• 제목/요약/키워드: C8

검색결과 35,557건 처리시간 0.055초

Pyrolysis Paths of Polybutadiene Depending on Pyrolysis Temperature

  • Choi Sung-Seen;Han Dong-Hun
    • Macromolecular Research
    • /
    • 제14권3호
    • /
    • pp.354-358
    • /
    • 2006
  • Polybutadiene (BR) was pyrolyzed at $540-860^{\circ}C$ and the effect of pyrolysis temperature on variations in the relative abundance of the major pyrolysis products (C4-, C5-, C6-, C7-, and C8-species) was investigated. Formation of the C4-, C5-, C6-, and C7-species competed with that of the C8-species. Relative intensity of the C8-species decreased with increasing pyrolysis temperature, while that of the C5-, C6-, and C7-species increased. Pyrolysis paths were became more complicated with increasing pyrolysis temperature. We suggested the operation of double bond migration and succeeding rearrangements for the formation of the C5- and C7-species and various rearrangements, including a double bond, for the formation of the C6-species at high temperature. The activation energies for the pyrolysis product ratios of(C5+C6+C7)/C4 and C8/C4 were used to explain the competition reactions to form the pyrolysis products.

SiC/C 경사기능재료 증착층의 변화 (Variation of SiC/C FGM Layers)

  • 김유택;정순득;이성철;박진호
    • 한국재료학회지
    • /
    • 제8권6호
    • /
    • pp.477-483
    • /
    • 1998
  • $SiC_{4}$$C_{3}$$H_{ 8}$$H_{2}$$C_{3}$$H_{8}$ $H_{2}$, $CH_{3}$$SiCI_{3}$$CH_{4}$$H_{2}$계를 사용하여 흑연기판 위에 SiC와 SiC/C FGM을 CVD법에 의해 코팅하였다. $SiCI_{4}$$C_{3}$$H_{8}$ $H_{2}$ 계에서 SiC 증착 시 바람직한 수소의 비는 10-30사이였고 결정 배향성은 입력가스의 탄소비에 따라 여러번의 대 반전이 일어났다. 성장조건을 {111} 배향성을 갖도록 조절하는 것이 FGM층간 접착상태를 증진시킬 수 있는 방법으로 판단되었다. $CH_{3}$$SiCI_{3}$C$_{3}$$H_{8}$ $H_{2}$ 계에서는 SiC와 C의 비율을 조절하기가 $SiCI_{4}$$C_{3}$$H_{8} $H_{2}$계를 사용했을 때 보다 용이하였고, FGM 단면 관찰에서 층간의 뚜렷한 경계를 발견할 수 없을 정도로 우수한 층간 접착상태를 보였다.

  • PDF

평활한 완전 8방향 윤곽선과 이의 부호화 기법 (SMOOTHLY PERFECT 8-CONNECTED CONTOUR AND ITS CODING TECHNIQUE)

  • 조성호;김인철;이상욱
    • 한국방송∙미디어공학회:학술대회논문집
    • /
    • 한국방송공학회 1996년도 학술대회
    • /
    • pp.195-198
    • /
    • 1996
  • In this paper, we introduce the notion of the smoothly perfect 8-connected (SP8C) contour and propose a coding technique for the SP8C contours. Based on the contour simplification using the majority filter proposed by Gu[6], SP8C contours are extracted on the contour lattice from the segmented image. By noting that, unlike the perfect 8-connected contours, the SP8C contours are restricted to travel in only 3 different directions along the contours, we also propose two techniques for encoding the SP8C contours. The one is the modified version of the neighbouring direction segment coding by Kandeko[2], while the other is to employ the notion of the entropy coding. From the comparison in terms of the entropy, it is shown that the proposed SP8C contours require les bits in encoding the diagonal contours than the 4-connected contours employed by Gu. And computer simulations reveal that the contours can be efficiently encoded by the proposed technique.

  • PDF

반응성 염료(RB-8, RB-49, RR-218)의 결정화 및 입도분포 특성 (Reactive Dye(RB-8, RB-49, RR-218) in Crystallization and Characteristic of Population Density)

  • 한현각;이종훈;인대영
    • Korean Chemical Engineering Research
    • /
    • 제50권2호
    • /
    • pp.198-203
    • /
    • 2012
  • 염석결정화 방법으로 염료용액으로 부터 염료를 결정화하였다. 이번 연구에서 반응성 염료(RB-8, RB-49, RR-218)의 모액의 용해도와 결정화 속도를 연구하였다. 그 결과 연속식 결정화기에서 반응성 염료(RB-8, RB-49, RR-218)에 대한 결정화 속도식 RB-8에서 결정성장 속도 $G=7.1{\times}10^{-4}{\Delta}C^{0.67}$와 핵생성 속도 $B^0=3.1{\times}10^{15}{\Delta}C[1.2{\times}10^{-8}+{\Delta}C^{0.7}M_T{^2}]$이고 RB-49는 결정성장 속도 $G=5.2{\times}10^{-4}C^{0.3441}$와 핵생성 속도 $B^0=7.2{\times}10^{15}{\Delta}C[3.3{\times}10^{-8}+({\Delta}C)^{0.7}M_T{^2}]$, RR-218의 결정성장 속도 $G=4.4{\times}10^{-4}C^{0.2361}$와 핵생성 속도 $B^0=6.3{\times}10^{15}{\Delta}C[7.9{\times}10^{-8}+({\Delta}C)^{0.7}M_T{^2}]$의 실험식으로 표현할 수 있다. 또한 특성 곡선 법을 적용하여 입도분포를 계산한 결과 실험식과 일치하는 결과를 확인할 수 있었다.

PTMSP/LDH 복합막의 탄화수소 기체투과 특성 (Hydrocarbon Gas Permeation Characteristics of PTMSP/LDH Composite Membranes)

  • 정연임;이현경
    • 멤브레인
    • /
    • 제24권6호
    • /
    • pp.423-430
    • /
    • 2014
  • PTMSP[Poly(1-trimethylsilyl-1-propyne)]에 LDH (layered double hydroxide)의 함량을 0, 1, 3, 5 wt%로 달리하여 PTMSP/LDH 복합막을 제조하고, PTMSP/LDH 복합막의 LDH 함량에 따른 $H_2$, $N_2$, $CH_4$, $C_3H_8$, $n-C_4H_{10}$의 기체투과도와 선택도를 조사하였다. PTMSP/LDH 복합막의 LDH 함량이 0~5 wt%로 증가하면 $H_2$$N_2$의 투과도는 점차 감소하였고, $n-C_4H_{10}$의 투과도는 급격히 증가하였다. 그리고 $CH_4$$C_3H_8$의 투과도는 0~3 wt% 범위에서는 감소하고 3~5 wt% 범위에서는 증가하였다. PTMSP/LDH 복합막의 LDH 함량이 5 wt%로 증가하면 $H_2$$N_2$에 대한 $H_2$, $N_2$, $CH_4$, $C_3H_8$, $n-C_4H_{10}$의 선택도는 점차 증가하였고, $CH_4$에 대한 $C_3H_8$$n-C_4H_{10}$의 선택도는 0~3 wt% 범위에서는 증가하고, 3~5 wt% 범위에서는 감소하였다. PTMSP/LDH 복합막의 $CH_4$$n-C_4H_{10}$의 투과도가 증가하면 $H_2$$N_2$에 대한 $CH_4$$n-C_4H_{10}$의 선택도는 증가하였고, $n-C_4H_{10}$의 투과도가 증가하면 $CH_4$에 대한 $n-C_4H_{10}$의 선택도는 $n-C_4H_{10}$의 투과도 182,000 barrer까지는 증가하다가 그 이상에서는 감소하였다. $C_3H_8$의 투과도가 증가하면 $H_2$$N_2$에 대한 $C_3H_8$의 선택도는 $C_3H_8$의 투과도 46,000~50,000 barrer 범위에서는 감소하고 50,000~52,300 barrer 범위에서 증가하였고 52,300~60,000 barrer 범위에서는 감소하였다. 그리고 $C_3H_8$의 투과도가 증가하면 $CH_4$에 대한 $C_3H_8$의 선택도는 52,300 barrer까지는 급격히 감소하였고, 그 이상에서는 급격히 증가하였다.

Effect of Dietary Protein and Lipid Levels on Compensatory Growth of Juvenile Olive Flounder (Paralichthys olivaceus) Reared in Suboptimal Temperature

  • Cho, S.H.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • 제24권3호
    • /
    • pp.407-413
    • /
    • 2011
  • Effect of dietary protein and lipid levels on compensatory growth of juvenile olive flounder (Paralichthys olivaceus) was determined in suboptimal temperature ($13.4{\pm}1.42^{\circ}C$). Five hundred forty fish averaging 79.2 g were randomly distributed into 27 of 300 L flow-through tanks (20 fish/tank). Nine treatments were prepared in triplicate: fish were hand-fed with control (C) diet for 10 weeks (10WF-C); four fish groups were starved for 1 week and then fed with C, high protein (HP), high lipid (HL) and combined high protein and high lipid (HPL) diets for 9 weeks, referred to as 9WF-C, 9WF-HP, 9WF-HL, 9WF-HPL, respectively; and other four fish groups were starved for 2 weeks and then fed with C, HP, HL and HPL diets for 8 weeks, referred to as 8WF-C, 8WF-HP, 8WF-HL and 8WF-HPL, respectively. Weight gain and specific growth rate of fish in 9WF-HP, 9WF-HPL, 8WF-HP and 8WF-HPL treatments were higher than those of fish in 9WF-HL and 8WF-HL treatments. Feed efficiency of fish in 8WF-HP treatment was higher than that of fish in 9WF-C, 9WF-HL and 8WF-HL treatments. Protein efficiency ratio of fish in 10WF-C, 8WF-C, 8WF-HP and 8WF-HPL treatments was higher that that of fish in 9WF-HL and 8WF-HL treatments. Juvenile olive flounder subjected to 2-week feed deprivation could achieve full compensatory growth with dietary supplementation of protein or combined high protein and high lipid.

Involvement of the Cyclic AMP-Protein Kinase A Pathway in Gap Junctional Communication in Preimplantation Mouse Embryos

  • Haengseok Song;Gye, Myung-Chan;Jun, Jin-Hyun
    • Animal cells and systems
    • /
    • 제2권1호
    • /
    • pp.99-106
    • /
    • 1998
  • In this study, we have examined the role of cAMP in gap junctional communication (GJC) in preimplantation mouse embryos. GJC was monitored by Lucifer Yellow (LY) injected into one blastomere of compacted embryos. The speed of GJC was defined as the time taken for the last blastomere of the embryo to become visibly fluorescent. The median time for 8-cell embrvos (140 sec) was similar to that for 16-cell (135 sec). To determine whether cAMP and cAMP-dependent protein kinase (PKA) are involved in the regulation of GJC, the effects of PKA inhibitor (H8) and cAMP analogues (Rp-cAMP and 8-Br-cAMP) on dye transfer between blastomeres of compacted embryos were examined. Some of the embryos treated with either H8 or Rp-cAMP failed to transfer LY to all blastomeres within 10 min. In contrast, 8-Br-cAMP speeded up fluorescent dye transfer. The median time to fill all blastomeres with LY was 140 sec in untreated controls and 90 sec in siblings treated with 8-Br-cAMP. Inhibition of PKA by H8 or Rp-cAMP induced delay or arrest in embryo development after compaction, but the increase of intracellular cAMP showed no effect. These findings suggest that GJC in preimplantation mouse embryos is regulated by cAMP-PKA pathway and transient interference by PKA inhibitors induces the developmental delay beyond compaction.

  • PDF

누에 번데기의 단백질 추출에 관한 연구 (Effect of Temperature, Time and pH on the Extraction of Protein in a Chrysalis of Silk Worm.)

  • 조철형;차월석;차월석
    • KSBB Journal
    • /
    • 제4권2호
    • /
    • pp.65-68
    • /
    • 1989
  • 누에 번데기의 단백질 추출 조건을 규명하고자 온도, ph및 시간 변화에 따라 추출된 단백질의 총 질소함량을 Kjeldahl법과 원소 분석기를 이용한 결과는 다음과 같다. 1. 누에 번데기의 초단백질 : 23.34%, 조지방 : 15.61%이나, 2. 온도 변화에 따른 ph 4에서 1시간 추출시 6$0^{\circ}C$:6.76%, 8$0^{\circ}C$:7.94%, 10$0^{\circ}C$:8.67%이고 C.H.N corder의 분석결과는 6$0^{\circ}C$:8.08%, 8$0^{\circ}C$:9.52%, 10$0^{\circ}C$:9.72%로서 두 가지 방법에서 수치는 다르지만 온도 상승에 따라 수용성 질소계수가 증가하는 경향임을 알 수 있다. 3. pH변화에 따른 8$0^{\circ}C$에서 1시간 추출시 pH 4:7.94%, pH 6:8.96%, pH : 8:9.70%, pH : 10:10.67%, pH : 12:10.98%로 온도 상승과 같이 pH증가에 따라 증가하는 경향을 보이고 있다. 4.추출시간의 변화에 따른 10$0^{\circ}C$에서 pH 4인경우 1시간:8.67%, 2시간:9.23%, 3시간:9.76%이고, C.H.N. corder의 결과는 1시간:9.72%, 2시간:10.06%, 3시간:10.83%로서 추출 시간이 늘어남에 따라 증가되는 경향을 보이고 있다.

  • PDF

Global Warming Gas Emission during Plasma Cleaning Process of Silicon Nitride Using C-C$_4$F$_8$O Feed Gas with Additive $N_2$

  • Kim, K.J.;Oh, C.H.;Lee, N.-E.;Kim, J.H.;Bae, J.W.;Yeom, G.Y.;Yoon, S.S.
    • 한국표면공학회지
    • /
    • 제34권5호
    • /
    • pp.403-408
    • /
    • 2001
  • In this work, the cyclic perfluorinated ether (c-C$_4$F$_{8}$O) with very high destructive removal efficiency (DRE) than other alternative gases, such as $C_3$F$_{8}$, c-C$_4$F$_{8}$ and NF$_3$ was used as an alternative process chemical. The plasma cleaning of silicon nitride using gas mixtures of c-C$_4$F$_{8}$O/O$_2$ and c-C$_4$F$_{8}$O/O$_2$+ $N_2$ was investigated in order to evaluate the effects of adding $N_2$ to c-C$_4$F$_{8}$O/O$_2$ on the global warming effects. Under optimum condition, the emitted net perfluorocompounds (PFCs) during cleaning of silicon nitride were quantified and then the effects of additive $N_2$ by obtaining the destructive removal efficiency (DRE) and the million metric tons of carbon equivalent (MMT-CE) were calculated. DRE and MMTCE were obtained by evaluating the volumetric emission using. Fourier transform-infrared spectroscopy (FT-IR). During the cleaning using c-C$_4$F$_{8}$O/O$_2$+$N_2$, DRE values as high as (equation omitted) 98% were obtained and MMTCE values were reduced by as high as 70% compared to the case of $C_2$F$_{6}$O$_2$. Recombination characteristics were indirectly investigated by combining the measurements of species in the chamber using optical emission spectroscopy (OES), before and after the cleaning, in order to understand any correlation between plasma and emission characteristics as well as cleaning rate of silicon nitride.silicon nitride.

  • PDF

온실(溫室)가루이의 숙주식물(宿主植物), 발육(發育) 및 주내분포(株內分布)에 관(關)한 연구(硏究) (Studies on Host Plants, Development, and Distribution within Plants of the Greenhouse Whitefly, Trialeurodes vaporariorum(Westwood))

  • 김인수;황창연;김정환;이문홍
    • 한국응용곤충학회지
    • /
    • 제25권4호
    • /
    • pp.201-207
    • /
    • 1986
  • 침입해충(侵入害蟲)인 온실가루이의 분포현황(分布現況), 온도(溫度)가 발육(發育)에 미치는 영향(影響) 및 주내분포(株內分布)에 관(關)한 조사결과(調査結果)는 다음과 같다. 1. 온실가루이는 영구온실내(永久溫室內)의 철쭉, 란타나, 포인세치아 등(等) 27과(科) 39종(種)의 관상식물(觀賞植物)에서 기생(寄生)하였다. 2. 산란전기간(産卵前期間)은 $25^{\circ}C$에서 1.1일(日), 산란기간(産卵期間)은 28.8일(日), 산란후기간(産卵後期間)은 0.5일(日) 성충수명(成蟲壽命)은 26.8일(日)로 $25^{\circ}C$가 적온(適溫)이었고, 숫컷의 성충수명(成蟲壽命)이 약(約) 6일(日) 짧았다. 3. 일당(日當) 산란수(産卵數)는 $25^{\circ}C$에서 9.8개(個), 총산란수(總産卵數)는 305개(個) 였다. 4. 난기간(卵期間)은 $25^{\circ}C$에서 8.2일(日), 유충기간(幼蟲期間)은 8.3일(日), 용기간은 7.5일(日)이었고, 한세대(世代)를 거치는데는 $22^{\circ}C,\;25^{\circ}C,\;30^{\circ}C$에서 각각(各各) 27.5일(日), 23.8일(日), 18.9일(日)로 온도(溫度)가 증가(增加)할수록 짧아지는 경향(傾向)이였다. 5. 난(卵)에서 유충(幼蟲)까지의 발육영점온도(發育零點溫度)는 $8.8^{\circ}C$였다. 6. 난(卵)에서 성충(成蟲)까지의 성공율(成功率)은 $22^{\circ}C,\;25^{\circ}C,\;30^{\circ}C$에 각각(各各) 70.3%, 58.0%, 66.4%였다. 7. 온실가루이 한세대기간(世代期間)동안의 성충(成蟲)과 난(卵)은 상위엽(上位葉)에 유충(幼蟲)은 중위엽(中位葉)에 용은 하위엽(下位葉)에 집중분포(集中分布)하였다.

  • PDF