace and on the concentration of products such as $CO_2$, CO and $NO_x$ were observed using TGA/DSC and DTF respectively. As results, it were found that the rate of devolitilation is nearly independent on the $O_2$ concentration if it is over 20% but the char burning rate is a sensitive function of $O_2$ percent, and the two rates can be controlled by $O_2$ concentration in order to be similar with those of air combustion case. It was also found that high concentration $CO_2$ can be captured by oxy-coal combustion and high concentration of CO and low value of $NO_x$ are exhausted in that case. Additionally, NO reducing reaction by CO with char as catalyst was observed and a meaningful results were obtained.

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A Study on the Direct Discharge Test for Verifying Design Concentration and Soaking Time for CO2 Fire Extinguishing System of Total Flooding (전역방출방식 CO2 소화설비의 설계농도 및 유지시간 검증을 위한 직접방사실험에 관한 연구)

  • Lee, Se-Myeoung;Moon, Sung-Woong;Ryu, Sang-Hoon
    • Fire Science and Engineering
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    • v.26 no.6
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    • pp.15-23
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    • 2012
  • Indirect Test Method is often used instead of direct test method in test method for extinguishing performance of $CO_2$ extinguishing facility because of high cost, environment problems and difficulties of procedure. But in the danger facilities for a unit of nation, such as a petrochemical plant, a nuclear power plant, or etc. is better to verify the performance of the extinguishment through direct discharge test. In $CO_2$ extinguishing system for total flooding system installed in dangerous facilities in Korea, each protected area in surface fire and deep-seated fire had selected and verified of extinguishing performance of $CO_2$ extinguishing facilities. To get recognized as extinguishing performance, discharged $CO_2$ concentration to protected area should be equivalence with design concentration standards (NFSC and NFPA). The Design Concentration means that $CO_2$ extinguishing agent is considerate of concentration for percentage of allowance (20 %) from extinguishing concentration which available to control of flame. As test result, surface fire and deep seated fire in protected area is obtained $CO_2$ design concentration and maintained design concentration more than 20 minutes as deep-seated fire. Through this study, we introduced direct discharging test method and decision method. And furthermore, especially in the dangerous facilities as a unit of Nation, we suggested necessity about reliability of extinguishing facilities to use direct test method.

The Effect of Oxygen and Carbon Dioxide Concentration on Soot Formation in Nonpremixed Flames Using Time Resolved LII Technique

  • Oh, Kwang-Chul;Shin, Hyun-Dong
    • Journal of Mechanical Science and Technology
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    • v.19 no.11
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    • pp.2068-2076
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    • 2005
  • The influence of oxygen concentration and CO$_{2}$ as diluent in oxidizer side on soot characteristics was studied by Laser Induced Incandescence, Time Resolved LII and Transmission Electron Microscopy photography in non-premixed co flowing flames. Through the comparison of TEM photographs and the decay rate of LII signal, suitable two delay times of TIRE-LII method and signal sensitivity ($\Delta$S$_{TIRE-LII/) were determined. The effects of O$_{2}$ and CO$_{2}$ as diluent in oxidizer side on soot formation are investigated with these calibrated techniques. The O$_{2}$+CO$_{2}$, N$_{2}$, and [Ar+CO$_{2}$] mixture in co-flow were used to isolate CO2 effects systematically. The number concentration of primary particle and soot volume fraction abruptly decrease by the addition of CO$_{2}$ to the co-flow. This suppression is resulted from the short residence time in inception region because of the late nucleation and the decrease of surface growth distance by the low flame temperature due to the higher thermal capacity and the chemical change of CO$_{2}$ including thermal dissociation. As the oxygen concentration increases, the number concentration of soot particles at the inception region increases and thus this increase of nucleation enhances the growth of soot particle.