• Title/Summary/Keyword: C-M diagrams

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PERIOD VARIATION OF EROS ECLIPSING BINARY SYSTEMS IN THE LARGE MAGELLAN CLOUD

  • RITTIPRUK, P.;HONG, K.S.;KANG, Y.W.
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.211-214
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    • 2015
  • We investigated the period variation for 79 eclipsing binary systems using 20 years (1990-2009) of EROS, Macho, and OGLE survey observations. We discovered 9 apsidal motions, 8 mass transfers, 5 period increasing and decreasing systems, 12 light-travel-time effects, 5 eccentric systems and 40 other systems showing no period variations. We select 3 representative eclipsing binary systems; EROS 1052 for apsidal motion, EROS 1056 for mass transfer, and EROS 1037 for the light-travel-time effect. We determine the period variation rate (dP/dt), orbital parameters of the 3rd body (e3, ${\omega}_3$, $f(m_3)$, $P_3$, $T_3$), apsidal motion parameters ($d{\omega}/dt$, U, Ps, Pa, e) and apsidal motion period by analyzing the light curves and O-C diagrams.

Effect of Ethanol on the Protolytic Properties of the Vitamins B Group

  • Ghasemi, J.;Shiri, F.
    • Journal of the Korean Chemical Society
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    • v.51 no.1
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    • pp.21-30
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    • 2007
  • A multiwavelength spectrophotometric titration method was applied to study protolytic constants of four water-soluble vitamins, folic acid(vitamin B9 or B0), thiamine(vitamin B1), riboflavin(vitamin B2) and pyridoxal (vitamin B6) in binary ethanol-water mixtures at 25oC and an ionic strength of 0.1M NaNO3. The protolytic equilibrium constants, spectral profiles, concentration diagrams and also the number of components has been calculated from the curve fitting of the pH-absorbance data with appropriate mass balance equations by an established factor analysis model. DATAN program was used for determination of acidity constant and SPECFIT program was used for calculation of standard deviations and partial correlation coefficients. A glass electrode calibration procedure based on the four parameter equation pH=α+SpcH+JH+[H+]+ JOH-Kw/[H+] based on the Gran,s plots was used to obtain pH-readings in the concentration scale (pcH). The effect of the solvent on the protolytic constants was discussed.

Emulsion Properties of Pseudo-Ceramide PC104/Water/Polyoxyethylene Cholesteryl Ether and Polyoxyethylene Cetyl Ether Mixtures.

  • Kim, Do-Hoon;Oh, Seong-Geun;Lee, Young-Jin;Kim, Youn-Joon;Kim, Han-Kon;Kang, Hak-Hee
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.330-342
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    • 2003
  • The formation of emulsions and micelles in water/ceramide PC104/CholE $O_{20}$/C$_{16}$E $O_{20}$ and water/ceramide PC104/CholE $O_{20}$ mixtures was investigated through the phase behavior studies. The phase diagrams showed the existence of micelle and emulsion regions in both systems. The mixed surfactant system (CholE $O_{20}$/C$_{16}$E $O_{20}$) showed the wider micellar and emulsion regions than the single surfactant system (CholE $O_{20}$). From FT-IR measurements, it was found that the polyoxyethylene (POE) groups of surfactants formed the hydrogen bonds with amido carbonyl group in ceramide PC104. This result indicated that the hydrophilic part (EO) of surfactants could stabilize the lamellar structure and emulsion of ceramide PC104. The mixed surfactant system (CholE $O_{20}$/C$_{16}$E $O_{20}$) resulted in the smaller emulsion droplet size due to the effect of curvature at the interface, thus further increasing emulsion stability. With the penetration of $C_{16}$E $O_{20}$into the interfacial layer of surfactants in emulsion, the curvature of the interface might be altered for the formation of smaller emulsion droplets. The mixed surfactant system could incorporate up to 4 wt. % of ceramide PC104 into emulsion more than single surfactant system.ystem.m.

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Phytoplankton and Bacterioplankton in the Intertidal and Subtidal Waters in the Vicinity of Kunsan (군산부근 조간대 및 조하대역에서의 식물플랑크톤과 Bacterioplankton)

  • Lee, Won Ho;Lee, Gean Hyoung;Choi, Moon Sul;Lee, Da Mi
    • 한국해양학회지
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    • v.24 no.3
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    • pp.157-164
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    • 1989
  • Quantitative species distribution and primary productivity of phytoplankton were studied monthly from August, 1987 to July, 1988 along with the quantitative distribution of total heterotrophic bacterioplankton and three groups of physiologically chracteristic bacterioplankton in the intertidal and subtidal waters off Kum River Estuary, Yellow Sea. A total of 121 phytoplankton taxa including 102 diatoms occurred, and cell concentration ranged from 15 to 5451 (cells/ml). The great spatio-temporal variations of the number of phytoplankton species and cell concentration well reflected the environmental differences between the intertidal and subtidal waters. Primary productivity (in Piopt, mgC/$m^3$/hr) ranged from 0.6 to 27.3. Just after the phytoplankton bloom (March) Piopt was very low in April at station 1, where amylolytic bacterioplankton also showed quite low population density. The peaks of primary productivity were not always coincided with those of phytoplankton standing crop. The ratio of Piopt's between samples well indicated the environmental differences between the intertidal and subtidal waters. Little characteristic trend was found in the scatter diagrams of phytoplankton standing crop along the population densities of total heterotrophic bacterioplankton and the three groups of physiologically characteristic bacterioplankton. In summer the phytoplankton standing crop was minimum in contrast with the high population density of bacterioplankton, which implies the influx of much allochthonous orgainc matter from Kum River. The scatter diagrams of Piopt along bacterioplankton population density revealed some phenomena there. Piopt had highly positive correlation with the population density of amylolytie bacterioplankton($R^2$=0.84) and that of lipolytic bacterioplankton($R^2$=0.70) while total heterotrophic bacterioplankton and proteolytic bacterioplankton had lesser correlations with Piopt. From the regression lines the increase of unit Piopt (mgC/$m^3$/hr) in the study area was calculated to mean the increase of $9.0{\times}10$ cells/ml and $8.0{\times}10$ cells/ml of amylolytic bacterioplankton and lipolytic bacterioplankton, respectively.

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High Pressure Phase Behavior in the Binary Polyethylene/Butane and Polyethylene/Dimethyl Ether Systems (이성분 폴리에틸렌/부탄과 폴리에틸렌/디메틸 에테르계의 고압 상거동)

  • Jeon, Nam-Seok;Byun, Hun-Soo
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.761-766
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    • 1999
  • In this paper, high pressure phase behavior in the binary polyethylene/butane and polyethylene/dimethyl ether has been studied. The pressure-temperature diagrams in polyethylene/butane were shown by increasing concentration for molecular weight standards, that is, $M_w=700,\;1000$ and 2000. It is found that the temperature and the pressures go up with increasing in concentrations for each molecular weight, but the latter lower in concentrations over 16 wt % polyethylene. In addition, the phase behaviors for each molecular weights with about 5 wt % polyethylene are shown in pressure-temperature, and pressures increase with increasing in molecular weight($M_w=700,\;1000$, and 2000). The phase behaviors in polyethylene/dimethyl ether are determined according to its molecular weight, and are shown for a range of pressures of 40~280 bar and temperatures of about $120{\sim}220^{\circ}C$. It is shown that in pressure-temperature of polyethylene/dimethyl ether the pressure increases with increasing in polyethylene molecular weight, and the difference in pressure for each molecular weight shows by about 60 bar. The gap in pressure between polyethylene/butane and polyethylene/dimethyl ether system with 5 wt % polyethylene for each molecular weight standards indicates about 25(700), 90(1000), and 100 bar(2000), respectively.

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Petrochemistry of Mesozoic Granites in Wolchulsan Area (월출산지역에 분포하는 중생대 화강암류에 대한 암석화학적 연구)

  • Kim, Cheong-Bin;Yoon, Chung-Han;Kim, Jeong-Taek;Park, Jay-Bong;Kang, Sang-Won;Kim, Dong-Ju
    • Economic and Environmental Geology
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    • v.27 no.4
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    • pp.375-385
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    • 1994
  • The studied area is composed of Precambrian gneiss complex, middle Jurassic biotite granite, late Cretaceour sediments, volcanics and pink feldspar granite. Characteristic minerals of the biotite granite is plagioclase and hornblende whereas the pink feldspar granite is pink feldspar (perthite) and quartz. Plagioclase compositions of the biotite granite and the pink feldspar granite are oligoclase to calcic andesine ($An_{18-44}$) and sodic albite ($An_{0.5-5.0}$), respectively. In the variation diagrams of the Harker and normative Q-Or-Pl diagram, the biotite granite belongs to the category from granodiorite to granite, the pink feldspar granite from nomal to late granite. The values of D.I. L.I. and alkalinity of the pink feldspar granite are higher than those of the biotite granite. While CaO is enriched in the biotite granite, $K_2O$ is enriched in the pink feldspar granite. The ratio of $K_2O/Na_2O$ which indicates the relative ratio of alkali is 1.06 in the pink feldspar granite, and 0.86 in the biotite granite. In A-M-F and N-C-K diagrams both these granites are plotted in peraluminus granite ($Al_2O_3$>$Na_2O+K_2O+CaO$) region, assigned to calc alkaline series and alkaline series respectively. Put into the form of A-C-F diagram, the biotite granite falls under I-type, and the pink feldspar granite S-type. On the base of whole rock ratios of $Fe^{+3}/Fe^{+2}+Fe^{+3}$ and $^{87}Sr/^{86}Sr$ for the granites in studied area, the biotite granite indicates ilmenite series (0.26) and S-type and/or contaminated I-type ($0.72020{\pm}0.00050$), the pink feldspar granite magnetite series (0.44) and I-type ($0.70826{\pm}0.00020$).

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Effects of Sulfobutyl Ether $\beta$-Cyclodextrin on Physicochemical Properties of Dexamethasone Dipropionate

  • Moon, Jee-Hyun;Oh, Ik-Sang;Chun, In-Koo
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1997.04a
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    • pp.116-116
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    • 1997
  • Complex formation of practically insoluble dexamethasone dipropionate (DDP) with ${\beta}$-cyclodextrin (${\beta}$-CD), dimethyl-${\beta}$-cyclodextrin (DMCD), trimethyl-${\beta}$-cyclodextrin (TMCD), 2-hydroxypropyl-${\beta}$-cyclodextrin (HPCD) and sulfobutyl ether ${\beta}$-cyclodextrin (SBCD) in water was investigated by solubility method at various temperatures. Water solubility of DDP was found to be 1.78 $\mu\textrm{g}$/$m\ell$ at 37$^{\circ}C$. Propylene glycol (PG)-water cosolvent increased the solubility of DDP, but the solubilization was not sufficient (8.93 $\mu\textrm{g}$/$m\ell$ in 20% PG). The addition of CD markedly increased the solubility of DDP in water, and A$\sub$L/ type phase solubility diagrams were obtained with ${\beta}$-CD, TMCD, HPCD and SBCD, where the apparent stability constants of the soluble complexes at 25$^{\circ}C$ were determined to be 1388, 216, 1054, and 1992 M$\^$-1/, respectively. However, DMCD remarkably increased the solubility of DDP, and showed an A$\sub$P/ type diagram, suggesting that DMCD forms a soluble complex of high order with DDP. The stability constant for the DDP-DMCD complex at 25$^{\circ}C$ was determined to be 19132 M$\^$-1/. The thermodynamic parameters were calculated for the inclusion complex formation in aqueous solution. CD (1${\times}$10$\^$-2/M) remarkably decreased the partition coefficients of DDP between isopropyl myristate/water in the order of TMCD < ${\beta}$-CD < HPCD < SBCD < DMCD, and in squalane/water system in the order of HPCD < TMCD < ${\beta}$-CD < DMCD < DMCD $\leq$ SBCD. This finding represents that, in a o/w type cream, cyclodextrin complexation with DDP may result in high concentration of DDP in aqueous phase. The permeation of DDP through a cellophane membrane was highly suppressed by the addition of CD, and the degree of suppression was different among CDs, indicating that CD may control the skin permeation of DDP. The dissolution rates of solid dispersions with CDs were much faster than those of drugs alone and corresponding physical mixtures. All DDP-CD solid dispersions exceeded the equilibrium solubility. Consequently these results suggest that complex formation of DDP with CDs may provide useful means to markedly enhance the solubility, and CDs are useful in the semi-solid preparations such as creams and gels for topical application.

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A PHOTOMETRIC STUDY OF FIVE OPEN CLUSTERS IN THE SDSS

  • Ryu, Jin-Hyuk;Lee, Myung-Gyoon
    • Journal of The Korean Astronomical Society
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    • v.44 no.5
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    • pp.177-193
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    • 2011
  • We present a photometric study of five open clusters (Czernik 5, Alessi 53, Berkeley 49, Berkeley 84, and Pfleiderer 3) in the Sloan Digital Sky Survey. The position and size of these clusters are determined using the radial number density profiles of the stars, and the member stars of the clusters are selected using the proper motion data in the literature. We estimate the reddening, distance and age of the clusters based on the isochrone fitting in the color-magnitude diagram. The foreground reddenings for these clusters are estimated to be E(B - V ) = 0.71 - 1.55 mag. The distances to these clusters are derived to be 2.0 - 4.4 kpc, and their distances from the Galactic center range from 7.57 kpc to 12.35 kpc. Their ages are in the range from 250 Myr to 1 Gyr. Berkeley 49 and Berkeley 84 are located in the Orion spur, Czernik 5 is in the Perseus arm, and Pfleiderer 3 and Alessi 53 are located beyond the Perseus arm.

A STUDY ON THE EVOLUTION OF GLOBULAR CLUSTERS

  • Lee, See-Woo
    • Journal of The Korean Astronomical Society
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    • v.11 no.1
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    • pp.1-30
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    • 1978
  • The four dimensional classification of globular dusters with the parameters, Z, Y, age and HB type is presented defining two new parameters. $(B-V)_{1/2}\;and\;S_{3/2}$ which are shown to be tightly correlated with Kinman's spectral types and the helium abundances obtained from the R-method, respectively. The Z- and Y- abundances are derived from $(B-V)_{1/2}\;and\;S_{3/2}$, respectively, and the latter parameters determine the age class of clusters with help of Dickens' HB type, which is a function of Z. Y and age. For the examined forty two globular clusters the computed range at Z and Y are $1.5{\times}10^{-4}{\leq}Z{\leq}4.5{\times}10^{-2}\;and\;0.23<Y{\leq}0.41$. The age difference between the oldest (HB type 1) and the youngest (HB type 7) clusters is roughly estimated to be $2-4{\times}10^9$ years. Using these four parameters the known anomalous C-M diagrams seem to be reasonably interpreted without taking into account some complicate parameters such as unusually overabundant heavy elements, mass loss and mass spread, etc. The four dimensional scheme strongly suggests the slow successive collapses of the proto-Galaxy rather than a single fast collapse, and by this slow collapse model the inversion of chemical abundance gradient in the Galaxy can be explained. It is also shown that the clump position along the RGB near the HB level removes down to the fainter magnitude as the Z(Y)- abundance increases (decreases).

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A Propeller Design Method with New Blade Sections (새로운 단면을 이용한 고효율 프로펠러 설계법)

  • J.T.,Lee;C.S.,Lee;M.C.,Kim;J.Y.,Ahn;H.C.,Kim
    • Bulletin of the Society of Naval Architects of Korea
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    • v.26 no.3
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    • pp.29-40
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    • 1989
  • A new blade section of propeller is developed to obtain higher propeller efficiency and better cavitation performance. Eleven foil sections are carefully designed and manufactured to compare the lift-drag characteristics and cavitation performances. It is expected that the developed section behaves better in the vicinity of the ship's wake, where the angle of attack variation is large, because of its wider width in lift-drag and cavitation-free bucket diagrams. A propeller design method using the selected foil section is presented. Three chordwise loading shapes are selected to investigate the influence of the lift-drag ratios on the propeller efficiencies and cavitation performances. Three propellers are designed, which correspond to the selected chordwise loading shapes. Two more propellers which use existing foil sections are designed to compare the section performance.

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