• 제목/요약/키워드: CD structure

검색결과 783건 처리시간 0.027초

Structural Characterization of Growth-Related Translationally Controlled Tumor Protein P23

  • Lee, Bong-Jin;Hong, Yoon-Hun;Park, Sang-Ho;Lee, Kyunglim
    • 한국자기공명학회논문지
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    • 제5권1호
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    • pp.46-55
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    • 2001
  • P23, a translationally controlled turner protein is involved in the interleukin-4 secretion from human basophils and is also known to be an IgE-dependent histamine-releasing factor. However, the precise physiological function and structure of P23 have not been elucidated. In the current study, we constructed the optimal expression and purification protocol of P23 and investigated the secondary structure and structural stability in various conditions. Circular dichroism (CD) investigation showed that the secondary structure of P23 adopts mainly a P-sheet conformation. CD spectroscopy and differential scanning calorimetry revealed that P23 is fairly stable in the pH range of neutral and mild-basic conditions and in the temperature range of 10 - 50$\^{C}$. Since the thermal stability and the P-sheet content of P23 were decreased by the addition of Ca$\^$2+/ ion, it could be suggested that Ca$\^$2+/ion induces structural change by partially destabilizing the structure of P23. In addition various H experiments were monitored to solve the aggregation of P23. Den results will provide the preliminary structural information about P23.

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Development of High Aperture Ratio 2.1” QVGA LTPS (Low Temperature Poly Si) LCD Using SLS (Sequential Lateral Solidification) Technology

  • Kang, Myung-Koo;Lee, Joong-Sun;Park, Jong-Hwa;Zhang, Lintao;Joo, Seung-Yong;Kim, Chul-Ho;Kim, Il-Kon;Kim, Sung-Ho;Park, Kyung-Soon;Yoo, Chun-Ki;Kim, Chi-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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    • pp.1033-1034
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    • 2005
  • High resolution 2.1” QVGA LTPS LCD (190ppi) having high aperture ratio of 65% could be successfully developed using state-of-the-art SLS technology and active/gate storage structure. Cost effective P-MOS 6-Mask structure was used. Full gate and transmission gate circuits are integrated in the panel. The high aperture ratio was obtained by using active/gate capacitance structure, which can reduce storage capacitance area. The aperture ratio was increased to 65% from 49% of conventional gate/data capacitance structure. The brightness was increased from 180cd to 270cd without any degradation of optical properties such as contrast ratio, flicker or crosstalk.

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Structural characterization of ladder-type cadmium(II) citrate complex, (C3H12N2)[{Cd(H2O)(C6H5O7)}2]·6H2O

  • Kim, Chong-Hyeak;Lee, Sueg-Geun
    • 분석과학
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    • 제20권4호
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    • pp.355-360
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    • 2007
  • The title complex, $(C_3H_{12}N_2)[\{Cd(H_2O)(C_6H_5O_7)\}_2]{\cdot}6H_2O$, I, has been prepared and its structure characterized by FT-IR, EDS, elemental analysis, ICP-AES, and X-ray single crystallography. It is triclinic system, $P{\bar{1}}$ space group with a = 10.236(2), b = 11.318(2), c = $13.198(2){\AA}$, ${\alpha}=77.95(1)^{\circ}$, ${\beta}=68.10(1)^{\circ}$, ${\gamma}=78.12(1)^{\circ}$, V = $1373.5(3){\AA}^3$, Z = 2. Complex I has constituted by protonated 1,3-diaminopropane cations, citrate coordinated cadmium(II) anions, and free water molecules. The central cadmium atoms have a capped trigonal prism geometry by seven coordination with six oxygen atoms of three different citrate ligands and one water molecule. Citrate ligands are bridged to three different cadmium atoms. Each cadmium atom is linked by carboxylate and hydroxyl groups of citrate ligand to construct an one-dimensional ladder-type assembly structure. The polymeric crystal structure is stabilized by three-dimensional networks of the intermolecular O-H${\cdots}$O and N-H${\cdots}$O hydrogen-bonding interaction.

400℃ 열처리한 삼원화합물 ZnxCd1-xS 박막의 분광학적 특성 연구 (Spectroscopic Characterization of 400℃ Annealed ZnxCd1-xS Thin Films)

  • 강광용;이승환;이남권;이정주;유윤식
    • 한국전자파학회논문지
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    • 제26권1호
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    • pp.101-112
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    • 2015
  • II~VI족 화합물 반도체 $Zn_xCd_{1-x}S$ 박막을 Indium-tin-oxide(ITO)가 도포된 유리기판 상에 열증발법을 사용하여 증착하였다. 박막의 합성비(molar ratio) x($0{\leq}x{\leq}1$)는 CdS(x=0) 박막과 ZnS(x=1) 박막을 포함하여, 삼원화합물 $Zn_xCd_{1-x}S$ 박막을 제조하기 위하여 변화시켰다. 또한, 증착한 박막의 결정성을 높이기 위하여 진공전기로에서 열처리 하였으며, 분광학적 특성조사를 위해서는 $400^{\circ}C$에서 열처리한 $Zn_xCd_{1-x}S$ 박막이 최적임을 알았다. $Zn_xCd_{1-x}S$ 박막의 합성비(x)와 전자적 구조를 조사하기 위하여 X-선 광전자 분광법(XPS)을 사용하였고, 박막시료의 광학적 에너지 띠 간격 $E_g$는 자외선-가시광-근접 적외선(UV-Vis-NIR) 분광법으로 측정하였으며, 합성비(x)값이 0에서 1까지 변화함에 따라 2.44~3.98 eV 범위의 값을 보여주었다. 끝으로, THz-TDS(Time Domain Spectroscopy) 시스템을 사용하고 $Zn_xCd_{1-x}S$ 박막의 THz파 특성을 측정하여 테라헤르츠(THz) 영역용 전자 및 광학 소자로서 응용가능성을 확인하였다.

묽은 자성 반도체 Cd1-xMnxTe의 자기 광학적 특성과 응용성 연구 (A Study on the Magneto-optical Properties and Application of Diluted Magnetic Semiconductor Cd1-xMnxTe)

  • 황영훈;엄영호;조성래
    • 한국자기학회지
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    • 제19권5호
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    • pp.186-190
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    • 2009
  • 본 연구에서는 수직 Bridgman 법으로 묽은 자성 반도체 Cd$_{1-x}$Mn$_x$Te 단결정을 성장시켜 Mn의 조성비 변화에 따른 자기광학적 특성과 응용성을 조사하였다. X-선 회절 실험으로부터 x < 0.82 조성에 대하여 zinc-blende 구조임을 확인하였다. 띠 간격 에너지는 온도 감소와 Mn 조성비 증가에 대하여 선형적으로 증가하였다. Faraday 회전은 광 에너지 증가 때문에 띠 간격 에너지 근처에서 증가하였고, Mn 조성비 x가 증가함에 따라 증가하였다. Cd$_{0.62}$Mn$_{0.38}$Te 결정을 이용한 광 아이솔레이트의 아이솔레이션과 삽입손실은 45와 0.35 dB이었다.

Characterization of a Novel Gene in the Extended MHC Region of Mouse, NG29/Cd320, a Homolog of the Human CD320

  • Park, Hyo-Jin;Kim, Ji-Yeon;Jung, Kyung-In;Kim, Tae-Jin
    • IMMUNE NETWORK
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    • 제9권4호
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    • pp.138-146
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    • 2009
  • Background: The MHC region of the chromosome contains a lot of genes involved in immune responses. Here we have investigated the mouse NG29/Cd320 gene in the centrometrically extended MHC region of chromosome 17. Methods: We cloned the NG29 gene by RT-PCR and confirmed the tissue distribution of its gene expression by northern blot hybridization. We generated the NG29 gene expression constructs and polyclonal antibody against the NG29 protein to perform the immunofluorescence, immunoprecipitation and flow cytometric analysis. Results: The murine NG29 gene and its human homologue, the CD320/8D6 gene, were similar in the gene structure and tissue expression patterns. We cloned the NG29 gene and confirmed its expression in plasma membrane and intracellular compartments by transfecting its expresssion constructs into HEK 293T cells. The immunoprecipitation studies with rabbit polyclonal antibody raised against the NG29-NusA fusion protein indicated that NG29 protein was a glycoprotein of about 45 kDa size. A flow cytometric analysis also showed the NG29 expression on the surface of Raw 264.7 macrophage cell line. Conclusion: These findings suggested that NG29 gene in mouse extended MHC class II region was the orthologue of human CD320 gene even though human CD320/8D6 gene was located in non-MHC region, chromosome 19p13.

Mesoporous silica의 표면특성이 Pb(II)와 Cd(II)의 흡착거동에 미치는 영향 (Influence of Surface Characteristics of Mesoporous Silica on Pb(II) and Cd(II) Adsorption Behavirous)

  • 이하영;이갑두;박상원
    • 대한환경공학회지
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    • 제30권6호
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    • pp.673-679
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    • 2008
  • 본 연구에서는 실리카 원으로 tetraethylorthosilcate(TEOS)를 이용하고, template로 cetyltrimethylammonium bromide(CTMABr)을 사용하여 메조포러스 실리카(mesoporous silica)를 수열합성 하였다. 최적의 합성 조건을 알기 위해 template와 실리카의 몰비를 조절하였다. 메조포러스 실리카의 표면 성질과 구조는 XRD, SEM 그리고 BET를 이용하여 살펴보았다. 비표면적($S_{BET}$), 전체 기공부피(V$_T$), 그리고 평균 기공지름(D$_{BJH}$)을 포함하는 N$_2$ 등온 흡착 특성은 BET식을 이용하여 확인하였다. 또한, 메조포러스 실리카의 Pb(II)와 Cd(II)의 흡착 특성은 Zeta potential과 ICP를 이용하여 측정하였다. 그 결과, N$_2$ 등온 흡착으로부터 S$_{BET}$는 100$\sim$1,500 m$^2$/g이었으며, 평균 기공 크기는 2$\sim$4 nm이었다. 메조포러스 실리카의 Pb이온과 Cd이온의 흡착 특성은 용액의 pH변화에 의존하였고, 기존의 흡착제인 실리카겔보다 더 좋은 흡착 거동을 보였다.

A Study on the Band Structure of ZnO/CdS Heterojunction for CIGS Solar-Cell Application

  • Sim, Hana;Lee, Jeongmin;Cho, Seongjae;Cho, Eou-Sik;Kwon, Sang Jik
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제15권2호
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    • pp.267-275
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    • 2015
  • In this paper, ZnO films were prepared by atomic layer deposition (ALD) and CdS films were deposited using chemical bath deposition (CBD) to form ZnO/CdS heterojunction. More accurate mapping of band arrangement of the ZnO/CdS heterojunction has been performed by analyzing its electrical and optical characteristics in depth by various methods including transmittance, x-ray photoemission spectroscopy (XPS), and ultraviolet photoemission spectroscopy (UPS). The optical bandgap energies ($E_g$) of ZnO and CdS were 3.27 eV and 2.34 eV, respectively. UPS was capable of extracting the ionization potential energies (IPEs) of the materials, which turned out to be 8.69 eV and 7.30 eV, respectively. The electron affinity (EA) values of ZnO and CdS calculated from IPE and $E_g$ were 5.42 eV and 4.96 eV, respectively. Energy-band structures of the heterojunction could be accurately drawn from these parameters taking the conduction band offset (CBO) into account, which will substantially help acquisition of the full band structures of the thin films in the CIGS solar-cell device and contribute to the optimal device designs.

Photoelectrochemical characterization of surface-modified CuInS2 nanorod arrays prepared via template-assisted growth and transfer

  • Yang, Wooseok;Kim, Jimin;Oh, Yunjung;Moon, Jooho
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.401-401
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    • 2016
  • Although vertically aligned one-dimensional (1D) structure has been considered as efficient forms for photoelectrode, development of efficient 1D nanostructured photocathode are still required. In this sense, we recently demonstrated a simple fabrication route for CuInS2 (CIS) nanorod arrays from aqueous solution by template-assisted growth-and-transfer method and their feasibility as a photoelectrode for water splitting. In this study, we further evaluated the photoelectrochemical properties surface-modified CIS nanorod arrays. Surface modification with CdS and ZnS was performed by successive ion layer adsorption and reaction (SILAR) method, which is well known as suitable technique for conformal coating throughout nanoporous structure. With surface modification of CdS and ZnS, both photoelectrochemical performance and stability of CuInS2 nanorod arrays were improved by shifting of the flat-band potential, which was analyzed both onset potential and Mott-schottky plot.

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Red OLEDs containing the dotted-line doped layer structure in its emitting region.

  • Lee, Chang-Min;Han, Jeong-Whan
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.612-615
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    • 2004
  • We present an extremely high efficient red organic light-emitting diodes (OLEDs) using a fluorescent dye 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB) doped into an emitting region which consists of multiple pairs of a doped and an undoped layer. An emitting region of OLEDs composes of a tris-(8-hydroxyquinolinato) aluminum (Alq3) codoped with rubrene of 5% wt. or a mixture of Alq3 and rubrene (1:1). The luminance yield of the codoped device and the mixed device are 6.5 cd/A and 9.2 cd/A at 10 mA/$cm^2$, respectively. We have considerably improved the luminance yields of red OLEDs as much as ${\sim}$90% at 10 mA/$cm^2$ compared with that of the device doped with only DCJTB. We attribute it to both the emitting assist dopant (rubrene) and the dotted-line doping structure in an emitting region of OLED.

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