• Title/Summary/Keyword: CNF slurry

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Effect of Modification PP on the Physical Properties and CNF Dispersion of PP Powder/CNF 1 wt% Slurry Composite (PP 분말/CNF 1 wt% 슬러리 복합체의 CNF 분산 및 물성에 대한 개질 PP의 영향)

  • Kim, Jun Seok;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.33 no.3
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    • pp.284-288
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    • 2022
  • Polypropylene (PP) powder/cellulose nanofibers (CNF) 1 wt% slurry composites were prepared by filtering their suspension under reduced pressure and dried them in an oven followed by the use of a twin screw extruder. PP modified with side branches and polar groups was used. The side branches and polar groups were introduced into PP by using divinylbenzene and maleic anhydride (MAH), respectively. As a result of examining the dispersibility of CNF and the physical properties of the composite, it was confirmed that the composite prepared from PP powder/CNF 1 wt% slurry showed equal or higher levels in tensile and flexural strength as compared with those using the composite prepared from CNF powder.

Electrical Properties of Carbon Black Composites for Flexible Fiber Heating Element (유연한 섬유상 발열체용 카본블랙 복합소재의 전기적 특성)

  • Park, Ji-Yong;Lee, Jong-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.405-411
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    • 2015
  • Carbon composites for flexible fiber heating element were examined to improve the electrical conductivity in this study. Carbon composites using carbon black, denka black, super-c, super-p with/without CNF or dispersant such as BCS03 and Sikament-nn were prepared. Carbon composite slurry was coated on plane film and yarns(cotton, polyester) and the performances of prepared heating materials were investigated by checking electrical surface resistance, adhesion strength. The plane heating element using carbon black under natural drying condition($25^{\circ}C$) had better physical properties such as surface resistance(185.3 Ohm/sq) and adhesion strength(above 90%) than those of other carbon composite heating elements. From these results, polyester heating element coated by carbon black showed better electrical line resistance(33.2 kOhm/cm) than cotton heating element. Then, it was found that polyester heating element coated by carbon black with CNF(3 wt%) and BCS03(1 wt%) appeared best properties(0.604 kOhm/cm).

Electrochemical Characteristics of all solid supercapacitor based on DAAQ(1,5-diaminoanthraquinone) and SPEEK(sulfonated polyether ether ketone) (DAAQ와 SPEEK를 이용한 전고상 슈퍼커패시터의 전기화학적 특성)

  • Kim, Jin-Yong;Kim, Hong-Il;Kim, Han-Joo;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.371-372
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    • 2005
  • Supercapacitors are promising devices for delivering high power density. Digital communications, electric vehicles and other devices that require electrical energy at high power levels in relatively short pulses have prompted considerable research on supercapacitors. In recent years, solid electrolytes have been investigated for supercapacitors. Solid electrolytes are advantageous over liquid electrolytes in respect of easy handling and reliability without electrolyte leakage. In this preliminary study, an electrochemical supercapacitor in all solid configuration has been fabricated using CNF-DAAQ and poly-vinylidenefluoride(PVdF). A new type of Supercapacitor was constructed by using carbon nanofibers(CNFs) and DAAQ(l,5-diaminoanthraquinone) monomer. DAAQ was deposited on the carbon nanofibers by chemical polymerization with $(NH_4)_2S_2O_8$ as oxidant in the 0.1M $H_2SO_4$. Dried SPEEK powder was mixed with N-methyl pyrrolidone to make 10 wt.% solution in an ultrasonic bath, the slurry was cast over a glass substrate heated to $70^{\circ}C$ for solvent evaporation. And then we used solid electrolyte of SPEEK. The unit cell consist of DAAQ-CNF/electrolyte/Pt. From the analysis, it is clear that surface of carbon nanofibers was quite uniformly coated with DAAQ. The performance characteristics of the supercapacitors have been evaluated using Cyclic Voltammetry.

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