• Title/Summary/Keyword: C-S-H phase

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A Study on Design of Controller Gain for PWM Converter (PWM 컨버터 제어기 이득의 해석적 설계)

  • Gho J.S.;Cho J.S.;Kang B.H.;Choe G.H.;Kwak C.H.;Chung S.E.
    • Proceedings of the KIPE Conference
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    • 2001.07a
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    • pp.491-495
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    • 2001
  • Compare with diode or thyristor bridge AC/DC converter, the 3 phase PWM converter has some merits of low THD and unit power factor. So, in many critical application like as UPS, using PWM converter is the trends. 3 phase PWM converter had been studied widely already. But analytical design procedure can not found from publication for hardware design and controller design. So, in this paper, 3 phase PWM converter analysis review was given. And from the DC analysis result, parameter design was done. From the AC model, the voltage controller and current controller was designed. The gain of controllers was calculated by analytical method.

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The Effect of Thermomechanical Treatment on the Transformation Characteristics and Mechanical Properties in a Cu-Al-Ni-Ti-Mn Alloy (Cu-Al-Ni-Ti-Mn 합금의 변태특성 및 기계적 성질에 미치는 가공열처리의 영향)

  • Kim, C.D.;Lee, Y.S.;Yang, G.S.;Jang, W.Y.;Kang, J.W.;Baek, S.N.;Gwak, S.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.2
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    • pp.145-156
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    • 1999
  • The distribution of the second phase, the change of transformation temperature and mechanical properties with thermomechanical treatment conditions were investigated by metallography, calorimetry, EDS, tensile test and fractography in a Cu-Al-Ni-Ti-Mn alloy. The cast structure revealed Ti-rich precipitates($X_L$ phase) between dendrite arms, which have been identified as $(Cu,Ni)_2TiAl$ intermetallic compounds. By homogenizing above $900^{\circ}C$, the $X_L$ phase was melted in the matrix, while the Xs phase was precipitated in matrix and the volume fraction of it was increased. When hot-rolled specimen was betatized below $750^{\circ}C$, recrystallization could not be observed. However, the specimen betatized above $800^{\circ}C$ was recrystallized and the grain size was about $50{\mu}m$, while Xs phase was precipitated in matrix. With raising betatizing temperature, $M_s$ and $A_s$ temperatures were fallen and transformation hysteresis became larger. The strain of the specimen betatized at $800^{\circ}C$ was 8.2% as maximum value. The maximum shape recovery rate could be obtained in the specimen betatized at $800^{\circ}C$ but it was decreased due to the presence of Xs phase with increasing betatizing temperature.

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Analysis of Nanostructural Deformation Behavior of Cement Clinker Substituting High-volume Fly ash by Pair Distribution Function (원자짝 분포 함수를 이용한 플라이애시를 대량 치환한 시멘트 클링커의 나노 구조 변형 거동 해석)

  • Jee, Hyeon-Seok;Park, Jae-Yeon;Bae, Sung-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.112-113
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    • 2019
  • Recently, supplementary cementitious materials such as blast-furnace slag, fly ash and silica fume have been widely used as substitutes for cementitious materials. In this study, the deformation behavior of compressive loading of C3S paste with 50% fly ash was analyzed by X-ray scattering data and pair distribution function analysis. The obtained results were compared with 131-day-old pure C3S paste. The Ca(OH)2 of the C3S-FA paste showed almost complete elastic behavior, consistent with the deformation behavior of the r-range of 20 to 40, and the C-S-H phase contributed to the range of PDF r-range of less than 20. In addition, C-S-H of C3S-FA showed greater deformation resistance than C3S paste.

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Theoretical Studies on the Gas-Phase Pyrolysis of Esters The effect of ${\alpha}$- and ${\beta}$-methylation of Ethyl Formates

  • Ikchoon Lee;Ok Ja Cha;Bon-Su Lee
    • Bulletin of the Korean Chemical Society
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    • v.11 no.1
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    • pp.49-54
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    • 1990
  • The gas-phase thermolysis reactions of ${\alpha}$- and ${\beta}$-methylated ethyl formates, Y = $CH-X-CHR_1CH_2R_2$ where X = Y = O or S and $R_1\;=\;R_2$ = H or $CH_3$, are investigated theoretically using the AM1 method. The experimental reactivity order is reproduced correctly by AM1 in all cases. The thermolysis proceeds through a six-membered cyclic transition state conforming to a retro-ene reaction, which can be conveniently interpreted using the frontier orbital theory of three-species interactions. The methyl group substituted at $C_{\alpha}\;or\;C_{\beta}$ is shown to elevate the ${\pi}$-HOMO of the donor fragment (Y = C) and depress the ${\sigma}^{\ast}$-LUMO of the acceptor fragment ($C_{\beta}$-H), increasing the nucleophilicity of Y toward ${\beta}$-hydrogen which in turn increases the reactivity. The two bond breaking processes of the $C_{\alpha}$-X and $C_{\beta}$-H bonds are concerted but not synchronous so that the reaction takes place in two stages as Taylor suggested. The initial cleavage of $C_{\alpha}$-X is of little importance but the subsequent scission of $C_{\beta}$-H occurs in a rate determining stage.

Characterization of the Galvanizing Behavior Depending on Annealing Dew Point and Chemical Composition in Dual-Phase Steels

  • Shin, K.S.;Park, S.H.;Jeon, S.H.;Bae, D.C.;Choi, Y.M.
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.247-253
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    • 2010
  • The characteristics of selective oxidation prior to hot-dip galvanizing with the annealing atmosphere dew point and chemical composition in dual-phase steels and their effect on the inhibition layer formation relevant to coating adhesion have been studied using a combination of electron microscopic and surface analytical techniques. The annealed and also galvanized samples of 3 kinds of Si/Mn ratios with varied amounts of Si addition were prepared by galvanizing simulator. The dew point was controlled at soaking temperature $800^{\circ}C$ in 15%$H_2$ -85%$N_2$ atmosphere. It was shown that good adhesion factors were mainly uniformity of oxide particle distribution of low number density and low Si/Mn ratio prior to hot-dip galvanizing. Their effect was the greatly reduced coating bare spots and the formation of uniform inhibition layer leading to good adhesion of Zn overlay. The mechanism of good adhesion is suggested by two processes: the formation of inhibition layer on the oxide free surface uncovered with no $SiO_2$-containing particles in particular, and the inhibition layer bridging of oxide particles. The growth of inhibition layer was enhanced markedly by the delayed reaction of Fe and Al with the increase of Si/Mn ratio.

Precipitation Behavior of Laves Phase and Mechanical Properties of 10%Cr Ferritic Heat-resistant Steel Applied to the Power Plants (발전플렌트용 10Cr페라이트 내열강의 라베스상 석출거동 및 기계적 성질)

  • Kang, C.Y.;Nam, K.W.;Kim, H.J.;Kim, C.G.;Bae, D.S.;Lee, J.M.
    • Journal of Power System Engineering
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    • v.5 no.1
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    • pp.97-103
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    • 2001
  • The present study was investigated changes of precipitation behaviour of laves phase in ferrite single phase and ferrite-martensite dual phase and the mechanical properties of 10%Cr ferritic alloys. In the ferrite phase, laves phase was mainly precipitated, whereas in the martensite phase, carbide was preferentially formed during the initial stage of aging and with increasing aging time. Laves phase and carbide were simultaneously precipitated by precipitation of laves phase at around carbide. Strength and toughness were lowered by the disk-type precipitator in the initial stage of aging and toughness was recovered with increasing of aging time and then, decreasing by precipitation of laves phase.

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A simple structured voltage disturbance generator for power quality improving devices (전력품질 개선장치를 위한 간단한 구조의 전압변동 발생기)

  • Lee, B.C.;Choi, S.H.;Paeng, S.H.;Nho, E.C.;Kim, I.D.;Chun, T.W.;Kim, H.G.
    • Proceedings of the KIPE Conference
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    • 2005.07a
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    • pp.552-554
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    • 2005
  • This paper deals with a simple structured voltage disturbance generator for power quality improving devices. The proposed generator can be applied to the performance test of custom power devices. Voltage sag, swell, outage, unbalance and phase jump after outage are provided by the generator. The improving phase jump operating principle of the generator is described and analysed. The usefulness of the generator is verified through simulation.

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Electrically Conductive Silicon Carbide without Oxide Sintering Additives

  • Frajkorova, Frantiska;Lences, Zoltan;Sajgalik, Pavol
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.342-346
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    • 2012
  • This work deals with the preparation of dense SiC based ceramics with high electrical conductivity without oxide sintering additives. SiC samples with different content of conductive Ti-NbC phase were hot pressed at $1850^{\circ}C$ for 1 h in Ar atmosphere under mechanical pressure of 30 MPa. The conductive phase is a mixture of Ti-NbC in weight ratio of Ti/NbC 1:4. Composite with 50% of conductive Ti-NbC phase showed the highest electrical conductivity of $30.6{\times}10^3\;S{\cdot}m^{-1}$, while the good mechanical properties of SiC matrix were preserved (fracture toughness 4.5 $MPa{\cdot}m^{1/2}$ and Vickers hardness 18.7 GPa). The obtained results show that use of NbC and Ti as sintering and also electrically conductive additives is appropriate for the preparation of SiC-based composite with sufficient electrical conductivity for electric discharge machining.

Effects of Hydration Treatments on the Phase Transition of Anodic Aluminum Oxide Layers (알루미늄 양극산화 피막의 상전이에 미치는 수화처리의 영향)

  • Joo, E.K.;Kim, S.S.;Oh, H.J.;Cho, S.H.;Chi, C.S.
    • Korean Journal of Materials Research
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    • v.12 no.7
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    • pp.540-544
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    • 2002
  • Hydration treatments were performed on the pure aluminum substrate at $100^{\circ}C$ followed by anodizing and heat treatments on the layers. The transformation behaviors of the oxide layers according to the hydration treatment were studied using TEM, XRD, RBS etc. Above $90^{\circ}C$ the hydrous oxide film could be formed, which were turned out to be hydrous oxides(AlOOH $nH_2$O). The anodization on the hydrous oxide film was more effective for the transition of amorphous anodic oxides to the crystalline $\Upsilon-Al_2$ $O_3$ comparing with the case for anodizing on the aluminum substrate without hydration treatment And additional heat treatments were also helpful for the acceleration of the transformation of the hydrous oxide to $\Upsilon-Al_2$ $O_3$. During the heat treatment the interface between $\Upsilon-Al_2$ $O_3$and the hydrous oxide layers migrated to the outer side of hydrous layer.