• Title/Summary/Keyword: CL Data

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Investigation of Soil Contamination at Major Roadside in Seoul - I. Manguro in Chungnanggu - (서울시 주요 도로변의 토양오염 조사 - I. 중랑구 망우로 주변 토양 -)

  • Kim, Kwon-Rae;Ryu, Hyung-Ju;Chung, Jong-Bae;Kim, Kye-Hoon
    • Applied Biological Chemistry
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    • v.44 no.2
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    • pp.103-108
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    • 2001
  • The objectives of this study were to investigate the contamination of the soils around the major roadsides in Seoul and to accumulate base-line data. Fifty topsoils ($0{\sim}5$ cm) and 48 subsoils ($20{\sim}50$ cm) were collected from 50 sampling sites near Manguro in Chungnanggu. The samples were air-dried, passed through 2-mm sieves, and analyzed to determine the physicochemical properties and the contents of heavy metals (Cd, Cu, Pb, Zn) and anions (Cl, $NO_3$, $SO_4$). Soil textures of top- and subsoils were mainly loamy sand and sandy loam, respectively. Average $_PH$ of top- and subsoil was approximately 7.5, much higher than that of the forest soils in Seoul. Average heavy metal contents were lower than the levels allowed by the Soil Environment Conservation Act of Korea, whereas much higher than those of the forest soils. Contents of some heavy metals were higher than the maximum allowed levels. Anion concentrations were also much higher than those of the forest soils. A careful management to prevent the aggravation of the present contamination level and the diffusion of contaminants is recommended.

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Characteristics of Gasification for a Refused Plastic Fuel (플라스틱 고형 연료의 가스화 특성)

  • Chun, Young Nam;Lim, Mun Sup;Jo, Dae Young
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.11
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    • pp.636-641
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    • 2015
  • Waste energy conversion to SRF (Solid Refuse Fuel) has the effects not alternative fossil fuel usage but also the reduction of greenhouse gas. But the direct burning of the SRF including a plastic waste generates air pollution problem like soot, dioxin, etc. so that an application of pyrolysis and gasification treatment should be needed. The purpose of this study is to supply a basic thermal data of the pyrolysis gasification characteristics in the plastic-rich SRF which are needed for developing the novel pyrolyser or gasifier. To do so, a bench-scale test rig was newly engineered, and then experiments were achieved for the production characteristics of gas, tar, and char. While SRF sample, gasification air ratio, holding time changed as 2 g, 0.691, 32 min respectively, the $H_2$ 1.36%, $CH_4$ 2.18%, CO 1.88%, $Cl_2$ 15.9 ppm, HCl 6.4 ppm were composed. Also light tar benzene $4.03g/m^3$, naphthalene $0.39g/m^3$, anthracene $0.11g/m^3$, pyrene $0.06g/m^3$, gravimetric tar $18g/m^3$, and char 0.29 g was formed.

High Loading for Air Pollution in the Byunsan Peninsula of Korea by an Interplay of the Saemangeum Project and Winter Monsoon

  • Ma, Chang-Jin;Kang, Gong-Unn;Kim, Ki-Hyun
    • Asian Journal of Atmospheric Environment
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    • v.6 no.3
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    • pp.234-243
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    • 2012
  • The wintertime high loading for atmospheric pollutants is certainly expected in the Byunsan Peninsula of Korea because of a great-scale reclamation project having construction of 33 km tidal sea dike impounding an area of over 40,000 ha and long-range transport. The goal of this study is to trace the origin of this wintertime burden for ambient particulate matter (hereafter called "PM") in the Byunsan Peninsula of Korea. The size-segregated (i.e., cutoff size from 0.01 ${\mu}m$ to 4.7 ${\mu}m$) PM sampling was conducted at a ground-based site of Byunsan Peninsula located in the west coast of Korean Peninsula during the height of dike constructing. Data archived in this study are the mass concentrations of ionic, elemental, and carbonic components in size-fractioned PM. The elemental mass of individual submicrometer particles was also analyzed. The sum of 5-source (i.e., elemental carbon, organic materials, inorganic secondary pollutants, crustal matter, and sea-salts) concentrations shows the bimodal distribution (major and minor peaks formed around $D_p$, 0.65 ${\mu}m$ and $D_p$, 4.7 ${\mu}m$, respectively) by border with 0.19 ${\mu}m$ of cutoff size. The concentrations of EC in $PM_{1.1-0.01}$ in winter and spring times were 4.62 ${\mu}g\;m^{-3}$ and 3.74 ${\mu}g\;m^{-3}$, respectively. Elemental masses of submicron individual particles are classified into two groups, i.e., the major elements (Cl, Al, Si, S, and P) and the minor trace elements. Cluster analysis differentiated the elements in submicron individual particles into 4-cluster. Among them, three clusters are in agreement with the major (Al, Si, S, and P), minor (Fe, Ca, and K), and trace compositions of coal burning. Meanwhile, Cl classified as an independent cluster has different source profile which was mainly due to the Saemangeum seawall project. Some highly toxic elements (e.g., Cr, Mn, and As (and/or Pb)) were also detected in some part of submicron individual PM. As a consequence, the combination of the Saemangeum project and winter monsoon played a considerable part in the double aggravation of wintertime air pollution in the Byunsan Peninsular.

Characteristics of Silver Ion-Exchange and Methyl Iodide Adsorption at High Temperature Condition by Surface-Modified Natural Zeolite (표면개질 천연제올라이트를 이용한 은이온 교환 및 고온공정에서 메틸요오드 흡착특성)

  • Park, Geun Il;Cho, Il-Hoon;Kim, Kae-Nam;Lee, Min Ok;Yu, Jae-Hyung
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.10
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    • pp.1765-1775
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    • 2000
  • The removal of radioactive organic iodide generated from high temperature process in nuclear facility was generally performed by silver ion-exchanged synthetic zeolite (AgX). The purpose of this study is to obtain fundamental data for the substitution of natural zeolite(NZ) in stead of synthetic zeolite as supporter for the removal of methyl iodide in high temperature conditions. Therefore, NZ was modified with NaCl, $NaNO_3$ solution, and the analysis of the physical or surface characteristics through XRD, SEM-EDAX, and BET analysis was performed. In order to obtain the optimal surface-modification condition of NZ, adsorption capacities at $150^{\circ}C$ on surface-modified silver ion-exchanged NZ prepared with the variation of solution concentration were evaluated. The optimal condition of surface modification is that concentration of $NaNO_3$ and $AgNO_3$ are 1N and 1.2N, respectively(namely Ag-SMNZ). The adsorption isotherm of methyl iodide on Ag-SMNZ in a range of $100^{\circ}C$ to $300^{\circ}C$ was obtained, which is similar to that of 13X, and the maximum adsorption amount of Ag-SMNZ reached approximately 50% that of AgX. It would be evaluated that the adsorption capacity at $150{\sim}200^{\circ}C$ is relatively higher than other temperature, and the chemisorption between silver and iodide is attributed to a strong binding even after desorption test.

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Survey on Groundwater Quality under Plastic Film House Cultivation Areas in Southern Part of Gyeonggi Province (경기(京畿) 남부지역(南部地域) 시설재배지(施設栽培地)의 지하수질(地下水質) 평가(評價))

  • Jung, Goo-Bok;Lee, Jong-Sik;Kim, Bok-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.4
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    • pp.389-395
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    • 1996
  • This survey was conducted to investigate the factors affecting the chemical components of groundwater in the plastic house area cultivated with horticulture crops. The data were evaluated with depth of groundwater, topography and years of cultivation as major factors. $NO_3-N$ content of groundwater was higher at waterside(Alluvial plain) than Inland plain(Alluvial plain), local valley & fan or mountain foot area, and also was detected the highest concentration in 6-10m depth well. The contents of $NO_3-N$ and $SO_4{^{2-}}$ in groundwater were increased with cultivation years. The ionic composition (${\sum}A/{\sum}C$ : ratio between total equivalant of anions and cations) of groundwater decreased with depth and was higher at waterside(alluvial plain) than other topography. The $NO_3-N$ content was negatively correlated with pH whereas it was positively correlated with $SO_4{^{2-}}$, $Cl^-$, $K^+$, $Ca^{2+}$, and $Mg^{2+}$.

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Stress Responses of Olive Flounder (Paralichthys olivaceus) to Salinity Changes (염분변화에 따른 넙치(Paralichthys olivaceus)의 스트레스 반응)

  • Park, Hyung-Jun;Min, Byung-Hwa
    • Korean Journal of Ichthyology
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    • v.30 no.1
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    • pp.1-8
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    • 2018
  • We tried to determine the optimum salinity for a cultured of olive flounder (Paralichthys olivaceus) by investigating after exposing the fish at different salinity (10, 15, 20 and 25 psu) for 24 and 48 hours compared with control group (fish before transfer to experimental tank). As a control groups, we compared an analyzed with other experimental groups using olive flounder in natural sea water. Hematological parameters including hematocrit (Ht) and hemoglobin (Hb), cortisol and glucose, aspartate aminotransferase (AST) and alanine aminotransferase (ALT), $NH_3$, osmolality, total protein (TP), $Na^+$, $K^+$ and $Cl^-$ mostly exhibited significant changes at 10 and 15 psu groups compared with control groups for 24 and 48 hours exposed. Plasma SOD (superoxide dismutase) and CAT (catalase) activity also increased with experimental groups (10 and 15 psu) compared to the control groups. The expression of HSP70 mRNA was also higher at low-salinity (10 and 15 psu) than at control group. In particular, after 24 hours exposed, it expression to 15 psu groups showed a significant difference compared to the control group. However, after 48 hours exposed, it expression was higher in the 10 psu groups than the control. It is assumed that the changes in the hematological responses and hormone, homeostasis and metabolism were resulted in to protect fish body from stress. Based on these results, we are expected that it will be used as basic data for the culture of olive flounder prepared for low salinity.

Measurements and Modeling of the Activity Coefficients and Solubilities of L-alanine in Aqueous Electrolyte Solutions (전해질 수용액에서 L-Alanine의 활동도계수와 용해도의 측정 및 모델링)

  • Lee, Bong-Seop;Kim, Ki-Chang
    • Korean Chemical Engineering Research
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    • v.48 no.4
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    • pp.519-533
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    • 2010
  • Activity oefficients and solubilities of L-Alanine in aqueous solutions containing each of four electrolytes(NaCl, KCl, $NaNO_3$ and $KNO_3$) were measured at 298.15 K. The measurements of activity coefficients were carried out in the electrochemical cell coupled with two ion-selective electrodes(cation and anion), and the solubilities were measured by the gravimetric analysis of saturated solutions in equilibrium with the solid phase of L-alanine. To model the activity coefficients and solubilities of amino acid in the amino acid/electrolyte aqueous solutions, thermodynamic relations of the residual Helmholtz free energy in the amino acid/electrolyte aqueous solutions were developed based on the perturbed-chain statistical associating fluid theory(PC-SAFT) combined with the primitive mean spherical approximation(primitive-MSA). In the present model, it is assumed that the zwitterions of L-alanine are associated with each other and cross-associated with water molecules, and also cross-associated with the cation and anion dissociated from an electrolyte(inorganic salt). The activity coefficients and solubilities of L-Alanine calculated from the theoretical model proposed in this work are found to be well agreeable with experimental data.

The Analysis and Design of Advanced Neurofuzzy Polynomial Networks (고급 뉴로퍼지 다항식 네트워크의 해석과 설계)

  • Park, Byeong-Jun;O, Seong-Gwon
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.39 no.3
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    • pp.18-31
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    • 2002
  • In this study, we introduce a concept of advanced neurofuzzy polynomial networks(ANFPN), a hybrid modeling architecture combining neurofuzzy networks(NFN) and polynomial neural networks(PNN). These networks are highly nonlinear rule-based models. The development of the ANFPN dwells on the technologies of Computational Intelligence(Cl), namely fuzzy sets, neural networks and genetic algorithms. NFN contributes to the formation of the premise part of the rule-based structure of the ANFPN. The consequence part of the ANFPN is designed using PNN. At the premise part of the ANFPN, NFN uses both the simplified fuzzy inference and error back-propagation learning rule. The parameters of the membership functions, learning rates and momentum coefficients are adjusted with the use of genetic optimization. As the consequence structure of ANFPN, PNN is a flexible network architecture whose structure(topology) is developed through learning. In particular, the number of layers and nodes of the PNN are not fixed in advance but is generated in a dynamic way. In this study, we introduce two kinds of ANFPN architectures, namely the basic and the modified one. Here the basic and the modified architecture depend on the number of input variables and the order of polynomial in each layer of PNN structure. Owing to the specific features of two combined architectures, it is possible to consider the nonlinear characteristics of process system and to obtain the better output performance with superb predictive ability. The availability and feasibility of the ANFPN are discussed and illustrated with the aid of two representative numerical examples. The results show that the proposed ANFPN can produce the model with higher accuracy and predictive ability than any other method presented previously.

A Development of Fusion Processor Architecture for Efficient Main Memory Access in CPU-GPU Environment (CPU-GPU환경에서 효율적인 메인메모리 접근을 위한 융합 프로세서 구조 개발)

  • Park, Hyun-Moon;Kwon, Jin-San;Hwang, Tae-Ho;Kim, Dong-Sun
    • The Journal of the Korea institute of electronic communication sciences
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    • v.11 no.2
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    • pp.151-158
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    • 2016
  • The HSA resolves an old problem with existing CPU and GPU architectures by allowing both units to directly access each other's memory pools via unified virtual memory. In a physically realized system, however, frequent data exchanges between CPU and GPU for a virtual memory block result bottlenecks and coherence request overheads. In this paper, we propose Fusion Processor Architecture for efficient access of main memory from both CPU and GPU. It consists of Job Manager, Re-mapper, and Pre-fetcher to control, organize, and distribute work loads and working areas for GPU cores. These components help on reducing memory exchanges between the two processors and improving overall efficiency by eliminating faulty page table requests. To verify proposed algorithm architectures, we develop an emulator based on QEMU, and compare several architectures such as CUDA(Compute Unified Device Architecture), OpenMP, OpenCL. As a result, Proposed fusion processor architectures show 198% faster than others by removing unnecessary memory copies and cache-miss overheads.

Determination of Iodine Contents in Ten kinds of Frequently used Oriental Herb Medicinal Products for Cancer Patient (암환자에게 다빈도로 활용되는 한약제제 10종에 대한 요오드의 함량 분석)

  • Lee, Chang-Hee;Choi, Jung-Eun;Kim, Sun-Ha;Chung, Yong-Sam;Moon, Jong-Hwa;Yoo, Hwa-Seung
    • Journal of Korean Traditional Oncology
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    • v.16 no.1
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    • pp.41-53
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    • 2011
  • Background and Objectives: Iodine is an essential constituent of the thyroid hormones associated with the growth and development of humans and animals as an inorganic nutrition. This element may be accumulated in human blood, tissues and body through the intake of foodstuffs, a beverage, a nutritional supplement and a medicine, among others. The aim of the research is to find out a better medicinal stuff for the thyroid cancer patient who required a low level of iodine diet. Methods: Neutron activation analysis (NAA) used for the iodine analysis is one of nuclear analytical techniques using radiation and radioisotopes and very useful as sensitive analytical technique for performing both qualitative and quantitative multi-elemental non-destructive analysis of major, minor and trace components in variety of environmental and biological materials. In this study, iodine contents in ten kinds of oriental herb medicinal products, which is frequently used to cancer patients are determined by using instrumental neutron activation analysis (INAA) at the HANARO research reactor. The samples prescribed are manufactured as powdered form for taking medicine easily. The analytical quality control is performed to assure an uncertainty of the measurement and to compensate the measured data using a biological certified reference material, NIST SRM 1572, Citrus Leaves. The measured value is $1.89{\pm}0.35mg/kg$, and the relative error is 2.88%, and relative standard deviation is 19 % due to high counting error by small counts of gamma ray spectrum. The standard deviations for other elements such as Cl, K, Mn and Na were in the range of 2 to 8%. Result: The level of iodine contents of Biki-huan, Chungryong-huan and Chungcho-huan, samples detected is less than 6 mg/kg except Hangam Plus sample (more than 210 mg/kg) and six samples were not detected. Iodine in the samples of Shoxiho-tang, Shopunghualhyl-tang, Shocungryong-tang, Banhasaxim-tang, Insampaedox-san and Myunyuk Plus were not measured, but possible level of content can be estimated from the detection limits. In addition, the concentrations of some major elements like Cl, K, Mn, Na, in the samples were determined with the detection limits. Conclusions: Most of samples showed low iodine contents of less than 6 mg/kg but it turned out that most of testing samples can be used to classify the level of iodine diet samples considering the recommended low level of iodine diet 50 ${\mu}g$/day, and a better medicinal stuff for the thyroid cancer patient can be found.