• Title/Summary/Keyword: C-유기화합물

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A Study on the Characteristic Trace Organic Pollutants in the Industrial Wastewater (산업폐수중 미량유기오염물질 배출 특성)

  • Chung, Y.H.;Kim, S.C.;Shin, S.K.;Kang, I.G.;Lee, J.I.;Lee, W.S.;Lee, J.B.
    • Analytical Science and Technology
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    • v.11 no.1
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    • pp.62-72
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    • 1998
  • This study was performed to characterize the trace organic pollutants in the industrial wastewater and to establish the database of the trace organic pollutants. The four manufacturing industries, which are refined petroleum, industrial chemicals, rubber & plastics and fabricated metals, were surveyed. The wastewater and discharging water of these 30 factories are analyzed to characterize the trace organic pollutants. In industrial chemicals, the kinds of products and organic pollutants are very various. Therefore to select the characteristic organic pollutants in this categories are also very difficult. In industrial chemicals, the gas chromatograpic peak patterns of wastewater are represented the various type according to their products, therefore the typical patterns of the characteristic organic pollutants could not be obtained because the kinds of manufactured goods and organic pollutants are very various. In refined petroleum, the effluent is discharged in the distillatory process of atmosphere pressure and contained the saturated hydrocarbons, phenol compounds, benzene compounds and naphtalene compounds. The saturated hydrocarbons peaks from $C_{15}$ to $C_{35}$ are represented the typical oil patterns by the uniform intervals therefore the peak can be easily distinguished. In rubber & plastics, the wastewater is discharged in the washing process which contains the additives. The problem of wastewater is not serious because the manufacturing process is not produced the effluent or the produced cooling water is recycled in that process.

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A Study of Platform for Management and Real-Time Service of Distributed Objects (분산 객체들의 관리와 실시간 서비스를 위한 플랫폼의 연구)

  • Kim, Myung-Hee;Joo, Su-Chong
    • Proceedings of the Korea Information Processing Society Conference
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    • 2001.10a
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    • pp.297-300
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    • 2001
  • 최근의 컴퓨팅 환경은 이질적인 클라이언트와 서버들간의 상호 운용성을 요구하는 분산 어플리케이션을 위한 프로그래밍 파라다임을 지원하기 위한 분산 객체 컴퓨팅 환경으로 발전되고 있다. 여기에는 복잡한 네트워킹과 다양한 멀티미디어 응용 서비스를 위한 객체지향 기술들이 접목되고 있다. 이러한 분산 컴퓨팅 환경에서 처리되는 어플리케이션들의 실시간 서비스 지원을 위해 요구되는 실시간 특성과 분산 객체들의 관리의 어려움을 해결하기 위하여 본 논문에서는 실시간 객체그룹 플랫폼을 구축한다. 기존의 연구들은 실시간 CORBA를 사용하거나 또는 ORB를 수정하거나 실시간 운영체제상에 특정 CORBA 제품군을 사용하여 분산 환경의 특정 영역의 성능향상만을 도모하고 있다. 그러므로, 본 논문은 ORB의 수정 없이 표준 CORBA상에서 실시간 특성을 지원한 수 있는 실시간 객체그룹 플랫폼을 설계한다. 본 논문의 실시간 객체그룹 구조는 객체들의 관리적인 측면과 실시간 어플리케이션 서비스 지원 측면에 대한 요구사항들을 분석하여 정립한 모델이며, 구성요소들의 기능을 관리와 서비스로 분리하여 각각의 기능수행시에 발생하는 객체간의 상호작용이 다른 기능에 영향을 미치지 않도록 한다. 또한, 구축된 플랫폼은 실시간 어플리케이션 개발자에게 실시간 특성 파라미터의 표현과 처리에 대한 투명성을 부여하여 어플리케이션에 유연성과 확장성을 제공하기가 용이하도록 한다. 따라서, 본 논문은 실시간 객체그룹 플랫폼의 구성요소들에 대한 역할을 정의하고 기능을 정립하며, 각 구성요소들을 설계하고 구현하였으며, 구현되어진 실시간 객체그룹 플랫폼의 기능과 수행 성능을 검증한다.가지 유기화합물 중에서는 35.6%를 차지하였다. BTEX 각각 개별물질은 미국 환경보호청이 제시하는 일일 노출 기준량(Reference Concentration; RfC) 보다는 현저히 낮았다. 총 휘발성 유기화합물읜 농도는 실내가 실외 보다 높았다(I/O ratio 2.5). BTEX의 상대적 함량도 실내가 실외보다 높아 실내에도 발생원이 있음을 암시하고 있다. 자료 분석결과 유치원 실내의 벤젠은 실외로부터 유입되고 있었고, 톨루엔, 에틸벤젠, 크실렌은 실외뿐 아니라 실내에서도 발생하고 있었다. 정량한 8개 화합물 각각과 총 휘발성 유기화합물의 스피어만 상관계수는 벤젠을 제외하고는 모두 유의하였다. 이중 톨루엔과 크실렌은 총 휘발성 유기화합물과 좋은 상관성 (톨루엔 0.76, 크실렌, 0.87)을 나타내었다. 이 연구는 톨루엔과 크실렌이 총 휘발성 유기화합물의 좋은 지표를 사용될 있고, 톨루엔, 에틸벤젠, 크실렌 등 많은 휘발성 유기화합물의 발생원은 실외뿐 아니라 실내에도 있음을 나타내고 있다.>10)의 $[^{18}F]F_2$를 얻었다. 결론: $^{18}O(p,n)^{18}F$ 핵반응을 이용하여 친전자성 방사성동위원소 $[^{18}F]F_2$를 생산하였다. 표적 챔버는 알루미늄으로 제작하였으며 본 연구에서 연구된 $[^{18}F]F_2$가스는 친핵성 치환반응으로 방사성동위원소를 도입하기 어려운 다양한 방사성의 약품개발에 유용하게 이용될 수 있을 것이다.었으나 움직임 보정 후 영상을 이용하여 비교한 경우, 결합능 변화가 선조체 영역에서 국한되어 나타

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Development of a Volatile organic Compounds(VoCs) Liquefier on Integrated Management System based on ICT (ICT 기반의 휘발성 유기 화합물(VoC) 액화기 통합관리시스템 개발)

  • Kim, Gwan-Hyung
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.6
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    • pp.1301-1306
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    • 2015
  • This paper is to automate the intelligent and equipment to recycle the volatile organic compounds in various a gas stations and a laundry, in real life. In addition, based the ZigBee module and TCP/IP communications on ICT technologies, it's propose an integrated management system to monitor and manage an liquid at a remote location.Furthermore, it's propose a service model that can be freely managed from a remote location based on the app on android. In this paper, we present a communication protocol of the bridge modules and a liquefier of intelligent control system based ZigBee and MCU(Micro Controller Unit). Through the development of smart app based android mobile services in an integrated management system, it's represent for liquefier to a DB server for remote management(MS SQL 2012) and a web server (OS: Windows 2008).

Durability Characteristics of Concrete with Nano Level Ceramic Based Coating (나노합성 세라믹계 도장재를 도포한 콘크리트의 내구성능)

  • Kim, Seong-Soo;Lee, Jeong-Bae;Han, Seung-Woo
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.639-646
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    • 2007
  • This study performed several tests for the durability of the concrete coated with nano synthesis ceramics which do not contain volatile organic compounds harmful to environment. The tests were adhesion test on dry and humid concrete, SEM test, MIP analysis, carbonation, chloride diffusion by electronic facilitation, freezing-thawing resistance, alkaline resistance, and brine resistance test. In the adhesion test on dry and humid concrete, nano synthesis ceramics coating produced the highest results among all the coatings tested. Nano synthesis ceramics adhered solidly on the concrete surface. The adhesive strength seemed to result from the hydrogen bond between nano synthesis ceramics which are inorganic and generated by hydrolysis and re-condensation reaction and the concrete's hydrates such as calcium silicate aluminate or calcium silicate hydrate. SEM test and MIP analysis results show surface structure with finest crevices pore in the nano synthesis ceramics coating applied concretes. In the carbonation, chloride diffusion, and freezing-thawing resistance tests, the concretes with nano synthesis ceramics coating indicated the best results. Based on these test results, further progress in application of nano synthesis ceramics coatings to various concrete structures including costal structures and sewerage arrangements can be expected.

Changes of Organic Acids and Volatile Flavor Compounds in Kimchis Fermented with Different Ingredients (재료의 종류에 따른 김치의 유기산 및 휘발성 향미 성분의 변화)

  • Ryu, Jai-Yeon;Lee, Hye-Seong;Rhee, Hei-Soo
    • Korean Journal of Food Science and Technology
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    • v.16 no.2
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    • pp.169-174
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    • 1984
  • The changes of the content of organic acids, carbon dioxide, alcohols and carbonyl compounds of the various Kimchis which were made of cabbage with green onion, garlic, ginger or red pepper and fermented at $12^{\circ}C-16^{\circ}C$ were investigated. Nonvolatile organic acids identified were lactic, succinic, fumaric and malic acid. Volatile organic acids identified were acetic, formic, propionic, butyric, valeric, n-caproic and n-heptanoic acid. Carbonyl compounds identified were acetaldehyde and acetone. The content of lactic acid was increased with fermentation, and higher in Kimchis containing red pepper, garlic and green onion. The content of acetic acid was increased with fermentation, especially in Kimchi containing garlic. The content of carbon dioxide was higher in Kimchi containing garlic. Alcohols identified in all Kimchis was only ethanol. Carbonyl compounds had no direct effect on off-flavor of Kimchi.

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전해질로의 이온성 액체 응용

  • 김동범;원종옥;김훈식
    • Polymer Science and Technology
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    • v.15 no.4
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    • pp.449-456
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    • 2004
  • 이온성 액체 (ionic liquid)는 유기 양이온과 유기 (또는 무기) 음이온으로 이루어진 화합물이다. 이온들이 작아, 서로 가깝게 packing되어 있는 일반 이온성 염 (상온에서 고체상)과는 다르게, 이온성 액체는 양이온과 음이온의 크기가 상대적으로 커서, packing이 잘 되지 않아 낮은 lattice energy를 갖고 있게 되어,$^1$ 10$0^{\circ}C$나 그 이하의 낮은 녹는점을 갖는 염이다. 녹는점, 밀도, 점도, 친수성 및 소수성 특성은 주어진 이온성 액체의 양이온과 음이온을 적절히 선택하면 얼마든지 조절할 수 있어, 이온성 액체를 des구nor solvent로 부르고 있다.(중략)

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염소투입후 방치조건에 따른 유기할로겐 화합물의 발생특성

  • 윤도현;이용두
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2001.11a
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    • pp.87-89
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    • 2001
  • 온도조건에 따른 염소투입량과 염소투입 후 방치조건에 따른 유기할로겐화합물의 발생특성에 대해 검토하였다. 원수의 수질특성에 있어서 암모니아성 질소와 TOC의 농도가 높을수록 TOXs의 발생량은 높았고, 온도조건에 따른 TOXs의 발생량은 그다지 큰 차이는 없는 반면 염소투입량에 따른 실험에서는 큰 차이를 보였다. 방치조건에 따른 TOXs의 발생량은 실외에서 방치했을 경우 조금 높게 나타났다. 따라서 10~$30^{\circ}C$의 온도조건보다는 유기물의 농도와 염소투입량과 TOXs의 발생량과의 관계가 밀접하고, 실외방치시 시료수의 잔류염소와 외부로부터의 유기물등의 유입으로 인한 반응으로 인해 TOXs 발생량이 높아졌다고 추정되나 추후 면밀한 검토가 요구된다.

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Kinetic Study on the Oxidation Reaction of Alcohols by Cr(VI)-Quinoline Compound (크롬(VI)-퀴놀린 화합물에 의한 알코올류의 산화반응에 대한 반응속도론적 연구)

  • Park, Young-Cho;Kim, Soo-Jong
    • Journal of Convergence for Information Technology
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    • v.11 no.9
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    • pp.109-114
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    • 2021
  • Cr(VI)-quinoline compound[(C9H7NH)2Cr2O7] was synthesized by the reaction between of quinoline and chromium(VI) trioxide, and structure was FT-IR, elemental analysis. The oxidation ability of benzyl alcohol greatly depends upon the dielectric constant of the used organic solvent, where carbon tetrachloride was worst and N,N'-dimethylformamide was best solvent. Noticeably, in N,N'-dimethylformamide solvent, Cr(VI)-quinoline compound oxidized substituted benzyl alcohols. The Hammett reaction constant(ρ)=-0.69(303K). As a resuit, Cr(VI)-quinoline compound was found as efficicent oxidizing agent that converted benzyl alcohol, allyl alcohol, primary alcohol and secondary alcohols to the corresponding aldehydes or ketones. Cr(VI)-quinoline compound was selective oxidizing agent of benzyl alcohol, allyl alcohol and primary alcohol in the presence of secondary alcohol ones.

Reactions of Organostannyl Compounds with Unsaturated Compounds (유기주석화합물과 불포화화합물과의 반응)

  • Il-Kyu Lee;Bae-Seok Seo;Ghap-Ju Kim
    • Journal of the Korean Chemical Society
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    • v.24 no.5
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    • pp.393-397
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    • 1980
  • Trimethylstannyl-diethylamine, trimethylstannylethylsulfide, trimethylstannylmethoxide and trimethylstannylhydroxide were reacted with phenylisocyanate at various temperatures. The product was only triphenylisocyanurate below $100^{\circ}C$ and the mixtures of triphenylisocyanurate and diphenylcarbodiimide were obtained at $150^{\circ}C$. Whereas, in the reaction of trimethylstannyldiethylamine with chloral, N,N-diethylformamide and trimethylstannyltrichloromethide were produced. The products from the reaction of N-ethylhexamethyldistannazane with phenylisothiocyanate were bis(trimethylstannyl) sulfide and N-ethyl-N'-phenylcarbodiimide.

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High $T_c$ Superconductors $LnBa_2Cu_3O_{7-\delta}$ from 2-Ethylhexanoate Precursors (2-Ethylhexanoate 화합물에서 제조한 고온초전도체 $LnBa_2Cu_3O_{7-\delta}$)

  • Jung Ohk Kweon;Soon Bok Hong;Sung Uhk Lee;Jung Sik Oh;Won Yang Chung
    • Journal of the Korean Chemical Society
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    • v.36 no.6
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    • pp.818-823
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    • 1992
  • 2-Ethylhexanoate compounds which contained Y, Er, Yb, Ba, and Cu were prepared separately. These metallo-organic compounds were dissolved together in the common solvent and the solution was homogeneous. From these solution, high $T_c$ superconductors $YBa_2Cu_3O_{7-\delta}(Y_{123})$, $ErBa_2Cu_3O_{7-\delta}(Er_{123})$, and $YbBa_2Cu_3O_{7-\delta}(Yb_{123})$ were prepared. XRD analysis showed that these superconductors were not single phase and contained some impurity phases including $YBa_2Cu_4O_8(Y_{124})$. This was also confirmed from the magnetic susceptibility measurement. Generally, critical temperatures were higher than that of the superconductors prepared by ceramic method. Volume diamagnetic susceptibility showed little variation compared to the specimen made by ceramic method.

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