• Title/Summary/Keyword: CFCs

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Development of Pool Boiling Heat Transfer Correlation for Hydrocarbon Refrigerants (탄화수소계 냉매의 풀비등 열전달 상관식 개발)

  • Park Ki-Jung;Baek In-Cheol;Jung Dong-Soo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.3
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    • pp.247-253
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    • 2006
  • In this work, pool boiling heat transfer coefficients (HTCs) of hydrocarbon refrigerants are measured from a horizontal smooth tube of 19.0 mm outside diameter. Tested pure refrigerants are Propylene, Propane, Isobutane, Butane and Dimethylether (DME). The pool temperature was maintained at saturation temperature of $7^{\circ}C$ and heat flux was varied from $10kW/m^2$ to $80kW/m^2$ with an interval of $10kW/m^2$. Wall temperatures were measured directly by thermocouple hole of 0.5 mm out-diameter, 152 mm long and inserting ungrounded sheathed thermocouples from the side of the tube. Tested results show that HTCs of Propane, Propylene are 2.5%, 10.4% higher than those of R22 while those of Butane and Isobutane are 55.2%, 44.3% lower than those of R22 respectively. For pure refrigerants, new correlation can be applied to all of CFCs, HCFCS, HFCs, as well as hydrocarbons was developed. The mean deviation was 4.6%.

Development of the Chemical Flow Control System for Spinner Equipment in Semiconductor Manufacturing Process (반도체 제조공정의 스피너 장비를 위한 약액 흐름제어 시스템 개발)

  • Park, Hyoung-Keun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.4
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    • pp.1812-1816
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    • 2011
  • This research developed chemical flow control system(CFCS) essential for spinner equipment in nano semiconductor manufacturing process under the 100nm to prevent complex process defect due to missing spread after chemical injection. The devices developed in this research, which can be swiftly replaced in case abnormal state element changes or wafer manufacturing defect occurs, are anticipated to improve module yield as well as real-time monitoring on the state element. In addition, as a result of mounting H/W and S/W system to control detailed operation sequence in production line and executing performance check and verification, we can be exactly detected in five abnomal process type.

Assessment of Embryotoxicity of 2-Bromopropane in ICR Mice

  • Kim, Jong-Choon;Shin, Dong-Ho;Kim, Sung-Ho;Oh, Ki-Seok;Kim, Hyeon-Yeong;Her, Jeong-Doo;Jiang, Cheng-Zhe;Chung, Moon-Koo
    • Toxicological Research
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    • v.19 no.3
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    • pp.227-234
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    • 2003
  • 2-Bromopropane (2-BP), a halogenated propane analogue, is a substitute for chlorofluorocarbones (CFCs) which have a great potential to destroy the ozone layer and to warm the earth's environment. The present study was undertaken to evaluate the potential adverse effects of 2-BP on pregnant dams and embryo-fetal development after maternal exposure during the gestational days (GD) 6 through 17 in ICR mice. The test chemical was administered subcutaneously to pregnant mice at dose levels of 0, 313, 625 or 1,250 mg/kg/day. All dams were subjected to caesarean section on GD 18 and their fetuses were examined for external, visceral and skeletal abnormalities. In the 1,250 mg/kg group, maternal toxicity included an increase in the incidence of abnormal clinical signs and a decrease in the maternal body weight, body weight gain, and corrected body weight. Developmental toxicity included a decrease in the fetal body weight, a reduction in the placental weight, an increase in the fetal skeletal variation and ossification delay. There were no adverse effects on either pregnant dams or embryo-fetal development in the 313 and 625 mg/kg groups. These results suggest that a 12-day subcutaneous dose of 2-BP is embryotoxic at a maternally toxic dose (i.e., 1,250 mg/kg/day) in ICR mice. In the present experimental condition, the no-observed-adverse-effect level of 2-BP is considered to be 625 mg/kg/day for dams and embryo-fetuses, respectively.

Estimation of The Global Warming Potential of Fluorinated Green House Gases (불화온실가스의 흡수단면적 측정을 통한 지구온난화지수의 추정)

  • Kim, Jihye;Lee, Jeongsoon
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.4
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    • pp.387-397
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    • 2014
  • This work aims at estimating global warming potentials (GWP) of $CF_3Br$ and HFC-134a among green house gases. It has been reported that they have much higher GWP than $CO_2$ in the atmosphere. $CF_3Br$, halon 1301 which is well known to be a fire extinguisher, as one of the bromine-containing halons has been banned since 2003 due to destruction of ozone. HFCs, a kind of chiller which replaced chlorofluorocarbons (CFCs) are one of greenhouse gases regulated by the Kyoto Protocol. In this study, we produced GWPs of $CF_3Br$ and HFC-134a by calculating a life time and measuring an absorption cross section to obtain a radiative forcing (RF). Their absorption cross sections were measured by using Fourier-transformed infrared spectroscopy (FTS) with a gas cell filled with their certified reference materials at room temperature. As a result, the RFs of $CF_3Br$ and HFC-134a were 0.32 and $0.168Wm^{-2}ppb^{-1}$, respectively and the GWPs were calculated as 7989, 6076, 3903 for $CF_3Br$ and 3855, 1300, 656 for HFC-134a for the time horizon of 20, 100, 500 years, respectively. Overall, uncertainty of the estimated GWPs can be estimated to be about 2.6%. Our results were compared with those proposed by the previous studies (IPCC, 2007; WMO, 1999).

ROI-based Video Transmission using Cooperative Diversity over Wireless Ad-hoc Networks (무선 Ad-hoc 네트워크에서 협력 다이버시티를 이용한 관심영역 중심의 비디오 전송)

  • Jang, Uk;Lee, Sang-Hoon;Bae, Kyung-Hoon
    • Journal of Broadcast Engineering
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    • v.13 no.6
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    • pp.951-961
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    • 2008
  • Cooperative diversity is a cooperative technique which exploits user diversity by decoding the combined signal of the relayed signal and the direct signal in wireless multi-hop networks. Using the cooperation, the performance of the network system can be improved because cooperative diversity which is very strong against the fading channels can be achieved. In this paper, we propose the technique that provides the enhanced visual quality of the reconstructed video using the cooperative diversity with the FMO which is the error resilience tool of H.264/AVC standardization over wireless networks. The eye-tracker can detect the gaze point of user and transmit the gaze information to the nodes. After receiving the gaze information of user, each node performs ROI encoding according to the received gaze information. After encoding, video sources are divided into ROI and Non-ROI. Through the simulation results, the better visual quality of the reconstructed video is achieved when ROI and Non-ROI are transmitted through different channels.

다중 환경추적자를 이용한 제주도 지하수 유동 및 수질 특성 분석

  • 고동찬;김용재
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.138-141
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    • 2004
  • The environmental tracers tritium/helium-3 (3H/3He) and chlorofluorocarbons (CFCs) were investigated in ground water from Jeju Island, Korea, a basaltic volcanic island. The apparent 3H/3He and CFC-12 ages were in relatively good agreement in samples with low concentrations of terrigenic He. Ground water mixing was evaluated by comparing 3H and CFC-12 concentrations with mixing models, which distinguished old water with negligible 3H and CFC-12, young water with piston flow, and binary mixtures of the two end members. The ground water CFC-12 age is much older in water from wells completed in confined zones of the hydro-volcanic Seoguipo formation in coastal areas than in water from the basaltic aquifer. Comparison of major element concentrations in ground water with the CFC-12 age shows that nitrate contamination processes contribute more solutes in young water than are derived from water-rock interactions in non-contaminated old water. Chemical evolution of ground water resulting from silicate weathering in basaltic rocks reaches the zeolite-smectite phase boundary. The calcite saturation state of ground water increased with the CFC-12 apparent (piston flow) age. In agricultural areas, the temporal trend of nitrate concentration in ground water was consistent with the known history of chemical fertilizer use on Jeju Island, but the response of nitrate concentration in ground water to nitrogen inputs follows an approximate 10-year delay. Based on mass balance calculations, it was estimated that about 40% of the nitrogen applied by fertilizers reached the water table and contaminated ground water resources when the fertilizer use was at the highest level.

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Monitoring of Climate Change of Northeast Asia and Background Atmosphere in Korea

  • Oh, Sung-Nam;Chung, Hyo-Sang;Choi, Jae-Cheon;Bang, So-Young;Hyun, Myung-Suk
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.232-235
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    • 2003
  • In general, the parameters of climate change include aerosol chemical compounds, aerosol optical depth, greenhouse gases(carbon dioxide, CFCs, methane, nitrous oxide, tropospheric ozone), ozone distribution, precipitation acidity and chemical compounds, persistent organic pollutants and heavy metals, radioactivity, solar radiation including ultra-violet and standard meteorological parameters. Over the last ten years, the monitoring activities of Korea regarding to the climate change have been progressed within the WMO GAW and ACE-Asia IOP programs centered at the observation sites of Anmyeon and Jeju Gosan islands respectively. The Greenhouse gases were pointed out that standard air quality monitoring techniques are required to enhance data comparability and that data presentation formats need to be harmonized and easily understood. Especially, the impact of atmospheric aerosols on climate depends on their optical properties, which, in turn, are a function of aerosol size distribution and the spectral reflective indices. Aerosol optical depth and single scattering albedo in the visible are used as the two basic parameters in the atmospheric temperature variation studies. The former parameter is an indicator of the attenuation power of aerosols, while the latter represents the relative strength of scattering and absorption by aerosols. For aerosols with weak absorption, surface temperature decreases as the optical depth increases because of the domination of backscattering. For aerosols with strong absorption, however, warming could occur as the optical depth increases. The objective of the study is to characterize the means, variability, and trends of Greenhouse gases and aerosol properties on a regional basis using data from its baseline observatories in Korea peninsula. A further goal is to understand the factors that control radiative forcing of the greenhouse and aerosol.

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A Study for Improving the Vehicle Dismantling and Recycling System of Korea (한국의 자동차 해체·재활용 제도 개선 연구)

  • Lyou, Byung-Woon
    • Journal of Auto-vehicle Safety Association
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    • v.8 no.4
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    • pp.24-30
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    • 2016
  • In Korea, the Vehicle Dismantler and Recycler industry is supervised by the Ministry of Land, Infrastructure and Transport under the Automobile Management Act. Also, Korean Automotive recycling businesses are supervised by the Minister of Environment under the Resource Recirculation Act. The main concern of the Minister of Environment is how the wastes from Dismantled vehicles will be environmentally removed, stored, treated, recycled or disposed. In 2000, the European Union (EU) adopted the End-of-Life Vehicles Directive (2000/53/EC) which required Members to ensure the collection, treatment and recovery of end-of-life vehicles (ELVs). The Directive, the most tightly regulated and precautionary legal systems, required that the last owner of a vehicle could drop off the ELV at an authorized treatment facility and that the producers of the ELV should pay the cost of the program. The adoption of the ELVs directive has led the development of Automotive Dismantler and Recycler networks to reuse, refurbish, remanufacture, recycle and recover parts and materials embedded in ELVs. Also, the ELVs directive which has had an insignificant impact on Korean manufacturers has strong presence in the European market and has been successfully externalized on them. The Korean manufacturers not only achieve the 85% recycling target set by the ELVs directive but also meet the Extended Producer Responsibility (EPR) which requires manufacturers to contribute dismantling process. In order to improve the Korean vehicle dismantling and recycling system, the Automobile Management Act and the Resource Recirculation Act should be harmonized. Particularly the roles of the Ministry of Land, Infrastructure and Transport and the Minister of Environment should be sharply divided. Like Japan, the ELV management needs to be highly centralized, regulated, and controlled by the ministry specialized in Vehicle, namely the Ministry of Land, Infrastructure and Transport and the sub organizations. Like EU Members, recovery, reuse, and recycling must be distinguished. Recovery is defined as the final productive use of the parts and materials embedded in ELVs, which includes reuse and remanufacture of parts and recycling of the other materials. Dismantling process and reuse and remanufacture of parts must be governed by the Ministry of Land, Infrastructure and Transport. For environmental recycling or disposal of waste materials, such as CFCs, glass and plastic material, and toxic substances, governmental financial support system should be in place.

Application of the Health Risk Models Estimating Skin Cancer Caused by UVB Radiation (자외선(UVB) 노출 증가에 대한 피부암 위해도 예측 모델의 적용)

  • Shin, Dong-Chun;Lee, Jong-Tae;Chung, Yong;Kang, Na-Kyung;Yang, Ji-Yeon
    • Environmental Analysis Health and Toxicology
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    • v.11 no.1_2
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    • pp.1-10
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    • 1996
  • A decrease in stratospheric ozone probably caused by chloroflurocarbons (CFCs) emissions, has been observed large parts of-the globe. It is generally accepted that if ozone levels in the stratosphere are depleted, greater amounts of shortwave ultraviolet radiationB (UVB) will reach the earth's surface, resulting in increased incidence of nonmelanoma skin cancer. In this study, we evaluated several mathematical models, such as a power and an exponential model, and a geometric model considering the surface area of a human body part and ages for the prediction of Skin cancer incidence caused by exposure to the UVB radiation. These models basically estimated the risk of skin cancer based on those measurements of the local ozone in stratosphere and UVB. Both were measured at a part of Seoul with a Dobson ozone spectrometer and Robertson-Berger UV Biometer for 1995. As a result, we calculated the point estimation applying a biological amplification factor (BAF), UVB radiation and other factors. We used a Monte-Carlo simulation technique with assumption on the distribution of each considered factor. The sensitivity analysis of model by there components conducted using Gaussian sensitivity method. The annual integral of UVB radiation was 2275 MED (minimal erythema dose)/yr. Also, an estimate of the annual amount of UVB reaching the earth's surface at a korea's latitude and altitude was 3328 MED/yr. The values of the radiation amplification factor (RAF) were ranged from 0.9 to 1.5 in Seoul. To give the effective factors required to model the prediction of skin cancer incidence caused by exposure to the UVB radiation in Korea, we studied the pros and cons of above mentioned models with the application of those parameters measured in Seoul, Korea.

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Effects of Surfactant on SF6 Gas Hydrate Formation Rate (가스 하이드레이트 형성 원리를 이용한 SF6 처리 기술에 관한 연구)

  • Lee, Bo-Ram;Lee, Hyun-Ju;Kim, Shin-Ho;Lee, Ju-Dong;Kim, Yang-Do
    • Korean Journal of Materials Research
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    • v.18 no.2
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    • pp.73-76
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    • 2008
  • [ $SF_6$ ] gas has been widely used as an insulating, cleaning and covering gas due to its outstanding insulating feature and because of its inert properties. However, the global warming potential of $SF_6$ gas is extremely high relative to typical global warming gases such as $CO_2$, CFCs, and $CH_4$. For these reasons, it is necessary to separate and collect waste $SF_6$ gas. In this study, the effects of a surfactant (Tween) on the formation rate of $SF_6$ gas hydrates were investigated. The $SF_6$ gas hydrate formation rate increased with the addition of Tween and showed a nearly 6.5 times faster hydrate formation rate with an addition of 0.2 wt.% Tween compared to an addition of pure water. This is believed to be due to the increased solubility of $SF_6$ gas with the addition of the surfactant. It was also found that $SF_6$ gas hydrate in the surfactant solution showed two-stage hydrate formation rates with a formation rate that increased rapidly in the 2nd stage.