• Composites Research
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• v.26 no.6
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• pp.373-379
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• 2013

The coating of metal surface with carbon nanotubes (CNTs) has been studied for the heat transfer enhancement of the boiling and condensation of refrigerant. The MWCNT/copper composite powder was made by the attrition ball milling, which has been coated on the copper wafer by electrostatic powder coating and sintered with electric furnace. In this paper, experiments were performed to assess the characterization and comparison of CNT before and after sinterning and the morphology changes of the CNT/Cu-coated surface. The samples were examined by the scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDAX) and raman spectroscopy. To verify the heat transfer enhancement, boiling heat transfer tests were performed.

• Journal of Surface Science and Engineering
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• v.53 no.3
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• pp.87-94
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• 2020

Herein, sulfonated carbon nanotubes (CNT) have been prepared in dilute sulfuric acid (H₂SO₄) via a novel sulfonation approach based on gas-liquid interfacial plasma (GLIP) at room temperature. The sulfonic acid groups and total acid groups densities of CNT after GLIP treatment in 2 M H₂SO₄ for 45 min can reach to 0.53 mmol/g and 3.64 mmol/g, which is higher than that of sulfonated CNT prepared under 0.5 M / 1 M H₂SO₄. The plasma sulfonated CNT has been applied as catalysts for the conversion of microcrystalline cellulose to glucose. The effect of hydrolysis temperature and hydrolysis time on the conversion rate and product distribution have been discussed. It demonstrates that the total conversion rate of cellulose increasing with hydrolysis temperature and hydrolysis time. Furthermore, the GLIP sulfonated CNT prepared in 2 M H₂SO₄ for 45 min has shown high catalytic stability of 85.73 % after three cycle use.

• Journal of the Korean Ceramic Society
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• v.45 no.11
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• pp.651-657
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• 2008

In this study, CNT/$TiO_2$ composites were prepared using surface modified Multiwall carbon nanotube (MWCNT) and titanium n-butoxide (TNB) with benzene. The composites were characterized by nitrogen adsorption isotherms, scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray analysis (EDX), FT-IR spectra, and UV-vis absorption spectroscopy. The UV radiation induced photoactivity of the CNT/$TiO_2$ composites was tested using a fixed concentration of methylene blue (MB, $C_{16}H_{18}N_3S{\cdot}Cl{\cdot}3H_2O$) in an aqueous solution. Finally, it can be considered that the MB removal effect of the CNT/$TiO_2$ composites is not only due to the adsorption effect of MWCNT and photocatalytic degradation of $TiO_2$, but also to electron transfer between MWCNT and $TiO_2$.

• Korean Journal of Materials Research
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• v.30 no.3
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• pp.149-154
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• 2020

A powder-in-sheath rolling method is applied to the fabrication of a carbon nano tube (CNT) reinforced copper composite. A copper tube with outer diameter of 30 mm and wall thickness of 2 mm is used as sheath material. A mixture of pure copper powder and CNTs with a volume content of 3 % is filled in a tube by tap filling and then processed to an 93.3 % reduction using multi-pass rolling after heating for 0.5 h at 400 ℃. The specimen is then sintered for 1h at 500 ℃. The relative density of the 3 vol%CNT/Cu composite fabricated using powder in sheath rolling is 98 %, while that of the Cu powder compact is 99 %. The microstructure is somewhat heterogeneous in width direction in the composite, but is relatively homogeneous in the Cu powder compact. The hardness distribution is also ununiform in the width direction for the composite. The average hardness of the composites is higher by 8Hv than that of Cu powder compact. The tensile strength of the composite is 280 MPa, which is 20 MPa higher than that of the Cu powder compact. It is concluded that the powder in sheath rolling method is an effective process for fabrication of sound CNT reinforced Cu matrix composites.

• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1035-1038
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• 2013

Rolling circle amplification (RCA) of DNA on an aligned-carbon nanotube (a-CNT) surface was electrically interfaced by the a-CNT based filed effect transistor (FET). Since the electric conductance of the a-CNT will be dependent upon its local electric environment, the electric conductance of the FET is expected to give a very distinctive signature of the surface reaction along with this isothermal DNA amplification of the RCA. The a-CNT was initially grown on the quartz wafer with the patterned catalyst by chemical vapor deposition and transferred onto a flexible substrate after the formation of electrodes. After immobilization of a primer DNA, the rolling circle amplification was induced on chip with the a-CNT based FET device. The electric conductance showed a quite rapid increase at the early stage of the surface reaction and then the rate of increase was attenuated to reach a saturated stage of conductance change. It took about an hour to get the conductance saturation from the start of the conductance change. Atomic force microscopy was used as a complementary tool to support the successful amplification of DNA on the device surface. We hope that our results contribute to the efforts in the realization of a reliable nanodevice-based measurement of biologically or clinically important molecules.

• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1065-1069
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• 2013

A highly sensitive electrochemical detection method for bisphenol A (BPA) has been developed by using multi-walled carbon nanotube (CNT)-doped titania-Nafion composite modified glassy carbon (GC) electrode. The CNT-titania-Nafion/GC electrode exhibited excellent electrocatalytic activity towards BPA. Therefore, the CNT-titania-Nafion/GC electrode showed improved voltammetric responses for BPA compared to that obtained with bare GC electrode. In addition, cetyltrimethylammonium bromide (CTAB), a cationic surfactant, was added into the BPA sample solution in order to accumulate BPA through hydrophobic interaction between CTAB and BPA. The CNT-titania-Nafion/GC electrode gave a linear response ($r^2$ = 0.999) for BPA from $1.0{\times}10^{-8}$ M to $5.0{\times}10^{-6}$ M with a detection limit of $9.0{\times}10^{-10}$ M (S/N = 3). The modified electrode showed good selectivity against interfering species and also exhibited good reproducibility. The present electrochemical sensor based on the CNT-titania-Nafion/GC electrode was applied to the determination of BPA in food package samples.

• 대한공업교육학회지
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• v.30 no.2
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• pp.115-122
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• 2005

For an analysis of dynamic behavior in carbon nanotube(CNT) which is widely used as micro and nano-sensors, an electrostatic force of CNT was investigated. For larger gaps in between sensor and electrode the van der Waals force can be ignored. The boundary condition in the CNT was assumed to clamped-clamped case at both ends. In this paper electrostatic force is expressed as linear equation along deflection using Taylor series. The first and second terms(${\zeta}_0$ and ${\zeta}_1$) of the linear equation are analyzed. Based on the simulation results nondimensional number ${\Phi}_0$ and ${\Phi}_1$ which came from ${\zeta}_0$ and ${\zeta}_1$ were decreased according to the increment of the gap. Reduction ratio of the second term ${\zeta}_1$ is increased up to 99% along to the increment of the gap. The higher order terms can be ignored and therefore, electrostatic force can be expressed using the first two terms of the linear equation. This results play an important role in analyzing the nonlinear dynamic behavior of the CNT as well as the pull-in voltage of simply supported switches.

• Proceedings of the Materials Research Society of Korea Conference
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• 2009.05a
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• pp.32.2-32.2
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• 2009

높은 효율성을 가지는 전계방출 디스플레이(field emission displays)를 개발하기 위해 탄소나노튜브 음극소자 (CNT cathodes)의 표면처리에 대한 연구가 활발히 진행되고 있다. 열처리가 끝난 탄소나노튜브 음극소자(CNT cathodes)의 표면에는 유기성 바인더들이 타면서 잔여물들이 생성되게 되는데 이러한 잔여물들은 전계방출을 하는데 있어서 방해요소가 된다. 전계방출이 용이하게 하기 위해서는 이러한 잔여물들을 효과적으로 제거해 주어야한다. 표면처리의 방법으로는 여러 가지가 존재하는데 그중에서 테이핑 방법을 이용한 표면처리는 열처리 후에 남은 잔여물들을 제거하면서 CNTs를 돌출시키는 효율적인 방법이다. 하지만 이러한 테이핑 방법으로도 완벽하게 잔여물을 제거하기란 쉽지 않다. 본 연구는 첫 번째 열처리가 끝난 시편을 테이핑 방법을 이용하여 표면 처리를 실시하고 그것으로 끝나는 것이 아니라 표면처리가 끝난 시편에 두 번째 열처리를 실시하여 탄소나노튜브 음극소자(CNT cathodes)에 남아있는 잔여물들을 좀 더 효과적으로 제거해 주는데 그 목적이 있다. 재열처리시 온도는 $330^{\circ}C$ ~ $420^{\circ}C$까지 $30^{\circ}C$의 차이를 주어 4단계에 걸쳐 실험을 실시하였고 재열저리를 하기전과 재열처리를 실행한 후의 전류밀도의 차이를 관찰하여 효과적으로 잔여물들이 제거되었는지에 대해서 알아보았다. 재열처리를 실행하였을 때 재열처리를 하기 전에 비하여 전류밀도에서 우월하였으며 $360^{\circ}C$ 부근에서 가장 많은 차이를 보였다.

• Korean Journal of Materials Research
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• v.25 no.1
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• pp.48-53
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• 2015

$TiH_2$ nanopowder was made by high energy ball milling. The milled $TiH_2$ and CNT powders were then simultaneously synthesized and consolidated using pulsed current activated sintering (PCAS) within one minute under an applied pressure of 80 MPa. The milling did not induce any reaction between the constituent powders. Meanwhile, PCAS of the $TiH_2$-CNT mixture produced a Ti-TiC composite according to the reaction ($0.92TiH_2+0.08CNT{\rightarrow}0.84Ti+0.08TiC+0.92H_2$, $0.84TiH_2+0.16CNT{\rightarrow}0.68Ti+0.16TiC+0.84H_2$). Highly dense nanocrystalline Ti-TiC composites with a relative density of up to 99.7% were obtained. The hardness and fracture toughness of the dense Ti-8 mole% TiC and Ti-16 mole% TiC produced by PCAS were also investigated. The hardness of the Ti-8 mole% TiC and Ti-16 mole% TiC composites was higher than that of Ti. The hardness value of the Ti-16 mole% TiC composite was higher than that of the Ti-8 mole% TiC composite without a decrease in fracture toughness.

• Journal of Sensor Science and Technology
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• v.22 no.6
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• pp.400-403
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• 2013

The piezoelectric composite film of ferroelectric PZT ceramic ($PbZr_xTi_{1-x}O_3$) and polymer (PDMS, Polydimethylsiloxane) was prepared to improve the flexibility of piezoelectric material. The bar coating method was applied to fabricate flexible nanocomposite film with large surface area by low cost process. In the case of using metal electrode on the composite film, although there is no problem by bending process, the electrode is usually broken away from the film by stretching process. However, the well-attached, flexible CNT electrode on PZT/PDMS film improved flexibility, especially stretchability. PZT particles was usually settled down into polymer matrix due to gravity of the weighty particle, so to improve the dispersion of PZT powder in polymer matrix, small amount of additives (CNT powder, Carbon nanotube powder) was physically mixed with the matrix. By stretching the film, an output voltage of PZT(70 wt%)/PDMS with CNT (0.5 wt%) was measured.