• Journal of Photoscience
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• v.10 no.2
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• pp.203-208
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• 2003

Two coupled molecules were successfully synthesized by condensation of amine-donor-substituted barbituric acid derivativies as nonlinear optical chromophores. A flexible spacer of the alkyl chain with different lengths of carbon chains (5 and 6 carbons) was introduced between two chromophores, which prevented crystallization and aggregation of molecules. Two coupled molecules (B-Cn-B, n=5, 6) had glass-transition temperatures on a second heating around 81 and 76$^{\circ}C$ without melting points, respectively. To explore the linear optical properties, thin-films were prepared and examined by a photometry method using Nd:YVO$_4$ CW laser. Also, microscopic and macroscopic nonlinear optical properties were measured by Hyper-Rayleigh Scattering (HRS) and the Maker Fringes method using Nd:YAG ps pulse laser, respectively. In spite of the moderate hyperpolarizabilities of coupled molecules, the second order NLO coefficient (d$\_$33/) was larger than the conventional Disperse Red 1 doped PMMA polymeric system.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.93-93
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• 2010

We developed friction welded bimetallic sleeve for 220kV aluminum conductor XLPE cable. Not only friction welded bimetallic sleeve for Termination(EB-A, EB-G) but also friction welded sleeve for Joint of Al to Cu conductor was developed regardless of this project. Generally, friction welded sleeve used to connect Al conductor cable to Cu conductor cable and used for improvement of mechanical property of terminal by offer the copper side of friction welded bimetallic sleeve at the Termination. Connection method for Al-Cu conductor has mainly used friction welding at the solid state, because it is difficult to connect by using conventional welding method. this investigation introduces development of friction welded bimetallic sleeve by friction welding and test result of 220kV Al conductor XLPE cable and accessories using friction welded sleeve.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.15 no.6
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• pp.24-34
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• 2016

To attach a fuel tank to an excavator, two sets of mounting plates on which three bosses are attached are welded onto the tank. In this study, the welding process of a fuel tank for an excavator was modeled using a finite element numerical method. The tank was modeled as a simple plate to which the mounting plate or bosses were attached by fillet welding. Thermal and thermo-elasto-plastic analyses of the welding process were carried out to predict the temperature distribution and material distortion during welding, respectively. Three different welding sequences for the tank were also modelled to compare the deformation that occurred due to each welding sequence. The results of the analysis predicted that changing the welding sequence around the mounting plate could not position the boss within the allowable dimensional range. The results also revealed the sequence in which the maximum distortion of the bosses welded onto the tank was 30% less than the maximum distortion due to the other sequences.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.17 no.4
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• pp.169-176
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• 2018

Removal of angular deformation induced during the welding of butt joints in thick steel plates needs expert skill and is costly. To reduce deformation, proper joint designs are studied with a prediction of deformation prior to welding. However, as the thickness of a plate increases, a predictive analysis of the welding process is more difficult, especially if there is an increase in the number of welding passes in the joint. In this study, a numerical model with the finite element method (FEM) was developed to analyze the angular deformation in the multi-pass welding of butt joints of plates made of AH32 steel that had a thickness of up to 100 mm. A series of numerical simulations were then performed based on the developed model to predict the deformations for thick plates. With the results obtained by the analyses, this study suggested optimal X-shape grooves for the butt joints of thick plates to minimize the angular deformation. As the thickness of the plate increased to 100 mm, the ratio of the depth of the front-side groove to that of the back-side groove should be gradually increased to nearly 1:3.

• Korean Journal of Pharmacognosy
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• v.30 no.3
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• pp.335-339
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• 1999

Separation and quantitative determination of 20-hydroxyecdysone from Achyranthis Radix has been conducted by using HPLC method. 20-hydroxyecdysone in a methanol extract from the raw drug was separated on a reverse phase column using a $CH_3CN-H_2O\;(18:82)$ solvent system and the average content is $0.0931{\pm}0.0048%$. For the preparation of authentic standard, we isolated 20-hydroxyecdysone from the roots of Achyranthes fauriei by $SiO_2$ and RP-18 column chromatography.

• Analytical Science and Technology
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• v.11 no.6
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• pp.429-435
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• 1998

Free and glycine conjugated bile acids were detected fluoromatrically in high-performance liquid chromatography after derivatization with dansyl cadaverine. The coupling agent, diethyl phosphorocyanidate was used to form the amide bond between dansyl cadaverine and analytes. The dansyl derivatives of 8 bile acids were separated successfully on Cosmosil ODS column by using linear gradient elution of 20% MeOH-water/$CH_3CN$. The detection limits of cholic acid was reached 10 pg(S/N=5) per $1{\mu}l$ of injected volume. This new derivatization method would be applicable to detect the changes of bile acids in biological samples.

• The Journal of the Korean Society for Microbiology
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• v.19 no.1
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• pp.79-83
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• 1984

To determine the existence of anti-HLA antibodies finally in 220 human placental extracts to be proved negative antiserum by previous anti-HLA A,B,C antibody screening procedure, the present study was performed by fractionation of immunoglobulins using saturated ammonium sulfate and by simple batch method on DEAE cellulose. Thereafter using known 150 T-lymphocyte panels, complement-dependent microlymphocytotoxicity test was performed to observe the existence of anti-HLA antibodies and the degree of the antibody response of the concentrates. The following results were obtained: 1. Of total 141 placental sera concentrated 45 cases(31.9%) were showed significant anti-HLA A,B,C antibody response after concentration(Excellent, 19(13.5%), Good, 3(2.1%), Weak, 23(16.3%)). 2. Anti-HLA specificities of placental sera obtained after concentration were A2, A24, B13, B27, B44, B51, CN1, C7. 3. A new type C new-1 anti-HLA antibody that is only expressed in Korean people, was obtained. 4. 79 placental sera purrified by simple batch method using DEAE cellulose were showed negative anti-HLA antibody responses.

• Journal of Radiation Protection and Research
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• v.22 no.4
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• pp.243-250
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• 1997

A relative-calibration-method of solid-state-track-detector for measurement of radon in air has been developed, and the concentration of radon in each room of a 15th-floor-apartment was measured by using the relative calibrated SSTD. There is a tendency to decrease the concentration of radon when the floor is higher, but the main factor to reduce the concentration of radon in room appeared to be ventilation rate. Average concentration of radon of the 15th-floor-apartment was $1.50{\pm}0.51pCi/l$, and the highest and the lowest concentration of radon were $2.68{\pm}0.32pCi/l$, $0.69{\pm}0.16pCi/l$ respectively.

• Bulletin of the Korean Chemical Society
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• v.29 no.7
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• pp.1323-1325
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• 2008

The acetylene black (AB) was dispersed into water in the presence of dihexadecyl hydrogen phosphate (DHP) via ultrasonication, resulting in a stable and well-distributed AB/DHP suspension. After evaporation of water, an AB/DHP composite film-modified electrode was prepared. The electrochemical responses of $K_3$[Fe$(CN)_6$] at the unmodified electrode, DHP film-modified electrode and AB/DHP film-modified electrode were investigated. It is found that the AB/DHP film-modified electrode possesses larger surface area and electron transfer rate constant. Furthermore, the electrochemical behaviors of 1-naphthylacetic acid (NAA) were examined. At the AB/DHP film-modified electrode, the oxidation peak current of NAA remarkably increases. Based on this, a sensitive and convenient electrochemical method was proposed for the determination of NAA. The linear range is in the range from $4.0 {\times} 10^{-8}\;to\;5.0 {\times} 10^{-6}$ mol $L^{-1}$, and the detection limit is $1.0 {\times} 10^{-8}$ mol $L^{-1}$. Finally, this new sensing method was employed to determine NAA in several soil samples.

• Archives of Pharmacal Research
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• v.20 no.2
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• pp.184-190
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• 1997

A new method based on the chemical reaction has been devised for the sequential analysis of reducing oligosaccharides using 8-amino-2-naphthalenesulfonic acid (ANS), a fluorescent precolumn derivatization reagent for reducing saccharides. The procedure established includes 1) the derivatization of a reducing oligosaccharide to produce a Schiff base, 2) the reduction of the base with sodium cyanoborohydride $(NaBH_3/CN), 3)$ the methoxycarbonylation of the resultant secondary amino group, 4) the cleavage of the glycoside bond next to the reducing end, based on the intramolecular acid hydrolysis by the action of a sulfonic acid group of the ANS derivative, 5) the identification of the liberated reducing end by high-performance liquid chromatography (HPLC), and finally 6) the recovery of the resultant oligosaccharide fragment from the cleavage reaction mixture. The extensive examination of the conditions for the sequential analysis of reducing oligosaccharides resulted in the procedure of simplicity , high selectivity and high recovery. This procedure was found to be useful for the sequential analysis of di-, tri- and tetrasaccharides.