• 제목/요약/키워드: CMR Materials

검색결과 58건 처리시간 0.025초

Ln0.7Ca0.3MnO3 (Ln=Nd, Sm, La)의 소결 거동 및 특성 (Sintering behavior and characterization of Ln0.7Ca0.3MnO3 (Ln=Nd, Sm, La))

  • 전검배;구본흔;이찬규
    • 한국재료학회지
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    • 제16권1호
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    • pp.44-49
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    • 2006
  • Effects of doping rare earth element on Ln site of $Ln_{0.7}Ca_{0.3}MnO_3$ (Ln=Nd, Sm and La) were examined from sintering behavior, structure and magnetic properties. Sintering reactions proceeded rapidly in order of $La_{0.7}Ca_{0.3}MnO_3>Nd_{0.7}Ca_{0.3}MnO_3>Sm_{0.7}Ca_{0.3}MnO_3$. This result can be explained by diffusivity of metal cation. Size of a-axis increased as following order of La$Nd_{0.7}Ca_{0.3}MnO_3$, 93K for $Sm_{0.7}Ca_{0.3}MnO_3$ and 225K for $La_{0.7}Ca_{0.3}MnO_3$ were obtained. This result coincides with change of Mn-O bond length causing by a-axis lattice constant.

RF 스퍼터링을 이용하여 저온에서 SiO2/Si 기판 위에 증착된 La0.7Sr0.3MnO3 박막의 구조 및 전기적 특성 (Structural and Electrical Properties of SiO2/Si Film on La0.7Sr0.3MnO3Substrate by RF Magnetron Sputtering at Low Temperature)

  • 최선규;;하태정;유병곤;박영호
    • 한국세라믹학회지
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    • 제44권11호
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    • pp.645-649
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    • 2007
  • The $La_{0.7}Sr_{0.3}MnO_3$ was deposited on $SiO_2/Si$ substrate by RF magnetron sputtering. The oxygen gas flow rate was changed from 0 to 80 sccm and the substrate temperature was $350^{\circ}C$. The oxygen gas flow rate was changed to control the growth orientation and crystalline state of the film. Relatively high TCR (temperature coefficient of resistance) value (-2.33%/K) was obtained when comparing with the reported values of the films prepared by using high substrate anneal temperature. The decrease in the sheet resistance and TCR value were observed when grain size of the film increased with the increase of oxygen gas flow rate.

Influence of Inhibitors on the Corrosion of Al and Al-composites in Chloride-containing Solutions - A Review

  • Kumar, Neeraj;Srivastava, Ashok K.;Gautam, Prabhat;Manoj, M.K.
    • 한국재료학회지
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    • 제32권5호
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    • pp.280-286
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    • 2022
  • Corrosion is a natural, inevitable process, and is one of the world's most serious problems. Losses incurred due to corrosion are extremely expensive for society. Several technological strategies have been explored and implemented to address these losses. The use of inhibitors to prevent corrosion is a common and efficient method to reduce corrosion losses. This review covers Al and Al-composite corrosion inhibitors in chloride-containing solutions, because of their popularity in a broad array of industrial applications. A vast number of studies in the literature detail the common tendency of Al and Al-composites with reinforcements to deteriorate. Accordingly, it is worthwhile to employ inhibitors to protect them, as discussed in the present work. The emphasis is on selecting the smartest corrosion inhibitor and evaluating its performance. According to the study, the most commonly used corrosion inhibitors are 1,4-naphthoquinone (NQ), 1,5-naphthalene diol, 3-amino-1,2,4-triazole-5-thiol (ATAT), ammonium tetrathiotungstate, clotrimazole, amoxicillin, antimicrobial and antifungal drugs. Electrochemical impedance spectroscopy (EIS), potentiodynamic (PDP), and weight loss were among the most commonly used modern electrochemical technologies to test inhibitors' efficacy under environmental conditions.

Light-Chain Cardiac Amyloidosis: Cardiac Magnetic Resonance for Assessing Response to Chemotherapy

  • Yubo Guo;Xiao Li;Yajuan Gao;Kaini Shen;Lu Lin;Jian Wang;Jian Cao;Zhuoli Zhang;Ke Wan;Xi Yang Zhou;Yucheng Chen;Long Jiang Zhang;Jian Li;Yining Wang
    • Korean Journal of Radiology
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    • 제25권5호
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    • pp.426-437
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    • 2024
  • Objective: Cardiac magnetic resonance (CMR) is a diagnostic tool that provides precise and reproducible information about cardiac structure, function, and tissue characterization, aiding in the monitoring of chemotherapy response in patients with light-chain cardiac amyloidosis (AL-CA). This study aimed to evaluate the feasibility of CMR in monitoring responses to chemotherapy in patients with AL-CA. Materials and Methods: In this prospective study, we enrolled 111 patients with AL-CA (50.5% male; median age, 54 [interquartile range, 49-63] years). Patients underwent longitudinal monitoring using biomarkers and CMR imaging. At follow-up after chemotherapy, patients were categorized into superior and inferior response groups based on their hematological and cardiac laboratory responses to chemotherapy. Changes in CMR findings across therapies and differences between response groups were analyzed. Results: Following chemotherapy (before vs. after), there were significant increases in myocardial T2 (43.6 ± 3.5 ms vs. 44.6 ± 4.1 ms; P = 0.008), recovery in right ventricular (RV) longitudinal strain (median of -9.6% vs. -11.7%; P = 0.031), and decrease in RV extracellular volume fraction (ECV) (median of 53.9% vs. 51.6%; P = 0.048). These changes were more pronounced in the superior-response group. Patients with superior cardiac laboratory response showed significantly greater reductions in RV ECV (-2.9% [interquartile range, -8.7%-1.1%] vs. 1.7% [-5.5%-7.1%]; P = 0.017) and left ventricular ECV (-2.0% [-6.0%-1.3%] vs. 2.0% [-3.0%-5.0%]; P = 0.01) compared with those with inferior response. Conclusion: Cardiac amyloid deposition can regress following chemotherapy in patients with AL-CA, particularly showing more prominent regression, possibly earlier, in the RV. CMR emerges as an effective tool for monitoring associated tissue characteristics and ventricular functional recovery in patients with AL-CA undergoing chemotherapy, thereby supporting its utility in treatment response assessment.

심장 아밀로이드증의 지연 조영증강 MR 영상소견 (Delayed Enhancement Magnetic Resonance Imaging Findings in Cardiac Amyloidosis)

  • 송진화;박은아;이활;정진욱;박재형
    • Investigative Magnetic Resonance Imaging
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    • 제17권1호
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    • pp.33-40
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    • 2013
  • 목적 : 심장 아밀로이드증 환자의 심장 자기공명영상의 지연 조영증강영상에서 좌심근의 조영증강 패턴과 다른 심장부위의 조영증강 유무를 평가하고자 하였다. 대상 및 방법 : 2009년 9월부터 2011년 6월 사이 심장 아밀로이드증이 의심되어 심장 자기공명영상을 촬영한 9명의 환자를 후향적으로 분석하였다. 좌심근의 조영증강 여부 및 패턴, 그리고 좌우심방 및 우심실의 조영증강 유무를 평가하였다. 또한 심방중격 두께, 좌심방 혈액신호 강도에 대한 심방중격과 심외막 지방의 상대적 신호강도 비를 계산하여 허혈성 심질환 대조군 16명과 Wilcoxon rank sum test를 통해 통계적으로 비교분석 하였다. 결과 : 총 9명중 8명에서 좌심근 조영증강소견을 보였으며, 8명중 4명의 환자에서 심내막하 원형성, 나머지 4명에서 미만성 패턴을 보였다. 심방중격 두께는 심장 아밀로이드증 환자에서 허혈성 심질환 환자에 비해서 증가되어 있었고 (p = 0.02), 심장 아밀로이드증 환자군에서 심방중격 대 혈액 신호 강도비 (p = 0.0002) 및 심외막 지방 대 혈액 신호 강도비 (p = 0.0006) 모두 의미있게 높았다. 결론 : 좌심실의 심내막하 원형성 혹은 미만성 조영증강 패턴은 심장 아밀로이드증 환자의 지연 조영 심장 자기공명영상의 특징적인 소견이며, 심방중격 및 심외막 지방 대 혈액 신호 강도비 신호강도가 상대적으로 증가된다.

GFRP 보강근의 외피형상을 고려한 부착 해석모델 제안 (An Analytical Model Proposal Considering Different Surface Type of Bond Behavior between GFRP Rebar and Concrete)

  • 박지선;송태협;이정윤
    • 한국구조물진단유지관리공학회 논문집
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    • 제23권3호
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    • pp.150-159
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    • 2019
  • GFRP 보강근과 콘크리트의 부착성능은 접착력, 부착력 및 지압력으로 발휘되며 보강근의 표면처리 방식이나 외피형상에 따라 발휘되는 부착저항력의 종류와 크기는 다르다. GFRP 부착 해석모델에 대한 선행연구를 살펴보면 철근의 부착 해석모델을 일부 수정하여 발전시키거나 수치해석을 통한 매개변수의 수가 많은 복잡한 해석식을 제안하였다. 전자의 경우에는 규격화된 마디형상을 갖는 철근과 달리 구성재료, 배합방법, 제조방법에 따라 다양한 외피형상을 가지는 GFRP 보강근의 특성을 포괄적으로 제안하는 데는 제약이 있으며 후자의 경우에는 수치해석으로 인한 수학적 관계식으로 GFRP 보강근의 부착거동과의 역학적인 관계를 고려하기에는 어려움이 있다. 따라서 이 연구에서는 GFRP 보강근의 콘크리트와의 외피형상에 따라 달라지는 부착메커니즘을 반영한 부착 해석모델을 제안하고자 하였다. 제안한 부착 해석모델에 대한 적합성 검증을 위하여 타 연구자가 수행한 실험값과 비교하였으며 기존의 부착 해석모델인 BPE 부착 해석모델과 CMR 부착 해석모델과의 비교연구도 수행하였다. 비교결과 이 연구에서 제안한 부착 해석모델이 실제 거동에 가장 근사하게 평가하였다.

T1 Map-Based Radiomics for Prediction of Left Ventricular Reverse Remodeling in Patients With Nonischemic Dilated Cardiomyopathy

  • Suyon Chang;Kyunghwa Han;Yonghan Kwon;Lina Kim;Seunghyun Hwang;Hwiyoung Kim;Byoung Wook Choi
    • Korean Journal of Radiology
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    • 제24권5호
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    • pp.395-405
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    • 2023
  • Objective: This study aimed to develop and validate models using radiomics features on a native T1 map from cardiac magnetic resonance (CMR) to predict left ventricular reverse remodeling (LVRR) in patients with nonischemic dilated cardiomyopathy (NIDCM). Materials and Methods: Data from 274 patients with NIDCM who underwent CMR imaging with T1 mapping at Severance Hospital between April 2012 and December 2018 were retrospectively reviewed. Radiomic features were extracted from the native T1 maps. LVRR was determined using echocardiography performed ≥ 180 days after the CMR. The radiomics score was generated using the least absolute shrinkage and selection operator logistic regression models. Clinical, clinical + late gadolinium enhancement (LGE), clinical + radiomics, and clinical + LGE + radiomics models were built using a logistic regression method to predict LVRR. For internal validation of the result, bootstrap validation with 1000 resampling iterations was performed, and the optimism-corrected area under the receiver operating characteristic curve (AUC) with 95% confidence interval (CI) was computed. Model performance was compared using AUC with the DeLong test and bootstrap. Results: Among 274 patients, 123 (44.9%) were classified as LVRR-positive and 151 (55.1%) as LVRR-negative. The optimism-corrected AUC of the radiomics model in internal validation with bootstrapping was 0.753 (95% CI, 0.698-0.813). The clinical + radiomics model revealed a higher optimism-corrected AUC than that of the clinical + LGE model (0.794 vs. 0.716; difference, 0.078 [99% CI, 0.003-0.151]). The clinical + LGE + radiomics model significantly improved the prediction of LVRR compared with the clinical + LGE model (optimism-corrected AUC of 0.811 vs. 0.716; difference, 0.095 [99% CI, 0.022-0.139]). Conclusion: The radiomic characteristics extracted from a non-enhanced T1 map may improve the prediction of LVRR and offer added value over traditional LGE in patients with NIDCM. Additional external validation research is required.

APPLICATION OF SIR-C DATA FOR EXPLORATION OF MINERALIZEDD ZONES (HWANGGANG-Rl, KOREA)

  • Jiang, Wei W.;Park, S.W.;Park, Jeong-Ho;Lee, Cahng-Won;Kim, Duk-Jin;So, Byung-Han;So, C. S.;Moon, Wooil M.
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 1999년도 Proceedings of International Symposium on Remote Sensing
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    • pp.158-164
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    • 1999
  • This paper investigated and evaluated the NASA's Shuttle Imaging Radar-C (SIR-C) multiple frequency SAR data for differential backscattering effects of microwave from the surface geological materials overlying the skarn type mineralization. Although an integrated approach in mineral exploration is more cost effective and is well in use, there are still many technical and scientific issues to be further investigated and researched. In this study we have reprocessed several sets of previously surveyed exploration data and experimented with fuzzy logic digital fusion of the preprocessed data with respect to chosen exploration targets. Among the numerous fuzzy logic operators, which are currently available for a data driven integrated exploration strategy, we used varying combinations of fuzzy MIN, fuzzy MAX, and fuzzy SUM operators along with Gamma operator for fusion of exploration data, including the contact metamorphic zone information. The final exploration target tested was a skarn type W-Mo-F mineralization in the study area. The fuzzy logic derived mineral potential anomaly almost exactly matched the differential backscattering anomalies on the C-band and L-band SIR_C data when overlaid on each other. Although this high degree of correlation between these two data sets is remarkable, the differential backscattering anomaly over the skarn type W-Mo-F mineralization in the study area requires further investigation.

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압축강도 50 MPa, 단위중량 16 kN/m3 고강도 경량 콘크리트 부착-슬립 거동의 설계기준과의 비교 (Comparison of Bond-Slip Behavior and Design Criteria of High Strength Lightweight Concrete with Compressive Strength 50 MPa and Unit Weight 16 kN/m3)

  • 이동균;이도경;오준환;유성원
    • 한국건설순환자원학회논문집
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    • 제10권2호
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    • pp.168-175
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    • 2022
  • 최근 나노기술의 발달로 건설재료분야에 이의 적용이 지속적으로 증가하고 있는 실정이다. 하지만 현재까지는 압축강도 50 MPa, 단위중량 16 kN/m3 정도의 고강도 경량 콘크리트를 구조부재에 적용하기 위한 콘크리트와 철근의 부착 특성에 관한 연구가 부족한 실정이다. 따라서 본 논문에서는 압축강도 50 MPa, 단위중량 16 kN/m3 정도의 고강도 경량 콘크리트 81개의 시편을 제작하여 직접 인발 부착실험을 수행하였고, 실험결과와 현행 설계기준과 비교하여 부착특성을 평가하였다. ACI-408R의 부착강도 산정식과 실험결과는 비교적 유사한 것으로 판단되며, 통계분석을 통해 CEB-FIP, 수정된 CMR 부착거동 모델을 산정한 결과, 평균적으로 잘 묘사하는 것으로 판단된다.

부유대역용융법에 의한 $RE_{1-x}Ca_xMnO_3$ (RE=La, Nd)의 결정성장 (Crystal Growth of $RE_{1-x}Ca_xMnO_3$(RE=La, Nd) by Floating Zone Method)

  • 정준기;조남희;김철진;이태근
    • 한국결정학회지
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    • 제11권4호
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    • pp.231-237
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    • 2000
  • CMR Materials RE/sub 1-x/Ca/sub x/MnO₃(RE=La, Nd, A=Ca, Sr) were grown using the floating zone image furnace with halogen lamps as heat source. The growth condition was at 2∼10 mm/hr growth rate in air atmosphere, were 445∼50 rpm and 20∼25 rpm of rotation rate of feedrod and growing crystal, respectively. The grown crystals showed shiny black color and annealed at 1500℃ in a box furnace to release the residual stress during cooling. Characterization analyses of the crystal were carried out using XRD and SEM. The crystal structure of Nd/sub 0.7/Ca/sub 0.3/MnO₃ was analyzed with smart CCD XRD was lattice parameter of a=5.425(4)Å, b=5.434(4)Å, and c=7.712(5)Å, an orthorombic system with space group of pbnm.

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