• Title/Summary/Keyword: CD size

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Morphological Change of Crosslinked ${\beta}$-Cyclodextrin after Recycling

  • Han, Eun-Mi;Kim, Song-Hee;Kim, Ki-Woo;Kwak, Hae-Soo
    • Journal of Dairy Science and Biotechnology
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    • v.25 no.1
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    • pp.9-13
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    • 2007
  • The present study was carried out to examine the effect of crosslinked ${\beta}$-cyclodextrin(${\beta}$-CD) made by adipic acid on cholesterol removal rate and find the structural change after recycling on SEM observation. The size reduction and morphological changes were found during the recycling process and the profound changes were observed at 8th time reuse. After cholesterol removal in milk, the used crosslinked ${\beta}$-CD was washed for cholesterol dissociation and reused. In recycling study, the cholesterol removal rate at first trial was 92.5% in milk, which was mostly same as that using new crosslinked ${\beta}$-CD(92.4%). With repeated 10th reuse of crosslinked ${\beta}$-CD resulted in 81.4% of cholesterol removal in milk. Similar trend was found in cream and cholesterol removal was 91.5% at 1st trial and 83.4% at 10th trial. In both milk and cream samples, the removal rate at 1st reuse was not significantly different from that at 6th reuse(p>0.05). The present study indicated that crosslinked ${\beta}$-CD made by adipic acid resulted in the effective recycling efficiency, especially up to 6th reuse and morphological modifications were not distinguishable up to 8th reuse.

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Geochemical Dispersion of Cu, Pb, Zn, and Cd and Their Mode of Occurrences in Soils and Dusts in Changhang Smelter Area (장항제련소 지역 토양과 분진중의 Cu, Pb, Zn 및 Cd의 지구화학적 분산과 산출상태)

  • Kim, Ju-Yong;Chon, Hyo-Taek
    • Economic and Environmental Geology
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    • v.26 no.2
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    • pp.175-185
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    • 1993
  • Soils and dusts collected from Changhang smelter area were analyzed for Cu, Pb, Zn, and Cd in order to determine their dispersion pattern and mode of occurrences, and to investigate the pollution level of heavy metals such as Cu, Pb, Zn, and Cd by smelting activity. The soil pH of Changhang area is in the range of 3.7~8.8, and increased with increasing distance from the smelter site. The particles containing heavy metals are several tens of ${\mu}m$ in diameter, and have well crystal form. Samples collected near the smelter show similar particle properties in size, shape, and composition, which means that they could be originated from the same contamination source. Element couples of Cu, Pb, Zn, and Cd indicate high correlation with each other, which means that Cu, Pb, Zn, and Cd could be originated from the same point source of smelter. Heavy metal contents were decayed to background levels from 2.5 kilometer away from the smelter.

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CdSe Quantum Dots Sensitized TiO2 Electrodes for Photovoltaic Cells

  • Yum, Jun-Ho;Choi, Sang-Hyun;Kim, Seok-Soon;Kim, Dong-Yu;Sung, Yung-Eun
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.257-261
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    • 2007
  • The electronic properties of quantum dots can be tuned by changing the size of particles without any change in their chemical composition. CdSe quantum dots, the sizes of which were controlled by changing the concentrations of Cd and Se precursors, were adsorbed on $TiO_2$ photoelectrodes and used as sensitizers for photovoltaic cells. For applications of CdSe quantum dot as sensitizers, $CdSe/TiO_2$ films on conducting glass were employed in a sandwich-type cell that incorporated a platinum-coated conductive glass and an electrolyte consisting of an $I^-/I_3^-$ redox. The fill factor (FF) and efficiency for energy conversion ($\c{c}$) of the photovoltaic cell was 62 % and 0.32 %, respectively.

Vibration Control of CD-ROM Feeding System Using ER Fluids (ER 유체를 이용한 CD-ROM 피딩 시스템의 진동 제어)

  • 김형규;임수철;최승복;박영필
    • The Korean Journal of Rheology
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    • v.11 no.2
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    • pp.97-104
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    • 1999
  • This paper presents vibration control of a drive feeding system consisting of a new type of CD-ROM(compact discread only memory) mount using electro-rheologocal(ER) fluid. Chemically treated starch particles and silicon oil are used for ER fluid. and its field-dependent yield stresses are experimentally distilled under both the shear and the flow modes. On the basis of the yield stress, an appropriate size of ER CD-ROM mount adapted to conventional feeding system is designed and manufactured. Vibration isolation performance of the proposed mount is evaluated in the frequency domain and compared with that of conventional rubber mount. The ER CD-ROM mount is then installed to the drive feeding system and the system equation of motion is derived. Following the formulating the sky-hook controller, computer simulation is undertaken in order to evaluate vibration suppression of the feeding system subjected to various disturbances(excitations).

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Molecular Cloning and Enzymatic Characterization of Cyclomaltodextrinase from Hyperthermophilic Archaeon Thermococcus sp. CL1

  • Lee, Jae-Eun;Kim, In-Hwan;Jung, Jong-Hyun;Seo, Dong-Ho;Kang, Sung-Gyun;Holden, James F.;Cha, Jaeho;Park, Cheon-Seok
    • Journal of Microbiology and Biotechnology
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    • v.23 no.8
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    • pp.1060-1069
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    • 2013
  • Genome organization near cyclomaltodextrinases (CDases) was analyzed and compared for four different hyperthermophilic archaea: Thermococcus, Pyrococcus, Staphylothermus, and Thermofilum. A gene (CL1_0884) encoding a putative CDase from Thermococcus sp. CL1 (tccd) was cloned and expressed in Escherichia coli. TcCD was confirmed to be highly thermostable, with optimal activity at $85^{\circ}C$. The melting temperature of TcCD was determined to be $93^{\circ}C$ by both differential scanning calorimetry and differential scanning fluorimetry. A size-exclusion chromatography experiment showed that TcCD exists as a monomer. TcCD preferentially hydrolyzed ${\alpha}$-cyclodextrin (${\alpha}$-CD), and at the initial stage catalyzed a ring-opening reaction by cleaving one ${\alpha}$-1,4-glycosidic linkage of the CD ring to produce the corresponding single maltooligosaccharide. Furthermore, TcCD could hydrolyze branched CDs (G1-${\alpha}$-CD, G1-${\beta}$-CD, and G2-${\beta}$-CD) to yield significant amounts (45%, 40%, and 46%) of isomaltooligosaccharides (panose and $6^2$-${\alpha}$-maltosylmaltose) in addition to glucose and maltose. This enzyme is one of the most thermostable maltogenic amylases reported, and might be of potential value in the production of isomaltooligosaccharides in the food industry.

Synthesis of CdS with Graphene by CBD(Chemical Bath Deposition) Method and Its Photocatalytic Activity

  • Pawar, R.C.;Lee, Jin-Yong;Kim, Eun-Jeong;Kim, Hyungsub;Lee, Caroline Sunyong
    • Korean Journal of Materials Research
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    • v.22 no.10
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    • pp.504-507
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    • 2012
  • Synthesis of RGO (reduced graphene oxide)-CdS composite material was performed through CBD (chemical bath deposition) method in which graphene oxide served as the support and Cadmium Sulfate Hydrate as the starting material. Graphene-based semiconductor photocatalysts have attracted extensive attention due to their usefulness for environmental and energy applications. The band gap (2.4 eV) of CdS corresponds well with the spectrum of sunlight because the crystalline phase, size, morphology, specic surface area and defects, etc., of CdS can affect its photocatalytic activity. The specific surface structure (morphology) of the photocatalyst can be effective for the suppression of recombination between photogenerated electrons and holes. Graphene (GN) has unique properties such as a high value of Young's modulus, large theoretical specific surface area, excellent thermal conductivity, high mobility of charge carriers, and good optical transmittance. These excellent properties make GN an ideal building block in nanocomposites. It can act as an excellent electron-acceptor/transport material. Therefore, the morphology, structural characterization and crystal structure were observed using various analytical tools, such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and Raman spectroscopy. From this analysis, it is shown that CdS particles were well dispersed uniformly in the RGO sheet. Furthermore, the photocatalytic property of the resulting RGO-CdS composite is also discussed in relation to environmental applications such as the photocatalytic degradation of pollutants. It was found that the prepared RGO-CdS nanocomposites exhibited enhanced photocatalytic activity as compared with that of CdS nanoparticles. Therefore, better efficiency of photodegradation was found for water purification applications using RGO-CdS composite.

β-carotene regulates cancer stemness in colon cancer in vivo and in vitro

  • Lee, Kyung Eun;Kwon, Minseo;Kim, Yoo Sun;Kim, Yerin;Chung, Min Gi;Heo, Seung Chul;Kim, Yuri
    • Nutrition Research and Practice
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    • v.16 no.2
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    • pp.161-172
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    • 2022
  • BACKGROUND/OBJECTIVES: Colorectal cancer (CRC) is the third most common cancer worldwide and has a high recurrence rate, which is associated with cancer stem cells (CSCs). β-carotene (BC) possesses antioxidant activity and several anticancer mechanisms. However, no investigation has examined its effect on colon cancer stemness. MATERIALS/METHODS: CD133+CD44+ HCT116 and CD133+CD44+ HT-29 cells were isolated and analyzed their self-renewal capacity by clonogenic and sphere formation assays. Expressions of several CSCs markers and Wnt/β-catenin signaling were examined. In addition, CD133+CD44+ HCT116 cells were subcutaneously injected in xenograft mice and analyzed the effect of BC on tumor formation, tumor volume, and CSCs markers in tumors. RESULTS: BC inhibited self-renewal capacity and CSC markers, including CD44, CD133, ALDH1A1, NOTCH1, Sox2, and β-catenin in vitro. The effects of BC on CSC markers were confirmed in primary cells isolated from human CRC tumors. BC supplementation decreased the number and size of tumors and delayed the tumor-onset time in xenograft mice injected with CD133+CD44+ HCT116 cells. The inhibitory effect of BC on CSC markers and the Wnt/β-catenin signaling pathway in tumors was confirmed in vivo as well. CONCLUSIONS: These results suggest that BC may be a potential therapeutic agent for colon cancer by targeting colon CSCs.

A Study on the Development of an Engine Monitoring System for Small Vessel Using CSMA/CD (CSMA/CD 프로토콜을 이용한 중.소형 선박용 기관 모니터링 시스템 구성에 관한 연구)

  • 신명철;고두석;윤경국;안병원;김윤식
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.3 no.2
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    • pp.455-463
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    • 1999
  • This study is on the development of an engine monitoring system which can be applied not only for mid-size vessels but also small vessels less than 20 gross tonnage. Monitoring system consists of a set LMU(Local Monitoring Unit) that collect data from local machinery, a host computer that controls LMU and a stable communication system which adopts CSMA/CD protocol. The LMU is composed of 80C196KC microprocessor, which consists of CPU, digital input/output, analog input/output and communication module. Communication system between the host computer(compatible IBM PC) and LMUs is the multidrop configuration using RS-485 method and confirmed high performance communication by the aid of polling method as well as carrier sense multiple access with collision detection(CSMA/CD) protocol.

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The Effect of the Sn Amounts on the Microstructure of Rapidly Solidified Ag-Sn-In Alloys (급속응고한 Ag-Sn-In 미세조직에 미치는 Sn 함량 변화의 영향)

  • Cho, Dae-Hyoung;Kwon, Gi-Bong;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.26 no.2
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    • pp.92-97
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    • 2006
  • Contact material is widely used as electrical parts. Ag-Cd alloy has a good wear resistance and stable contact resistance. But the disadvantages of Ag-Cd alloy are coarse Cd oxides and harmful metal, Cd. To solve the disadvantages of that, Ag-Sn alloy that has stable and fine Sn oxide at high temperature has been developed. In order to optimize Sn amount that affects the formation of the oxide layer on the surface, we worked for the microstructures and properties of Ag-Sn material fabricated by rapid solidification process. The experimental procedure were melting using high frequency induction, melt spinning, and internal oxidation. We have shown that the optimized Sn amount for high hardness is 7.09 wt%Sn. Surface oxide layer forms when Sn amount is over 9.45 wt%. The size of Sn oxide is 20 nm.

Growth and optical properties for CdSe thin film by Chemical Bath Deposition Method (Chemical Bath Deposition 방법으로 성장된 CdSe 박막의 광전도셀 특성)

  • You, Sang-Ha;Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.75-76
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    • 2006
  • olycrystailine CdSe thin films were grown on ceramic substrate using a chemical bath deposition (CBD)method. They were annealed at various temperature and X-ray diffraction patterns were measured by X-ray diffractometer in order to study CdSe polycrystal structure. Its grain size was about 0.3 ${\mu}m$. Hall effect on this sample was measured by Van der Pauw method and studied on carrier density and movility depending on temperature. We measured also spectral response, sensitivity($\gamma$), maximum allowable power dissipation and response time on these samples.

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