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BAlq를 적용한 유기발광소자의 제작 및 특성 분석에 관한 연구 (A Study on the Fabrication and Characteristic Analysis of Organic Light Emitting Device using BAlq)

  • 오환술;황수웅;강성종
    • 한국전기전자재료학회논문지
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    • 제17권1호
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    • pp.83-88
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    • 2004
  • BAlq was fabricated as for hole blocking layer in the OLED devices to investigate its electrical and optical characteristics. Device structure was ITO/$\alpha$ -NPD/EML/BAlq/Alq3/Al:Li using TYG-201, DPVBi (4, 4 - Bis (2, 2 - diphenylethen-1 - yls) - Biphenyl), Alq and DCJTB (4-(dicyanomethylene)-2- (1-propyls)6-methy 4H-pyrans) as green emitting material, blue emitting material, host material for red emission and red emitting guest material respectively. The OLED device showed optimum working voltage and electron density at 600 cd/$m^2$ when thickness of BAlq is 25$\AA$ for RGB OLED devices while their efficiencies are better at 50$\AA$ of BAlq. Red and blue color OLEDs also fabricated using 30$\AA$ thickness of BAlq and compared with those without BAlq layer. BAlq was more effective in electrical properties such as working voltage, current density and efficiency of red OLED than blue and green ones. This study describes that 30$\AA$ is optimum thickness of BAlq for best performance of full color OLED devices when using BAlq as a hole blocking material.

제강전로(製鋼轉爐)슬래그를 이용한 하수소화(下水消化)슬러지의 고화처리(固化處理) (Solidification of Digested Sewage Sludge with Converter Slag)

  • 김응호;조진규
    • 상하수도학회지
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    • 제9권3호
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    • pp.108-115
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    • 1995
  • The feasibility study of using converter slag as a solidifying agent of digested sewage sludge cake has been performed. The availability of converter slag as solidifying agent has been investigated by several trial tests. Based on the trial test results, the optimum mixing ratios of sludge cake and solidification additive are estabilished. Finally the solidification characters of sludge cake are elucidated by SEM and EDS. It is ascertained that converter slag with a small amount of quicklime enhences the solidification. From the result of pH test, overall pH of specimens tends to decrease slowly with curing time. After solidifying specimens had been cured for 7 days, these are water-cured for 24 hours. The weight and strength of all the specimens are nearly the same regardless of the mixed ratios of solidifying agent. The result of leaching tests for four heavy metal ions, Cd, $Cr^{6+}$, Pb and Cu show that the leaching strength becomes below the decision criteria of the specific wastes, respectively. The SEM observation of the delicate structure shows that needlelike crystals appear after solidification which are not observed before. From the EDS analysis, it is found that the main ingredients of needlelike crystals are Ca, Si, Al and O.

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Preparation and Characterization of White Phosphorescence Polymer Light Emitting Diodes Using PFO:Ir(ppy)3:MDMO-PPV Emission Layer

  • Park, Byung-Min;Chang, Ho-Jung
    • 마이크로전자및패키징학회지
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    • 제18권4호
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    • pp.79-83
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    • 2011
  • White phosphorescence polymer light emitting diodes (WPhPLEDs) with a glass/ITO/PEDOT:PSS/PFO:$Ir(ppy)_3$:MDMO-PPV/TPBI/LiF/Al structure were fabricated to investigate the effects of $Ir(ppy)_3$ doping concentrations on the optical and electrical properties of the devices. PFO, $Ir(ppy)_3$ and MDMO-PPV conjugated polymers as host and guest materials in the emission layer were spin coated at various concentrations of $Ir(ppy)_3$ ranging from 0.0 to 20.0 vol.%. As the concentration of $Ir(ppy)_3$ increased from 5.0 to 20.0 vol.%, the luminance and current efficiency values of the devices decreased clearly, which are attributable to the quenching effect at a high doping concentration. The maximum luminance and current density were 2850 $cd/m^2$ and 741 $mA/cm^2$, respectively for a WPhPLED with an $Ir(ppy)_3$ concentration of 5.0 vol.%. The CIE color coordinates were about x=0.33 and y=0.34 at 11V, showing a good white color.

High operating temperature stable OLEDs with reduced reflectivity cathodes

  • Popovic, Zoran D.;Aziz, Hany;Vamvounis, George;Hu, Nan-Xing;Paine, Tony
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.21-24
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    • 2003
  • The understanding of the mechanism of device degradation has been accomplished recently, for devices using $AlQ_3$ electron transport and emitter molecule. In this presentation the experimental evidence for the degradation mechanism of $AlQ_3$ based devices will be reviewed, showing that the hypothesis of an unstable $AlQ_3^+$ cation explains a large amount of experimental data. This hypothesis, however, explains not only the room temperature device degradation in time but also sheds light on temperature stability of OLEDs. Dependence of half-life of a series of devices with an emitter layer composed of a mixture of $AlQ_3$ and different hole transport molecules (mixed emitter layer) will be discussed when they are operated at elevated temperatures. These results can also be explained in the framework of an unstable $AlQ_3^+$ species. An OLED structure containing a doped mixed emitter layer will be described, which shows extraordinary stability, half-life of 1200 hours at operating temperature of 70 C and initial luminance of 1650 $cd/m^2$. We will also discuss a novel Black $Cathode^{TM}$ OLED with reduced optical reflectivity, which is also stable at elevated temperatures. The new cathode utilizes a conductive light-absorbing layer made of a mixture of metals and organic materials.

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분무합성법으로 제작한$\alpha-Ga_2S_3$$\alpha-Ga_2S_3:Co^{2+}$ 박막의 광학적 특성 (Optical Properties of Undoped and $Co^{2+}$-doped $\alpha-Ga_2S_3$Thin Films by Spray Pyrolysis)

  • 김형곤;김남오;박태형;진문석;김미향;오석균;김화택
    • 한국전기전자재료학회논문지
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    • 제14권7호
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    • pp.539-545
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    • 2001
  • Undoped and Co$^{2+}$ $\alpha$-Ga$_2$S$_3$ thin films were grown by spray pyrolysis method. It has been found that these thin films have a monoclinic structure and direct optical energy gap and indirect were located to 3.477eV and 3.123 eV at 10K respectively. In the photoluminescence due to a D0A(donor-acceptor) pair recombination were observed at 502 nm and 671 nm for the $\alpha$-Ga$_2$S$_3$ thin film, where is excited by the 325 nm-line of He-Cd laser. These peaks are identified to be corresponding to the electron transition between the energy levels of Co$^{2+}$ ion sited a the T$_{d}$ symmetry point in the $\alpha$-Ga$_2$S$_3$;Co$^{2+}$ thin film. film.

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Ga 함량에 따른 $Cu(In_xGa_{1-x})Se_2$ 태양전지의 특성분석 (Characterization of $Cu(In_xGa_{1-x})Se_2$ Solar Cells with Ga Content)

  • 김석기;권세한;이두열;이정철;강기환;윤경훈;안병태;송진수
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 하계학술대회 논문집 D
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    • pp.1264-1267
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    • 1998
  • $Cu(In_xGa_{1-x})Se_2$ thin films were prepared and characterized with various Ga contents. As the Ga content increased, the grain size of CIGS film became smaller. The 2 $\theta$ values in XRD patterns were shifted to larger values and the overlapped peaks were splitted. The energy bandgap increased from 1.04 to 1.67 eV and the resistivity decreased. The solar cell fabricated with ZnO/CdS/$Cu(In_{0.7}Ga_{0.3})Se_2/Mo$ structure yielded an efficeincy of 14.48% with an acitive area of 0.18 $cm^2$. The efficiency decreased with further increase of Ga content.

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나노선 기반 논리 회로의 이차원 시뮬레이션 연구 (Two-dimensional numerical simulation study on the nanowire-based logic circuits)

  • 최창용;조원주;정홍배;구상모
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.82-82
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    • 2008
  • One-dimensional (1D) nanowires have been received much attention due to their potential for applications in various field. Recently some logic applications fabricated on various nanowires, such as ZnO, CdS, Si, are reported. These logic circuits, which consist of two- or three field effect transistors(FETs), are basic components of computation machine such as central process unit (CPU). FETs fabricated on nanowire generally have surrounded shapes of gate structure, which improve the device performance. Highly integrated circuits can also be achieved by fabricating on nano-scaled nanowires. But the numerical and SPICE simulation about the logic circuitry have never been reported and analyses of detailed parameters related to performance, such as channel doping, gate shapes, souce/drain contact and etc., were strongly needed. In our study, NAND and NOT logic circuits were simulated and characterized using 2- and 3-dimensional numerical simulation (SILVACO ATLAS) and built-in spice module(mixed mode).

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과포정계 합금의 응고조직에 미치는 대류의 영향 (Effect of Convection on the Solidification Microstructure of Hyper-Peritectic Systems)

  • 박병규;김무근;박장식;김근오;최재광
    • 대한기계학회논문집B
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    • 제25권7호
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    • pp.958-966
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    • 2001
  • This study has examined the microstructural development in the Bridgman type directional solidification of hyper-peritectic Sn-Cd alloys, and the temperature and flow field have been numerically simulated to see if there is any change induced by convection. The directional solidification experiments carried out in quartz tubes with inside diameters of 0.4∼6mm showed that the resulting microstructures are clearly dependent on the size of tube diameters. The bigger ampoules where the effect of convection is highly expected produced saw-like structures resulting from the primary $\alpha$ and peritectic $\beta$ phase growing together at a planar solid-liquid front, with the former being surrounded by the latter. In the smaller ampoules, where the effect of convection is expected low however, the saw structure disappears, and as is understood from the theoretical prediction based on diffusion-controlled solidification the initial growth of the primary $\alpha$ phase is replaced by the nucleation of the peritectic $\beta$ phase whose growth continues to the end of the solidification.

범용 열/유체 유동해석 프로그램 NUFLEX의 개발 (DEVELOPMENT OF GENERAL PURPOSE THERMO/FLUID FLOW ANALYSIS PROGRAM NUFLEX)

  • 허남건;원찬식;유홍선;손기헌;김사량
    • 한국전산유체공학회지
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    • 제12권2호
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    • pp.8-13
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    • 2007
  • A general purpose program NUFLEX for the analysis 3-D thermo/fluid flow and pre/post processor in complex geometry has been developed, which consists of a flow solver based on FVM and GUI based pre/post processor. The solver employs a general non-orthogonal grid system with structured grid and solves laminar and turbulent flows with standard/RNG $k-{\varepsilon}$ turbulence model. In addition, NUFLEX is incorporated with various physical models, such as interfacial tracking, cavitation, MHD, melting/solidification and spray models. For the purpose of evaluation of the program and testing the applicability, many actual problems are solved and compared with the available data. Comparison of the results with that by STAR-CD or FLUENT program has been also made for the same flow configuration and grid structure to test the validity of NUFLEX.

HIMSEN 6H21/32 엔진 실린더 내 유동해석 (Analysis on the In-cylinder Flow of HIMSEN 6H21/32 Engine)

  • 윤욱현;김진원;하지수
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집B
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    • pp.934-939
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    • 2001
  • In computational study of the flow in piston engines and the flow through moving valves, the use of moving vertices is essential for modelling flows with moving boundaries. The positions of cell vertices in such cases must be allowed to vary with time. To simulate 3-dimensional port-valve and piston-cylinder of HIMSEN 6H21/32 engine, a commercially available code, STAR-CD, was used. Changes in mesh geometry was specified by PROSTAR commands.(i.e. the Change Grid operation in the EVENTS command module.) Control of the intake flow is expected to play an important role as designers seek to obtain better fuel spray characteristics, fuel mixing and mixture preparation, combustion performance, and emissions reductions to meet national standards. As a result of analysis, velocity fields indicate the presence of a structured flow comprised of one pair of counter-rotating vortices under the intake valve during the early induction process. These flow structures remain visible for most of the intake process. As the piston moves towards BDC, these vortices develops into a larger tumbling motion that dominates the flow structure.

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