• Proceedings of the Zoological Society Korea Conference
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• 2000.04a
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• pp.75.1-75
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• 2000

No Abstract, See Full Text

• Korean Journal of Materials Research
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• v.4 no.2
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• pp.227-232
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• 1994

Diamondlike carbon thin film has been fabricated with low discharging frequency, 450KHz by plasma enhanced chemical vapor deposition. Its physical properties such as optical band gap, microhardness and internal stress have been compared with 13.56MHz film. Optical band gap of 450KHz DLC thin film was less than 13.56MHz film and it was found that C-H bond concentration and total hydrogen contents in the film decreased greatly as the result of FT-IR and CHN analysis. Also, when DLC thin film was fabricated with low discharging frequency, it was expected that the adhesion of the film to the substrate was improved by the great decrease of internal stress without any considerable decrease of microhardness.

• Applied Chemistry for Engineering
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• v.9 no.4
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• pp.548-553
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• 1998

The N-unsaturated alkylcarbazole derivatives were synthesized by the nucleophilic unimolucular substitution reaction ($S_N1$) of carbazole with unsaturated alkyl chloride. These reactions between carbazole and unsaturated alkyl chloride were conducted in dimethyl sulfoxide (DMSO) containing alkali (NaOH or KOH) at room temperature for 4 hrs under nitrogen atmosphere. The mole ratios of carbazole, alkali and unsaturated alkyl chloride were 1:6:1, respectively. All of the compounds of starting materials and reaction products were characterized by CHN analysis, $^1H$-NMR and FR-IR spectroscopy.

• Steel and Composite Structures
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• v.11 no.6
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• pp.469-488
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• 2011

This paper consists of two parts; the first part describes the laboratory work concerning the behavior of lightweight aggregate concrete filled steel tubes (LACFT). Based on eccentricity tests, fifty-four specimens with different slenderness ratios (L/D= 3, 7, and 14) were tested. The main parameters varied in the test are: load eccentricity; steel ratio; and slenderness ratio. The standard load-strain curves of LACFT columns under eccentric loading were summarized and significant parameters affecting LACFT column's bearing capacity, failure mechanism and failure mode such as confinement effect and bond strength were all studied and analyzed through the comparison with predicted strength of concrete filled steel tube columns (CFT) using the existing codes such as AISC-LRFD (1999), CHN DBJ 13-51-2003 (2003) and CHN CECS 28:90 (1990). The second part of this paper presents the results of parametric study and introduces a practical and accurate method for determination of the maximum compressive strength of confined concrete core ($f_{max}$), In addition to, the study of the effect of aspect-ratio and length-width ratio on the yield stress of steel tubes ( $f_{sy}$) under biaxial state of stress in CFT columns and the effect of these two factors on the ultimate load carrying capacity of axially loaded CFT/LACFT columns.

• Journal of the Korean Society for Marine Environment & Energy
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• v.9 no.4
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• pp.235-242
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• 2006

The precise estimation of total and organic carbon contents in sediments is fundamental to understand the benthic environment. To test the precision and accuracy of CHN analyzer and the procedure to quantify total and organic carbon contents(using in-situ acidification with sulfurous acid($H_2SO_3$)) in the sediment, the reference material s such as Acetanilide($C_8H_9NO$), Sulfanilammide($C_6H_8N_2O_2S$), and BCSS-1(standard estuary sediment) were used. The results indicate that CHN analyzer to quantify carbon and nitrogen content has high precision(percent error=3.29%) and accuracy(relative standard deviation=1.26%). Additionally, we conducted the instrumental comparison of carbon values analyzed using CHN analyzer and Coulometeric Carbon Analyzer. Total carbon contents measured from two different instruments were highly correlated($R^2=0.9993$, n=84, p<0.0001) with a linear relationship and show no significant differences(paired t-test, p=0.0003). The organic carbon contents from two instruments also showed the similar results with a significant linear relationship($R^2=0.8867$, n=84, p<0.0001) and no significant differences(paired t-test, p<0.0001). Although it is possible to overestimate organic carbon contents for some sediment types having high inorganic carbon contents(such as calcareous ooze) due to procedural and analytical errors, analysis of organic carbon contents in sediments using CHN Analyzer and current procedures seems to provide the best estimates. Therefore, we recommend that this method can be applied to measure the carbon content in normal any sediment samples and are considered to be one of the best procedure far routine analysis of total and organic carbon.

• Analytical Science and Technology
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• v.7 no.3
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• pp.315-320
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• 1994

Li-GICs as a high performance energy storager were synthesized as a function of the Li content by the admixture and add-pressure method. The characteristics of these prepared compounds have been determined from the studies by X-ray diffraction, UV-VIS spectrometry and CHN analysis. It follows from the results of X-ray diffraction that the lower-stage intercalation compounds are formed as the Li contents increase, however the mixed stages in these compounds are also observed. In the case of the $Li_{40wt%}$, the compound with the structure of stage 1 has been predominently, but the structure of only stage 1 is not obtained. The $d_{001}$ value of stage 1 was determined to be ca. $3.70{\AA}$. An analysis of spectrometric data shows that each of the compounds gives distingushible energy state spectra. It is seen from the spectra that the positions of $R_{min}$ values, with increase in the Li contents, are shifted in the region of higher energy state. Such a result can be attributed to the formation of stable stages. The results of CHN analysis allow us to find the mixing state related to chemical compositions of the intercalated compounds and the superiority to admixture and add-pressure method. From the results determined, it reveals that $Li_{10wt%}$-GIC and $Li_{20wt%}$-GIC can be utilized for an anode of rechargable battery.

• Korean Journal of Crystallography
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• v.18 no.1_2
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• pp.1-6
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• 2007

An Organometallic compound, $C_{16}H_{35}B_{10}IrS_2Si$, was synthesized from o-carborane, $Cp^*Ir(S_2C_2B{10}H_{10})$, and $Me_3SiCHN_2$. The molecular structure of this complex has been determined by X-ray diffraction. Crystallographic data : monoclinic, space group $P2_1/n$, $a=10.1986(12)\;{\AA}$, $b=14.834(5)\;{\AA}$, $c=17.139\;{\AA}$, ${\beta}=92.24(2)^{\circ}$, Z=4, $V=2591.0(14)\;{\AA}^3$. The structure was solved by direct methods and refined by full-matrix leat-squares methods to give a model with a reliability factor R=0.053 for 5080 reflections.

• Korean Journal of Materials Research
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• v.5 no.8
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• pp.966-978
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• 1995

Amidoximated composite fiber adsorbents were prepared for separation of uranium from seawater and characterized by various instrumental techniques, such as IR spectroscopy, CHN elemetal analyzer and SEM. The swelling ratios and yields of the AN-TEGMA and AN-TEGMA-DVB copolymers were decreased with an increase in crosslinklng agents, such as DVB and TEGMA composition. The yield of 85-92% and 82-88% of AN-TEGMA and AN-TEGMA-DVB copolymers respectively were found. The porosity was also decreased with increase in crosslinking compositions, and it was found that the AN-TEGMA-DVB porosity copolymers were smaller than the value of AN-TEGMA copolymer. We investigated that the adsorbent with the composite fiber adsorbents were well dispersed on the surface of Its by SEM. The optimum contents of containing adsorbent in the copolymer was 40 weight percent. The capacity of uraniyl ion through the composite fiber adsorbent containing the amidoxime group was miximized a pH level of 8. Also, if was found that the synthesized composite fiber adsorbent was good material, due to a pH level of 8.3 of seawater, for separation of uraniyl ion from seawater.

• Journal of the Korean Society for Marine Environment & Energy
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• v.8 no.4
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• pp.213-219
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• 2005

In this study, we try to Quantitatively assess the micropollutants in Gwangyang bay, Gamag bay and Yeoa bay, using simultaneous analytical method fir 310 chemicals. In the results, several dozen organic pollutants were detected in sampling sites, and the major chemicals detected were CH type chemicals, such as aliphatic and polycyclic compounds, and CHN(O) type chemicals, such as aromatic ammines and nitro compounds. The concentration of organic pollutants was higher in summer than in winter. However, there was no association of species of organic pollutants with season. The total concentration of pesticides at each sampling site was measured within the range of $ND{\sim}9.11{\mu}g/L$. Insecticides and fungicides of pesticide type were detected in Gwangyang bay and Gamag bay, while six kinds of endocrine disrupter were detected in southern coastal waters. From the results of this study, we should estimated that the insecticides, the fungicides, and a few of the endocrine disrupters are major pollutant factors in southern coastal waters.

• Proceedings of KOSOMES biannual meeting
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• 2008.05a
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• pp.159-164
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• 2008

In order to understand the spatio-temporal distribution of geochemical parametrs in surface sediments of the artificial Lake Shihwa in the vicinity of Kyunggi Hay in Korea, surface sediments were sampled at 14 sites in July 2007 and analyzed by CHN analyzer and ICP/MS. Metal concentrations in the sediments tended to be decreasing from the head to the mouth of the Lake Shihwa because of extreme pollutant discharge from various kinds of anthropogenic sources such as the Banweol and Shihwa Industrial Complex and cities. With the deposition of fine-grained sediments, high metal concentrations were also observed in the central part of lake. Although various programs(improvement of wastewater collection and treatment system, sea-lake water exchange etc) to improve the environmental conditions around the Lake Shihwa after dike construction were carried out, it was not dear to reach a good environmental quality. Therefore, further environmental programs should be conducted continuously for environmental improvement.