• 제목/요약/키워드: CH Chemiluminescence

검색결과 52건 처리시간 0.021초

실시간 연소제어를 위한 화염 내 라디칼 계측기법 연구 (An Experimental Study on the Measurement of Radicals in Flame for Real TIme Combustion Control)

  • 권승진;김세원;신명철;류태우;김용모
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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    • pp.53-59
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    • 2006
  • This study is measurement of radicals in gas & light oil diffusion flame focused on burner exit. The goal of this study is to analyse the relationship between flame chemiluminescence($OH^{\ast}$, $CH^{\ast}$, $C_2^{\ast}$) intensities and flame conditions. The investigation performed turbulent diffusion flame of commercial burner in varying the excess air ratio from 1.0 to 1.8. The optical emissions were measured by photomultiplier(PMT) using optical band pass filter and spectrometer system. The effects of excess air ratio and NOx emission characteristics on the radical emission intensities were investigated experimentally.

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광학식 수광 프로브의 실험적 성능평가 (Experimental Performance Evaluation of Optical Receiving Probe)

  • 양영준
    • 한국산업융합학회 논문집
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    • 제7권3호
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    • pp.265-271
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    • 2004
  • A light collecting probe named Multi-colored Integrated Receiving Optics (MICRO) is experimentally examined to verify its performance. For these purposes, the time-series signals of MICRO probe is compared with those of electro-static probe and light-guided probe by monitoring, for example. such as OH radical chemiluminescence. CH radical band and droplet Mie scattering In addition, the experiment was conducted by using laminar premixed Bunsen flame, turbulent premixed Bunsen flame and premixed spray flame, respectively. It was confirmed that the performance of MICRO probe was very useful and convenient to obtain the chemiluminescence signals from local regions in turbulent premixed Bunsen flame and premixed spray flame.

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스월을 강화한 메탄/공기 부분 예혼합화염에서 자발광($OH^{\ast}$, $CH^{\ast}$, 그리고 $C_2^{\ast}$) 배출특성과 배기배출물에 관한 실험적 연구 (An Experimental Investigation of the Characteristic of Radical ($OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$) and Pollutant Emission in Partially Premixed Swirling Methane-air Flames.)

  • 안경민;정용기;장영준;전충환
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2005년도 제31회 KOSCO SYMPOSIUM 논문집
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    • pp.320-327
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    • 2005
  • An experimental study was performed to investigate the effects of partially premixing, varying the equivalence ratios from $1.36{\sim}{\infty}$, and swirlers with swirl numbers of 0, 0.28, 0.64, and 1.32, on the characteristic of radical ($OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$) and pollutant emission in partially premixed swirling flames. The signal from the electronically excited state of $OH^{\ast}$, $CH^{\ast}$, and $C_2^{\ast}$ was detected through a band pass filter with a photo multiplier tube, and flow fields images were detected through a schlieren system. The results demonstrated that the flame height decreases and jet spreading angle increase with increasing a swirl number. The more momentum ratio and swirl number increase, the more decrease flame height, and the generation of sooting flame is promoted.

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Laminar Lifted Methane Jet Flames in Co-flow Air

  • Sapkal, Narayan P.;Lee, Won June;Park, Jeong;Lee, Byeong Jun;Kwon, Oh Boong
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
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    • pp.83-86
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    • 2015
  • The Laminar lifted methane jet flames diluted with helium and nitrogen in co-flow air have been investigated experimentally. The chemiluminescence intensities of $OH^{\ast}$ and $CH_2O^{\ast}$ radicals and the radius of curvature for tri-brachial flame were measured using an intensified charge coupled device (ICCD) camera, monochromator and digital video camera. The product of $OH^{\ast}$ and $CH_2O^{\ast}$ is used as a excellent proxy of heat release rate. These methane jet flames could be lifted in buoyancy and jet dominated regimes despite the Schmidt number less than unity. Lifted flames were stabilized due to buoyancy induced convection in buoyancy-dominated regime. It was confirmed that increased $OH^{\ast}$ and $CH_2O^{\ast}$ concentration caused an increase of edge flame speed via enhanced chemical reaction in buoyancy dominated regime. In jet momentum dominated regime lifted flames were observed even for nozzle exit velocities much higher than stoichiometric laminar flame speed. An increase in radius of curvature in addition to the increased $OH^{\ast}$ and $CH_2O^{\ast}$ concentration stabilizes such lifted flames.

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Emission Intensities of Ro-vibrational Bands of Hydrocarbons in the Auroral Regions of Jupiter

  • 김상준
    • 천문학회보
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    • 제37권1호
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    • pp.100.2-100.2
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    • 2012
  • We have investigated excitation processes of the 3-micron bands of $CH_4$, $C_2H_2$, and $C_2H_6$ over the auroral regions of Jupiter including particle bombardments, Joule heating, scattering of solar radiation, and possible chemiluminescence. We also considered possible LTE or Non-LTE conditions of these processes. We constructed particle precipitation models including $H_2$, He, H, and the hydrocarbon molecules for the atmosphere of the auroral regions. We present preliminary results from these models, and comparisons of the model results with spectroscopic observations in the 3 micron wavelength range of Jupiter.

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미분탄 이중 스월화염에서 스월강도 및 석탄 입경 변화 영향 연구 (Effects of Swirl Intensity and Particle Size on Dual Swirl Pulverized Coal Flames)

  • 최민성;성연모;이상민;문철언;최경민;김덕줄
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.1-4
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    • 2014
  • The present work focuses on the analysis of the pulverized coal combustion aerodynamics of the dual swirl burner by the control of the swirl-modes such as the outer swirl intensity (OSI). The detailed structure of pulverized coal swirling flames with swirl-mode was studied experimentally by particle image velocimetry and local flame colors based on $OH^*$, $CH^*$, and ${C_2}^*$ radicals. For all co-swirling conditions, the internal recirculation zone (IRZ) was observed near the inner shear layer with respect to the processing vortex core structure. Furthermore, a co-rotating vortex in the outer shear layer and the exhaust tube vortex (ETV) along the central axis were observed. The intensity of $CH^*$ signal was higher with small coal particle size, conversely, the size of the distribution of the $CH^*$ signal becomes larger. Therefore, the control of the aerodynamics with changing swirl intensities may play an important role in improving both environmental and combustion performances.

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메탄/순산소 예혼합 화염의 선회특성 (Combustion Characteristics of Methane/Oxygen in Pre-Mixed Swirl Flame)

  • 김한석;최원석;조주형;안국영
    • 대한기계학회논문집B
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    • 제33권5호
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    • pp.343-348
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    • 2009
  • The present study has experimentally investigated the effects of $CO_2$ diluted oxygen on the structure of swirl-stabilized flame in a lab-scale combustor. The methane fuel and oxidant mixture gas ($CO_2$ and $O_2$) were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for various amount of carbon dioxide addition to the methane fuel and various swirl strengths. The effects of carbon dioxide addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using chemiluminescence techniques to provide information about flow field. The results show that the hot combustion zone increases at the upstream reaction zone because of an increase in the recirculation flow for an increase in swirl intensity. The hot combustion zone is also increased at the downstream zone by recirculation flow because of an increase in swirl intensity which results in higher centrifugal force. The OH and CH radical intensities of reaction zone decrease with carbon dioxide addition because the carbon dioxide plays a role of diluted gas in the reaction zone.

메탄/순산소 예혼합 화염의 선회 특성 (Combustion Characteristics of Methane/Oxygen Gas in Pre-mixed Swirl Flame)

  • 최원석;김한석;조주형;김용모;안국영;우타관
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.1979-1983
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    • 2008
  • The effects of carbon dioxide addition to oxygen have been investigated with swirl-stabilized premixed methane flame in a laboratory-scale pre-mixed combustor. The methane fuel and oxydant mixture gas ($CO_2$ and $O_2$) were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for different amount of carbon dioxide addition to the methane fuel and different swirl strengths. The effects of carbon dioxide addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using chemiluminescence techniques to provide information about flow field. The results show that the flame area increases at upstream of reaction zone because of increase in recirculation flow for increase in swirl intensity. The flame area is also increased at the downstream zone by recirculation flow because of increase in swirl intensity which results in higher centrifugal force. The OH and CH radical intensity of reaction zone decrease with carbon dioxide addition because the carbon dioxide plays a role of dilution gas in the reaction zone.

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연소실 압력변동이 화염안정화와 배출특성에 미치는 영향 (Influence of changing Combustor Pressure on Flame Stabilization and Emission Charncteristics)

  • 김종률;최경민;김덕줄
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2354-2359
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    • 2007
  • Influence of changing combustor pressure on flame stabilization and emission index in the swirl-stabilized flame was investigated. The combustor pressure was controlled by suction fan at combustor exit. Pressure index ($P^{\ast}$=Pabs/Patm), where Pabs and Patm indicated the absolute pressure and atmosphere pressure, respectively, was controlled in the range of 0.7${\sim}$1.3 for each equivalence ratio conditions. The flammable limits of swirl flames were largely influenced by changing combustor pressure and they showed similar tendency with laminar flames. NOx emission index decreased with decreasing pressure index for overall equivalence ratio conditions. R.m.s. of pressure fluctuations is increased with decreasing combustor pressure. This flame fluctuation caused incomplete combustion, hence CO emission index increased. These oscillating flames were measured by simultaneous $CH^{\ast}$ chemiluminescence time-series visualization and pressure fluctuation measurement.

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Experimental Study on Laminar Lifted Methane Jet Flame Diluted with Nitrogen and Helium

  • Sapkal, Narayan;Lee, Won June;Park, Jeong;Kwon, Oh Boomg
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.387-389
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    • 2014
  • Laminar lifted methane jet flame diluted with nitrogen and helium in co-flow air has been investigated experimentally. This paper examines the role of chemistry, intermediate species responsible for stabilization of lifted flame. To elucidate the stabilization mechanism in lifted methane jet flames with Sc<1, the chemiluminescence intensities of $CH^*$ and $OH^*$ were measured using ICCD camera at various nozzle exit velocities and fuel mole fractions. It has been observed that the $OH^*$ species can play an important role in stabilization of lifted methane jet flame as they are good indicators of heat release rate which can affect on flame speed and increase stability through reduction in ignition delay time.

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