• Title/Summary/Keyword: C-C Coupling

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Influence of a silane coupling agent on the optoelectrical properties of carbon nanotube/binder hybrid thin films

  • Han, Joong-Tark;Woo, Jong-Seok;Jeong, Hee-Jin;Jeong, Seung-Yol;Lee, Geon-Woong
    • Carbon letters
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    • v.12 no.2
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    • pp.90-94
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    • 2011
  • We present the effect of a coupling agent on the optoelectrical properties of few-walled carbon nanotube (FWCNT)/epoxy resin hybrid films fabricated on glass substrates. The FWCNT/epoxy resin mixture solution was successfully prepared by the direct mixing of a $HNO_3$-treated FWCNT solution and epoxy resin. FWCNT/binder hybrid films containing different amounts of the coupling agent were then fabricated on UV-ozone-treated glass substrates. To determine the critical binder content ($X_c$), the effects of varying the binder content in the FWCNT/silane hybrid films on their optoelectrical properties were investigated. In this system, the $X_c$ value was approximately 75 wt%. It was found that above $X_c$, the coupling agent effectively decreased the sheet resistance of the films. From microscopy images, it was observed that by adding the coupling agent, more uniform FWCNT/binder films were formed.

Coupling Measures for Classes in Object-Oriented System (객체 지향 시스템에서의 클래스 결합도 척도)

  • 이종석;천은홍
    • Journal of Korea Society of Industrial Information Systems
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    • v.6 no.4
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    • pp.22-29
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    • 2001
  • As the importance of software measurement increases, there are more researches developing the new software measure. Given the importance of object-oriented development techniques, one specific area where this has occurred is coupling measurement in object-oriented systems. This thesis presents the coupling measure COM based on the methods and OOC based on the classes in measuring the coupling of object-oriented systems. And, it evaluates them using the coupling properties suggested by Briand while it compares them with other coupling measures by applying them to a system developed in the language of C++programming language.

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Palladium-Catalyzed Coupling between Quinolone Moieties and Heteroacyl Stannes - Synthesis of C-7 Heteroacyl Quinolone Derivatives

  • 함원훈;양재권;임태균
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1994.04a
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    • pp.221-221
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    • 1994
  • The cross-coupling reaction of organo tin reagents with a variety of organic halides, catalyzed by palladium, provides a novel method for generating a carbon-carbon bond. We use this method for antibacterial agents, and synthesis of new quinolone derivatives which have carbon-carbon bond at C-7 position of general quinolone moieties. Aryl tin, quinolone moieties, and palladium catalyst were refluxed in DMF to afford new quinolone derivatives. This palladium catalyzed coupling reactions have capacity for further synthetic elaboration.

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The Effects of AC Corrosion on Underground Gas Pipeline Running Parallel with High Power Cables (전력케이블과 가스배관의 병행구간에 대한 교류부식 영향)

  • 배정효;김대경;김기준
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.10
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    • pp.577-582
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    • 2000
  • This paper analyze the interference problems, especially Ac corrosion when the gas pipeline is buried with power cable in the same submarine tunnel. This paper present the results of the study about interference mechanism(inductive coupling, conductive coupling, resistive coupling), AC corrosion, limitation of safety voltage, modeling of power cables, gas pipeline and grounding systems, analysis of induction voltage and optimal arrangement of power cables.

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Preparation of Graphene Based PdOx and CuOx/MnOx Nanocomposites and Their Catalytic Applications in C-C Coupling and CH3SH Decomposition Reactions

  • Lee, Gyeong-Hun;Park, Jun-Beom
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.175.2-175.2
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    • 2014
  • Graphene (G) has been modified with palladium, copper, and manganese oxide nanoparticles (NPs), and their catalytic applications have been studied in C-C coupling reactions and methylmercaptan (CH3SH) decomposition reactions. In this research, graphite oxide (GO) sheets were exfoliated and oxidized from graphite powder and impregnated with metal precursors including Pd2+, Cu2+, and Mn2+. The thermal treatments of the metal impregnated GO in preferred gas environments produced Pd NPs on graphene (Pd/G), PdO NPs on GO (PdO/GO), and CuOx and MnOx NPs on graphene (CuOx/MnOx/G). In case of Pd/G and PdO/GO, the TEM images show that, although the mean size of the Pd NPs changed significantly before and after the C-C coupling reaction, that of the PdO NPs didn't, implying that the PdO/GO was superior to Pd/G in terms of the recyclability. Also, we demonstrate that the CuOx/MnOx/G exerts the excellent catalytic efficiency in CH3SH decomposition reaction comparing with conventional catalysts. The chemical and electronic structural changes were investigated using XRD and XPS.

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Piezoelectric Characteristics of PZT-PSN Ceramics Depending on WO3Addition (PZT-PSN 세라믹스의 WO3의 첨가량에 따른 압전 특성)

  • 배숙희;김성곤;김철수;이경화;이상렬
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.9
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    • pp.794-797
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    • 2002
  • Piezoelectric properties of PZT-PSN ceramics were investigated as a function of WO$_3$ addition from 0 wt% to 6.0 wt%. The dielectric and piezoelectric characteristics of PZT-PSN ceramics have been investigated at different calcination (80$0^{\circ}C$~90$0^{\circ}C$) and sintering (110$0^{\circ}C$~130$0^{\circ}C$) temperatures. The grain size was increased with the addition of WO$_3$and the sintering temperatures. Anisotropic properties of electromechanical coupling coefficient and piezoelectric coefficient are proven to be dependent on processing temperatures and amount of addition. At the specimen with 0.6 wt% WO$_3$ addition, using calcination temperature of 80$0^{\circ}C$ and sintering temperature of 110$0^{\circ}C$ , mechanical quality factor(Q$_{m}$) and electromechanical coupling coefficient(k$_{p}$) showed the excellent results of 1560 and 0.48, respectively Experimental results indicated that the PZT-PSN system ceramics with WO$_3$impurity could be effectively used for the microtransformer and actuator applications, etc.etc.

Deuterium NMR Studies of $({\mu}_3-C^2H)[Co(CO)_3]_3$

  • Woo, Ae-Ja;Maria I. Altbach;Leslie G. Butler
    • Journal of the Korean Magnetic Resonance Society
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    • v.1 no.2
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    • pp.95-102
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    • 1997
  • Deuterium quadrupole coupling constant (e2qzzQ/h) of ($\mu$3-C2H)[Co(CO)3]3 was determined by using solid-state deuterium MAS NMR spectroscopy. The small quadrupole coupling constant of bridging methyne unit relative to sp-acethylene in propyne is discussed in terms of the C-H bond length and the negative charge on the carbon.

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Influence of Silane Coupling Agent on Retraction Behaviors of NR Vulcanizates Reinforced with Carbon Black and Clay (실란 커플링제가 카본블랙과 점토로 보강된 천연 고무 가황물의 회복 특성에 미치는 영향)

  • Choi, Sung-Seen;Park, Byung-Ho;Kim, Wan-Soo;Kim, Wan-Doo
    • Elastomers and Composites
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    • v.40 no.2
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    • pp.112-118
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    • 2005
  • Influence of a silane coupling agent on the reatraction behaviors of NR vulcanizates reinforced with carbon black and c lay was studied. Bis-(3-(triethoxysilyl)-propyl )-tetrasulfide (TESPT) was used as a silane coupling agent. The vulcanizates containing the silane coupling agent were, on the whole, recovered faster than those without the silane coupling agent. However, for the vulcanizate with the higher clay content at low temperature region (below $-12^{\circ}C$), the vulcanizate containing the silane coupling agent was recovered slower than that without the silane coupling agent. The recovery difference of the vulcanizates with and without silane coupling agent decreased with increase of clay content. The experimental results were explained with crosslink density, modulus, and bound rubber content.

Mechanistic Study of Half-titanocene-based Reductive Pinacol Coupling Reaction

  • Kim, Young-Jo;Do, Young-Kyu;Park, Sung-Jin
    • Bulletin of the Korean Chemical Society
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    • v.32 no.11
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    • pp.3973-3978
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    • 2011
  • The reductive pinacol coupling reaction of aldehydes or ketones creating a new C-C bond has been a major tool to produce 1,2-diol compounds. The reaction mechanism is known to be composed of sequential three steps (activation, coupling, and dissociation). In this work, we studied the dissociation step of half-titanocene-based catalytic systems. Cp and $Cp^*$ derivatives of the pinacolato-bridged dinuclear complex were synthesized and evaluated as possible models for intermediates from the coupling step. We monitored $^1H$-NMR spectra of the reaction between the metalla-pinacol intermediates and $D_2O$. New reaction routes of the dissociation step including oxo- and pinacolato-dibridged dinuclear complexes and oxo-bridged multinuclear complexes have been suggested.

Experimental Studies on the Performance of the Active Phased-Array. Antenna Coupled by Transmission Line (전송선로로 결합된 능동 위상차배열 안테나의 동작특성에 관한 실험적 연구)

  • 최영규
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.3
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    • pp.175-181
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    • 2004
  • In order to increase the coupling efficiency of the Power and Phase of the active Phase way antenna, we have fabricated the active phased-array antenna which is coupled by the transmission line, and investigated the relationship between the length of the coupling transmission line and coupling power and phase. The following three types of driving method -(1) giving the frequency difference between the two active antenna, (2) applying the input signal to the one side of the two antennas, and changing the eigen frequency of the other side antenna, (3) appling the different phase inputs to the active antennas was investigated. The experimental results showed that the interval of the antenna elements has not affected the power and the phase of the antenna.