• Journal of Electrochemical Science and Technology
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• v.15 no.2
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• pp.291-298
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• 2024

Due to its high theoretical capacity, Silicon (Si) has shown great potential as an anode material for lithium-ion batteries (LIBs). However, the large volume change of Si during cycling leads to poor cycling stability and low Coulombic efficiency. In this study, we synthesized Si/Carbon C45:Graphene composites using a ball-milling method with a fixed Si content (20%) and investigated the influence of the C45/Gr ratio on the electrochemical performance of the composites. The results showed that carbon C45 networks can provide good conductivity, but tend to break at Si locations, resulting in poor conductivity. However, the addition of graphene helps to reconnect the broken C45 networks, improving the conductivity of the composite. Moreover, the C45 can also act as a protective coating around Si particles, reducing the volume expansion of Si during charging/discharging cycles. The Si/C45:Gr (70:10 wt%) composite exhibits improved electrochemical performance with high capacity (~1660 mAh g^-1 at 0.1 C) and cycling stability (~1370 mAh g^-1 after 100 cycles). This work highlights the effective role of carbon C45 and graphene in Si/C composites for enhancing the performance of Si-based anode materials for LIBs.

• Proceedings of the KWS Conference
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• 2001.10a
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• pp.134-139
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• 2001

This paper describes the weldability of JIS S45C medium carbon steel (same material with KS SM45C and SAE 1045) for machine structural use by Nd:YAG laser. This material have a limitation to the industrial application in spite of good mechanical characteristics. This is due to its difficult welding work from high carbon contents. We therefore have investigated laser weldability of this material to extend the application of medium carbon steel. The results of this study provide application possibility of Nd:YAG laser welding for medium carbon steel.

• Journal of the Korean Ceramic Society
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• v.45 no.9
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• pp.561-566
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• 2008

Carbon fiber fabric-silicon carbide composites were fabricated by liquid silicon infiltration (LSI) process. The porous two-dimensional carbon fiber fabric performs were prepared by 13 plies of 2D-plain-weave fabric in a three laminating method, [0/90], [${\pm}45$], [$0/90/{\pm}45$] lay-up, respectively. Before laminating, a thin pyrolytic carbon (PyC) layer deposited on the surface of 2D-plain weave fabric sheets as interfacial layer with $C_3H_8$ and $N_2$ gas at $900^{\circ}C$. A densification of the preforms for $C_f-Si-SiC$ matrix composite was achieved according to the LSI process at $1650^{\circ}C$ for 30 min. in vacuum atmosphere. The bending strength of the each composite were measured and the microstructural consideration was performed by a FE-SEM.

• Journal of Korea Foundry Society
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• v.23 no.2
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• pp.86-93
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• 2003

It has been a major concern in the foundry that steel castings manufactured by the evaporative pattern casting process encounter the carbon pick-up problem. A carbon rich layer at the evaporative pattern cast surface is a result of interactions between the gaseous products from foamed polystyrene and the molten metal. The carburized layer with a high hardness makes it difficult to machine the casting. In this study, the influence of the density of EPS pattern and coatings on carbon pick-up phenomena of S25C and S45C commercial carbon cast steel were investigated. As the density of EPS pattern is increased, the carbon concentration of decomposed pattern is increased and the thickness of carburized layer at the surface of steel castings is increased. Also as the density of coatings is increased, the permeability of coatings is decreased and the thickness of carburized layer at the surface of steel castings is increased. S25C steel which has lower original carbon content compared to S45C steel exhibited severe carburization.

• Korean Journal of Food Science and Technology
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• v.37 no.3
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• pp.372-376
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• 2005

Respiratory characteristics and quality of Fuji apple were investigated at critical conditions for dipping treatment in mild hot water ($40-65^^{\circ}C$) to extend freshness. Dipping treatment conditions under which no damages occurred in peel and flesh of apples stored at $0^{\circ}C$ for 1 month after treatment were: 180 min at $40^{\circ}C$, 60 min at $45^{\circ}C$, 45 min at $50^{\circ}C$, 3 min at $55^{\circ}C$, 1 min at $60^{\circ}C$, and 20 sec at $65^{\circ}C$. Internal carbon dioxide concentrations of apples drastically increased immediately after treatments at 40, 45, and $50^{\circ}C$, then decreased to normal level 1 day after treatment at $0^{\circ}C$. Although internal oxygen concentration of apples showed reversed trend to internal carbon dioxide, no significant differences were observed in concentrations of carbon dioxide and oxygen during storage after treatment of apples at 55, 60, and $65^{\circ}C$. Concentration of internal ethylene of apples treated at 40, 45, and $50^{\circ}C$ increased, similarly to that of carbon dioxide upon heat treatment, then, during storage, decreased to below levels of control and apples treated at 55, 60, and $65^{\circ}C$. Firmness of apples treated at 45 and $50^{\circ}C$ were 6.42 and 10.53% higher than that of control at $0^{\circ}C$ after 7 days after treatment.

• Journal of the Korean Ceramic Society
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• v.45 no.7
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• pp.430-437
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• 2008

Porous self-bonded silicon carbide (SBSC) ceramics were fabricated at temperatures ranging from 1700 to $1850^{\circ}C$ using SiC, silicon (Si), and three different carbon (C) sources, including carbon black, phenol resin, and xylene. The effects of the Si:C ratio and carbon source on porosity and strength were investigated as a function of sintering temperature. Porous SBSC ceramics fabricated from phenol resin showed higher porosity than the others. In contrast, porous SBSC ceramics fabricated from carbon black showed better strength than the others. Regardless of the carbon source, the porosity increased with decreasing the Si:C ratio whereas the strength increased with increasing the Si:C ratio.

• Journal of the Korean Society for Precision Engineering
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• v.20 no.7
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• pp.44-55
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• 2003

The Nd:YAG laser process is known to have high speed and deep penetration capability to become one of the most advanced welding technologies. This paper describes the machining characteristics of SM45C carbon steel welding by use of an Nd:YAG laser. In spite of its good mechanical characteristics, SM45C carbon steel has a high carbon contents and suffers a limitation in the industrial application due to the poor welding properties. The major process parameters studied in the present laser welding experiment were position of focus, travel speed and laser power. Optical microscope and SEM were used to investigate the microstructures of the welded zone. The experimental results showed that penetration depth of the welding process increases with laser power. Both the microstructural investigation and the theoretical calculations indicated that materials undergoes a very high heating and cooling cycle during welding process. It was also found that the austenite nucleation takes place at the initial stage and the completion temperature of austenite transformation is much higher than in the case of the arc welding.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.15 no.4
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• pp.40-45
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• 2016

Interrupted cutting has different cutting characteristics compared with continuous cutting. In interrupted cutting, the workpiece has a groove that regularly impacts the cutting tool and workpiece. Therefore, tool damage occurs rapidly, and this increases the cutting force and surface roughness. In this study, we performed interrupted cutting of carbon steel for machine structure (SM45C) using a coated carbide tool (TT7100). To predict the cutting force, we analyzed the experimental results with a regression analysis. The results were as follows: We confirmed that the factors affecting the principal force and radial force were cutting speed, depth of cut, and feed rate. From the multi-regression analysis, we deduced regression equations, and their coefficients of determination were 89.6, 89.27, and 28.27 for the principal, radial, and feed forces, respectively. This means that the regression equations were significant for the principal and radial forces but not for the feed force.

• International Journal of Korean Welding Society
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• v.2 no.1
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• pp.15-20
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• 2002

This paper describes the weldability and mechanical behavior of JIS S45C medium carbon steel (corresponding to KS SM45C and SAE 1045) for machine structures in CW Nd:YAG laser welding. In general, medium carbon steels have a limited application to the industrial fields in spite of good mechanical characteristics. This is due to welding difficulty because of the high carbon contents and impurities in this material. Therefore, in this study the laser weldability of medium carbon steel with adjusted contents of S and P has been investigated in order to extend the application to medium carbon steels. Several experiments and numerical simulations have been conducted to determine the characteristics of mechanical behavior in CW Nd:YAC laser welds. The results of the simulations concur with the experiment results. From the result of this study, the application possibility of CW Nd:YAG laser welding to medium carbon steel has been confirmed. Also, the appropriateness of mechanical behavior simulation has been verified to analyze and predict the welding phenomena.

• Journal of the Korean Society for Nondestructive Testing
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• v.9 no.1
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• pp.77-82
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• 1989

DC potential drop(DCPD) measurement system was made and the optimum measuring conditions have been studied. The room temperature resistivity of commercially available medium carbon steel(S45C) was measured using this technique. DCPD was measured in the specimens which were hardened and tempered at different temperatures. It was found that DCPD reflected the change of the microstructure during tempering very sensitively. It was possible to monitor the stage of tempering of S45C steel nondestructively using DCPD measurement.