• Title/Summary/Keyword: CA15-3

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Effects of Fluoride Additions on Sintering and Microwave Dielectric Properties of CaWO$_4$ (Fluoride 첨가에 따른 CaWO$_4$의 소결 및 고주파 유전특성)

  • 이경호;김용철;방재철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.127-130
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    • 2002
  • In this study, development of a new LTCC material using a non-glassy system was attempted with respect to reducing the fabrication process steps and cost down. Lowering the sintering temperature can be achieved by liquid phase sintering. For LTCC application, the starting material must have quality factor as high as possible in microwave frequency range. And also, the material should have a low dielectric constant for enhancing the signal propagation speed. Regarding these factors, dielectric constants of various materials were estimated by the Clausius-Mosotti equation. Among them, CaWO$_4$ was tamed out the suitable LTCC material. CaWO$_4$ can be sintered up to 98% of full density at 1200$^{\circ}C$ for 3 hours. It's measured dielectric constant, quality factor, and temperature coefficient of resonant frequency were 10.15, 62880GHz, and -27.8ppm/$^{\circ}C$, respectively. In order to modify the dielectric properties and densification temperature, 0.5∼1.5 wt% LiF were added to CaWO$_4$. LiF addition reduced the sintering temperature/time down to 800$^{\circ}C$/10∼30min due to the reactive liquid phase sintering. Dielectric constant lowered from 10.15 to 9.38 and Q x fo increased up to 92000GHz with increasing LiF content.

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Dielectric and Piezoelectric Properties of (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 Ceramics as a Function of Calcination Temperature (하소온도 변화에 따른 (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3 세라믹스의 유전 및 압전 특성)

  • Lee, Kab-Soo;Yoo, Ju-Hyun;Jeong, Woy-Seung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.9
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    • pp.651-655
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    • 2013
  • $(Ba_{0.85}Ca_{0.15})(Ti_{0.9}Zr_{0.1})O_3$ + 0.04 wt% $CeO_2$ lead-free ceramics were synthesized by conventional sintering process and the effect of calcination temperature on microstructure, dielectric and piezoelectric properties were investigated. Improved piezoelectric properties have been observed at $1,125^{\circ}C$ calcination temperature which show the optimal electrical properties, $k_p$~0.457, $d_{33}$~367 pC/N, $Q_m$~158 and $T_c$~$85^{\circ}C$. These results show that the piezoelectric properties can be improved by appropriate calcination temperature.

Behavior of Charged Particles do $(Sr_{0.85}{\cdot}Ca_{0.15})_mTiO_3$ Grain Boundary Layer Ceramics ($(Sr_{0.85}{\cdot}Ca_{0.15})_mTiO_3$ 입계층 세라믹의 하전입자 거동)

  • 김진사;정동효;김상남;박재세;최운식;이준용
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.209-212
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    • 1995
  • In this paper, the $(Sr_{0.85}{\cdot}Ca_{0.15})TiO_3$ of paraelectric grain boundary layer (GBL) ceramics were fabricated. The characteristics of electrical conduction and the thermally stimulated current(TSC) were measured respectively. The region I below 200[V/cm] shows the ohmic conduction, the region II between 200[V/cm] and 1000[V/cm] can be explained by the Pool-Frenkel emission theory, and the region III above 2000[V/cm] is dominated by the tunneling effect. As a result, The origins of these peaks are that the ${\alpha}$ peak observed at $-20[^{\circ}C]$ looks like to be ascribed to the ionization excitation from donor level in the grain, and the ${\alpha}^{\prime}$ peak observed at $-20[^{\circ}C]$ appears to show up by detrap of the trapped carrier of border between the oxidation layer and the grain, and the ${\beta}$ peak observed at $80[^{\circ}C]$ seems to be resulted from hopping conduction of existing carrier in the trap site of the border between the oxidation and second phase.

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Effects of Dietary Calcium Levels on Productive Performance, Eggshell Quality and Overall Calcium Status in Aged Laying Hens

  • An, S.H.;Kim, D.W.;An, B.K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.10
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    • pp.1477-1482
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    • 2016
  • This study was conducted to investigate the effects of diets with varying levels of calcium on egg production, shell quality and overall calcium status in aged laying hens. A total of five hundred 70-wk-old Hy-Line Brown layers were divided five groups and fed one of the five experimental diets with 3.5%, 3.8%, 4.1%, 4.4%, or 4.7% Ca, for 10 weeks. There were no significant differences in feed intake, egg production and egg weight among groups. The cracked eggs were linearly reduced as dietary Ca levels increased to 4.7% (p<0.01). A significant linear improvement for eggshell strength and thickness were determined with increasing dietary Ca levels (p<0.01). The contents of serum Ca and phosphorus were not affected by dietary Ca levels. With increase in dietary Ca levels, the tibial breaking strength slightly increased. There were no significant differences in the tibial contents of ash, Ca and phosphorus among groups. In conclusion, eggshell quality, as measured by appearance, strength and thickness of eggshell, were influenced by dietary Ca content as expected (p<0.05). These results suggested that aged laying hens require relatively higher level of Ca than required levels from current Korean feeding standards for poultry.

Activation Property of Blast Furnace Slag by Calcined Alunite (하소(?燒) 명반석(明礬石)에 의(依)한 고로수쇄(高爐水碎)슬래그의 활성화(活性化) 특성(特性))

  • Kim, Hyung-Seok;Jo, Young-Do;Ahn, Ji-Whan;Kimura, Kunio;Han, Choon
    • Resources Recycling
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    • v.15 no.4 s.72
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    • pp.27-35
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    • 2006
  • In order to use alunite as an activator of blast furnace slag, we studied the hydration characteristics of the calcined alunite and the ground blast furnace slag. The alunite calcined at $650{\cire}C$ consists of KAl($KAl(SO_{4})_{2}$ and $Al_{2}O_{3}$. The calcined alunite reacts with $Ca(OH)_{2}$ and gypsum to form etrringite ($3CaO{\cdot}Al_{2}O_{3}{\cdot}3CaSO_{4}{\cdot}32H_{2}O$) as fellows:$2KAl(SO_{4})_{2}+2Al_{2}O_{3}+13Ca(OH)_{2}+5CaSO_{4}{\cdot}2H_{2}O+73H_{2}O{\rightarrow}3(3CaO{\cdot}Al_{2}O_{3}{\cdot}3CaSO_{4}{\cdot}32H_{2}O)+2KOH$. The $SO_{4}^{2-}$ ions from calcined alunite reacts with CaO in blast furnace slag to from gypsum, which reacts with CaO and $Al_{2}O_{3}$ to from ettringite in calcined alunite-blast furnace slag system. Therefore blast furnace slag can be activated by calcined alunite.

Preparations and characteristics of the ceramic balls for heavy metals absorption and antibacterial activities in the drinking water (음용수중의 중금속흡착과 항균성용 세라믹 볼의 제조 및 특성평가)

  • Park, Chun-Won;Park, Ra-Young;Park, Sun-Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.6
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    • pp.263-268
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    • 2005
  • The ceramic balls impregnated with $20{\sim}40nm$ sized Ag colloid were examined for heavy metals absorption and antibacterial activities in the drinking water. The preparation conditions of ceramic ball that the porosity was excellent were as follows: starting material: 85 wt% $Ca_{10}(PO_4)_6(OH)_2$, binder: 5 wt% PVA and 15 wt% ${\alpha}-Ca_3(PO_4)_2$, heating temperature: $1000^{\circ}C$, duration: 3 hrs. The ceramic balls obtained under these conditions showed specific surface area of $110m^2/g$, pore size of $120{\mu}m$ and porosity of 80%. Also, as the results of a performance test on a rate of adsorbing and removing heavy metals in the drinking water by using the.AAS, heavy metals such as Zn, Mn, Fe and Cu were removed to the extent that their content became 0.03mg/l or lower after 1 day and they showed an excellent bactericidal activity that all coliforms were killed after 3 hrs.

Sealing Ability of Three Different Materials Used as Retrograde Filling

  • Park, Ji-Hoon;Kang, Seung-Bok;Choi, Yong-Hoon;Bae, Ji-Hyun
    • Journal of Korean Dental Science
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    • v.5 no.2
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    • pp.60-67
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    • 2012
  • Purpose: To test the apical leakage prevention performance of three different materials through protein leakage procedures using bovine serum albumin (BSA) and Bradford protein reagent. Materials and Methods: A total of 60 human single-rooted teeth were divided into 4 groups, and conventional root canal filling was done. The root was cut 3 mm from the apex, and a cavity was formed. Proroot MTA (MTA), Fuji II LC (GI), Fuji II LC with XP bond (GIA), and Caviton (CA) were used as experimental materials to fill the cavity in a retrograde filling manner. The extent of BSA leakage was then measured with a ultraviolet visible spectrophotometer 24, 48, and 72 hours after filling. Result: After 24 hours, among the 15 teeth of each group, 2 in MTA, 4 in GI, 3 in GIA, and 7 in CA showed leakage. After 48 hours, 3 in MTA, 5 in GI, 5 in GIA, and 10 in CA had leakage and discoloration. After 72 hours, among the 15 teeth of each group, 3 in MTA, 6 in GI, 5 in GIA, and 10 in CA showed leakage. The leakage in the CA group was greater than that in the MTA group at 48 and 72 hours based on Fisher's exact test (P=0.025), and the difference was statistically significant. Similarly, the leakage in the CA group was greater than that in the MTA group over time based on the Kaplan-Meier survival estimate (P=0.011), and the difference was statistically significant. Conclusion: Glass ionomer, glass ionomer after adhesive application, and MTA all showed leakage. Caviton showed greater leakage compared to MTA 48 and 72 hours after filling, and the difference was statistically significant; thus suggesting that Caviton is not appropriate as retrograde filling material considering its sealing ability.

Food habits of Sand eel, Ammodytes personatus (까나리, Ammodytes personatus의 식성)

  • KIM Yeong-Hye;KANG Yong-Joo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.24 no.2
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    • pp.89-98
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    • 1991
  • Food habits of Sand eel, Ammodytes Personatus, in the costal waters, Shinsudo, Samchunpo, was studied from March to May, 1988. Main food item was Calanus sinicus. Although food diversity increased with age, evenness decreased with age. Importance indices of food items of Paracalanus Parvus and Corycaeus latus were high in younger age. But that of sagitta crassa and Gammaridae were high in older age. As while, that of Ca. sinicus was very high in every age. Food items of A. personatus were equal to all groups except 0.5 month group because it had the complete digestive tract after 1.5 month group.

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Corrosion Control in Water Pipes by Adjusting the Corrosivity of Drinking Water : Effect and impact of the Corrosion Inhibitor (수돗물 부식성 제어를 통한 수도관 부식방지 : 부식억제제별 효과와 영향에 대한 분석)

  • Park, Young-Bog;Park, Ju-Hyun;Park, Eun-Hee;Lee, Jin-Suk;Kim, Hyen-Ton;Choi, Young-June;Chung, Hyen-Mi;Huh, Yu-jeong;Choi, In-cheol
    • Corrosion Science and Technology
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    • v.15 no.6
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    • pp.303-310
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    • 2016
  • The tap water used in Seoul was found to be corrosive. Its corrosivity was effectively reduced by that the additions of alkali agent such as NaOH, $Ca(OH)_2$ and corrosion inhibitor such as $H_3PO_4$. For the corrosion test, carbon steel pipe 50 m long was exposed to the drinking water produced by a pilot plant at $36.5^{\circ}C$, similar to the existing process where it takes about 20 minutes to reduce the initial chlorine content of 0.5 mg/L to 0.05 mg/L. $CO_2$ and $Ca(OH)_2$ was added not only to control the Langelier index (LI) above -1.0 and but also, to increase the duration time of residual chlorine by about 6 times. The persistence effect of residual chlorine was in the order of $H_3PO_4$ > $Ca(OH)_2$ > NaOH. Measurements of weight loss showed that corrosion inhibition was effective in order of $Ca(OH)_2$ > $H_3PO_4$ > NaOH > no addition, where the concentrations of $Ca(OH)_2$ and phosphate were 5 ~ 10 mg/L (as $Ca^{2+}$) and 1 mg/L (as $PO{_4}^{3-}$), respectively.

Compound HRAS/PIK3CA Mutations in Chinese Patients with Alveolar Rhabdomyosarcomas

  • Liu, Chun-Xia;Li, Xiao-Ying;Li, Cheng-Fang;Chen, Yun-Zhao;Cui, Xiao-Bin;Hu, Jian-Ming;Li, Feng
    • Asian Pacific Journal of Cancer Prevention
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    • v.15 no.4
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    • pp.1771-1774
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    • 2014
  • The rhabdomyosarcoma (RMS) is the most common type of soft tissue tumor in children and adolescents; yet only a few screens for oncogenic mutations have been conducted for RMS. To identify novel mutations and potential therapeutic targets, we conducted a high-throughput Sequenom mass spectrometry-based analysis of 238 known mutations in 19 oncogenes in 17 primary formalin-fixed paraffin-embedded RMS tissue samples and two RMS cell lines. Mutations were detected in 31.6% (6 of 19) of the RMS specimens. Specifically, mutations in the NRAS gene were found in 27.3% (3 of 11) of embryonal RMS cases, while mutations in NRAS, HRAS, and PIK3CA genes were identified in 37.5% (3 of 8) of alveolar RMS (ARMS) cases; moreover, PIK3CA mutations were found in 25% (2 of 8) of ARMS specimens. The results demonstrate that tumor profiling in archival tissue samples is a useful tool for identifying diagnostic markers and potential therapeutic targets and suggests that these HRAS/ PIK3CA mutations play a critical role in the genesis of RMS.