• Title/Summary/Keyword: CARBON REDUCTION

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A Study on the Growth Morphology of VGCF Nano-Materials by Acetylene Pyrolysis over Stainless Steel Catalyst - Effect of Reduction Pretreatment and Hydrogen Supply (스테인리스 스틸 촉매 상에서 아세틸렌 분해에 의한 VGCF 나노물질의 성장 형태 연구 - 환원 전처리 및 수소공급 효과)

  • Park, Seok Joo;Lee, Dong Geun
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.563-571
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    • 2006
  • Vapor grown carbon fiber (VGCF) nano-materials such as carbon nanotubes and carbon nanofibers were directly grown on the surface of the stainless steel mesh pre-treated by reduction. The reduction of the stainless steel mesh by hydrogen formed small catalytic particles and large particles with bi-modal distribution on the metal surface. When the VGCFs were synthesized on the reduced mesh, carbon nanotubes (CNTs) were dominantly grown from the small catalytic particles without supplying hydrogen gas. However, carbon nanofibers (CNFs) were dominantly grown from the large catalytic particles with hydrogen.

The Analysis of Potential Reduction of CO2 Emission In Soil and Vegetation due to Land use Change (토지이용변화에 따른 식생 및 토양의 이산화탄소 저감잠재량 분석)

  • Lee, Dong-Kun;Park, Chan
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.12 no.2
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    • pp.95-105
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    • 2009
  • Land Use Changes (LUCs) have effects on greenhouse gas emissions and carbon stocks in soil and vegetation. Therefore, predictions for LUC are very important for achieving quantitative targets of $CO_2$ reduction rates. Some research exists on carbon fluxes and carbon cycles to estimate carbon stocks in terrestrial ecosystems in Korea. However, these researches have limitations in terms of helping us understand future potential reductions of $CO_2$ that reflect the influence of LUC. The aim of this study is to analyze the reduction levels of $CO_2$ emissions while considering LUC scenarios that effect carbon fluxes for LCS basic study in the year 2030. In this study, a common approach to model the effects of LUC on carbon stocks is the use of CA-Markov technical process with LUC patterns in the past. Potential reduction of $CO_2$ is calculated by change of land use that contains different soil organic carbon, each land use type, and biomass in vegetation. An IPCC analytical method of natural carbon sink and coefficient results from previous study in Korea is used as a calculation method for potential reduction of $CO_2$. As a result, 12,419 KtC will be reduced annually, which is 8.3% percent of 2005 $CO_2$ emissions in Korea. This will result in 3,226 hundred million won of economic efficiency. In conclusion, conservation of natural carbon sinks is necessary even if the amount of potential reduction change is little.

Synthesis of Nitrogen-doped Carbon Nanofibers for Oxygen Reduction Reaction (산소환원반응 촉매용 질소 도핑된 탄소나노섬유의 제조)

  • An, Geon-Hyoung;Lee, Eun-Hwan;Ahn, Hyo-Jin
    • Journal of Powder Materials
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    • v.23 no.6
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    • pp.420-425
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    • 2016
  • N-doped carbon nanofibers as catalysts for oxygen-reduction reactions are synthesized using electrospinning and carbonization. Their morphologies, structures, chemical bonding states, and electrochemical performance are characterized. The optimized N-doped carbon nanofibers exhibit graphitization of carbon nanofibers and an increased nitrogen doping as well as a uniform network structure. In particular, the optimized N-doped carbon nanofibers show outstanding catalytic activity for oxygen-reduction reactions, such as a half-wave potential ($E_{1/2}$) of 0.43 V, kinetic limiting current density of $6.2mAcm^{-2}$, electron reduction pathways (n = 3.1), and excellent long-term stability after 2000 cycles, resulting in a lower $E_{1/2}$ potential degradation of 13 mV. The improvement in the electrochemical performance results from the synergistic effect of the graphitization of carbon nanofibers and the increased amount of nitrogen doping.

Effect of Exogenous Potassium on the Reduction in Tar, Nicotine and Carbon Monoxide Deliveries in the Mainstream smoke of Cigarettes (가리염 첨가가 궐련 주류연중 타르, 니코틴, 일산화탄소 이행량에 미치는 영향)

  • 안기영;김천석
    • Journal of the Korean Society of Tobacco Science
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    • v.17 no.1
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    • pp.62-67
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    • 1995
  • Deliveries of tar, nicotine and carbon monoxide in mainstream smoke decreased with increment of exogenous potassium content of tobacco. Potassium malate was more effective than potassium nitrate, potassium carbonate, potassium citrate and potassium oxalate for the reduction of carbon monoxide, but potassium nitrate was more effective than potassium palate, potassium carbonat, potassium citrate and potassium oxalate for the reduction of carbon in the case of nicotine. Puff count and burning rate were slightly changed with added potassium salts.

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Influence of carbon black on electrochemical performance of graphene-based electrode for supercapacitor (슈퍼커패시터를 위한 그래핀 기반 전극의 전기화학적 특성에 대한 카본블랙 도입의 효과)

  • Kim, Ki-Seok;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.95.1-95.1
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    • 2011
  • In this work, graphene was prepared by modified Hummers method and prepared graphene was applied to electrode materials for supercapacitor. In addition, to enhance the electrochemical performance of graphene, carbon black was deposited onto graphene via chemical reduction. The effect of the carbon black content incorporated on the electrochemical properties of the graphene-based electrodes was investigated. It was found that nano-scaled carbon black aggregates were deposited and dispersed onto the graphene by the chemical reduction of acid treated carbon black and graphite oxide. From the cyclic voltammograms, carbon black-deposited graphene (CB-GR) showed improved electrochemical performance, i.e., current density, quicker response, and better specific capacitance than that of pristine graphene. This indicates that the carbon black deposited onto graphene served as an conductive materials between graphene layers, leading to reducing the contact resistance of graphene and resulted in the increase of the charge transfer between graphene layers by bridge effect.

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A Study on Carbon Reduction Measures in Korean Aquaculture Using the Carbon Offset Market - Focused on the External Projects of the Emission Trading System (ETS) - (양식업부문의 시장유인적 탄소저감 방안에 관한 연구 - 배출권거래제 외부사업을 중심으로 -)

  • Pil-Gyu Jung;Yong-Min Shin
    • The Journal of Fisheries Business Administration
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    • v.55 no.3
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    • pp.27-42
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    • 2024
  • As global climate change impacts become more apparent, countries are implementing various policies to achieve carbon neutrality that can be categorized into direct regulations and market-based indirect regulations. The latter, utilizing economic incentives, is considered more efficient in transforming corporate behavior and promoting voluntary efforts for carbon reduction. In alignment with international trends, South Korea has introduced the Emission Trading System (ETS) in 2015. Despite this, the domestic carbon market remains underdeveloped, with low ETS participation, particularly in the aquaculture sector. In order to activate external projects under the ETS, this study proposes short-term strategies including linking ETS with popular eco-friendly energy distribution projects, developing standardized monitoring techniques, and integrating carbon reduction initiatives with other support mechanisms such as direct payment programs. Long-term strategies focus on developing new methodologies for external projects, promoting the use of renewable energy, and enhancing technologies to reduce energy consumption in aquaculture operations. By implementing these strategies, the study aims to enhance the participation of the aquaculture sector in carbon reduction efforts, contributing to the overall goal of carbon neutrality.

A Policy Suggestion for the Adaptation of Climate Change in Korea (우리나라의 기후변화 대응방안에 관한 정책 제언)

  • Shin, Im Chul;Kim, Yeongsin
    • Atmosphere
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    • v.19 no.1
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    • pp.53-66
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    • 2009
  • The purpose of this study is to describe the roles of carbon dioxide in the climate change, and carbon dioxide reduction policies in some countries. In addition, ways to cope with climate change in Korea are also discussed. Currently, global temperatures are rising due to the carbon dioxide produced by human beings. Global temperatures will rise approximately $6^{\circ}C$ until 2100 if we emit carbon dioxide at a present rate. Temperature rise will affect the terrestrial and oceanic resources, and ultimately influence the socio-economic structures including political stability. Most of the carbon dioxide comes from fossil fuels. Therefore, it is urgent to reduce the use of energy, which comes from fossil fuels. Solving the climate change due to the increases in carbon dioxide is a global problem. Korea should participate in the international community and cooperate with each other in order to reduce the carbon dioxide concentration. No policy was announced for the reduction of carbon dioxide so far. Korea should make a policy for the reduction of carbon dioxide in a specific year compared to that of certain standard year such as 1990 or 2005. Making policy should be based on the scientific result of the amount of carbon dioxide emitted and absorbed. Germanwatch announced the Climate Change Performance Index (CCPI) in order to evaluate an effort to reduce the carbon dioxide for 56 countries which emits 90 % of global carbon dioxide. Ranking for Korea is 51 among 56 countries. This clearly indicates that the appropriate carbon dioxide reduction has not been exercised yet in Korea. Researchers have a moral responsibility to provide updated new ideas and knowledges regarding climate change. Politicians should have a sharp insight to judge the ideas provided by researchers. People need an ethics to reduce the carbon dioxide in every day's life. Scientific research should not be influenced by stress caused by external budget and negative impact of capitalism. Science should be based on the pure curiosity.

Reduction Characteristics of Oxygen Carrier Particles for Chemical-looping Combustor with Different Fuels (매체순환식 가스연소기용 산소공여입자들의 연료별 연소특성)

  • Ryu, Ho-Jung;Kim, Kyung-Su;Park, Yeong-Seong;Park, Moon-Hee
    • Journal of Hydrogen and New Energy
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    • v.20 no.1
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    • pp.45-54
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    • 2009
  • Reduction reactivity and carbon deposition characteristics of three oxygen carrier particles(OCN01, OCN02, OCN03) have been investigated by using hydrogen, methane, syngas, and natural gas as fuels. For all particles, the maximum conversion, the oxygen transfer capacity, and the degree of carbon deposition increased as the reactive carbon contents increased. The reduction rate and the oxygen transfer rate increased as the moles of required oxygen per input gas increased. The change of maximum conversion, reduction rate, oxygen transfer capacity, oxygen transfer rate and degree of carbon deposition for different fuels can be explained consistently by using parameters such as the reactive carbon contents and the moles of require oxygen per input gas.

A Study on the Reduction of Electric Arc Furnace Dust with Carbon (탄소에 의한 전기로 분진의 환원반응에 관한 연구)

  • 진영주;김영진;박병구;이광학;김영홍;이재운
    • Resources Recycling
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    • v.7 no.3
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    • pp.27-35
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    • 1998
  • EAF dust generated from electric arc steelmaking process is classified as "hazardous" materials by tbe environmental regulation because of the existence of water leachable heavy metals such as Fe, Zn, Pb, and Cd. However, Fe and Zn among t the elements in the dust can be recovered to high valuable materials by applying a proper process. Therefore, in order to study t the possibility of recovery of iron from EAF dust, the effect oE carbon content and basicity, of synthesized EAF dust on the reduction rate of iron oxide was studied. Experimental results are as follows: TIle softening and melting temperature of the slag w was illcreased with increasing carbon addition amount [or carbon reduction eqUIvalent. At the carbon addition amount of 100% for carbon reduction equivalent and basicity of 1.7, reduction rate of $Fe_2O$ in the slag was the highest. The reaction order fur reduction of $Fe_2O$ by carbon was nearly first order.

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Preparation of Silicon-Carbon Composite via Magnesiothermic Reduction Method and Its Application to the Anode Material for Lithium Ion Battery (마그네슘열환원법을 이용한 실리콘-탄소 복합재 제조 및 리튬이차전지 음극재로의 이용)

  • Kim, Eudem;Kwon, Soon Hyung;Kim, Myung-Soo;Jung, Ji Chul
    • Korean Journal of Materials Research
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    • v.24 no.5
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    • pp.243-248
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    • 2014
  • Silicon-carbon composite was prepared by the magnesiothermic reduction of mesoporous silica and subsequent impregnation with a carbon precursor. This was applied for use as an anode material for high-performance lithium-ion batteries. Well-ordered mesoporous silica(SBA-15) was employed as a starting material for the mesoporous silicon, and sucrose was used as a carbon source. It was found that complete removal of by-products ($Mg_2Si$ and $Mg_2SiO_4$) formed by side reactions of silica and magnesium during the magnesiothermic reduction, was a crucial factor for successful formation of mesoporous silicon. Successful formation of the silicon-carbon composite was well confirmed by appropriate characterization tools (e.g., $N_2$ adsorption-desorption, small-angle X-ray scattering, X-ray diffraction, and thermogravimetric analyses). A lithium-ion battery was fabricated using the prepared silicon-carbon composite as the anode, and lithium foil as the counter-electrode. Electrochemical analysis revealed that the silicon-carbon composite showed better cycling stability than graphite, when used as the anode in the lithium-ion battery. This improvement could be due to the fact that carbon efficiently suppressed the change in volume of the silicon material caused by the charge-discharge cycle. This indicates that silicon-carbon composite, prepared via the magnesiothermic reduction and impregnation methods, could be an efficient anode material for lithium ion batteries.