• 제목/요약/키워드: C1 reduction

검색결과 3,940건 처리시간 0.034초

Characteristics of Thermal Performance on the Different Ambient Air Temperatures of Green Roof Plants

  • Han, Seung Won;Park, Joon Sung;Kim, Jae Soon;Jeong, Myung Il
    • 환경생물
    • /
    • 제34권4호
    • /
    • pp.272-280
    • /
    • 2016
  • Changes in land use and increase in urban energy consumption influence urban life. This study analyzed the characteristics and patterns of urban heat and presents management schemes to generate a comfortable and sustainable urban environment. The study aimed to demonstrate the positive effects of artificial ground greening on improving the microclimate through evapotranspiration using perennial herbs. We have designed a chamber that could control constant temperature and humidity, measure temperature reductions in each plant and changes in sensible heat and latent heat. This study identified Sedum kamtschaticum as the most effective plant in controlling temperature. At $22^{\circ}C$, $3.2^{\circ}C$ temperature reduction was observed, whereas four other plants showed a $1.5^{\circ}C$ reduction. At $25^{\circ}C$, $2.0^{\circ}C$ temperature reduction was observed. On the other hand, the use of Sedum sarmentosum resulted in the lowest effect. Zoysia japonica is the most commonly used ground covering plant, although the temperature reduction of Lysimachia nummularia was more effective at high temperature conditions. Sensible heat and latent heat were calculated to evaluate the thermal performance of energy. At a temperature >$30^{\circ}C$, L. nummularia and S. sarmentosum emitted high latent heat. In this study, we analyzed the thermal performance of green roof perennial plants; in particular, we analyzed the evapotranspiration and temperature reduction of each plant. Since the substrate depth and types, plant species, and seasonal change may influence temperature reduction and latent heat of green roofs, further studies are necessary.

거리협곡 벽면녹화 조성유형에 따른 미기상 변화 및 열환경 평가 (A Study on Verifying the Effect of Thermal Environment Control of Street Canyons based on Application of Green Wall System)

  • 김정호;최원준;윤용한
    • 한국환경과학회지
    • /
    • 제25권2호
    • /
    • pp.311-322
    • /
    • 2016
  • This study reduced and built Street Canyons created by skyscrapers in order to verify effect of Street Canyons by green wall within the city centre and analysed influence factors on temperature reduction according to applicative types of green wall in the lab. Applicative types were divided into three types such as non- greening type(Case A), one-side greening type(Case B), both side greening type(Case C). The result of analysis of each types showed that average temperature of Case B and Case C is respectively $1.0^{\circ}C$ and $1.7^{\circ}C$ lower than Case A. The result of analysis of WBGT was that the highest temperature was given by Case A($40.2^{\circ}C$) and second one was from Case B($39.8^{\circ}C$) and third one was from ($39.1^{\circ}C$) and in UTCI Case A records the highest temperature of $34.7^{\circ}C$ and Case B provided the second highest temperature of $33.9^{\circ}C$ and Case B gave the lowest temperature of $32.7^{\circ}C$. In PMV the highest temperature of 2.65 was from Case B and second one of 2.61 was from Case A and third one of 2.54 was from Case C. Duncan analysis of each types based on solar radiation and thermal comfort generated that there was analytical significance between Case A and Case B and Case B in terms of each types of average temperature reduction. The significance of thermal comfort in WBGT, MRT, PMV showed non-significance but, In UTCI it was analysed that there was significance between Case C and Case A.

경량모듈형 옥상녹화시스템의 온도저감 및 열수지 평가 (Assessment of Temperature Reduction and Heat Budget of Extensive Modular Green Roof System)

  • 김세창;박봉주
    • 원예과학기술지
    • /
    • 제31권4호
    • /
    • pp.503-511
    • /
    • 2013
  • 본 연구는 돌나물과 한국잔디를 식재한 경량 모듈형 옥상녹화시스템의 온도저감과 열수지를 평가하였다. 식물생육은 초고와 피복율을 측정하였으며, 2012년 8월 2일부터 3일까지 48시간 동안 콘크리트와 옥상녹화 표면, 토양 속, 모듈 하부의 온도와 순복사, 증발산량을 측정하였다. 기온이 $34.6^{\circ}C$로 가장 높았던 8월 3일 15:00시의 표면온도는 콘크리트가 $57.5^{\circ}C$로 가장 높았으며, 그 다음으로 돌나물 $40.1^{\circ}C$, 한국잔디 $38.3^{\circ}C$의 순으로 옥상녹화 조성 시 큰 폭으로 온도가 저감되는 것으로 나타났다. 토양 속과 모듈 하부도 옥상녹화에 의한 온도저감 효과가 나타났으며, 한국잔디가 돌나물보다 온도저감 효과가 큰 것으로 나타났다. 콘크리트 표면과 비교하여 옥상녹화 최고 온도는 약 2시간 정도 지연되는 것으로 나타났다. 표면의 온도저감에는 식물종, 기온, 토양수분이 영향을 미치고, 모듈 하부의 온도저감에는 식물종, 기온, 토양수분, 표면온도가 유의하게 영향을 미친 것으로 나타났다. 열수지 분석결과, 현열은 콘크리트 표면이 가장 높았으며, 옥상녹화 시 감소하는 경향을 보였으며 잠열은 한국잔디가 돌나물보다 높았다. 따라서 온열환경 개선을 위해서는 한국잔디가 돌나물보다 옥상녹화 적용에 더 효과적임을 알 수 있었다.

1.5wt%C 초고탄소 워크롤 제조를 위한 단조 공정 설계: 기공압착 및 접합강도 분석 (Process Design for Manufacturing 1.5wt%C Ultrahigh Carbon Workroll: Void Closure Behavior and Bonding Strength)

  • 임형철;이호원;김병민;강성훈
    • 소성∙가공
    • /
    • 제22권5호
    • /
    • pp.269-274
    • /
    • 2013
  • Experiments and numerical simulations of the incremental upsetting test were carried out to investigate void closure behavior and mechanical characteristic of a 1.5wt%C ultra-high carbon steel. The experimental results showed that the voids become quickly smaller as the reduction ratio increases. The simulation results confirmed this behavior and indicated that the voids were completely closed at a reduction ratio of about 40~45% during incremental upsetting. After the completion of the incremental upsetting tests, the process of diffusion bonding was employed to heal the closed voids in the deformed specimens. To check the appropriate temperature for diffusion bonding, deformed specimens were kept at 800, 900, 1000 and $1100^{\circ}C$ for an hour. In order to investigate the effect of holding time for diffusion bonding at $1100^{\circ}C$, specimens were kept at 10, 20, 30, 40, 50 and 60minutes in the furnace. A distinction between closed and healed voids was clearly established using microstructural observations. In addition, subsequent tensile tests demonstrated that complete healing of a closed void was achieved for diffusion bonding temperatures in the range $900{\sim}1100^{\circ}C$ with a holding time larger than 1 hour.

그래핀 옥사이드(GO)의 환원정도가 PC-GO 화학반응 및 물성에 미치는 영향 (Effects of the Degree of GO Reduction on PC-GO Chemical Reactions and Physical Properties)

  • 박주영;신진환;김연철
    • 공업화학
    • /
    • 제26권1호
    • /
    • pp.53-58
    • /
    • 2015
  • 3 phr의 그래핀 옥사이드(GO)를 포함하는 폴리카보네이트(PC)/GO를 클로로포름에서 용액 혼합하여 응고물 침전한 후 240, 260, $280^{\circ}C$의 이축압출기를 이용하여 PC/GO 복합체를 제조하였다. DSC와 TGA 측정결과 PC/GO 복합체의 유리전이 온도($T_g$)의 변화는 거의 없었고, 분해거동을 통해 확인한 열안정성의 경우 $260^{\circ}C$ 압출시편이 우수하게 나타났다. 동적기계적분석(DMA)을 이용한 저장탄성률 측정결과 PC 대비 PC/GO 복합체의 값이 크게 나타났으며 압출온도별로는 큰 차이가 없는 것을 확인하였다. 이들 결과로부터 환원시간에 따른 PC/RGO 복합체의 압출온도를 $260^{\circ}C$로 고정하였다. GO의 환원시간에 따른 PC/RGO 복합체의 화학반응 정도는 $3000cm^{-1}$ 부근에서 나타나는 C-H 신축진동피크를 통해 확인하였고, 환원시간이 1 h일 때의 GO와 유사한 화학반응 정도를 나타내었다. GO의 환원시간에 따른 PC/GO 복합체의 복소점도(complex viscosity)가 감소하는 것을 확인하였으며, 이는 PC-GO 사이의 화학반응에 의한 분산성에 기인한 것으로 주사전자현미경(SEM)을 통해 확인하였다.

초기 반응단계에서 코크스에 의한 EAF DUST의 고온열적 거동 (High Temperature Thermal Behavior of EAF Dust by Coke at Initial Reaction Stage)

  • 정봉진;배상민;문석민;신형기
    • 자원리싸이클링
    • /
    • 제7권5호
    • /
    • pp.19-25
    • /
    • 1998
  • EAF dust 처리를 위해 RAPID system으로 명명된 Extended Arc Plasma Furnace 공정개발의 기초자료를 확보하기 위해서 EAF dust 처리공정의 초기반응 단계에서 코크스에 의한 EAF dust의 고욘열적거동을 조사하였다. 실험조건은 반응기내의 온도를 1000, 1100, 1200 및 130$0^{\circ}C$로 변화시키고, 각각의 반응온도에 대해서 반응시간이 3, 5, 8 및 12분인 경우에 석회석의 소성, EAF dust 자체의 열분해, EAF dust 혼합시료의 환원 및 휘발거동을 파악하였다. RAPID system에서 EAF dust의 용융 및 환원에 적합한 탄소환원 당량 180%와 염기도 1.7를 고려하여 혼합시료(EAF dust: 코크스 : 석회석=80:10:10 wt%)를 제조하였으며, 각 시료의 크기는 약 0.1mm 이하로써 입도분포는 200 mesh 이하가 80%를 나타내고 있다. 석회석의 소성은 $1100^{\circ}C$이상에서 3분이내에 완결되었으며, EAF dust 자체를 열분해시켰을 경우 $1300^{\circ}C$ 및 12분인 경우에 약 14%의 무게감량이 일어났고, 일부 입자들의 부분적인 소결 및 용융현상이 관찰되었다. EAF dust 혼합시료는 초기 반응단계에서 반응온도 및 반응시간이 증가함에 따라서 무게 감량폭이 더 증가하였으며, $1300^{\circ}C$ 및 12분인 경우에 46%이 무게감량이 일어났다 이와 같이 EAF dust의 휘발 및 환원 거동에 관련된 무게감량 정보는 공정내에서 EAF dust의 처리시간을 결정하여 주고 궁극적으로 대용량의 전기로 분진처리 공정 설계시 전기로 분진의 처리량을 결정하는 주요인자중의 하나로써 사용될 수 있다.

  • PDF

A Continuous Spectrophotometric Assay for NADPH-cytochrome P450 Reductase Activity Using 1,1-Diphenyl-2-Picrylhydrazyl

  • Yim, Sung-Kun;Yun, Su-Jung;Yun, Chul-Ho
    • BMB Reports
    • /
    • 제37권5호
    • /
    • pp.629-633
    • /
    • 2004
  • NADPH-cytochrome P450 reductase (CPR) transfers electrons from NADPH to cytochrome P450, and catalyzes the one-electron reduction of many drugs and foreign compounds. Various forms of spectrophotometric titration have been performed to investigate the electron-accepting properties of CPR, particularly, to examine its ability to reduce cytochrome c and ferricyanide. In this study, the reduction of 1,1-diphenyl-2-picrylhydrazyl (DPPH) by CPR was assessed as a means of monitoring CPR activity. The principle advantage of DPPH is that its reduction can be assayed directly in the reaction medium by a continuous spectrophotometry. Thus, electrons released from NADPH by CPR were transferred to DPPH, and DPPH reduction was then followed spectrophotometrically by measuring $A_{520}$ reduction. Optimal assay concentrations of DPPH, CPR, potassium phosphate buffer, and NADPH were first established. DPPH reduction activity was found to depend upon the strength of the buffer used, which was optimal at 100 mM potassium phosphate and pH 7.6. The extinction coefficient of DPPH was $4.09\;mM^{-1}\;cm^{-1}$. DPPH reduction followed classical Michaelis-Menten kinetics ($K_m\;=\;28\;{\mu}M$, $K_{cat}\;=\;1690\;min^{-1}$). This method uses readily available materials, and has the additional advantages of being rapid and inexpensive.

pH-Dependent Electrochemical Behavior of N-Monosubstituted-4,$4^{\prime}$-Bipyridinium Ions

  • Park, Joon-woo;Kim, Yuna;Lee, Chong-Mok
    • Bulletin of the Korean Chemical Society
    • /
    • 제15권10호
    • /
    • pp.896-900
    • /
    • 1994
  • The pH-dependent reduction behavior of N-monosubstituted-4,4'-bipyridinium ions ($RBPY^+: R=methyl(C_1)$; benzyl; n-octyl; n-dodecyl) has been investigated by electrochemical and spectroelectrochemical techniques. At acidic condition, $RBPY^+$ is protonated and the protonated species are reduced by two consecutive one-electron processes. The $2e^-$ reduced species undergoes a chemical reaction with $H^+$. The second-order rate constant $(k_H)$ of the homogeneous chemical process is $(3.7{\pm}0.3){\times}10^3M^{-1}s^{-1}$ for the two electron reduction product of $C_1BPY^+$. At high pH, the electrode reduction of $RBPY^+$ is one-step $2e^-$ transfer process with concomitant addition of $H^+$, which is confirmed by cyclic voltammetric study using a microdisk electrode.

Vertical Reduction Using Atlantoaxial Facet Spacer in Basilar Invagination with Atlantoaxial Instability

  • Kim, Il-Sup;Hong, Jae-Taek;Sung, Jae-Hoon;Byun, Jae-Hoon
    • Journal of Korean Neurosurgical Society
    • /
    • 제50권6호
    • /
    • pp.528-531
    • /
    • 2011
  • Although posterior segmental fixation technique is becoming increasingly popular, surgical treatment of craniovertebral junctional disorders is still challenging because of its complex anatomy and surrounding critical neurovascular structures. Basilar invagination is major pathology of craniovertebral junction that has been a subject of clinical interest because of its various clinical presentations and difficulty of treatment. Most authors recommend a posterior occipitocervical fixation following transoral decompression or posterior decompression and occipitocervical fixation. However, both surgical modalities inadvertently sacrifice C0-1 and C1-2 joint motion. We report two cases of basilar invagination reduced by the vertical distraction between C1-2 facet joint. We reduced the C1-2 joint in an anatomical position and fused the joint with iliac bone graft and C1-2 segmental fixation using the polyaxial screws and rods C-1 lateral mass and the C-2 pedicle.

SCR 촉매와 AOC 촉매에서 환원제 분사에 따른 $NO_x$ 저감효율과 $NH_3$ 변환효율에 관한 실험적 연구 (An Experimental Study on $NO_x$ Reduction Efficiency and $NH_3$ Conversion Efficiency under Various Conditions of Reductant Injection on SCR and AOC)

  • 동윤희;최정황;조용석;이성욱;이승호;오상기;박현대
    • 한국자동차공학회논문집
    • /
    • 제18권5호
    • /
    • pp.85-90
    • /
    • 2010
  • As the environmental regulation of vehicle emission is strengthened, investigations for $NO_x$ and PM reduction strategies are popularly conducted. Two current available technologies for continuous $NO_x$ reduction onboard diesel vehicles are Selective Catalytic Reduction (SCR) using aqueous urea and lean $NO_x$ trap (LNT) catalysts. The experiments were conducted to investigate the $NO_x$ reduction performance of SCR system which can control the ratio of $NO/NO_2$, temperature and SV(space velocity), and the model gas was used which is similar to a diesel exhaust gas. The maximum reduction efficiency is indicated when the $NO:NO_2$ ratio is 1:1 and the SV is 30,000 $h^{-1}$ in $300^{\circ}C$. Generally, ammonia slip from SCR reactors are rooted to incomplete conversion of $NH_3$ over the SCR. In this research, slip was occurred in 6cases (except low SV and $NO:NO_2$ ratio is 1:1) after SCR. Among 6 case of slip occurrence, the maximum conversion efficiency is observed when SV is 60,000 $h^{-1}$ in $400^{\circ}C$.