• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.11a
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• pp.67-67
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• 2007

This study investigated the effect of $H_2$ upon the growth of CNTs by changing the ratios of $H_2$ to Ar during the growth using $C_2H_2$. With higher contents of $H_2$ in Ar, CNTs became longer and thinner, resulting in their higher aspect ratios.

• Advances in concrete construction
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• v.9 no.6
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• pp.577-588
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• 2020

In this paper, vibration attributes of chiral double-walled carbon nanotubes (CNTs) based on nonlocal elastic shell model have been investigated. The impact of small scale is being perceived by establishing Flügge shell model. The wave propagation is engaged to frame the ruling equations as eigen value system. The influence of nonlocal parameter subjected to different end supports has been overtly examined. A suitable choice of material properties and nonlocal parameter been focused to analyze the vibration characteristics. The new set of inner and outer tubes radii investigated in detail against aspect ratio and length. The dominance of boundary conditions via nonlocal parameter is shown graphically. Whereas for lower aspect ratio the frequencies coincide but as it continues to expand the difference between all respective boundary conditions slightly tend to increase. The results generated furnish the evidence regarding applicability of nonlocal shell model and also verified by earlier published literature.

• Computers and Concrete
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• v.26 no.1
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• pp.31-52
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• 2020

This paper investigates the size dependent effect on the vibration analysis of a porous nanocomposite viscoelastic plate reinforced by functionally graded-single walled carbon nanotubes (FG-SWCNTs) by considering nonlocal strain gradient theory. Therefore, using energy method and Hamilton's principle, the equations of motion are derived. In this article, the effects of nonlocal parameter, aspect ratio, strain gradient parameter, volume fraction of carbon nanotubes (CNTs), damping coefficient, porosity coefficient, and temperature change on the natural frequency are perused. The innovation of this paper is to compare the effectiveness of each mentioned parameters individually on the free vibrations of this plate and to represent the appropriate value for each parameter to achieve an ideal nanocomposite plate that minimizes vibration. The results are verified with those referenced in the paper. The results illustrate that the effect of damping coefficient on the increase of natural frequency is significantly higher than the other parameters effect, and the effects of the strain gradient parameter and nonlocal parameter on the natural frequency increase are less than damping coefficient effect, respectively. Furthermore, the results indicate that the natural frequency decreases with a rise in the nonlocal parameter, aspect ratio and temperature change. Also, the natural frequency increases with a rise in the strain gradient parameter and CNTs volume fraction. This study can be used for optimizing the industrial and medical designs, such as automotive industry, aerospace engineering and water purification system, by considering ideal properties for the nanocomposite plate.

• Advances in nano research
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• v.7 no.6
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• pp.431-442
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• 2019

Vibration analysis of carbon nanotubes (CNTs) is very essential field owing to their many promising applications in tiny instruments. In current study, the Eringen's nonlocal elasticity theory with clamped-clamped and clamped-free end conditions is utilized for the vibration analysis of armchair and zigzag SWCNTs. The Fourier method is utilized to solve the ordinary differential equation. The motion equation for this system is developed using a novel wave propagation method. Complex exponential functions have been used and the axial model depends on BCs that has been described at the edges of CNTs. The behavior of different nonlocal parameters is considered to find the vibrational frequency of SWCNTs. It is exhibited that the effect of frequencies against aspect ratio by varying the bending rigidity. It has been investigated that by increasing the nonlocal parameter decreases the frequencies and on increasing the aspect ratio increases the frequencies for both the tubes. To generate the fundamental natural frequencies of SWCNTs, computer software MATLAB engaged. The numerical results are validated with existing open text. Since the percentage of error is negligible, the model has been concluded as valid.

• Carbon letters
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• v.12 no.4
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• pp.185-193
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• 2011

Carbon nanotubes (CNTs) have developed into one of the most competitively researched nano-materials of this decade because of their structural uniqueness and excellent physical properties such as nanoscale one dimensionality, high aspect ratio, high mechanical strength, thermal conductivity and excellent electrical conductivity. Mass production and structure control of CNTs are key factors for a feasible CNT industry. Water and ethanol vapor enhance the catalytic activity for massive growth of vertically aligned CNTs. A shower system for gas flow improves the growth of vertically aligned single walled CNTs (SWCNTs) by controlling the gas flow direction. Delivery of gases from the top of the nanotubes enables direct and precise supply of carbon source and water vapor to the catalysts. High quality vertically aligned SWCNTs synthesized using plasma enhance the chemical vapor deposition technique on substrate with suitable metal catalyst particles. This review provides an introduction to the concept of the growth of vertically aligned SWCNTs and covers advanced topics on the controlled synthesis of vertically aligned SWCNTs.

• Journal of the Korean Applied Science and Technology
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• v.21 no.2
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• pp.174-181
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• 2004

Multi-walled carbon nanotubes (CNTs) were prepared by thermal chemical vapor deposition (CVD) and microwave plasma chemical vapor deposition (MPCVD) using various combination of binary catalysts with four transition metals such as Fe, Co, Cu, and Ni. In the preparation of CNTs from acetylene precursor by thermal CVD, the CNTs with very high yield of 43.6 % was produced over $Fe-Co/Al_2O_3$. The highest yield of CNTs was obtained with the catalyst reduced for 3 hr and the yield was decreased with increasing reduction time to 5 hr, due to the formation of $FeAl_2O_4$ metal-aluminate. On the other hand, the CNTs prepared by acethylene plasma CVD had more straight, smaller diameter, and larger aspect ratio(L/D) than those prepared by thermal CVD, although their yield had lower value of 27.7%. The degree of graphitization of CNTs measured by $I_d/I_g$ value and thermal degradation temperature were 1.04 and $602^{\circ}C$, respectively.

• Elastomers and Composites
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• v.45 no.2
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• pp.80-86
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• 2010

Carbon nanotubes (CNTs) exhibit excellent mechanical, electrical, and magnetic properties as well as nanometer scale diameter and high aspect ratio, which make them an ideal reinforcing agent for high strength polymer composites. The functionalized CNTs are believed to be very promising in the fields such as preparation of functional and composite materials. CNT-Polymer composites are expected to have good processability characteristics of the polymer and excellent functional properties of the CNTs. However, since CNTs usually form stabilized bundles due to Van der Waals interactions, are extremely difficult to disperse and align in a polymer matrix. The biggest issues in the preparation of CNT-reinforced composites reside in efficient dispersion of CNTs into a polymer matrix, and the alignment and control of the CNTs in the matrix. There are several methods for the dispersion of nanotubes in the polymer matrix such as solution mixing, bulk mixing, melt mixing, in-situ polymerization and chemical functionalization of the carbon nanotubes, etc. These methods and preparation of high performance CNT-polymer composites are described in this review.

• Advances in concrete construction
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• v.8 no.3
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• pp.207-215
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• 2019

Application of nanotechnology can be used to tailor made cementitious composites owing to small dimension and physical behaviour of resulting hydration products. Because of high aspect ratio and extremely high strength, carbon nanotubes (CNTs) are perfect reinforcing materials. Hence, there is a great prospect to use CNTs in developing new generation cementitious materials. In the present paper, a parametric study has been conducted on cementitious composites reinforced by two types of multi walled carbon nanotubes (MWCNTs) designated as Type I CNT (10-20 nm outer dia.) and Type II CNT (30-50 nm outer dia.) with various concentrations ranging from 0.1% to 0.5% by weight of cement. To evaluate important properties such as flexural strength, strain to failure, elastic modulus and modulus of toughness of the CNT admixed specimens at different curing periods, flexural bending tests were performed. Results show that composites with Type II CNTs gave more strength as compared to Type I CNTs. The highest increase in strength (flexural and compressive) is of the order of 22% and 33%, respectively, compared to control samples. Modulus of toughness at 28 days showed highest improvement of 265% for Type II 0.3% CNT composites. It is obvious that an optimum percentage of CNT could exists for composites to achieve suitable reinforcement behaviour and desired strength properties. Based on the parametric study, a tentative optimum CNT concentration (0.3% by weight of cement) has been proposed. Scanning electron microscope image shows perfect crack bridging mechanism; several of the CNTs were shown to act as crack arrestors across fine cracks along with some CNTs breakage.

• 한국정보디스플레이학회:학술대회논문집
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• 2008.10a
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• pp.1529-1531
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• 2008

Since the discovery over a decade ago, carbon nanotubes (CNTs) have been attracting considerable attentions both from scientists and engineers. Because of the excellent field emission properties, such as high aspect ratio, extremely small diameter, and high emission current, CNTs become a potential candidate as field emitter for field emission display (FED) and lighting (FEL) as backlight for LCD. Due to the exceptional physical properties, such as superior thermal and electrical conductivities, as well as high stiffness and strength, the CNT-based composites can be as light-weight heat-sink or thermal spreader materials used for power electronic devices, such as power LED for general illumination. The CNTs for above applications will be reviewed, and related materials and devices will be demonstrated in this paper.

• Korean Journal of Metals and Materials
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• v.48 no.2
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• pp.180-186
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• 2010

For the application of field emission display (FED), it is essential to develop a carbon nanotube (CNT) cathode with high emission current density. In this study, we developed and demonstrated a post-heat treatment (PHT) process to improve field emission properties of CNT cathodes. Since the PHT is intended to burn out organic materials covering the CNTs, the PHT was carried out by heating samples at a high temperature in an atmosphere. The PHT process is applied for samples processed by surface treatment with an adhesive tape. Compared to samples prior to the PHT, samples after the PHT at $360^{\circ}C$ showed about 17% improvement in emission current density. The major reason for the increased current density is mainly the increased aspect ratio of the CNTs because of the removal of the adhesive organic residues covering the CNTs, which were attached on the CNT surfaces during the surface treatment using the adhesive taping method.