• Title/Summary/Keyword: CN Method

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Analytical Determination of Cyanide in Maesil (Prunus mume) Extracts (매실추출제품의 시안화합물 분석법에 관한 연구)

  • Kim, Eun-Jung;Lee, Hwee-Jae;Jang, Jin-Wook;Kim, In-Young;Kim, Do-Hyeong;Kim, Hyun-Ah;Lee, Soo-Min;Jang, Ho-Won;Kim, Sang-Yub;Jang, Young-Mi;Im, Dong-Kil;Lee, Sun-Hee
    • Korean Journal of Food Science and Technology
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    • v.42 no.2
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    • pp.130-135
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    • 2010
  • Picrate, enzyme-picrate and instrumental analysis methods using IC (Ion Chromatography) and HPLC (High Performance Liquid Chromatography) were compared for their effectiveness in determining cyanide in extracts of Maesil, which is classified as a harmful substance. First, the picrate method showed the shortest analysis time (about 5 hr). The color of picrate paper changed at 0.01 mg/$200\;mL\;CN^-$. However, it was difficult to detect cyanide from amygdalin of glucosides. Second, we performed a qualitative analysis for total cyanide (free cyanide and cyanide from amygdalin) by the enzyme-picrate method using $\beta$-glucosidase and a quantitative analysis by spectrophotometry. Finally, analysis of cyanide by IC and HPLC required the longest determining time (about 17 hr) as well as pretreatment for each free cyanide and amygdalin. These results suggest that enzyme-picrate is the most effective analysis method for the detection of cyanide in Maesil extracts.

Development of the Ecohydrologic Model for Simulating Water Balance and Vegetation Dynamics (물수지 및 식생 동역학 모의를 위한 생태수문모형 개발)

  • Choi, Daegyu;Choi, Hyunil;Kim, Kyunghyun;Kim, Sangdan
    • Journal of Korean Society on Water Environment
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    • v.28 no.4
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    • pp.582-594
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    • 2012
  • A simple ecohydorlogic model that simulates hydrologic components and vegetation dynamics simultaneously based on equations of soil water dynamics and vegetation's growth and mortality is discussed. In order to simulate ungauged watersheds, the proposed model is calibrated with indirected estimated observation data set; 1) empirically estimated annual vaporization, 2) monthly surface runoff estimated by NRCS-CN method, and 3) vegetation fraction estimated by SPOT/VEGETATION NDVI. In order to check whether the model is performed well with indirectly estimated data or not, four upper dam watersheds (Andong, Habcheon, Namgang, Milyang) in Nakdong River watershed are selected, and the model is verified.

Development of an Estimation Method for Specific Flood (비홍수량 산정 방법의 개발)

  • Jeong, Jong-Ho;Park, Cheong-Hoon;Yoon, Yong-Nam
    • Proceedings of the Korea Water Resources Association Conference
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    • 2005.05b
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    • pp.230-239
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    • 2005
  • 유역특성을 충분히 고려한 비홍수량 산정 공식을 유도하여 개략적인 홍수량 산정 및 홍수량 범위 예측 등을 가능하게 하는 것의 실무적 필요성이 대두되고 있다. 이에 따라 홍수량 산정의 주요 입력인자 조건을 설정하고 이들 조합에 의한 홍수량 산정 결과를 회귀분석함으로써 유역특성을 충분히 고려하고 일종의 지역빈도해석 개념의 비홍수량 산정 공식을 제시하고자 한다. 이를 위하여 유역형상은 타원형, 강우량은 50년빈도 전국평균 확률강우량, 강우분포는 Huff 방법의 전국평균 4분위, CN은 80, 유입시간은 10분, 평균유속은 3.0m/sec의 조건을 기준조합으로 채택하고, 홍수량 산정 모형은 Clark 단위도법 및 Sabol 공식을 적용하여 기준조합의 비홍수량 회귀식을 유도한 다음, 각종 인자들의 변화에 따른 비홍수량의 변화를 추가로 고려할 수 있는 회귀 식을 제시하였다.

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2-amino-3-[(E)-4-(diethylamino)-2-alkoxy-benzylideneamino]- fumaronitrile 유도체 ICT 화합물의 결정 구조

  • Kim, Byung-Soon;Matsumoto, Shinya;Son, Young-A
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.62-62
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    • 2011
  • Intramolecular charge transfer (ICT) system has received great attentions due to their promising optoelectronic properties For the efficient ICT of the chromophore, their organic compound mainly consists of strong electron donors (e.g. $NR_2$ or OR groups) and acceptors (e.g. CN or $NO_2$ groups). According to the molecular design and synthesis, the ICT compounds can be extended in many application fields. In this study, we have synthesized ICT compounds having a strong electron acceptor and donor. These novel ICT compounds were easily synthesized by a previously described method with some modifications. Their single crystals were grown and their structures were solved and described in this presentation.

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Analysis of Hydrological Impact for Long-term Land Cover Change using WMS HEC-l Model in Anseong-Cheon Watershed (WMS HEC-1을 이용한 안성천 유역의 경년 수문 변화 분석)

  • Park, Geun-Ae;Kim, Seong-Joon
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2002.10a
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    • pp.293-296
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    • 2002
  • The purpose of this study is to evaluate the hydrological impact due to temporal land cover change urbanization of Anseong-cheon watershed $(585.09km^2)$. WMS (Watershed Modeling System) HEC-1 was adopted, and burned DEM with $200{\times}200m$ resolution and soil map reclassified by hydrologic soil groups were prepared. Land cover for 1985, 1990, 1995 and 2000 were classified by maximum likelihood method, using Landsat MSS and TM imageries. Calibration and verification of HEC-1 were conducted using 4 storm events. Peak flow at Pyeong taek station increased $25.9m^3/sec$ during the past 15 years due to paddy and forest decrease. Streamflow impact by just paddy area decrease and forest area decrease were also analysed keeping watershed CN values unchanged of the given year, respectively.

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Simultaneous detection of residual fungicide in Bean Sprouts by Solid-phase Extraction (고체상 추출법에 의한 콩나물 중의 잔류농약 동시 검출)

  • Lee, Myunghwoon;Lee, Taejoon;Pyo, Dongjin
    • Analytical Science and Technology
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    • v.6 no.5
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    • pp.509-514
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    • 1993
  • Benomyl, topsin-M and thiram been known as one of the seed disinfectant. For these studies benomyl, topsin-M and thiram simultaneously had been analyzed by high performance liquid chromatographic method using ODS cartridge, benomyl, topsin-M and thiram was chromatographed using an ODS column and eluent 40% Acetonitrile at a flow rate of 1ml/min. The UV Detector responses at 276nm.

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Observation of Surface Morphology and Electrical Properties of Polyurethane Polymer LB Films (폴리우레탄 고분자 LB막의 표면구조 관찰 및 전기적 특성)

  • Seo, Jeong-Yeul;Shin, Hoon-Kyu;Kwon, Young-Soo
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.50 no.8
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    • pp.371-375
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    • 2001
  • We attempted to fabricate polyurethane derivatives (PU-CN, PU-DCM) LB films by using LB method. Also, we investigated the monolayer behavior at the air-water interface by surface pressure-area (${\pi}$-A) isotherms. The surface morphologies and the physicochemical properties of LB films were investigated by atomic force microscopy(AFM) and UV-vis spectroscopy, respectively. And, the electrical properties of polyurethane derivatives LB films were investigated by using the conductivity and the dielectric constant. In the surface morphologies, physicochemical and electrical properties of polyurethane derivatives LB films, the properties is different as to the polyurethane derivatives, it is considered that this phenomena could be described by the difference of lumophore pendant which was adhered at PU main chain.

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Quantum Mechanical Studies of the Structures and Reactions of oxiranes (Oxiranes의 구조와 반응에 관한 양자역학적 연구)

  • Shi Choon Kim
    • Journal of the Korean Chemical Society
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    • v.30 no.2
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    • pp.248-258
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    • 1986
  • The electronic structures and geometries of model substituted oxiranes, and carbonyl ylides containing cyano, methoxy and thiomethoxy substituents were investigated by MNDO-SCF-MO method. Stabilization and geometries caused by substituents, the ease of formation of carbonyl ylides from oxiranes and the reactivities of the cycloaddition of substituted carbonyl ylides were investigated.

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A Study on Saccharides in Honey via HPLC (HPLC에 의한 벌꿀의 당성분에 관한 연구)

  • 김완구;정희선
    • Journal of Environmental Health Sciences
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    • v.8 no.2
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    • pp.57-65
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    • 1982
  • Saccharides in Korean honey have been analyzed by traditional wet chemical methods and several chromatographic technics gas, paper, column and thin layer chromatography. A simple, rapid and versatile method for the separation and determination of saccharides via high performance liquid chromatography were used eluting with $H_2O : CH_CN$ at 25:75, at a flow rate of 1.0ml/min. Acasia honey contained 36.8% fructose, 31.4% glucose, 1.7% sucrose and bush clover honey held 34.4% fructose, 32.3% glucose and 30% sucrose. Difference on the regional distribution were not found in the quantity of saccharides (42 species). The quality of inferior honey was assumed to contain much maltose, sugar and glucose than common honey.

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A Study on the Case of Quality Innovation with Building Evaluation Method for System Diagnosis (시스템 진단 평가 체계 구축을 통한 품질 혁신 사례 연구)

  • Ryou, In-Ho;Shin, Hyun-Jong;Yun, Kwang-Dong
    • 한국IT서비스학회:학술대회논문집
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    • 2007.05a
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    • pp.431-438
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    • 2007
  • SI 프로젝트에서 품질을 혁신하기 위해서는 시스템 생명 주기 각 단계에서 품질 관리 활동을 강화해야 할 뿐만 아니라 통합된 시스템 관점에서 각 계층(Layer)별, 요소(Component)별 특성을 고려하여 체계적인 시스템 진단 평가 활동을 수행할 필요성이 있다. 시스템 진단 평가 활동은 품질 이슈를 찾아내는 작업과 품질 이슈를 해결하는 작업이 톱니바퀴처럼 맞물려 수행되어야 한다. LG CNS는 프로젝트의 품질 이슈를 적기 진단하기 위해서 시스템 진단 평가 체계를 구축했으며, 프로젝트 현장에서 이를 적용하여 품질 혁신에 기여하고 있다.

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