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Effect of Alumina Content on the Hot Corrosion of SiC by NaCl and Na2SO4 (NaCl과 Na₂SO₄에 의한 SiC 고온 부식에 미치는 Alumina 첨가량의 영향)

  • 이수영
    • Journal of the Korean Ceramic Society
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    • v.28 no.8
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    • pp.625-625
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    • 1991
  • The specimens for the corrosion test were made by hot-pressing of SiC power with 2 wt% Nl2O3 and 10wt% Al2O3 additions at 2000℃ and 2050℃. The specimens were corroded in 37 mole% NaCl and 63 mole% Na2SO4 salt mixture at 1000℃ up to 60 min. SiO2 layer was formed on SiC and then this oxide layer was dissolved by Na2O ion in the salt mixture. The rate of corrosion of the specimen containing 10 wt% Al2O3 was slower than that of the specimen containing 2 wt% Al2O3. This is due to the presence of continuous grain boundary phase in the specimen containing 10 wt% Al2O3. The oxidation of SiC produced gas bubbles at the SiC-SiO2 interface. The rate of corrosion follows a linear rate law up to 50 min. and then was accelerated. This acceleration is due to the disruption oxide layer by the gas evolution at SiC-SiO2 interface. Pitting corrosion has found at open pores and grain boundaries.

Evaluation of antibacterial activity against Candida albicans according to the dosage of various denture cleansers

  • Bae, Cha-Hwan;Lim, Yun-Kyong;Kook, Joong-Ki;Son, Mee-Kyoung;Heo, Yu-Ri
    • The Journal of Advanced Prosthodontics
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    • v.13 no.2
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    • pp.100-106
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    • 2021
  • PURPOSE. The purpose of this study is to compare the antibacterial activity of currently purchasable denture cleansers against Candida albicans. Materials and methods: This study used tablet-type denture cleansers, PolidentⓇ, CoolingdentⓇ and FittydentⓇ, along with liquid denture cleansers, HexamedineⓇ, ListerineⓇ and Apple vinegarⓇ. The antibacterial activities of denture cleansers were evaluated based on the number of C. albicans and concentrations of the denture cleansers. Results. In the 0.5 × 106 cfu/㎖ culture medium, the C. albicans' death rate of PolidentⓇ was significantly lower than those of FittydentⓇ, HexamedineⓇ, ListerineⓇ, and Apple vinegarⓇ(P<.05). In the 0.5 × 107 cfu/, the C. albicans' death rates of PolidentⓇ and CoolingdentⓇ were significantly lower than those of FittydentⓇ, HexamedineⓇ, ListerineⓇ and Apple vinegarⓇ(P<.05). The C. albicans' death rates of PolidentⓇ and CoolingdentⓇ were significantly decreased at 0.02 g and 0.01 g. The C. albicans' death rate of FittydentⓇ was significantly decreased at 0.005 g (P<.05). The C. albicans' death rate of HexamedineⓇ was significantly decreased at 1/16 dilution. The C. albicans' death rate of ListerineⓇ was decreased at 1/8 dilution, and the antibacterial activity of Apple vinegarⓇ was decreased at 1/4 dilution (P<.05). Conclusion. As the number of C. albicans increased, the antibacterial activities of the denture cleansers decrease. In the tablet-type denture cleanser, all denture cleansers showed 100% C. albicans' death rate when used at a dose of 1 tablet. One denture cleanser showed the same antibacterial effect with only 1/3 of a tablet. In the liquid type denture cleanser, the level of dilution required was different for each denture cleanser.

Effect of Pt-Co/C Cathode Catalyst on Electrochemical Durability of Membrane in PEMFC (PEMFC에서 Pt-Co/C Cathode 촉매가 고분자막의 전기화학적 내구성에 미치는 영향)

  • Sohyeong Oh;Dong Geun Yoo;Myoung Hwan Kim;Ji Young Park;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.61 no.2
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    • pp.189-195
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    • 2023
  • As a PEMFC (Polymer Exchange Membrane Fuel Cell) cathode catalyst, Pt-Co/C has recently been widely used because of its improved durability. In a fuel cell, electrodes and electrolytes have a close influence on each other in terms of performance and durability. The effect on the electrochemical durability of the electrolyte membrane when Pt-Co/C was replaced in the Pt/C electrode catalyst was studied. The durability of Pt-Co/C MEA (Membrane Electrode Assembly) was higher than that of Pt/C MEA in the electrochemical accelerated degradation process of PEMFC membrane. As a result of analyzing the FER (Fluorine Emission Rate) and hydrogen permeability, it was shown that the degradation rate of the membrane of Pt-Co/C MEA was lower than that of Pt/C MEA. In the OCV (Open Circuit Voltage) holding process, the rate of decrease of the active area of the Pt-Co/C electrode was lower than that of the Pt/C electrode, and the amount of Pt deposited on the membrane was smaller in Pt-Co/C MEA than in Pt/C MEA. Pt inside the polymer membrane deteriorates the membrane by generating radicals, so the degradation rate of the membrane of Pt/C MEA with a high Pt deposition rate was higher than Pt-Co/C MEA. When the Pt-Co/C catalyst was used, the electrode durability was improved, and the amount of Pt deposited on the membrane was also reduced, thereby improving the electrochemical durability of the membrane.

Relationship of the Clearance Rate and Nonylphenol Uptake Rate of Three Bivalve Species with Different Size Classes and Temperatures (이매패류 3종의 크기 및 수온에 따른 여수율과 노닐페놀 흡수율의 관계)

  • Yang, Songyi;Lee, Jong Hyeon;Lee, Byeong Gweon
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.18 no.2
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    • pp.80-88
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    • 2013
  • The present study was conducted to evaluate relationship between nonylphenol uptake rate and clearance rate of Ruditapes philippinarum, Corbicula japonica and Mytilus edulis. Variation of the temperature and body size of the bivalves was used to modulate clearance rate and nonylphenol uptake rate in this experiment. Clearance rate and nonylphenol uptake rate experiments were determined for two different size classes of the bivalves (R. philippinarum: 0.35, 0.73 g, C. japonica : 0.047, 0.1000g, M. edulis: 0.30, 0.37 g; mean flesh dry weight) and three different temperature regime (5, 13 and $18^{\circ}C$). Weight-specific clearance rate in all animal size and temperature ranges increased in the order of R. philippinarum, C. japonica and M. edulis. The weight-specific nonylphenol uptake rate did not show specific trend among species. The clearance rate and nonylphenol uptake rate generally decreased with animal size and increased with water temperature. For all three species nonylphenol uptake rate had a strong relationship with clearance rate. For a given clearance rate ranges, the nonylphenol uptake rate was in the order of R. philippinarum > C. japonica > M. edulis. The results suggest that water ventilation capacity of filter-feeding organisms is an important physiological factor controlling uptake rate of dissolved nonylphenol.

Effect of Salts and Temperature upon the Rate and Extent of Aggregation of Casein during Acidification of Milk (산에 의한 우유단백질의 응고속도에 염과 온도가 미치는 영향)

  • Kim, Byung-Yong;Kim, Myung-Hwan;Kinsella, John E.
    • Korean Journal of Food Science and Technology
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    • v.24 no.1
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    • pp.42-48
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    • 1992
  • The rate and extent of coagulation of milk using fast acidification with 0.1 N HCl were monitored by changes in viscosity and turbidity at various temperatures and pH. Also the gelation rate of milk using slow acidification with D-glucono-${\delta}$-lactone was measured in a small strain rheological scanner. Coagulation of milk casein occurred in a specific pH range and was accompanied by an abrupt increase in viscosity at pH 5.0. Acid coagulation rate was enhanced by increasing temperature from $20^{\circ}C{\sim}50^{\circ}C$, and the maximum rate was shown around pH 5.0. The addition of salt ($CaCl_{2}$) reduced the maximum coagulation rate at all temperature ranges and shifted the pH ranges for maximum coagulation rate and the onset pH of coagulation. The onset of gelation and the rate of network formation during slow acidification were facilitated by Cl ion, but suppressed by SCN-ion, as indicated by the rate of rigidity development. The susceptibility to syneresis was greater in the gel made at lower temperature and around pH 4.6, while preheated milk at $90^{\circ}C$ for 5 min prior to acidification showed the same syneresis profile at all heating temperatures ($60{\sim}90^{\circ}C$).

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The effect of nitrogen flow rate in a predeposition with Boron nitride (보론 나이트라이드를 사용하는 Predeposition 공정에서 질소류량의 영향)

  • 박형무;김충기
    • 전기의세계
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    • v.30 no.4
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    • pp.227-230
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    • 1981
  • The variation of sheet resistance and the reduction of masking oxide thickness with the flow rate of nitrogen gas has been measured in Boron predeposition process with Planar Diffusion source, BN-975. At 900.deg. C, the sheet resistance varied as much as 75% when the nitrogen flow rate was changed from 0.4 liters/min to 2.0 liters/min. At 975.deg. C, however, only 12% of sheet resistance variation was observed under the same flow rate change. The reduction of masking oxide thickness at 975.deg. C for a 5 min predeposition was 600 nm when the nitrogen flow rate was 0.4 liters/min. When the flow rate incresased to 1.9 liters/min, however, only 100nm of masking oxide was consumed in a similar predeposition process.

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Investigation on the selection of capillary tube for the alternative refrigerant R-407C (대체냉매 R-407C의 모세관 선정에 관한 연구)

  • 김용환;김창년;박영무
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.1
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    • pp.56-65
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    • 1998
  • In this paper, experimental investigation of capillary tube performance for R-407C is performed. The experimental setup is made of real vapor-compression refrigerating system. In this study, mass flow rate is measured for capillary tubes of various diameter and length as inlet pressure and degree of subcooling are changed. These data are compared with the results of a numerical model. The mass flow rates of the numerical model are less than by 14% compared with the measured mass flow rates. It is found that mass flow rate and length for R-407c are less than those of R-22 under the same condition. Also based on this experimental study and the numerical model, a set of capillary tube selection charts for R-407C is constructed.

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The Effect of the Changing of C-O-C to C-S-C and C=O to C=S on Reactivity of 4-Nitrophenyl Benzoate with Alkali Metal Ethoxides in Ethanol

  • Kwon, Dong-Sook;Park, Hee-Sun;Um, Ik-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.12 no.1
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    • pp.93-97
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    • 1991
  • Rate constants have been measured spectrophotometrically for the reactions of alkali metal ethoxides with 4-nitrophenyl benzoate, S-4-nitrophenyl thiobenzoate and 4-nitrophenyl thionbenzoate in ethanol at 25$^{\circ}$C. Substitution of S for O in the leaving group has not affected reactivity significantly, while the effect of the similar replacement in the acyl group has led to rate decrease by a factor of 10, although pronounced rate enhancements have been expected for both systems. The replacement of O by a polarizable S has also influenced the reactivity of the esters toward alkali metal ethoxides, i.e. the reactivity decreases as the size of the metal ion decreases. The alkali metal ions have showed inhibition effect instead of catalytic effect which would have been expected for the present system. The effect of replaced sulfur atom on the reactivity for the present system is attributed to the nature of hard and soft acids and bases.

Effect of Temperature and Daylength on Growth and Bolting of Angelica gigas NAKAI (온도(溫度) 및 일장조건(日長條件)에 따른 참당귀 생육특성(生育特性)과 추대현상(抽臺現象))

  • Ahn, Sang-Deuk;Yu, Chang-Youn;Seo, Jeong-Sik
    • Korean Journal of Medicinal Crop Science
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    • v.2 no.1
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    • pp.20-25
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    • 1994
  • This study was carried out to investigate the effect of temperature and daylength on the bolting of Angelica gigas Nakai for decreasing the rate of bolting.Seedlings were transplanted on early December to the PVC pot(1 /1000) in the greenhouse con­trolled the temperature of 15, 20 and $25^{\circ}C$, and the daylength of 8, 12, and 16hrs. Growth of aerial parts, bolting rate and root characteristics of A. gigas were investigated. Seedlings of A. gigas untreated with low temperature were nomally emerged, bolted and flowered in maturing stage. In this results, it was assumed that A. gigas was low sensitive to low temperature. The early growth stage was good at $20^{\circ}C\;and\;25^{\circ}C$, but the late growth was effective at $15^{\circ}C\;and\;20^{\circ}C$. The bolting rate was the highest at $20^{\circ}C$ while the root weight was the lowest. Although the bolting rate was high at $15^{\circ}C$, the yield was increased by the delay of bolting and flowering stage. The bolting rate was increased in the longer daylength and showed more sensitive to the daylength condition than to the temperature. Thus, A. gigas cultivated in gully field with cool temperature or under the shading light could be reduced could the bolting rate.

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Filtration of Red Tide Dinoflagellates by an Intertidal Bivalve, Glauconome chinensis Gray: An Implication for the Potentials of Bivalves in Tidal Flats

  • Lee Chang-Hoon;Song Jae Yoon;Chung Ee-Yung
    • Fisheries and Aquatic Sciences
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    • v.6 no.2
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    • pp.66-73
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    • 2003
  • To understand the physiology of a suspension-feeding bivalve and its potential impacts on the dynamics of red tides on tidal flats, rates of clearance and ingestion of Glauconome chinensis were measured as a function of algal concentration, when the bivalve was fed on a nontoxic strain of red tide dinoflagellate Prorocentrum minimum, Cochlodinium polykrikoides or Scrippsiella trochoidea. With increasing algal concentration, weight-specific clearance rate increased rapidly at lower concentrations and after reaching the maximum at ca. 0.2 to 1.0 mgC/L, it decreased at higher concentrations. Maximum clearance rate was nearly equal for different algal species and ranged between 2.1 and 2.6 L/g/hr. Weight-specific ingestion rate also increased at lower algal concentrations but saturated at higher concentrations. Maximum ingestion rate was 2 to 10 fold different with different algal species: S. trochoidea (10.1 mgC/g/hr), P. minimum (3.9 mgC/g/hr), and C. polykrikoides (0.99 mgC/g/hr). Nitrogen and protein content showed that S. trochoidea is the best among the tested three red tide dinoflagellates. The maximum filtration capacity, calculated by combining the data on ingestion rate from laboratory experiments and those from the field for the density of the bivalve and the red tide dinoflagellates was 4.7, 1.4, and 25.3 tons/m2/day for P. minimum, C. polykrikoides, and S. trochoidea, respectively. It is hypothesized that the abundant suspension-feeding bivalves in tidal flats can effectively mitigate the outbreak of red tides.